KR100812641B1 - The improving quality of water depulator for sea, tideland, aquarium and a migratory bird land - Google Patents
The improving quality of water depulator for sea, tideland, aquarium and a migratory bird land Download PDFInfo
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- KR100812641B1 KR100812641B1 KR1020060125394A KR20060125394A KR100812641B1 KR 100812641 B1 KR100812641 B1 KR 100812641B1 KR 1020060125394 A KR1020060125394 A KR 1020060125394A KR 20060125394 A KR20060125394 A KR 20060125394A KR 100812641 B1 KR100812641 B1 KR 100812641B1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/08—Seawater, e.g. for desalination
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/002—Construction details of the apparatus
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/003—Downstream control, i.e. outlet monitoring, e.g. to check the treating agents, such as halogens or ozone, leaving the process
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Abstract
Description
본 발명은 해상, 갯벌, 수족관 및 철새도래지에 살포함으로써 녹조 또는 적조의 발생에 의한 양식장의 피해를 예방하고, 활어 수송차 또는 수족관의 물에 살포함으로써 어패류가 오랫동안 생존할 수 있으며, 철새 도래지에 살포함으로써 조류독감과 같은 각종 병원성 세균의 살균과 증식을 억제할 수 있는 해상, 갯벌, 수족관 및 철새도래지 살포용 수질정화제이다.The present invention prevents damage to farms caused by green algae or red tide by spraying on the sea, tidal flats, aquariums and migratory birds, and can be survived for a long time by spraying live fish tanks or aquarium water, by spraying on migratory birds It is a water purifier for spraying sea, tidal flats, aquariums and migratory birds that can inhibit the sterilization and proliferation of various pathogenic bacteria such as bird flu.
일반적으로 공장과 도시에 접한 바다는 생활하수나 공장폐수와 같이 문명사회로부터 배출되는 오폐수에 의하여 상당부분 오염되어 있다.In general, the sea facing factories and cities is largely contaminated by wastewater discharged from civilized society, such as domestic sewage and factory wastewater.
오폐수가 유입된 바다에는 유기물질농도가 증가되어 부영양화에 의한 적조 및 녹조현상을 발생시키고, 물속의 용존산소의 농도를 감소시킴에 따라 수중 생태계와 환경이 파괴되는 것인데, 한번 파괴된 수중생태계와 환경은 다시 원상태로 회복시키는 일은 매우 어렵고 많은 기간이 필요하다.In the sea where wastewater flows in, organic matter concentration increases, causing red tide and green algae phenomena due to eutrophication, and decreasing the concentration of dissolved oxygen in the water, which destroys the aquatic ecosystem and environment. It is very difficult and takes a long time to get it back.
상기와 같이 바다에 오폐수가 유입되어 발생하는 부영영화와 양식장에서의 배설물과 사료찌꺼기 등에 의한 부영양화에 의하여 수질이 악화되고, 녹조, 적조가 발생되며, 수질의 산성화에 의한 어패류의 서식환경이 나빠져서 어패류의 수확이 감소하게 되거나 오염된 어패류를 수확하여 사람들이 섭취하게 된다.As described above, water quality is deteriorated by eutrophication caused by wastewater introduced into the sea and eutrophication by excreta and feed residues in aquaculture, green algae and red tide are generated, and the habitat environment of fish and shellfish due to acidification of water is deteriorated. The harvest of the fish is reduced or the contaminated fish and shellfish are harvested and consumed by people.
종래에는 중탄산나트륨(NaHCO3)과 황산구리(CuSO4)와 같은 화공약품을 혼합한 수질정화제를 사용하였으나 이와 같은 정화제는 오염된 수질을 효과적으로 개선,정화시킬 수 없으며 화공약품에 의한 제2의 환경공해를 유발시킬 뿐 아니라, 종래의 황토 살포 방법은 갯벌이 대량의 황토로 피복되어 산소용존량이 저하되고 물과 토양이 산성화되는 폐단이 있었다.Conventionally, water purifiers using a chemical compound, such as sodium bicarbonate (NaHCO 3 ) and copper sulfate (CuSO 4 ), have been used. However, such a purifier cannot effectively improve or purify the contaminated water. In addition, the conventional loess spreading method has a closed end where the tidal-flat is covered with a large amount of loess, so that the oxygen dissolved amount is lowered and the water and the soil are acidified.
