KR100693829B1 - weste oil by microbialbioprocessing synthesis producer. - Google Patents

weste oil by microbialbioprocessing synthesis producer. Download PDF

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KR100693829B1
KR100693829B1 KR1020060112009A KR20060112009A KR100693829B1 KR 100693829 B1 KR100693829 B1 KR 100693829B1 KR 1020060112009 A KR1020060112009 A KR 1020060112009A KR 20060112009 A KR20060112009 A KR 20060112009A KR 100693829 B1 KR100693829 B1 KR 100693829B1
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chamber
high frequency
induction heating
frequency induction
reduction reaction
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송호엽
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
    • C10G31/06—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by heating, cooling, or pressure treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/466—Entrained flow processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1003—Waste materials
    • C10G2300/1007—Used oils

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Abstract

본 발명은 국제적으로 환경의 문제거리가 되고 있는 폐변압기에서 발생되는 PCBs 폐오일과 각종 산업현장에서 발생되는 폐오일을 2차 오염물질인 다이옥신(PCD/DFS) Total PCBs 및 CO-PCBs, PAHs, PAHs, SOx, NOx와 같은 유해물질 발생을 줄여 환경친화적으로 처리하고 재활용 하기 위한 방법으로 PCBs 폐오일(탄화물질/Carbonaceous material)의 유기물을 가스상의 연료인 합성가스(Syngas/H2 + CO)인 기본청정연료로 환원시키는 신에너지 및 재생에너지 개발 이용에 관한 것이다.The present invention relates to PCBs waste oils generated from waste transformers, which are a global environmental problem, and waste oils generated from various industrial sites, and dioxins (PCD / DFS) total PCBs, CO-PCBs, PAHs, As a method to reduce the generation of harmful substances such as PAHs, SOx, and NOx, and to treat and recycle in an environmentally friendly manner, the organic matter of PCBs waste oil (carbonaceous material / carbonaceous material) is syngas / H 2 + CO It relates to the development and use of new energy and renewable energy to reduce to basic clean fuel.

초음파 진동실, 고주파 유도가열실, 환원반응실이 수직으로 구성되어 있는 폐오일 처리방법 과 합성가스(Syngas/H2 + CO) 발생장치에 관한 것이다.The present invention relates to a waste oil treatment method and a synthesis gas (Syngas / H 2 + CO) generator in which an ultrasonic vibration chamber, a high frequency induction heating chamber, and a reduction reaction chamber are formed vertically.

하단부의 초음파 진동실에서 PCBs 폐오일의 유기물을 초음파로 이온 시켜 고주파 유도가열실로 부양시켜 고주파 유도가열실에서 1300℃의 고열로 외부의 공기가 차단된 상태에서 산화반응 없이 열을 높여 환원반응실로 부양시켜 환원반응실의 방열판이 온도를 낮추어 PCBs 폐오일을 2차 오염 물질 발생 없이 환경친화적으로 처리하고 합성가스(Syngas/H2 + CO)를 만들어 재활용하는 폐오일 처리방법 과 합성가스 발생장치에 관한 것이다.Ultrasonic ion of PCBs waste oil is ultrasonically ionized in the lower part of the ultrasonic vibration chamber to support the high frequency induction heating chamber.The high frequency induction heating chamber raises the heat without oxidation reaction in the state where the outside air is blocked by high temperature of 1300 ℃ and supports the reduction reaction chamber. To reduce the temperature of the heat sink in the reduction reaction chamber to treat PCBs waste oil environmentally without generating secondary pollutants, and to make and recycle syngas (Syngas / H 2 + CO). will be.

고주파 유도가열실, 고주파 유도가열코일, 환원반응실, 고주파 유도가열망, 초음파 진동실, 다이옥신, 합성가스, 노즐, 환원반응. High frequency induction heating chamber, high frequency induction heating coil, reduction reaction chamber, high frequency induction heating network, ultrasonic vibration chamber, dioxin, syngas, nozzle, reduction reaction.

Description

폐오일 처리방법(Weste oil by microbialbioprocessing)과 합성가스발생장치(Synthesis producer).{weste oil by microbialbioprocessing synthesis producer.}Waste oil by microbialbioprocessing and Synthesis producer. {Weste oil by microbialbioprocessing synthesis producer.}

도1은 폐오일 처리방법과 합성가스 발생장치 전체 단면도.1 is a cross-sectional view showing a waste oil treatment method and a syngas generator.

