KR100834535B1 - Method for manufacturing high hardness and high toughness of hot-work tool steels - Google Patents

Abstract

Provided are a method for producing a hot tool steel for use as a tool or tool for a hot tool. The manufacturing method of this hot-hole oral cavity is weight%, C: 0.25-0.5%, Si: 0.2-1.5%, Mn: 0.2-1.5%, Cr: 2.5-9.5%, Ni: 2.5% or less, Mo: 0.3- After austenizing the steel billet containing 2.5% and containing one or two of W: 5.0% or less and V: 1.5% or less, other unavoidable impurities and the remaining Fe in the range of 950 to 1150 ° C. After cooling at a rate of 3 ~ 100 ℃ / min, and then tempering in the range of 180 ~ 420 ℃.

According to the present invention by securing a stable hardness to meet the target and at the same time to produce a heat treatment material having sufficient toughness, there is an effect of improving the quality of the tool and mold products manufactured by hot working steel and lower the production cost.

Hot Work Oral, High Hardness, High Toughness, Low Temperature Tempering, Chrome-based, Oxidation Resistance

Description

Method for manufacturing high hardness and high toughness of hot-work tool steels

1 is a graph showing a change in the impact energy of hot oral cavity by the conventional tempering treatment method.

2 is a graph showing the change in hardness of the hot pores by the conventional tempering treatment method.

3 is a graph showing a change in the impact energy of the hot pores by the tempering treatment method of the present invention.

4 is a graph showing the hardness change of the hot pores by the tempering treatment method of the present invention.

The present invention relates to a method for producing hot oral cavity for use as a tool or die for hot working. More particularly, the present invention relates to a method for manufacturing hot oral cavity which can impart high toughness to prevent defects such as cracking while maintaining high hardness.

Many hot work component manufacturing processes include punching, shearing or forming at high temperatures. Hot oral cavity has been developed to withstand the complex effects of heat, pressure and wear associated with these high temperature processes.

The hot pores are largely divided into chromium, tungsten, and molybdenum-based hot pores. Among them, chromium-based hot oral cavity is known to have very good softening resistance due to heat due to the addition of chromium and carbide forming elements. In general, the chromium-based hot pores maintain heat softening resistance up to about 550 ° C. In addition, the low carbon content and the total alloying element content is excellent in toughness at the general working hardness of 40 ~ 55 HRc, so it is widely used not only for tools and molds but also for hot structures.

Typically, the chromium-based hot oral cavity is tempered in the range of 500 ~ 650 ℃ after austenizing treatment. It is intended to prevent surface cracking by securing toughness through tempering treatment. However, if the tempering treatment temperature is increased based on 550 ° C., the toughness increases but hardness is not secured. If the tempering treatment temperature is lowered, the hardness is secured but the toughness is rapidly reduced. Currently, we are using empirically selecting tempering treatment temperature that can secure the toughness and hardness at an appropriate line. It is true.

The present invention is to solve the problems of the prior art, according to the present invention there is provided a method for producing hot oral cavity which can ensure high toughness and high toughness. Furthermore, there is additionally provided a method for producing hot oral cavity, which can improve oxidation resistance, which greatly affects the life of tools and mold products manufactured from hot oral cavity.

The method for producing hot oral cavity of the present invention for achieving the above object,

By weight percent, C: 0.25-0.5%, Si: 0.2-1.5%, Mn: 0.2-1.5%, Cr: 2.5-9.5%, Ni: 2.5% or less, Mo: 0.3-2.5% : 5.0% or less and V: 1.5% or less, one or two, other unavoidable impurities and the steel billet composed of the remaining Fe after austenizing in the range of 950 to 1150 ° C, and then 3 to 100 ° C / min. Cooling at a rate and then tempering in the range of 180 ~ 420 ℃.

In addition, according to the present invention, when the Cr content is in the range of 6.0 ~ 9.5%, the tempering treatment in the temperature range of 550 ~ 620 ℃ greatly improve the oxidation resistance.

In addition, it is preferable that the tool steel obtained according to the present invention is subjected to ion nitriding or gas nitriding after the tempering treatment to form a nitride layer having a thickness of 100 to 500 µm on the steel surface.

EMBODIMENT OF THE INVENTION Hereinafter, this invention is demonstrated in detail.

The inventors of the present invention, while conducting research to secure hardness and toughness at the same time in the chromium-based hot working steel, confirmed the following matters.

(1) In case of tempering at temperatures lower than 500 ~ 550 ℃, the tempering treatment temperature at which 50 HRC or more can be obtained in the general hot oral cavity, the impact energy is increased in a specific temperature range, and (2) the impact energy is increased. In this temperature range, the hardness is maintained above 50 HRc.

