KR100876834B1 - Method for manufacturing semiconductor device - Google Patents

Method for manufacturing semiconductor device Download PDF

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Publication number
KR100876834B1
KR100876834B1 KR1020070066741A KR20070066741A KR100876834B1 KR 100876834 B1 KR100876834 B1 KR 100876834B1 KR 1020070066741 A KR1020070066741 A KR 1020070066741A KR 20070066741 A KR20070066741 A KR 20070066741A KR 100876834 B1 KR100876834 B1 KR 100876834B1
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KR
South Korea
Prior art keywords
gate
layer
forming
hard mask
spacer
Prior art date
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KR1020070066741A
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Korean (ko)
Inventor
김나현
Original Assignee
주식회사 하이닉스반도체
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Priority to KR1020070066741A priority Critical patent/KR100876834B1/en
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Publication of KR100876834B1 publication Critical patent/KR100876834B1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/43Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/49Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
    • H01L29/4916Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a silicon layer, e.g. polysilicon doped with boron, phosphorus or nitrogen
    • H01L29/4925Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a silicon layer, e.g. polysilicon doped with boron, phosphorus or nitrogen with a multiple layer structure, e.g. several silicon layers with different crystal structure or grain arrangement
    • H01L29/4941Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a silicon layer, e.g. polysilicon doped with boron, phosphorus or nitrogen with a multiple layer structure, e.g. several silicon layers with different crystal structure or grain arrangement with a barrier layer between the silicon and the metal or metal silicide upper layer, e.g. Silicide/TiN/Polysilicon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/6656Unipolar field-effect transistors with an insulated gate, i.e. MISFET using multiple spacer layers, e.g. multiple sidewall spacers

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • General Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrodes Of Semiconductors (AREA)
  • Insulated Gate Type Field-Effect Transistor (AREA)

Abstract

The present invention relates to a method of fabricating a semiconductor device, the method comprising: forming a gate insulating film, a gate polysilicon layer, a gate electrode layer, and a gate hard mask layer on an upper surface of a semiconductor substrate to prevent the gate from leaning; Forming a gate hard mask layer pattern by etching the gate hard mask layer by a photolithography process using a gate mask, forming a first spacer on sidewalls of the gate hard mask layer pattern, a gate hard mask layer pattern, and a first mask Forming a gate by etching the gate electrode layer and the gate polysilicon layer using the spacer as a mask, and forming a second spacer on the sidewall of the gate, so that stress generated during subsequent thermal processing is applied directly to the gate. It is a technology that can prevent the gate from leaking because it is not supported.

Description

Manufacturing method of semiconductor device {METHOD FOR MANUFACTURING SEMICONDUCTOR DEVICE}

1 is a cross-sectional view showing a method for manufacturing a semiconductor device according to the prior art.

2A to 2F are cross-sectional views illustrating a method of manufacturing a semiconductor device in accordance with the present invention.

<Description of the symbols for the main parts of the drawings>

            100 semiconductor substrate 102 gate insulating film

            104: gate polysilicon layer

            104a: gate polysilicon layer pattern

            106: diffusion barrier 106a: diffusion barrier pattern

            108: gate electrode layer 108a: gate electrode layer pattern

            110: gate hard mask layer

            110a: gate hard mask layer pattern

            112: oxide film for first spacer 112a: first spacer

            114: capping insulating film 114a: second spacer

            116 gate 118 oxide film

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a semiconductor device, and more particularly, to a method for forming a gate of a semiconductor device.

As is well known, the gates of semiconductor devices have usually been formed of polysilicon. This is because the polysilicon sufficiently satisfies the physical properties required as a gate such as high melting point, ease of thin film formation, ease of line pattern, stability to an oxidizing atmosphere, and flat surface formation.

In addition, in actual semiconductor devices, the polysilicon gate contains a dopant such as phosphorus (P), arsenic (As), and boron (B) to realize low resistance.

However, as the degree of integration of semiconductor devices increases, variable values such as the line width of the gate, the thickness of the gate insulating layer, the junction depth, and the like decrease, thereby limiting the polysilicon to realize the low resistance required on the fine line width.

Accordingly, various studies on materials for gate electrodes applicable to highly integrated devices have been conducted. As one of them, a gate electrode having a laminated structure of polysilicon and tungsten has been proposed.

1 is a cross-sectional view showing a method of manufacturing a semiconductor device according to the prior art.

Referring to FIG. 1, a gate insulating layer 12, a gate polysilicon layer 14, a diffusion barrier layer 16, a gate electrode layer 18, and a gate hard mask layer 20 are formed on a semiconductor substrate 10.

