KR100790488B1 - Anion sol of diffusing aromatic rosemary for air purification and preparing method thereof - Google Patents

Abstract

An aromatic rosemary anion diffusing solution and method for preparing the same are provided to be applied to indoor walls, interior materials, and furniture, and therefore to block the emission of harmful substances. An aromatic rosemary anion diffusing solution includes 100wt% of water, 35-45wt% of rosemary oil, 35-45wt% of an anion liquid composition made of sericite powder and water, 7-12wt% of ethanol, and 7-12wt% of a liquid antimicrobial. First, the rosemary oil and the anion liquid composition prepared(S10) are mixed with the liquid antimicrobial and water(S20) and nano-ground for 30-40min(S30). The nano-ground mixture is then agitated and heated at 120-130deg.C for 50-70min(S40). Finally, the mixture is cooled to a temperature below 75deg.C, and ethanol is added thereto(S50).

Description

ANION SOL OF DIFFUSING AROMATIC ROSEMARY FOR AIR PURIFICATION AND PREPARING METHOD THEREOF

1 is a flow chart of the manufacturing method of the anion sol for air purification according to an embodiment of the present invention

The present invention relates to an anionic sol and a method of manufacturing the same, which finishes the interior wall, interior materials and furniture of the building to block the emission of harmful substances and emanates rosemary scent, and more specifically, finish the interior wall, interior materials and furniture of the building It prevents the release of organic compounds and volatile substances, emits rosemary scent, generates far infrared rays and negative ions and at the same time has the effect of inhibiting bacteria due to antibacterial action.

In general, the interior of the building is a synthetic resin or wood floorboard is bonded to the floor with a synthetic resin adhesive, and the wall surface is covered with a mortar of cement.

The interior of the building on the floor of the building is a synthetic resin adhesive that is used to finish by bonding a synthetic resin or wood floorboard has the advantage of excellent physical properties associated with the adhesion, such as adhesive strength or adhesive durability. However, various organic compounds or volatile substances contained in the synthetic resin adhesive are emitted into the air, which adversely affects the health of the building residents, and causes odors to offend the residents, as well as the so-called sick house syndrome.

Various interior materials including doors, shelves, etc., and various furnitures are also manufactured by bonding multiple sheets of synthetic resin boards or wooden boards with adhesive to form a multi-layered structure, and coloring the surface of the door formed by the multi-layered structure or by adhering veneers. to be.

Interior materials and furniture produced in this way are relatively light weight and inexpensive and are widely used. Synthetic resin adhesive is used to bond synthetic resin board or wood board into multilayer structure, and synthetic paint is used for coloring. Such synthetic resin adhesive has the advantage of excellent various physical properties related to adhesion such as adhesive strength and durability. Synthetic paints have the advantages of beautiful color and excellent durability, but due to the sick house syndrome caused by synthetic resin adhesives and various organic compounds or volatile substances contained in synthetic paints, it not only adversely affects the health of people living in facilities. There is a problem that an unpleasant smell occurs.

Accordingly, in order to prevent or suppress the divergence of various organic compounds or volatile substances that adversely affect the health of people, various compositions for coating the inner wall and the surface of the finish have been developed. However, since the conventional coating composition itself emits harmful substances to the human body, or due to insufficient physical properties associated with the bonding, it is difficult to actually use the coating on the inner wall, the finishing material, and in order to suppress the odor generated in the room, In addition, chemical deodorants may be contained or separately used deodorants and fragrances.

For example, Korean Patent Laid-Open Publication No. 1995-25070 (published on September 15, 1995) discloses an aqueous polyester acid solution composed of a graft copolymer dispersed in a synthetic solvent of water or a water-soluble organic solvent.

However, the polyester aqueous acid solution itself emits a harmful substance to the human body, there is a problem that an unpleasant and odor affecting the human body occurs.

In addition, Korean Patent Laid-Open Publication No. 2004-26051 (published on March 27, 2004) discloses an ocher paint having a persistent fragrance dissipation property by applying microcapsules that can emit an aroma for a long time to the ocher paint.

However, organic compounds or volatile substances may be emitted from the pigments contained in the ocher paint, which may adversely affect the health of the occupants, and may cause insufficient durability to affect the durability of the inner wall or the finish.

In addition, Korean Laid-Open Patent Publication No. 2002-17719 (published on March 17, 2002) discloses a coating film that continuously emits natural fragrance and emits far infrared rays, including cactus powder, ocher, eosinophil cluster powder, and seaweed concentrate powder. Is disclosed.

