KR100814226B1 - Shaped yarn - Google Patents
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- KR100814226B1 KR100814226B1 KR1020070000939A KR20070000939A KR100814226B1 KR 100814226 B1 KR100814226 B1 KR 100814226B1 KR 1020070000939 A KR1020070000939 A KR 1020070000939A KR 20070000939 A KR20070000939 A KR 20070000939A KR 100814226 B1 KR100814226 B1 KR 100814226B1
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
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- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Abstract
Description
도 1은 본 발명의 이형단면 합성섬유를 방사하는데 사용되는 방사구금의 단면도이다.1 is a cross-sectional view of a spinneret used to spin a cross-section synthetic fiber of the present invention.
도 2는 본 발명의 이형단면 합성섬유의 단면사진이다.Figure 2 is a cross-sectional photograph of a release cross-section synthetic fiber of the present invention.
도 3은 본 발명의 이형단면 합성섬유로 제직되고 염색된 직물의 사진이다.Figure 3 is a photograph of a woven fabric dyed with a cross-section synthetic fiber of the present invention.
※ 도면의 주요부분에 대한 부호의 설명※ Explanation of code for main part of drawing
a : 장축부길이 b : 장축부굵기a: Long shaft length b: Long shaft thickness
c : 단축부길이 A1 : 섬유단면내접면c: short section length A1: fiber cross section
A2 : 섬유단면외접면A2: fiber cross section
본 발명은 섬유단면이 2개의 대칭축을 갖는 섬유로서 특유한 채널을 가지는 흡한속건성이 우수한 이형단면 합성섬유에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a release cross-section synthetic fiber having excellent sweat absorption quick-drying property in which the fiber cross section has two unique axes of symmetry.
일반적인 합성섬유는 소수성이기 때문에 수분의 흡수와 배출이 불량하고 정전기를 많이 발생시키는 단점을 가진다. 이러한 합성섬유의 근본적인 단점을 보완하기 위하여 친수성 물질을 합성섬유에 첨가하거나 공중합하는 방법의 화학적인 방 법을 활용하거나 섬유의 단면을 중공화하거나 이형단면화하는 물리적인 방법을 활용하고 있다.Since general synthetic fibers are hydrophobic, they have disadvantages of poor absorption and discharge of moisture and generation of static electricity. In order to compensate for the fundamental disadvantages of the synthetic fibers, the chemical method of adding or copolymerizing a hydrophilic material to the synthetic fiber or using a physical method of hollowing or releasing the cross section of the fiber is used.
섬유의 이형단면화방법에서 널리 채택되는 섬유단면은 아령형, W자형, 王자형, 십자형등이 있는데, 이러한 이형단면 합성섬유의 제조에 있어서 중요한 점은 높은 이형도를 가지는 섬유를 안정적인 공정성으로 제조하는 것이 중요하다. 기존의 여러 이형단면형태의 구성은 단축부가 장축부에 비해 확연히 짧아 가연이나 연사시 단축부의 이형형태가 없어져 버려 실제적인 흡한속건성능을 발휘시키기 위한 모세관현상을 발현시킬 수 있는 채널형성이 저하되는 문제가 있었다.Fiber cross-sections widely adopted in the method of release cross-section of the fiber is a dumbbell, W-shaped, wang-shaped, cross-shaped, etc. An important point in the production of such cross-section synthetic fibers is to produce a fiber having a high degree of release with a stable processability It is important. Many existing heteromorphic cross-sectional configurations have shorter shafts than short shafts, which means that there is no deformation of short shafts during flamming or twisting, resulting in deterioration of channel formation that can result in capillary phenomena for real quick absorption and dryness. There was.
대한민국특허출원제2003-78289호에서는 4개의 타원형 돌출부를 갖는 흡한속건성 폴리아미드 섬유를 제조하는 방법을 소개하고 있으나, 이러한 2개의 대칭축만을 갖는 정사각형을 기본으로 하는 이형단면은 방사구금 제작 및 섬유제조공정중의 단면형성성의 어려움으로 인해 공정성 불량 및 물성편차 및 제조공정성 불량 등으로 이제까지 개발에 성공하지 못하였다.Korean Patent Application No. 2003-78289 introduces a method for producing a quick-absorbing quick-drying polyamide fiber having four elliptical protrusions. Deformed sections based on squares with only two axes of symmetry have not been successfully developed due to poor processability, physical property deviations and poor manufacturing processability due to difficulties in cross-section formation during spinneret manufacturing and fiber manufacturing.