도2는 도1의 전체구조도.2 is an overall structural diagram of FIG.

<도면의 주요부분에 대한 부호의 설명><Description of Symbols for Main Parts of Drawings>

1 : 초음파 진동판 2 : 초음파 진동실1: ultrasonic vibration plate 2: ultrasonic vibration chamber

3 : 회전분사장치 4 : 고주파 전기유도 가열망3: rotary spray device 4: high frequency electric induction heating network

5 : 고주파 유도가열코일 6 : 단열재5: high frequency induction heating coil 6: insulation material

7 : 고주파 유도가열로 8 : 고주파 유도가열실7: high frequency induction heating furnace 8: high frequency induction heating chamber

9 : 환원반응실 10 : 방열판9: reduction reaction chamber 10: heat sink

본 발명은 국제적으로 환경 공해의 문제거리가 되고 있는 폐변압기에서 발생되는 PCBs 폐오일 및 각종 산업현장에서 발생되는 폐오일을 2차 오염 물질인 다이옥신(PCD/DFS) Total PCBs 및 CO-PCBs, PAHs, PAHs, SOx, NOx와 기타 유해물질을 줄여 환경친화적으로 처리하고 재활용하는데 그 목적이 있다.The present invention relates to PCBs waste oil generated from waste transformers that are a problem of environmental pollution internationally and waste oils generated from various industrial sites as total pollutants such as dioxins (PCD / DFS) total PCBs and CO-PCBs, PAHs. The goal is to reduce environmental pollution, PAHs, SOx, NOx and other harmful substances.

폐오일은 1200℃에서 환원반응속도가 최고치에 달하나 2차 오염 물질인 다이옥신(Dioxins) SOx. NOx와 같은 유해물질 발생 없이 환원시키려면 폐오일을 고온 1300℃에서 공기를 차단시키고 밀폐된 공간 고주파 유도가열실에서 고온으로 산화반응 없이 환원시켜 일산화탄소와 수소농도가 높은 신재생에너지인 합성가스(Syngas/H2 + CO)를 만들고 PCBS 폐오일과 각종 산업현장에서 발생되는 폐오일의 유해물질을 줄여 환경친화적으로 처리하는 것이 본 고안의 기술적인 과제이다.Waste oil has the highest reduction reaction rate at 1200 ℃ but is the second pollutant, Dioxins SOx. Synthetic gas (Syngas) is a new renewable energy with high carbon monoxide and hydrogen concentration by reducing waste oil at high temperature of 1300 ℃ and reducing it to high temperature in a closed space high frequency induction heating chamber to reduce it without generating harmful substances such as NOx. / H 2 + CO) and reduce the harmful substances of waste oil generated from PCBS waste oil and various industrial sites and environmentally friendly treatment is a technical challenge of the present invention.

본 발명에서 도시한 바와 같이 초음파 진동실로 주입된 PCBs 폐오일의 유기물을 초음파를 이용, PCBs 폐오일을 이온시켜 분사노즐을 통해 고주파 유도가열실로 부양된 폐오일의 유기물을 고주파 유도가열실에서 1300℃의 고온으로 가열하여 고주파 유도가열실내에 여러층으로 설치되어 있는 고주파 전기유도가열망을 통과하면서 고주파 유도가열실내의 폐오일 온도를 균일하게 하여 환원반응 작용을 배가시켜 환원반응실로 부양시켜 환원반응실의 방열판이 여러개로 중첩되어 있는 방열판을 지나면서 흡열반응으로 온도가 낮춰져 환원반응으로 수소농도가 높은 신재생에너지인 합성가스(Syngas/H2 + CO)를 발생시킨다.As shown in the present invention, the organic material of waste PCBs injected into the ultrasonic vibration chamber is ionized using ultrasonic waves to ionize PCBs waste oil, and the organic matter of waste oil supported by the high frequency induction heating chamber through the spray nozzle is 1300 ° C. in the high frequency induction heating chamber. Heating at high temperature and passing through the high frequency electric induction heating network installed in multiple layers in the high frequency induction heating chamber to uniform the waste oil temperature in the high frequency induction heating chamber to double the reduction reaction to provide the reduction reaction chamber. As the heat sinks of several heat sinks pass through the heat sink, the temperature is lowered by the endothermic reaction to generate syngas (Syngas / H 2 + CO), a new renewable energy with high hydrogen concentration.