The coating film that emits the natural aroma as described above is composed of only natural materials so that no organic compound or volatile substance is emitted from itself. However, since the physical properties associated with the bonding is insufficient, it is difficult to actually use the coating on the finishing material, and there is a problem that the function of blocking the emission of organic compounds or volatile materials is insufficient.

Accordingly, the first object of the present invention is to include a rosemary oil, anionic liquid composition, ethanol, liquid antimicrobial agent nano-sprayed on the interior wall, interior materials and furniture to form a film to block the emission of harmful substances, rosemary fragrance is emitted and far infrared rays and It is to provide an anion sol having an antibacterial action while generating an anion.

A second object of the present invention consists of nano grinding of a mixture of rosemary oil, anionic liquid composition, ethanol, liquid antimicrobial agent, and water, stirring at constant temperature, and further adding ethanol while cooling and nano to interior walls, interior materials and furniture. The present invention provides a method for preparing an anionic sol that is sprayed to block harmful substance emission and that rosemary odor is emitted.

In order to achieve the first object of the present invention described above, the anion sol for purifying air in which the rosemary scent is released according to an embodiment of the present invention is 35 to 45 parts by weight of rosemary oil, 35 to 45 parts by weight of anionic liquid composition, 7 to ethanol 12 parts by weight, 7 to 12 parts by weight of the liquid antibacterial agent, and 100 parts by weight of water are included.

In addition, in order to achieve the second object of the present invention, a method of preparing an anion sol for purifying air in which the rosemary scent is released according to an embodiment of the present invention comprises the steps of preparing a rosemary oil, preparing an anionic liquid composition, the rosemary Mixing 35 to 45 parts by weight of oil, 35 to 45 parts by weight of anionic liquid composition, 7 to 12 parts by weight of liquid antimicrobial agent, and 100 parts by weight of water to form a mixture, nano-crushing the mixture for 30 to 40 minutes, the Heat-treating the nano-crushed mixture with stirring at 120-130 ° C. for 50-70 minutes, and further adding 7-12 parts by weight of ethanol based on 100 parts by weight of water of the mixture at 75 ° C. or lower while cooling the stirred mixture. Steps are included.

An anionic sol for purifying the air of rosemary according to the present invention forms a film on the interior wall of the building, the surface of interior materials and furniture to prevent the release of various organic compounds or volatile substances, deodorizes odors and emits rosemary scent, far infrared rays It generates a large amount of anions and at the same time inhibits the development of bacteria due to antibacterial action.

With reference to an embodiment will be described in detail an anion sol for air purification is released of the rosemary scent of the present invention.

The anion sol for purifying air of the rosemary odor according to the present invention is 35 to 45 parts by weight of rosemary oil, 35 to 45 parts by weight of anionic liquid composition, 7 to 12 parts by weight of ethanol, 7 to 12 parts by weight of liquid antibacterial agent, and 100 parts by weight of water. Rosemary oil and anionic liquid composition are used as the main components. In addition, ethanol which provides an antiseptic effect on the anion sol for air purification and a liquid antimicrobial agent that provides antibacterial activity are used.

Rosemary, an active ingredient of rosemary oil contained in an anionic sol for air purification, is an evergreen shrub native to the Mediterranean coast, and the sharp leaves like pine leaves have a fresh and fresh scent. Rosemary leaves have a strong fragrance that gives a scent when touched with a little touch, and the fragrance does not disappear even when the leaves are dried, and it is pharmacologically effective in rejuvenating, promoting blood circulation, antibacterial action, and indigestion.

If the content of the rosemary oil contained in the air purification anion sol of the present invention is less than 35 parts by weight, the pharmacological and deodorizing action of the air purification anion sol is lowered, and if the content of rosemary oil exceeds 45 parts by weight, the anion of the anion sol for air purification The content of the liquid composition is relatively reduced, so that the amount of far infrared rays and anions are released.

Rosemary oil used in the present invention is composed of 15 to 20 parts by weight of rosemary leaf pulverized, 100 parts by weight of vegetable oil is mixed, the vegetable oil is at least one oil selected from the group consisting of edible oil, olive oil, canola oil, grape seed oil Included.

When the content of rosemary leaf pulverized powder, which is an active ingredient included in 100 parts by weight of vegetable oil, which is a base of rosemary oil, is less than 15 parts by weight, the aroma and pharmacological action of rosemary oil are lowered. Since the rosemary leaf pulverization is no longer soluble in vegetable oil, unnecessary waste of the rosemary leaf pulverization is generated.