Based on the results of this study, the present invention is characterized by securing a high toughness with high hardness of the hot-hole oral cavity by tempering at 180-420 ° C, which is lower than the tempering treatment temperature of 500-550 ° C., which shows the high hardness of the hot-hole oral cavity. have. The hot pores to which the present invention can be applied are in weight percent, C: 0.25-0.5%, Si: 0.2-1.5%, Cr: 2.5-9.5%, Ni: 2.5% or less, Mo: 0.3-2.5%, W: 5.0% or less, Mo: 0.3-2.5%, including one or two of W: 5.0% or less and V: 1.5%, unavoidable impurities, and remaining Fe. Such composition is a common component range of hot pore.
Furthermore, according to the results of the inventors of the present invention, when the Cr content in the composition of the hot pores satisfies the range of 6.0 to 9.5% by weight, the oxidation resistance when the tempering treatment is performed at a temperature range of 550 to 620 ° C. Is to improve further. The tempering temperature as described above is sufficiently inferred from the experimental results of Table 3 below, which measured the degree of oxidation at 600 ° C. for 200 hours.

Further, according to the study of the present invention, when the Cr content in the present invention applying the low temperature tempering satisfies the range of 6.0 to 9.5% by weight, oxidation resistance is further improved. That is, when the low temperature tempering is applied while the Cr content is 6.0 to 9.5% in the component range of the above-described ordinary hot hole oral cavity, oxidation resistance is further improved along with high hardness and high toughness. The hot tool manufactured by applying low temperature tempering with Cr content of 6.0 to 9.5% is more preferable because the oxidation resistance is secured in the range of 550 to 620 ° C., which is the use temperature of the hot oral cavity.

The method for producing hot oral cavity of the present invention includes austenizing a billet having the above steel component, followed by quenching and then tempering.

The temperature range during the austenizing treatment is preferably limited to 950 ~ 1150 ℃. If the austenizing temperature is less than 950 ° C, the holding time required for transformation into a complete austenite phase becomes too long, and if it exceeds 1150 ° C, the austenite grain size may rapidly increase even in a short time. At this time, the holding time after reaching the final austenizing treatment temperature is more preferably within 1 hour to prevent excessive growth of the austenite grains. The austenitizing treatment time is determined according to the temperature conditions determined. Typically at the above austenizing temperature it is sufficient to treat at least about 30 minutes per inch of billet, but the invention is not limited thereto.

In addition, the cooling rate during the rapid cooling is preferably limited to 3 ~ 100 ℃ / min. If the cooling rate is less than 3 ℃ / min, in the case of alloys with low Cr content, there is a possibility that the unmodified austenite may remain, and if it exceeds 100 ℃ / min, there is a problem that the residual stress is severe due to excessive quenching to be.

In addition, the tempering treatment is usually carried out at 500 ~ 550 ℃, in the present invention will be carried out in a lower temperature range of 180 ~ 420 ℃. The reason is that the impact toughness of the material can be reduced if the tempering temperature is less than 180 ° C., and the impact toughness can be similarly reduced if it exceeds 420 ° C. As described above, the low temperature tempering treatment of the present invention ensures a high hardness of 50 HRc or more and at the same time obtains an impact energy of 3 to 5 times or more as compared with the conventional art. In addition, as in the case of a conventional heat treatment material, it is possible to minimize the possibility of causing serious defects due to material deviation or temperature deviation in the heat treatment furnace, and has the advantage of working stably in a wider temperature range. Tempering treatment time is about 30 minutes or more is enough. In addition, the tempering treatment time usually does not exceed 50 hours, because there is a fear that the precipitate is coarsened and the physical properties deteriorate with economical efficiency. In the present invention, the tempering time is not limited to the above conditions.

In general, the maximum maximum exposure temperature of the hot oral cavity is often 500 to 650 ° C., so the tempering treatment is performed at a temperature range of 180 to 420 ° C., so that the effect of the tempering treatment may disappear in actual work. However, the area affected by high temperature exposure during the actual work is limited to the range of 1 ~ 2mm of the surface of the tool or the mold, and the remaining area maintains the high hardness-toughness characteristics. This can further improve the life of the tool or mold.

The tempered hot ball steel as described above is molded as a tool according to a conventional method. In some cases, the formed hot tool may be surface treated to further increase surface hardness. One such example is a method of forming a nitride layer having a thickness of 100 to 500 µm on a steel surface by performing ion nitriding or gas nitriding. As described above, the hot tool in which the nitride layer is formed may further increase the surface hardness to 60 HRc or more. In the present invention, the ion nitriding or gas nitriding treatment is not particularly limited because it may be performed according to a conventional method. As an example, gas nitriding is carried out in an ammonia gas atmosphere at about 500 to 550 캜 for at least about 1 hour. In addition, an example of ion nitriding is a method of adjusting the pressure in the container to about 0.1 to 2.5 Mpa and applying a voltage of 300 to 1000 V using a material as a cathode in a mixed gas atmosphere of nitrogen and hydrogen to perform ion nitriding.

According to the present invention, oxidation resistance is further improved when the Cr content satisfies the range of 6.0 to 9.5% by weight in the component system of the hot oral cavity described above. The hot tool manufactured by applying low temperature tempering with Cr content of 6.0 to 9.5% is more preferable because the oxidation resistance is secured in the range of 550 to 620 ° C., which is the use temperature of the hot oral cavity.

Hereinafter, the present invention will be described in more detail with reference to Examples, but these Examples are only for illustrating the practice of the present invention, and the present invention is not limited by the description of these Examples.