In this case, the gate insulating film 12 is formed of an oxide film, and the diffusion barrier 16 is formed of a tungsten silicide (Wsix) film.

The gate electrode layer 18 is formed of a tungsten (W) film, and the gate hard mask layer 20 is formed of a nitride film.

Next, the gate hard mask layer 20, the gate electrode layer 18, the diffusion barrier 16, and the gate polysilicon layer 14 having a predetermined depth may be formed by a photolithography process using a mask defining a gate pattern. Etch it.

Next, a capping insulating film 22 is formed over the entire surface.

In this case, since the capping insulating film 22 is formed at a high temperature of 710 ° C. or higher, the capping insulating film 22 is constricted by the densification of the film quality of the gate hard mask layer 20 by the thermal process. ) To stress.

In particular, when the exposed gate polysilicon layer 14 is not etched with the same thickness on the left and right sides, a thickness difference d1 occurs between the left and the right sides.

That is, when the right side is formed thicker than the left side, since the contact area of the capping insulating layer 22 is as large as the portion (A) on the left side, as shown in FIG. ), The force F1 applied to the left side of the gate is greater than the force F2 applied to the right side.

Therefore, the gate is leaned due to the difference between the forces (F1-F2) applied to the left and the right.

As a result, when forming the subsequent storage electrode contact plug, there is a problem of lowering yield by causing a self alignment contact (SAC) defect between the gate and the storage electrode contact plug.

SUMMARY OF THE INVENTION An object of the present invention is to provide a method for manufacturing a semiconductor device capable of preventing the gate from leaking.

Method for manufacturing a semiconductor device according to the invention,

Forming a gate insulating film, a gate polysilicon layer, a gate electrode layer, and a gate hard mask layer on the semiconductor substrate;

Forming a gate hard mask layer pattern by etching the gate hard mask layer by a photolithography process using a gate mask;

Forming a first spacer on sidewalls of the gate hard mask layer pattern;

Etching the gate electrode layer and the gate polysilicon layer using the gate hard mask layer pattern and the first spacer as a mask to form a gate; And

Forming a second spacer on the gate sidewall

Characterized in that it comprises a.

In the present invention, further comprising forming a diffusion barrier layer between the gate polysilicon layer and the gate electrode layer,

The gate hard mask layer pattern forming step may be performed by remaining 5 to 20% of the thickness of the gate electrode layer in a region other than the gate region;

The first spacer forming step

Forming an oxide film over the entire surface,

Performing an entire surface etching process on the oxide film;

The oxide film is formed to a thickness of 10 ~ 1000Å,

The second spacer forming step

Forming a capping insulation layer over the entire surface;

Performing an entire surface etching process on the capping insulation layer;

Performing a selective gate reoxidation process to form an oxide film on sidewalls of the gate polysilicon layer

It characterized in that it further comprises.

Hereinafter, with reference to the accompanying drawings will be described in detail an embodiment of the present invention.

2A through 2F are cross-sectional views illustrating a method of manufacturing a semiconductor device in accordance with the present invention.

Referring to FIG. 2A, a gate insulating layer 102, a gate polysilicon layer 104, a diffusion barrier layer 106, a gate electrode layer 108, and a gate hard mask layer 110 are formed on the semiconductor substrate 100.

In this case, the gate insulating layer 102 is formed of an oxide film, and the diffusion barrier layer 106 is formed of a tungsten silicide (WSix) film.

The gate electrode layer 108 is formed of a tungsten (W) layer, and the gate hard mask layer 110 is formed of a nitride film.

Referring to FIG. 2B, a photosensitive film is formed on the gate hard mask layer 110.

Then, the photoresist film is exposed and developed with an exposure mask defining a gate pattern to form a photoresist pattern.

Next, the gate hard mask layer 110 is etched using the photoresist pattern as a mask to form a gate hard mask layer pattern 110a.

In this case, during the etching process of the gate hard mask layer 110, the etching target is preferably etched so as to remain on the surface of the gate electrode layer 108.

This is to prevent the gate electrode layer 108 from oxidizing in a subsequent oxide film forming process, and is preferably formed to remain by 5 to 20% of the thickness of the gate electrode layer 108.

Then, the photoresist pattern is removed.

Referring to FIG. 2C, the oxide film 112 for the first spacer is formed on the entire surface.

At this time, the first spacer oxide film 112 is preferably formed to a thickness of 10 ~ 1000Å.

Referring to FIG. 2D, a first spacer 112a is formed on sidewalls of the gate hard mask layer pattern 110a by performing an entire surface etching process.