Cicada, an active ingredient of the anionic liquid composition included in the anion sol for air purification, is a substance that emits 90% or more of far-infrared rays that promotes blood circulation and activates cellular activity of the human body, and emits powerful anions to adsorb various harmful substances. Has

The anionic liquid composition is a supernatant that is nano-pulverized a mixture of mica powder and water at a high speed of 1000 rpm or more, and the nano-pulverized mixture is left for a predetermined time to be divided into a slurry and a supernatant, and separated into solid and liquid. In order to form the anionic liquid composition as described above, the mixture of the mica powder and water is nano-pulverized at a high speed of 1000 rpm or more, and the mica powder must be pulverized into fine particles having a diameter unit of nm.

When the content of the anion liquid composition contained in the anion sol for air purification of the present invention is less than 35 parts by weight, the harmful substances blocking action and far infrared rays, anion emission of the air purification anion sol is reduced, the content of the anion liquid composition exceeds 45 parts by weight This results in a relatively reduced content of rosemary oil, reducing the pharmacological and deodorizing effects of the anion sol for air purification.

In addition, if the content of ethanol contained in the air purification anion sol is less than 7 parts by weight, the preservation of the air purification anion sol is lowered, if the content of ethanol exceeds 12 parts by weight, the density of the air purification anion sol is reduced to block harmful substances Is lowered.

In addition, if the amount of the liquid antimicrobial agent included in the anion sol for air purification is less than 7 parts by weight, the antibacterial effect of the anion sol for air purification is lowered. Will decrease.

An embodiment of a method of preparing an anion sol for purifying air in which rosemary fragrance of the above configuration is released will be described in detail with reference to the accompanying drawings.

1 is a flowchart illustrating a method for preparing an anion sol for purifying air in which rosemary scent is released according to an embodiment of the present invention.

Referring to FIG. 1, first, a rosemary oil and an anionic liquid composition, which are main ingredients for constituting an anion sol for purifying air of a rosemary according to an embodiment of the present invention, are prepared (step S10).

Rosemary leaf, which is an active ingredient of rosemary oil, one of the main ingredients of anion sol for air purification, has a strong and fresh scent, and is pharmacologically effective for rejuvenation, promoting blood circulation, antibacterial action, and indigestion.

The rosemary leaves are pulverized to form a rosemary leaf pulverized product, and 15 to 20 parts by weight of the rosemary leaf pulverized product and 100 parts by weight of vegetable oil are mixed and stirred to form a rosemary oil.

When the content of rosemary leaf pulverized powder, which is an active ingredient included in 100 parts by weight of vegetable oil, which is a base of rosemary oil, is less than 15 parts by weight, the aroma and pharmacological action of rosemary oil are lowered. Since the rosemary leaf pulverization is no longer soluble in vegetable oil, unnecessary waste of the rosemary leaf pulverization is generated.

In the manufacturing step of the rosemary oil as described above, the solid of the rosemary leaf remains in the rosemary oil, but the solid of the rosemary leaf is completely crushed and dissolved in the vegetable oil during the nano grinding and stirring process of the rosemary oil which is carried out in the following Do not remove solids of rosemary leaves from the rosemary oil.

Cicada, an active ingredient in the anion liquid composition, one of the main ingredients of anion sol for air purification, emits 90% or more of far-infrared rays that promote blood circulation and activate cellular activity. Has the ability to

These mica is pulverized to form mica powder, and 40 to 60 parts by weight of the mica powder and 100 parts by weight of water are mixed to form a water mixture of mica.

If the content of the mica powder to 100 parts by weight of water in the formation process in the mica water mixture is less than 40 parts by weight, the concentration of the mica sol is reduced to reduce the far-infrared emission, the content of the mica powder to 100 parts by weight of water Excessive wealth causes waste due to overuse of the mica.

The biotite water mixture formed as described above is nano-pulverized by a nano grinder, and the nano-crushed biotite water mixture is left for a predetermined time to be divided into a slurry and a supernatant.

The slurry and the supernatant are filtered to recover the anionic liquid composition as the supernatant.

 The rosemary oil, anionic liquid composition, liquid antimicrobial agent, and water prepared as described above are mixed to form a mixture (step S20).

Specifically, 35 to 45 parts by weight of rosemary oil, 35 to 45 parts by weight of the anionic liquid composition, 7 to 12 parts by weight of the liquid antimicrobial agent, and 100 parts by weight of water are mixed to form a mixture.