본 발명은 상기와 같은 문제점을 해결하기 위한 것으로서 해상, 갯벌, 수족관 및 철새도래지의 물이나 갯벌에 살포함으로써 수질이 부영양화되는 현상을 막아서 녹조, 적조현상을 예방 방지하고, 수족관 어패류의 서식환경을 개선하며, 철새도래지의 조류독감과 같은 각종 병원성 세균을 살균 및 증식을 억제할 수 있는 해상, 갯벌, 수족관 및 철새도래지 살포용 수질정화제를 제공하는 것이 본 발명의 목적이다.The present invention is to solve the above problems by spraying on water or tidal flats of sea, tidal flats, aquarium and migratory birds to prevent eutrophication of water quality to prevent green algae, red tide phenomenon, and improve the habitat environment of aquarium fish and shellfish In addition, it is an object of the present invention to provide a water purification agent for sea, mud flats, aquarium and migratory bird spraying that can suppress the sterilization and proliferation of various pathogenic bacteria such as bird flu in the migratory bird.
상기의 목적을 달성하기 위하여 본 발명은 수산화마그네슘(Mg(OH)2) 15~35중량%, 탄산칼슘(CaCO3) 15~33중량%, 산화칼슘(Ca0) 10~25중량%, 모려 5~10중량%, 산화알루미늄(Al2O3) 5~10중량%, 산화규소(SiO2) 5~10중량%, 산화칼륨(K2O) 3~5중량%, 산화제2철(Fe2O3) 1~2중량%, 게르마늄 1~8중량% 및 기타 천연유기물 1~2중량%가 혼합됨으로써 해상 살포용 수질정화제가 구성된다.In order to achieve the above object, the present invention is magnesium hydroxide (Mg (OH) 2 ) 15-35% by weight, calcium carbonate (CaCO 3 ) 15-33% by weight, calcium oxide (Ca0) 10-25% by weight, 5 ~ 10% by weight, 5-10% by weight of aluminum oxide (Al 2 O 3 ), 5-10% by weight of silicon oxide (SiO 2 ), 3-5% by weight of potassium oxide (K 2 O), ferric oxide (Fe 2 O 3 ) 1 to 2% by weight, 1 to 8% by weight of germanium and 1 to 2% by weight of other natural organic matter are mixed to form a water purification agent for marine spraying.
또한, 수산화마그네슘(Mg(OH)2) 20~35중량%, 탄산칼슘(CaCO3) 20~35중량%, 산화칼슘(CaO) 10~25중량%, 모려 10~25중량%, 산화알루미늄(Al2O3) 1~5중량%, 산화제2철(Fe2O3) 1~2중량% 및 기타 천연무기물 3~6중량%가 혼합됨으로써 갯벌 살포용 수질정화제가 구성된다.In addition, 20 to 35% by weight of magnesium hydroxide (Mg (OH) 2 ), 20 to 35% by weight of calcium carbonate (CaCO 3 ), 10 to 25% by weight of calcium oxide (CaO), 10 to 25% by weight, aluminum oxide ( Al 2 O 3 ) 1 to 5% by weight, 1 to 2% by weight of ferric oxide (Fe 2 O 3 ) and 3 to 6% by weight of other natural minerals are mixed to form a water purification agent for tidal flat spraying.
또한, 수산화마그네슘(Mg(OH)2) 30~60중량%, 탄산칼슘(CaCO3) 20~50중량%, 산화칼슘(CaO) 10~30중량%, 모려 5~10중량%, 산화알루미늄(Al2O3) 3~5중량% 및 산화제2철(Fe2O3) 1~3중량%가 혼합됨으로써 수족관 살포용 수질정화제가 구성된다.In addition, magnesium hydroxide (Mg (OH) 2 ) 30-60% by weight, calcium carbonate (CaCO 3 ) 20-50% by weight, calcium oxide (CaO) 10-30% by weight, 5-10% by weight, aluminum oxide ( 3-5% by weight of Al 2 O 3 ) and 1-3% by weight of ferric oxide (Fe 2 O 3 ) are mixed to form an aquarium water purification agent.