EXAMPLE

A forging billet having a diameter of 250 mm or more having a composition as shown in Table 1 was prepared. After the forging billet was austenized in a heat treatment furnace of 950 ~ 1150 ℃ and then cooled at an average cooling rate of 4.5 ℃ / min. Then it was tempered to the tempering temperature of Table 2 below. Rockwell hardness and Charpy V-notch impact energy values of the specimens prepared as described above were measured, and the results are shown in Table 2 below. The austenizing treatment was performed for about 1 hour and the tempering treatment for approximately 2 hours.

division Ingredient (% by weight) C Si Mn Cr Ni P S Mo W V Fe River A 0.37 0.6 0.4 4.7 0.08 0.009 0.003 1.6 - 0.53 Remainder River B 0.36 0.4 0.4 9.0 0.02 0.027 0.005 1.2 1.2 0.35 Remainder Kang C 0.34 1.0 0.5 5.2 0.02 0.029 0.004 1.3 1.2 0.35 Remainder Kang D 0.39 1.0 0.4 5.4 0.01 0.018 0.003 1.2 - 0.62 Remainder Kang E 0.42 0.9 0.5 3.2 0.02 0.026 0.005 2.2 - 0.34 Remainder River F 0.40 1.0 0.3 5.3 0.01 0.027 0.005 1.3 4.9 - Remainder Steel G 0.36 0.4 0.4 6.5 0.02 0.027 0.005 1.2 1.2 0.35 Remainder

division Tempering temperature 300 ℃ 500 ℃ Impact value (J) Hardness (HRc) Impact value (J) Hardness (HRc) River A 17.2 51.4 4.4 52.6 River B 20.9 52.6 5.2 53.6 Kang C 21.3 53.5 5.2 55.6 Kang D 20.5 52.0 4.5 53.9 Kang E 14.5 56.2 2.4 56.8 River F 17.6 51.5 3.7 52.0 Steel G 21.1 52.6 5.2 54.5

division After 200 hours at 600 ℃, weight increase (g) River A 0.037 River B 0.0064 Steel G 0.011

In order to investigate the effects of the tempering treatment imparting toughness, the steels A and B are measured at a Rockwell hardness and Charpy V-notch impact energy after repeated two or more times in a temperature range of 100 to 650 ° C. It was.

1 is a graph showing a change in the impact energy of steel A at a typical tempering treatment temperature. As shown in Figure 1, it can be seen that the impact energy is rapidly increased above 550 ° C, which is a typical tempering treatment temperature. On the other hand, as shown in Figure 2 it was found that the hardness is greatly reduced.

However, the application of the tempering treatment of the present invention, as can be seen in Figures 3 and 4, as well as maintaining a high hardness, the impact energy is increased in reverse to represent 3 to 5 times the impact energy at 500 ~ 550 ℃ Able to know.

Table 2 shows Rockwell hardness values and Charpy V-notch impact energy values measured at a temperature of 500 ° C. and 300 ° C. of the tempering treatment temperature of the present invention. The results are shown. It was found that at the tempering treatment temperature of the present invention, the hardness value not only maintained a value of 50 HRc or more, but also exhibited high toughness. But. Hardness values were maintained above 50 HRc at typical tempering temperatures, but toughness values were very poor.

Table 3 shows the results of measuring the weight increase by oxidation after maintaining each test specimen at 600 ° C. for 200 hours. Test Sample B and Test Sample G are 3.5 to 6.0 times more resistant to oxidation than Test Sample A.

As described above, according to the present invention, by producing a heat treatment material having sufficient toughness while ensuring a stable hardness to meet the target, there is an effect of improving the quality of the tool and mold product manufactured by hot oral cavity and lowering the production cost.

In addition, since the hot pores obtained through the present invention also improve the oxidation resistance, there is an effect of improving the quality of the tool and the mold product manufactured by the hot pores.

Claims (4)

By weight percent, C: 0.25-0.5%, Si: 0.2-1.5%, Mn: 0.2-1.5%, Cr: 2.5-9.5%, Ni: 2.5% or less, Mo: 0.3-2.5% : 5.0% or less and V: 1.5% or less, one or two, other unavoidable impurities and the steel billet composed of the remaining Fe after austenizing in the range of 950 to 1150 ° C, and then 3 to 100 ° C / min. Method of producing a high hardness hot tough oral cavity comprising cooling at a rate and then tempering in the range of 180 ~ 420 ℃. By weight percent, C: 0.25-0.5%, Si: 0.2-1.5%, Mn: 0.2-1.5%, Cr: 6.0-9.5%, Ni: 2.5% or less, Mo: 0.3-2.5% and W : 5.0% or less and V: 1.5% or less, one or two, other unavoidable impurities and the steel billet composed of the remaining Fe after austenizing in the range of 950 to 1150 ° C, and then 3 to 100 ° C / min. Method of producing a high hardness hot tough oral cavity comprising cooling at a rate and then tempering in the range of 550 ~ 620 ℃. delete The method of claim 1, wherein after the tempering treatment, an ion nitriding or gas nitriding treatment is performed to form a nitride layer having a thickness of 100 to 500 µm on the steel surface.

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