그러므로 본 발명에 의하면 종래의 이형단면사가 가지는 물성불량, 작업성 불량 및 염색후 염색차발생등의 문제점을 극복한 흡한속건소재용 정사각형을 기본으로 하는 2개의 대칭축을 갖는 이형단면 합성섬유를 제공하는 것을 기술적과제로 한다.Therefore, according to the present invention, there is provided a cross-sectional synthetic fiber having two symmetric axes based on a square for a sweat-absorbing quick-drying material which overcomes problems such as poor physical properties, poor workability, and dyeing difference after dyeing according to the present invention. This is a technical task.
그러므로 본 발명에 의하면, 이형단면 합성섬유에 있어서, 섬유단면모양이 2개의 대칭축을 가지고 장축부의 길이에 대한 단축부 길이의 비가 0.9 ~ 1.0이고, 장축부의 길이에 대한 장축부굵기의 비가 0.15 ~ 0.25이고, 섬유단면의 외접원과 섬유단면의 최소내접원의 면적비가 0.02~0.10인 폴리에틸렌테레프탈레이트 또는 폴리트리메틸렌테레프탈레이트 이형단면섬유인 것을 특징으로 하는 이형단면 합성섬유가 제공된다.Therefore, according to the present invention, in the cross-sectional synthetic fibers, the fiber cross-section has two symmetry axes, and the ratio of the length of the short axis to the length of the major axis is 0.9 to 1.0, and the ratio of the length of the major axis to the length of the long axis is 0.15 to 0.25. The present invention provides a release cross-section synthetic fiber, characterized in that the polyethylene terephthalate or polytrimethylene terephthalate release cross section fiber having an area ratio of the circumscribed circle of the fiber cross section and the minimum inscribed circle of the fiber cross section is 0.02 to 0.10.
이하 본 발명을 보다 상세히 설명하기로 한다.Hereinafter, the present invention will be described in more detail.
본 발명의 이형단면 합성섬유는 그 섬유단면이 2개의 대칭축을 갖는 섬유로서 특유한 채널을 가지는 흡한속건성이 우수한 섬유이다.The release cross-section synthetic fiber of the present invention is a fiber having a fiber cross section having two axes of symmetry, and having excellent peculiarity of sweat absorption and quick drying.
흡한속건성을 향상시키기 위해서는 섬유의 이형도와 필라멘트수를 높게 하여야 하는데 이로써 수분전달 채널을 확보하여 모세관현상을 극대화 시켜 양호한 흡한속건성능을 발휘할 수 있는 것이다. 따라서 본 발명에서는 상기 필요조건을 충족하기 위해 특히 바람직한 합성섬유 필라멘트를 제공한다.In order to improve the sweat-absorbent quick-drying, the degree of release and filament of the fiber should be increased, thereby maximizing capillary phenomena by securing a water transfer channel, thereby exhibiting good sweat-absorbent quick-drying performance. The present invention therefore provides a particularly preferred synthetic fiber filament for meeting the above requirements.
본 발명의 이형단면 합성섬유는 섬유단면모양이 2개의 대칭축을 가지고 장축부의 길이에 대한 단축부 길이의 비가 0.9 ~ 1.0이고, 장축부의 길이에 대한 장축부굵기의 비가 0.15 ~ 0.25이고, 섬유단면의 외접원과 섬유단면의 최소내접원의 면적비가 0.02~0.10인 것을 특징으로 한다. 또한, 상기 이형단면 합성섬유는 장축부의 길이에 대한 단축부 길이의 비가 0.95 ~ 1.00인 것이 바람직하다.The cross-sectional synthetic fiber of the present invention has a symmetrical fiber section having two symmetrical axes, and the ratio of the length of the short axis to the length of the major axis is 0.9 to 1.0, the ratio of the length of the major axis to the length of the major axis is 0.15 to 0.25, The area ratio of the circumscribed circle and the smallest circumscribed circle of the fiber cross section is 0.02 to 0.10. In addition, the release cross-section synthetic fiber is preferably a ratio of the length of the short axis portion to the length of the long axis portion is 0.95 ~ 1.00.