If the content of the rosemary oil contained in 100 parts by weight of the solvent of the mixture is less than 35 parts by weight, the pharmacological action and deodorizing function of the anion sol for air purification is reduced, and if the content of rosemary oil exceeds 45 parts by weight, the anion sol for air purification The content of the anion liquid composition of the relative decreases, the amount of far infrared rays, anion is lowered.

In addition, if the content of the anionic liquid composition contained in 100 parts by weight of the water of the solvent is less than 35 parts by weight, the harmful substances blocking function of the anion sol for air purification, far infrared rays, anion emissions are reduced, the content of the anion liquid composition is 45 parts by weight When exceeded, the content of rosemary oil is relatively reduced, which lowers the pharmacological and deodorizing function of the anion sol for air purification.

Separately, if the amount of the liquid antimicrobial agent included in 100 parts by weight of water is less than 7 parts by weight, the antimicrobial function of the anion sol for air purification is lowered. Relative decrease.

The mixture formed as described above is nano-pulverized for 30 to 40 minutes at a high speed of 7700 to 8500 rpm in the nano grinder (step S30).

If the time for nano pulverizing the mixture is less than 30 minutes, the mixture is not nano-pulverized properly. If the time for nano pulverizing the mixture is 40 minutes, the mixture is nano-pulverized in nm.

By nano grinding of the mixture as described above, the solids of the rosemary leaves remaining in the rosemary oil contained in the mixture are completely ground.

The nano pulverized mixture is heat treated with stirring (step S40).

Specifically, the nano-pulverized mixture is injected into the reactor and heat treated with stirring at 120 to 130 ° C. and 450 to 470 rpm at a low speed for 50 to 70 minutes.

If the stirring and heat treatment temperature of the mixture is lower than 120 ° C., the mixture is not sufficiently heat treated, and if the stirring and heat treatment temperature of the mixture exceeds 130 ° C., the components of the mixture may be denatured.

In addition, if the stirring and heat treatment time of the mixture is less than 50 minutes, the solids of the rosemary leaves remaining in the rosemary oil contained in the mixture is not completely dissolved, and if the stirring and heat treatment time of the mixture exceeds 70 minutes, the moisture of the mixture Overevaporation.

While cooling the stirred mixture, further add ethanol to provide preservative action (step S50).

Specifically, while the mixture is naturally cooled while stirring and heat treatment, when the mixture is cooled to 75 ° C or less, 7 to 12 parts by weight of ethanol is further added based on 100 parts by weight of water of the mixture. That is, since the boiling point of ethanol is 78 ° C., when the stirred and heat-treated mixture is cooled to 75 ° C. or lower, ethanol is added to the mixture.

If the amount of ethanol added to the mixture is less than 7 parts by weight, the anion sol for air purification is liable to decay or deteriorate. If the amount of ethanol is added to the mixture exceeds 12 parts by weight, the density of the anion sol for air purification is lowered to prevent harmful substances. Degrades.

An anionic sol for purifying the air of rosemary, prepared by adding ethanol as described above, is filled in a nano injector capable of spraying fine particles in nm, and nano-sprayed on the inner wall of the building to form a film on the surface of the inner wall. do.

The present invention will be described in detail below with reference to a preferred embodiment.

<Example>

1. Rosemary oil and anionic liquid composition were prepared.

a) Rosemary leaves were ground to form a rosemary leaf pulverization. 200 g of the rosemary leaf mill and 1000 g of olive oil were mixed and stirred to form a rosemary oil.

b) Cicadas are pulverized to form a mica powder, and 500 g of the mica powder and 1000 g of purified water were mixed to form a water mixture of mica. The biotite water mixture was injected into a nano grinder and nano-pulverized at 2000 rpm for 50 minutes. The nano-crushed biotite water mixture was left for 30 minutes to separate the slurry and the supernatant. The slurry and the supernatant were filtered to obtain an anionic liquid composition as a supernatant.

2. 400 g of the rosemary oil, 400 g of the anionic liquid composition, and 100 g of the liquid antimicrobial agent were mixed with 1000 g of purified water to form a mixture.

3. The mixture was injected into the nano grinder and nano grind for 40 minutes at 8000 rpm.

4. The nano-pulverized mixture was injected into the reactor and heat treated with stirring at 120 ° C. and 450 rpm for 60 minutes.

5. While the stirred mixture was naturally cooled, when the mixture was cooled to 75 ° C. or lower, 100 g of ethanol was added to prepare an anionic sol for purifying rosemary.