Next, the gate electrode layer 108, the diffusion barrier layer 106, and the gate polysilicon layer 104 having a predetermined depth are etched using the gate hard mask layer pattern 110a and the first spacer 112a as a mask. Thus, the gate electrode layer pattern 108a, the diffusion barrier layer pattern 106a, and the gate polysilicon layer pattern 104a are formed.

Referring to FIG. 2E, a capping insulating layer 114 is formed on the entire surface.

In this case, in the thermal process for forming the capping insulating layer 114, the gate hard mask layer pattern 110a is densified and the volume is reduced to generate stress.

However, since the stress is not directly applied to the capping insulating layer 114 by the first spacer 112a, the gate may be tilted.

Meanwhile, the capping insulating film 114 may be formed of a nitride film.

Referring to FIG. 2F, the capping insulating layer 114 is etched to form a second spacer 114a.

Next, the gate polysilicon layer pattern 104a is etched to form the gate 116.

Next, a selective gate re-oxidation process is performed to form an oxide film 118 on sidewalls of the gate polysilicon layer pattern 104a.

As described above, the method of manufacturing a semiconductor device according to the present invention forms a spacer on a sidewall of a gate hard mask layer pattern so that a stress generated during a subsequent thermal process is not directly applied to the gate, so that the gate is inclined. The phenomenon can be prevented.

In the method of fabricating a semiconductor device according to the present invention, a spacer may be formed on a sidewall of a gate hard mask layer pattern, thereby preventing the gate from being leaned because stress generated in a subsequent thermal process is not directly applied to the gate. This prevents SAC defects between the gate and the landing plug, thereby improving device yield.

In addition, a preferred embodiment of the present invention is for the purpose of illustration, those skilled in the art will be able to various modifications, changes, substitutions and additions through the spirit and scope of the appended claims, such modifications and changes are the following claims It should be seen as belonging to a range.

Claims (7)

Forming a gate insulating layer, a gate polysilicon layer, a gate electrode layer, and a gate hard mask layer on the semiconductor substrate; Forming a gate hard mask layer pattern by etching the gate hard mask layer by a photolithography process using a gate mask; Forming a first spacer on sidewalls of the gate hardmask layer pattern; Etching the gate electrode layer and the gate polysilicon layer using the gate hard mask layer pattern and the first spacer as a mask to form a gate; And Forming a second spacer on the gate sidewall Method of manufacturing a semiconductor device comprising a. 2. The method of claim 1, further comprising forming a diffusion barrier layer between the gate polysilicon layer and the gate electrode layer. The method of claim 1, wherein the forming of the gate hard mask layer pattern comprises forming the gate hard mask layer pattern by remaining 5 to 20% of the thickness of the gate electrode layer in a region other than the gate region. The method of claim 1, wherein the first spacer forming step Forming an oxide film over the entire surface; And Performing an entire surface etching process on the oxide layer Method of manufacturing a semiconductor device comprising a. The method of manufacturing a semiconductor device according to claim 4, wherein the oxide film is formed to a thickness of 10 to 1000 GPa. The method of claim 1, wherein the second spacer forming step Forming a capping insulation layer over the entire surface; And Performing an entire surface etching process on the capping insulating layer Method of manufacturing a semiconductor device comprising a. The method of claim 1, further comprising: forming an oxide film on sidewalls of the gate polysilicon layer by performing a selective gate reoxidation process. Method for manufacturing a semiconductor device characterized in that it further comprises
KR1020070066741A 2007-07-03 2007-07-03 Method for manufacturing semiconductor device KR100876834B1 (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050065148A (en) * 2003-12-24 2005-06-29 주식회사 하이닉스반도체 Method for forming gate spacer
KR20050110225A (en) * 2004-05-18 2005-11-23 주식회사 하이닉스반도체 Method for forming gate electrode of semiconductor device
KR20060098646A (en) * 2005-03-03 2006-09-19 삼성전자주식회사 Fabrication method of a mos transistor having a spacer
KR20070002872A (en) * 2005-06-30 2007-01-05 주식회사 하이닉스반도체 Semiconductor device with dual polysilicon gate and method for manufacturing the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050065148A (en) * 2003-12-24 2005-06-29 주식회사 하이닉스반도체 Method for forming gate spacer
KR20050110225A (en) * 2004-05-18 2005-11-23 주식회사 하이닉스반도체 Method for forming gate electrode of semiconductor device
KR20060098646A (en) * 2005-03-03 2006-09-19 삼성전자주식회사 Fabrication method of a mos transistor having a spacer
KR20070002872A (en) * 2005-06-30 2007-01-05 주식회사 하이닉스반도체 Semiconductor device with dual polysilicon gate and method for manufacturing the same

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