상기와 같이 본 발명의 이형단면 합성섬유는 그 섬유단면이 정사각형에 내접하는 대칭축이 2개인 십자형 단면으로서 장축과 단축의 비가 거의 같은 값을 갖는다. 이에 반해 직사각형의 이형단면형태는 단축의 길이가 짧아 가연 및 연사시 단 축의 길이가 찌그러져 수분이동채널이 없어져 버려 흡한속건성이 저하되는 문제점이 있다. 또한, 육엽 및 날개수가 훨씬 많은 이형단면섬유는 방사구금을 제작하는 것이 힘들 뿐만 아니라, 제조조건이 매우 까다롭고, 물성의 편차 및 공정성이 매우 불량하여 상품으로서의 가치가 떨어지게 되는 문제점이 있다.As described above, the release cross-section synthetic fiber of the present invention is a cross-section having two axes of symmetry in which the fiber cross section is inscribed in a square, and has a ratio of the long axis and the short axis almost equal. On the other hand, the rectangular shaped cross-sectional shape of the rectangle has a problem that the length of the short axis is short and the length of the short axis is distorted during the twisting and twisting, so that the moisture transfer channel disappears and the sweat absorption quick-drying property is deteriorated. In addition, the sectional fibers having a much higher number of leaves and blades are not only difficult to manufacture spinnerets, but also have very difficult manufacturing conditions, and have very poor variation in properties and fairness, thereby degrading their value as commodities.
본 발명은 이형도가 우수한 이형단면 합성섬유를 제조하는 것으로서, 구금의 설계 단계에서부터 각 단면간의 배면압을 조절하여 이형도가 균일한 이형단면을 발현시키며 각각의 단면을 고르게 배열함으로써 우수한 흡한속건성능을 발현하는 원사의 제조가 가능한 것이 그 특징이다. The present invention is to produce a release cross-section synthetic fiber excellent in the degree of release, by controlling the back pressure between the cross-section from the design stage of the detention expresses a uniform release cross-section of uniformity and evenly arranged each cross-section expressing excellent sweat absorption quick drying performance Its feature is that the yarn can be manufactured.
본 발명의 이형단면 합성섬유를 방사하는데 사용되는 방사구금은 도 1에 도시된 바와 같은 정사각형 타입의 십자형 구금으로서 장축부길이(a), 장축부굵기(c), 단축부길이(b) 및 섬유단면의 외접원(A2)과 섬유단면의 최소내접원(A1)의 면적비가 이형단면 합성섬유의 단면조건을 만족할 수 있도록 상기 조건과 일치하는 방사구금을 사용하는 것이 바람직하다. The spinneret used to spin the release cross-section synthetic fiber of the present invention is a cross-type mold of square type as shown in Figure 1, the long axis length (a), the long axis thickness (c), the short axis length (b) and the fiber It is preferable to use a spinneret in accordance with the above conditions so that the area ratio of the circumscribed circle A2 of the cross section and the minimum inscribed circle A1 of the fiber cross section satisfies the cross-sectional condition of the hetero-cross section synthetic fiber.
본 발명의 이형단면 합성섬유는 나일론 6, 나일론 66, 폴리에틸렌테레프탈레이트 및 폴리트리메틸렌테레프탈레이트로 이루어진 군으로부터 선택되는 어느 하나인 것이 바람직한데, 특히 단면형성성이 우수한 폴리에틸렌테레프탈레이트계가 흡한속건성능이 우수하다.The release cross-section synthetic fiber of the present invention is preferably any one selected from the group consisting of nylon 6, nylon 66, polyethylene terephthalate and polytrimethylene terephthalate, especially polyethylene terephthalate system having excellent cross-sectional form sweat absorption quick drying performance great.