폐오일(-CH2) 유기물이 1300℃에서 산화반응 없이 환원반응할 경우 다음과 같은 화학식으로 반응이 진행된다.When the waste oil (-CH 2 ) organic material is reduced at 1300 ° C. without oxidation, the reaction proceeds as follows.

[화학식 Ⅰ][Formula I]

Figure 112006509042819-pat00001
Figure 112006509042819-pat00001

[화학식 Ⅱ][Formula II]

Figure 112006509042819-pat00002
Figure 112006509042819-pat00002

이와 같은 화학반응으로 2차 오염 물질 발생 없이 환경친화적으로 PCBs 폐오일을 처리하고 일산화탄소(CO)와 수소(H2)농도가 높은 신재생에너지인 합성가스(Syngas/H2 + CO)를 만들어 산업발전의 원동력인 발전기 터빈을 돌려 전기생산에 활용하는데 그 목적이 있다.Through this chemical reaction, wastewater is treated in an environmentally friendly way without generating secondary pollutants, and the synthesis gas (Syngas / H 2 + CO), a new renewable energy with high concentration of carbon monoxide (CO) and hydrogen (H 2 ), is produced. The purpose is to turn the generator turbine, which is the driving force of power generation, to be used for electricity production.

다음과 같은 목적을 달성하기 위해 본 발명은 PCBs 폐오일 처리방법 과 합성가스(Syngas/H2 + CO) 발생장치는 PCBs 폐오일의 유기물을 가스화 생성물인 일산화탄소와 수소농도가 높은 신재생에너지인 합성가스(Syngas/H2 + CO)를 만들어 재활용하고 제2차 오염 유해물질인 다이옥신(PCD/DFS) Total PCBs 및 CO-PCBs, PAHs, PAHs, SOx, NOx와 기타 유해물질을 줄여 환경친화적으로 처리하기 위한 방법의 폐오일 처리방법과 합성가스 발생장치에 관한 고안이다.In order to achieve the following objects, the present invention is a PCBs waste oil treatment method and a synthesis gas (Syngas / H 2 + CO) generator is a synthesis of carbon monoxide and hydrogen high renewable energy of the organic matter of PCBs waste oil synthesis Create and recycle gases (Syngas / H 2 + CO) and reduce environmental pollution by reducing total PCBs and CO-PCBs, PAHs, PAHs, SOx, NOx and other harmful substances as secondary pollutant The invention relates to a waste oil treatment method and a syngas generator.

1차 초음파 진동실에서 PCBs 폐오일을 이온시켜 고주파 유도가열실로 보내면 고주파 유도가열실 하단부에 분사노즐을 통해 고주파 유도가열실 내부로 품어서 부양시킨 PCBs 폐오일 및 산업폐기물 오일을 1300℃의 온도로 고주파 유도 장치가 온도를 높여주고 고주파 유도가열실 내부에 여러개의 층으로 쌓여 있는 고주파 유도발열체망이 고주파 유도가열실 내부 폐오일을 균일하게 온도를 높여 환원작용을 배가시켜 환원반응실로 부양시키면 환원반응실 내부의 방열판이 온도를 낮춰 환원반응을 일으켜 질 좋은 일산화탄소와 수소농도가 높은 신재생에너지인 합성가스(Syngas/H2 + CO)를 발생시키고 PCBs 폐오일 및 산업폐기물 오일을 환경친화적으로 처리되는 폐오일 처리방법 및 합성가스 발생장치에 관한 발명이 본 기술 분야의 목적이다.When PCBs waste oil is ionized in the first ultrasonic vibration chamber and sent to the high frequency induction heating chamber, PCBs waste oil and industrial waste oil, which are buried in the high frequency induction heating chamber by the injection nozzle at the bottom of the high frequency induction heating chamber, are raised to a temperature of 1300 ℃. When the high frequency induction device raises the temperature and the high frequency induction heating element network stacked in multiple layers inside the high frequency induction heating chamber raises the waste oil inside the high frequency induction heating chamber uniformly and doubles the reduction action to reduce the reaction. The heat sink inside the chamber lowers the temperature to generate syngas (Syngas / H 2 + CO), a new renewable energy with high carbon monoxide and high hydrogen concentration, and to treat PCBs waste oil and industrial waste oil environmentally. The present invention relates to a waste oil treatment method and a syngas generator.