또한, 수산화마그네슘(Mg(OH)2) 20~40중량%, 탄산칼슘(CaCO3) 20~40중량%, 산화칼슘(CaO) 20~25중량%, 모려 5~10중량%, 산화알루미늄(Al2O3) 2~6중량%, 산화제2철(Fe2O3) 1~5중량% 및 산화규소(SiO2) 제2~4중량%가 혼합됨으로써 철새도래지 살포용 수질정화제가 구성된다.In addition, 20-40% by weight of magnesium hydroxide (Mg (OH) 2 ), 20-40% by weight of calcium carbonate (CaCO 3 ), 20-25% by weight of calcium oxide (CaO), 5-10% by weight, aluminum oxide ( Al 2 O 3 ) 2-6% by weight, 1-5% by weight of ferric oxide (Fe 2 O 3 ) and 2-4% by weight of silicon oxide (SiO 2 ) are mixed to form a water purification agent for spraying migratory birds .
일반적으로 하천이나 바다의 부영양화(富營養化, eutrophication)는 도시하수, 축산폐수 및 산업페수등이 유입되어 발생되거나 양식장의 배설물과 사료찌꺼기에 의해 발생되고, 이러한 부영양화는 식물플랑크톤을 급속하게 증가시켜 녹조 및 적조현상을 발생시킨다.In general, eutrophication of rivers and seas is caused by the inflow of urban sewage, livestock waste, and industrial wastes, or by feces and feed residues from farms, and this eutrophication rapidly increases phytoplankton. It causes green algae and red tide.
특히, 상기와 같은 하천과 바다의 부영영화는 인(P)과 질소(N)가 주요 원인물질이다. 식물체가 생장하는데에는 여러 원소들이 필요하지만 하천과 바다 생태계에는 인(P)의 양이 적어 성장을 억제받는다. 이러한 상태에서 하천과 바다에 인(P)이 유입되면 식물플랑크톤이 급속하게 증가하여서 녹조와 적조현상이 발생하게 된다.In particular, the euphoric film of the rivers and seas as described above, phosphorus (P) and nitrogen (N) is the main cause. Plants need several elements to grow, but rivers and sea ecosystems contain less phosphorus (P), which inhibits growth. In this state, when phosphorus (P) flows into rivers and seas, phytoplankton rapidly increases, causing green algae and red tide.
인(P)에는 무기인과 유기인이 있고, 오염된 하천과 바다에는 무기인이 많이 함유되어 있으며, 유기인은 분해하기가 어려워 수중으로 용출되는 것은 적으나 무기인은 수중으로 용출되기 쉬워서 부영영화의 원인이 된다.Phosphorus (P) contains inorganic phosphorus and organic phosphorus, and polluted rivers and seas contain a lot of inorganic phosphorus. Organic phosphorus is difficult to dissolve, so it is hard to dissolve in water, but inorganic phosphorus is easy to dissolve in water. It causes a movie.
본 발명은 일 실시예로서 수산화마그네슘(Mg(OH)2) 15~35중량%, 탄산칼슘(CaCO3) 15~33중량%, 산화칼슘(Ca0) 10~25중량%, 모려(굴껍질, 25㎛크기의 분말) 5~10중량%, 산화알루미늄(Al2O3) 5~10중량%, 산화규소(SiO2) 5~10중량%, 산화칼륨(K2O) 3~5중량%, 산화제2철(Fe2O3) 1~2중량%, 게르마늄 1~8중량% 및 기타 천연유기물 1~2중량%가 혼합된 것으로서, 이를 바다 및 양식장의 해상에 살포함으로써 녹조와 적조를 방지할 수 있도록 구성된 수질 개선 정화제이다.As an embodiment of the present invention, 15% to 35% by weight of magnesium hydroxide (Mg (OH) 2 ), 15% to 33% by weight of calcium carbonate (CaCO 3 ), 10% to 25% by weight of calcium oxide (Ca0), and a seed (oyster shell, 25 μm powder) 5-10 wt%, aluminum oxide (Al 2 O 3 ) 5-10 wt%, silicon oxide (SiO 2 ) 5-10 wt%, potassium oxide (K 2 O) 3-5 wt% , 1 to 2% by weight of ferric oxide (Fe 2 O 3 ), 1 to 8% by weight of germanium and 1 to 2% by weight of other natural organic matter, which is sprayed on the sea and fish farms to prevent green algae and red tide It is a water quality purifying agent that is configured to be.