Experimental Example 1

An anionic sol for purifying the air of rosemary produced by the above embodiment was filled in a D-707 spray gun (Dong-A Co., Ltd.), which is a nano injector, and nano-sprayed on the inner wall of the building, for air purification on the surface of the inner wall. A film of anionic sol was formed.

As described above, the amount of negative ions was measured on the surface of the inner wall on which the film of the anion sol for air purification was formed using a contact type ion meter Com-3010P20-A (manufactured by Com. Systems, Japan).

As a result of performing the anion release measurement test as described above, anion of 450 to 650 Ion / cc was detected on the surface of the inner wall where the film of the anion sol for air purification was formed.

That is, it was shown that a large amount of anions are released from the anion sol for air purification prepared according to the present invention.

Experimental Example 2

Formaldehyde (HCHO) and other volatile organic compounds were tested for the examples of the inner wall where the film of the anion sol for air purification was formed as described above and the comparative example for the inner wall of the film of the anion sol for air purification.

The detection experiment of the formaldehyde and other volatile organic compounds was carried out by XP308B (product of New Cosmos Electric, Japan), which is a volatile organic compound detection equipment, and the results are shown in Table 1 below.

<Table 1>

division sample Formaldehyde (ppm) Other Volatile Organic Compounds (ppm) Volatile Organic Compound Detection Experiment Comparative example 0.45 0.93 Example 0.01 0.03

In Table 1, the example was detected much less volatile organic compounds than the comparative example, it was shown that the excellent effect of blocking the harmful substances of the air purification anion sol release the rosemary odor according to the present invention.

The anion sol for purifying air of the rosemary fragrance according to the present invention forms a film on the interior walls, interior materials and furniture of the building to block the emission of various organic compounds or volatile substances harmful to the human body, and to suppress the generation of bacteria due to the antibacterial action. It has an effect.

In addition, it emits a large amount of far-infrared rays, anions, which are beneficial to the human body, while deodorizing odors that are unpleasant to the human body, while continuously releasing rosemary scent, thereby improving the health and comfort of residents.

Although the above has been described with reference to a preferred embodiment of the present invention, those skilled in the art will be able to variously modify and change the present invention without departing from the spirit and scope of the invention as set forth in the claims below. It will be appreciated.

Claims (7)

Per 100 parts by weight of water 35 to 45 parts by weight of rosemary oil; 35 to 45 parts by weight of an anionic liquid composition, which is a supernatant which is separated into a slurry and a supernatant by nano-crushing a mixture of mica powder and water and leaving it in a slurry and a supernatant; 7 to 12 parts by weight of ethanol; And Anion sol for purifying air is released rosemary flavor containing 7 to 12 parts by weight of the liquid antibacterial agent. The method of claim 1, wherein the rosemary oil Per 100 parts by weight of vegetable oil Rosemary leaf pulverized anion sol for air purification, characterized in that it contains 15 to 20 parts by weight of rosemary leaf pulverization. 3. The anion sol for air purification according to claim 2, wherein the vegetable oil comprises at least one oil selected from the group consisting of edible oil, olive oil, canola oil, and grape seed oil. delete Preparing rosemary oil; Preparing an anionic liquid composition; Forming a mixture by mixing 35 to 45 parts by weight of the rosemary oil, 35 to 45 parts by weight of anionic liquid composition, and 7 to 12 parts by weight of a liquid antimicrobial agent, based on 100 parts by weight of water; Nano grinding the mixture for 30 to 40 minutes; Heat-treating the nano-pulverized mixture with stirring at 120 to 130 ° C. for 50 to 70 minutes; And Adding 7 to 12 parts by weight of ethanol based on 100 parts by weight of water of the mixture at 75 ° C. or less while cooling the stirred mixture, Preparing the anionic liquid composition Mixing 40 to 60 parts by weight of the mica hair powder with respect to 100 parts by weight of water to form a mica hair water mixture; Nano-crushing and leaving the biotite aqueous mixture separated into a slurry and a supernatant; And The method of producing an anion sol for purifying the air of the rosemary is released comprising the step of recovering the anionic liquid composition as a supernatant by filtering the slurry and the supernatant. 6. The method of claim 5 wherein the step of preparing rosemary oil comprises the steps of pulverizing the rosemary leaves to form a rosemary leaf pulverization; The method of producing an anionic sol for purifying the rosemary fragrance, characterized in that the mixture comprises agitating 15 to 20 parts by weight of the rosemary leaf pulverized with respect to 100 parts by weight of vegetable oil. delete

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