밀폐된 공간에서 공기를 차단하고 PCBs 폐오일을 초음파와 고주파를 이용하여 1300℃ 온도를 일정하게 유지하여 산화반응 없이 2차 오염 물질인 다이옥신(PCD/DFS) Total PCBs 및 CO-PCBs, PAHs, PAHs, SOx, NOx와 기타 유해물질 발생을 줄이고 환경친화적으로 PCBs 폐오일을 처리하고 양질의 합성가스(Syngas/H2 + CO)를 생산하는 것이 기술적인 과제이다.Blocks air in an enclosed space and maintains PCBs waste oil at a constant temperature of 1300 ° C using ultrasonic waves and high frequency, so that dioxin (PCD / DFS) total PCBs and CO-PCBs, PAHs, PAHs are secondary pollutants without oxidation. The technical challenge is to reduce the generation of SOx, NOx and other harmful substances, to treat PCBs waste oil in an environmentally friendly manner, and to produce high quality syngas (Syngas / H 2 + CO).

PCBs 폐오일을 초음파로 이온시켜 고주파 유도 발열체와 가열체를 이용해 1300℃ 고온의 온도를 일정하게 유지하여 고주파 유도가열실 내에서 온도를 높여 환원반응실에서 흡열반응으로 산화반응 없이 합성가스(Syngas/H2 + CO)로 환원반응을 일으키는 것이 기술적인 과제이다.The waste oil of PCBs is ionized by ultrasonic waves to maintain a high temperature of 1300 ℃ using a high frequency induction heating element and a heating element to raise the temperature in the high frequency induction heating chamber, thereby increasing the temperature in the high temperature induction heating chamber. It is a technical problem to cause a reduction reaction with H 2 + CO).

이와 같은 과제를 이루기 위해 별도 독립된 초음파 진동실의 밀폐용기에서 밀폐용기 안에 초음파 진동판을 설치, 초음파로 PCBs 폐오일을 이온시켜 고주파 유도가열실 외벽에 고주파 발열체를 설치하고 고주파 유도가열실에 고주파 가열체를 만들고 고주파 유도가열실 내부에 고주파 유도발열체망을 여러개의 층으로 설치하여 고주파 유도가열실 내부에 지속적으로 1300℃의 균일한 온도를 만들어 환원반응을 배가시켜 고주파 유도가열실 하단에서 회전 분사장치를 설치해 폐오일을 부양시켜 산화반응 없이 환원반응시켜 환경친화적으로 2차 오염 물질인 다이옥신(PCD/DFS) Total PCBs 및 CO-PCBs, PAHs, PAHs, SOx, NOx와 기타 유해물질을 줄여 환경친화적으로 PCBs 폐오일을 처리하고 신재생에너지인 합성가스(Syngas/H2 + CO)를 만들어 전기 발전용 연료로 재활용하는 것이 기술적인 과제이다.In order to achieve this task, an ultrasonic diaphragm is installed in an airtight container in a separate ultrasonic vibration chamber, ionized PCBs waste oil by ultrasonic waves, a high frequency heating element is installed on the outer wall of the high frequency induction heating chamber, and a high frequency heating element in the high frequency induction heating chamber. And install a high frequency induction heating network in multiple layers inside the high frequency induction heating chamber to create a uniform temperature of 1300 ℃ continuously in the high frequency induction heating chamber to double the reduction reaction and to rotate the rotary spray device at the bottom of the high frequency induction heating chamber. By installing waste oil to reduce waste without oxidation reaction, it is environmentally friendly by reducing total pollution of dioxin (PCD / DFS), secondary pollution pollutants and CO-PCBs, PAHs, PAHs, SOx, NOx and other harmful substances. Treatment of waste oil and recycling of renewable energy as fuel for electric power generation by producing syngas (Syngas / H 2 + CO) This is a technical challenge.

도1은 폐오일 처리방법 과 합성가스 발생장치 전체단면도.1 is a cross-sectional view of a waste oil treatment method and a syngas generator.

이하 첨부된 도면에 의해 상세히 설명한 다면 다음과 같다.If described in detail by the accompanying drawings as follows.