모려는 굴 껍질을 25㎛크기 이하의 분말로 가공한 것이고, 천연유기물은 재 첩조개가루를 25㎛크기 이하의 분말로 가공한 것이다.The oyster shell is processed into a oyster shell of 25㎛ size or less, and natural organic matter is processed into a powder of 25㎛ size or less.
본 발명의 다른 실시예로서 수산화마그네슘(Mg(OH)2) 20~35중량%, 탄산칼슘(CaCO3) 20~35중량%, 산화칼슘(CaO) 10~25중량%, 모려(굴껍질, 25㎛크기의 분말) 10~25중량%, 산화알루미늄(Al2O3) 1~5중량%, 산화제2철(Fe2O3) 1~2중량% 및 기타 천연무기물 3~6중량%가 혼합된 것으로서, 이를 바다 및 양식장의 갯벌 1헥타아르(ha)당 5톤(t)을 고르게 살포함으로써 질소(N), 인(P) 및 황화수소(H2S)의 수중용출을 억제하여서 수질을 개선하고, 어패류의 폐사율을 경감시킬 수 있는 수질 개선 정화제이다.As another embodiment of the present invention, magnesium hydroxide (Mg (OH) 2 ) 20 to 35% by weight, calcium carbonate (CaCO 3 ) 20 to 35% by weight, calcium oxide (CaO) 10 to 25% by weight, seed (oyster shell, 25 μm powder) 10-25 wt%, aluminum oxide (Al 2 O 3 ) 1-5 wt%, ferric oxide (Fe 2 O 3 ) 1-2 wt% and other natural inorganic 3-6 wt% As a mixture, it is evenly sprayed 5 tons (t) per hectare (ha) of sea and fish farms to improve water quality by inhibiting the elution of nitrogen (N), phosphorus (P) and hydrogen sulfide (H 2 S). It is a water quality improvement purification agent which can reduce the mortality rate of fish and shellfish.
모려는 굴 껍질을 25㎛크기 이하의 분말로 가공한 것이고, 천연무기물은 생석회가루이다.Soybean is a oyster shell processed into a powder of 25㎛ size or less, natural mineral is quicklime powder.
상기 혼합물을 바다와 양식장의 해상 또는 갯벌에 살포하면 수중의 무기인이 철(Fe), 알루미늄(Al) 및 칼슘(Ca)과 결합하여 철결합인(Fe-P), 알루미늄결합인(Al-P) 및 칼슘결합인(Ca-P)이 되어서 수중에 포함된 인(P)의 양을 감소시킴으로서 녹조와 적조를 예방할 수 있는 것이다.When the mixture is sprayed on the sea or tidal flats of the sea and fish farms, the inorganic phosphorus in the water is combined with iron (Fe), aluminum (Al), and calcium (Ca) to bind iron (Fe-P) and aluminum bond (Al- P) and calcium-binding phosphorus (Ca-P) by reducing the amount of phosphorus (P) contained in the water will be able to prevent green algae and red tide.
갯벌속의 질소(N)와 인(P)에 대해서는 본 발명의 규소(Si)성분을 공급함으로써 질소(N)와 인(P)과 규소(Si)가 결합하여서 질소(N)와 인(P)과 규소(Si)의 균형과 비율이 정상적으로 유지됨으로써 갯벌속의 질소(N)와 인(P)이 수중으로 용출되는 것을 방지하여서 녹조와 적조를 예방할 수 있는 것이다.Nitrogen (N) and phosphorus (P) in the tidal flat are supplied with the silicon (Si) component of the present invention, whereby nitrogen (N), phosphorus (P) and silicon (Si) combine to form nitrogen (N) and phosphorus (P). By maintaining the balance and proportion of silicon and Si normally, it is possible to prevent green algae and red tide by preventing nitrogen (N) and phosphorus (P) from being eluted into the water.