본 발명은 섬유간의 공극을 크게 하여 흡수성이 우수한 이형단면섬유를 직접방사 함으로써 섬유의 물성, 방사 공정성이 우수하고 도 3의 직물과 같은 염색후 염색차발생등의 문제점을 극복한 품질이 우수한 이형단면섬유를 공업적으로 생산 가능토록 하는 것이다. 따라서 방사구금을 개량하고, 방사조건을 최적화하여 균일한 이형단면원사를 제조할 수 있었다.In the present invention, by directly spinning the release cross-section fiber excellent in water absorption by increasing the voids between the fibers, excellent cross-sectional properties of the fiber excellent in physical properties, spinning processability and overcoming problems such as dyeing difference after dyeing, such as the fabric of Figure 3 It is to make the fiber industrially possible. Therefore, it was possible to produce a uniform release cross section yarn by improving the spinneret and optimizing the spinning conditions.
이하 다음의 실시예에서는 본 발명의 이형단면 합성섬유에 대한 비한정적인 예시를 하고 있다.The following examples are given as non-limiting examples of the release cross-section synthetic fiber of the present invention.
[실시예 1 내지 실시예 2 및 비교예 1 내지 비교예 2][Examples 1 to 2 and Comparative Examples 1 to 2]
고유점도 0.63의 폴리에스테르(PET) 수지를 290℃의 온도로 용융하여 하기 표 1의 조건에 맞는 36홀 구금(십자형구금)을 통해 각각 방사한 후, 토출된 사를 냉각장 1500㎜로, 0.45m/sec의 풍속으로 냉각 고화한 다음, 3,200m/min으로 권취한 후 1.68배 연신하여 50d/36f의 이형단면사를 제조하였다.After melting the polyester (PET) resin having an intrinsic viscosity of 0.63 at a temperature of 290 ° C and spinning through 36 hole molds (cross-shaped molds) meeting the conditions shown in Table 1 below, the discharged yarns were cooled to 1500 mm in a cooling cabinet, 0.45. After cooling and solidifying at a wind speed of m / sec, and then wound at 3,200 m / min and stretched 1.68 times to prepare a 50-sided cross-sectional yarn of 50d / 36f.
상기 실시예 및 비교예들에 의해 얻은 이명단면사의 흡수성은 JIS L 1907법, 건조성 JIS L 1906법, 광택도는 CCM 측정법에 의해 측정하였다.The absorptivity of the tinnitus cross section yarn obtained by the above Examples and Comparative Examples was measured by the JIS L 1907 method, the dryness JIS L 1906 method, and the glossiness by the CCM measurement method.
실시예 및 비교예들의 물성평가결과는 표 1과 같다 Physical property evaluation results of Examples and Comparative Examples are shown in Table 1.
주1) 장축부 길이에 대한 단축부 길이의 비 Note 1) Ratio of shortened part length to long shaft part length
주2) 장축부 길이에 대한 장축부 굵기의 비 Note 2) Ratio of major shaft thickness to major shaft length
주3) 섬유단면의 외접원과 섬유단면의 최소내접원의 면적비 Note 3) Area ratio between the circumscribed circle of the fiber section and the minimum inscribed circle of the fiber section
그러므로 본 발명에 의하면 넓은 표면적을 가지고 수분전달 채널을 가져 흡한속건성이 우수하고 작업성도 양호하며 염색후 염색차발생이 적은 우수한 물성의 이형단면 합성섬유를 제공할 수 있다.Therefore, according to the present invention, it is possible to provide a release cross-section synthetic fiber of excellent physical properties having a large surface area and a moisture-transfer channel having excellent sweat absorption and dryness, good workability, and low dyeing difference after dyeing.
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KR20040013274A (en) * | 2002-08-05 | 2004-02-14 | 주식회사 휴비스 | Shaped thermoplastic fiber |
JP2005179787A (en) | 2003-12-16 | 2005-07-07 | Mitsubishi Rayon Co Ltd | Crimped polypropylene yarn and method for producing the same |
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KR20040013274A (en) * | 2002-08-05 | 2004-02-14 | 주식회사 휴비스 | Shaped thermoplastic fiber |
JP2005179787A (en) | 2003-12-16 | 2005-07-07 | Mitsubishi Rayon Co Ltd | Crimped polypropylene yarn and method for producing the same |
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