도1-(2)는 초음파 진동실에서 PCBs 폐오일의 유기물을 초음파로 이온시켜 도1-(3)의 회전분사장치로 고주파 유도가열실(8)로 부양시켜 유입된 PCBs 폐오일이 고주파 유도가열실에서 1300℃로 온도를 높여 균일하게 고주파 유도가열망(4)에서 환원반응 작용을 배가시켜 환원반응실로 공급하여 환원반응실(9)로 들어가 환원반응실에서 흡열반응을 일으켜 방열판(10)으로 열을 낮추면 신재생에너지인 합성가스(Syngas/H2 + CO)가 발생된다.Fig. 1 (2) shows ultrasonic wave ionization of organic matter of PCBs waste oil in the ultrasonic vibration chamber, and the PCBs waste oil introduced into the high frequency induction heating chamber 8 by the rotary spraying device of Fig. Increasing the temperature to 1300 ℃ in the heating chamber to uniformly double the reduction reaction in the high frequency induction heating network (4) and feed it to the reduction reaction chamber to enter the reduction reaction chamber (9) to produce an endothermic reaction in the reduction reaction chamber (10). When the heat is lowered, new and renewable energy syngas (Syngas / H 2 + CO) is generated.

이와 같은 반응을 일으키기 위해 초음파와 고주파를 이용하여 고주파 유도가열실에서 지속적으로 1300℃ 온도를 유지해 PCBs 폐오일을 환원반응실로 부양시켜 수소농도가 높은 신재생에너지인 합성가스(Syngas/H2 +CO)를 만든다.In order to produce this reaction, by maintaining the temperature of 1300 ℃ continuously in the high frequency induction heating chamber by using ultrasonic waves and high frequency, the waste oil of PCBs is fed to the reduction reaction chamber to produce syngas (Syngas / H 2 + CO), a new renewable energy with high hydrogen concentration. )

고주파 유도가열실(8) 외벽에 고주파 유도가열코일(5)를 설치하고 초음파 진동실(2)내에 초음파 진동판을 설치(1)을 설치하여 초음파로 PCBs 폐오일을 이온시켜 회전분사장치(3)를 통해 고주파 유도가열실(8)로 부양시켜 PCBs 폐오일이 고주파 유도가열실 내에서 1300℃의 고온으로 지속적으로 온도를 높여 고주파 유도가열망(4)을 설치하여 지속적으로 균일하게 온도를 유지해 환원반응을 배가시켜 환원반응실로 부양시켜 흡열반응으로 환원반응을 일으켜 신재생에너지인 합성가스(Syngas/H2 + CO)를 발생시킨다.A high frequency induction heating coil (8) is installed on the outer wall of the high frequency induction heating coil (5) and an ultrasonic vibration plate (1) is installed in the ultrasonic vibration chamber (2) to ionize the PCBs waste oil with ultrasonic waves and rotate the spraying apparatus (3). By raising the high frequency induction heating chamber (8) through the PCB waste oil continuously raising the temperature to a high temperature of 1300 ℃ in the high frequency induction heating chamber by installing a high frequency induction heating network (4) to maintain a uniform temperature continuously The reaction is multiplied to support the reduction reaction chamber to generate a reduction reaction by endothermic reaction to generate syngas (Syngas / H 2 + CO), a renewable energy.

고온 1300℃를 지속적으로 유지하고 보온하기 위해 고주파 유도가열실(8) 외벽에 열 방출을 차단시키는 단열재(6)를 부착하고 온도를 균일하게 하기 위해 고주파 유도가열망을 고주파 유도가열실안에 설치하여 균일한 환원반응을 배가시킨다.In order to keep high temperature 1300 ℃ continuously and to insulate it, attach insulation material 6 to block heat release on outer wall of high frequency induction heating chamber 8 and install high frequency induction heating network in high frequency induction heating chamber to make temperature uniform. Double the uniform reduction reaction.

위와 같은 방법으로 수소농도가 높은 신재생에너지인 합성가스(Syngas/H2 + CO)를 얻고 폐오일도 2차 오염 물질 발생 없이 환경친화적으로 처리하는 발명의 구성이다.It is a configuration of the invention to obtain a synthesis gas (Syngas / H 2 + CO), a new renewable energy with a high hydrogen concentration in the above manner and to treat waste oil environmentally friendly without generating secondary pollutants.