본 발명의 또 다른 실시예로서 수산화마그네슘(Mg(OH)2) 30~60중량%, 탄산칼슘(CaCO3) 20~50중량%, 산화칼슘(CaO) 10~30중량%, 모려(굴껍질, 25㎛크기의 분말) 5~10중량%, 산화알루미늄(Al2O3) 3~5중량% 및 산화제2철(Fe2O3) 1~3중량%가 혼합되어서 활어 수송차나 수족관의 물과 상기 분말을 1500:1의 중량비율로 살포함으로써 수족관의 수질이 정화되도록 한 것이다.As another embodiment of the present invention, magnesium hydroxide (Mg (OH) 2 ) 30 to 60% by weight, calcium carbonate (CaCO 3 ) 20 to 50% by weight, calcium oxide (CaO) 10 to 30% by weight, oyster shell 5 ~ 10% by weight of powder, 25㎛ size), 3 ~ 5% by weight of aluminum oxide (Al 2 O 3 ) and 1-3% by weight of ferric oxide (Fe 2 O 3 ) And the powder is sprayed at a weight ratio of 1500: 1 to purify the water quality of the aquarium.
본 발명의 또다른 실시예로서수산화마그네슘(Mg(OH)2) 20~40중량%, 탄산칼슘(CaCO3) 20~40중량%, 산화칼슘(CaO) 20~25중량%, 모려 5~10중량%, 산화알루미늄(Al2O3) 2~6중량%, 산화제2철(Fe2O3) 1~5중량% 및 산화규소(SiO2) 제2~4중량%가 혼합되어서 이를 철새도래지 1ha당 분말 5t, 액상 10t을 살포함으로써 철새도래지의 수질이 정화되도록 한 것이다.As another embodiment of the present invention magnesium hydroxide (Mg (OH) 2 ) 20-40% by weight, calcium carbonate (CaCO 3 ) 20-40% by weight, calcium oxide (CaO) 20-25% by weight, 5-10 Weight%, 2-6% by weight of aluminum oxide (Al 2 O 3 ), 1-5% by weight of ferric oxide (Fe 2 O 3 ) and 2-4% by weight of silicon oxide (SiO 2 ), which is a migratory bird By spraying 5t of powder per 10ha and 10t of liquid, the water quality of migratory birds will be purified.
이상에서 살펴본 바와 같이 본 발명을 해상, 갯벌, 수족관 및 철새도래지에 살포하면 바다와 양식장의 수질이 부영양화되지 않기 때문에 녹조, 적조현상을 예방 방지하고, 수족관 어패류의 서식환경을 개선하며, 철새도래지의 수질을 개선한다.As described above, when the present invention is applied to sea, mud flats, aquariums and migratory birds, the water quality of the sea and fish farms is not eutrophicated, thus preventing green algae and red tide phenomena, improving the habitat environment of aquarium fish and shellfish, Improve water quality
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Citations (4)
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KR100334825B1 (en) | 1999-07-08 | 2002-05-03 | 주식회사 퍼텍코리아 | A drug of improvement for the restration of a marine environment. |
KR100349812B1 (en) | 2000-05-22 | 2002-08-23 | 윤연숙 | A reform material for polluted seawater or polluted shore of estuary greentos |
KR20030020098A (en) * | 2001-09-01 | 2003-03-08 | 이기양 | alternate omitted |
KR20060101408A (en) * | 2006-08-24 | 2006-09-22 | 손호익 | A ceramic ball for a rise in potential for hydrogen & occurrence of mineral |
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KR100334825B1 (en) | 1999-07-08 | 2002-05-03 | 주식회사 퍼텍코리아 | A drug of improvement for the restration of a marine environment. |
KR100349812B1 (en) | 2000-05-22 | 2002-08-23 | 윤연숙 | A reform material for polluted seawater or polluted shore of estuary greentos |
KR20030020098A (en) * | 2001-09-01 | 2003-03-08 | 이기양 | alternate omitted |
KR20060101408A (en) * | 2006-08-24 | 2006-09-22 | 손호익 | A ceramic ball for a rise in potential for hydrogen & occurrence of mineral |
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