이상에서 상술한 바와 같이 본 발명은 초음파와 고주파 유도장치를 이용하여 PCBs 폐오일을 초음파로 이온시키고 고주파 유도장치로 1300℃의 고온으로 밀폐된 용기에서 산화반응 없이 환원시켜 2차 오염 물질인 다이옥신(PCD/DFS) Total PCBs 및 CO-PCBs, PAHs, PAHs, SOx, NOx와 기타 유해물질을 줄이고 초음파 진동실, 고주파 유도가열실, 환원반응실을 통해 PCBs 폐오일을 환경친화적으로 처리하고 일산화탄소와 수소농도가 높은 신재생에너지인 합성가스(Syngas/H2 + CO)를 발생시켜 재활용 하고 환경친화적으로 PCBs 폐오일도 처리하는 두가지의 효과를 얻는 것이 발명의 효과이다.As described above, the present invention uses ultrasonic waves and high frequency induction apparatus to ionize PCBs waste oil with ultrasonic waves and dioxins as secondary pollutants by reducing them without oxidation in an airtight container at a high temperature of 1300 ° C. PCD / DFS) Total PCBs and CO-PCBs, PAHs, PAHs, SOx, NOx and other harmful substances are reduced, and environmentally friendly PCBs waste oil is treated through ultrasonic vibration chamber, high frequency induction heating chamber and reduction reaction chamber, and carbon monoxide and hydrogen The effect of the present invention is to obtain two effects of generating and recycling syngas (Syngas / H 2 + CO), which is a high concentration of renewable energy, and treating PCBs waste oil in an environmentally friendly manner.

Claims (2)

도1에서 초음파 진동실(2), 고주파 유도가열실(8), 환원반응실(9)이 수직으로 독립된 3실이 구성되어 있고 초음파 진동실(2)에서 초음파 진동판(1)이 폐오일을 이온시켜 회전분사장치(3)로 분사시켜 고주파 유도가열실(8)로 부양시켜 고주파 유도가열코일(5)로 1300℃로 지속적으로 열을 유지하고 고주파 유도가열망(4)을 설치하여 고주파 유도가열실의 온도를 균일하게 하여 환원반응을 배가시키는 장치 고주파 유도가열실로(7)를 단열재(6)가 지속적으로 열을 외부로의 방출을 단열시키고 산소를 차단시킨 밀폐된 용기안에서 산화반응 없이 환원반응 되게 하여 환원반응실(9)로 부양시켜 환원반응실 안에 방열판(10)을 설치해 열을 낮춰 환원반응으로 수소농도가 높은 신재생에너지인 합성가스(Syngas/H2 + CO)를 발생시키고 2차 오염 유해물질인 다이옥신(PCD/DFS) Total PCBs 및 CO-PCBs, PAHs, PAHs, SOx, NOx와 기타 산화물질을 줄여 환경친화적으로 폐오일도 처리하는 폐오일 처리방법 과 합성가스 발생장치.In FIG. 1, three chambers each consisting of the ultrasonic vibration chamber 2, the high frequency induction heating chamber 8, and the reduction reaction chamber 9 are vertically separated, and the ultrasonic vibration plate 1 in the ultrasonic vibration chamber 2 is used for the waste oil. Ionized and sprayed into the rotary spraying device (3) to support the high frequency induction heating chamber (8) to continuously maintain the heat at 1300 ° C with the high frequency induction heating coil (5), and to install the high frequency induction heating network (4) A device that doubles the reduction reaction by making the temperature of the heating chamber uniform. The high-frequency induction heating furnace 7 reduces heat without the oxidation reaction in a sealed container insulated from the heat of the heat by the insulation material 6 and blocks oxygen. It is made to react to support the reduction reaction chamber (9) to install a heat sink (10) in the reduction reaction chamber to lower the heat to generate a synthesis gas (Syngas / H 2 + CO), a new renewable energy of high hydrogen concentration by the reduction reaction 2 Dioxin (PCD / DFS) Waste oil treatment method and syngas generator to treat waste oil environmentally by reducing tal PCBs and CO-PCBs, PAHs, PAHs, SOx, NOx and other oxides. 청구항 1에서 초음파 진동실(2)의 초음파 주파수(kHz)와 음강도(W/IN2)를 조작할 수 있는 콘트롤(control) 부착.With a control that can operate the ultrasonic frequency (kHz) and the sound intensity (W / IN 2 ) of the ultrasonic vibration chamber (2) in claim 1. 고주파 유도가열실(8)의 고주파 유도가열장치에 있어서 고주파 주파수의(kHz) 조작콘트롤 형성.Operation control of high frequency frequency (kHz) is formed in the high frequency induction heating apparatus of the high frequency induction heating chamber (8). 환원반응실(9) 외부의 감겨져있는 폐오일 유입관이 환원반응실의 열을 식혀주고 환원반응실의 열을 받아 초음파진동실로 들어가는 유입폐오일의 열을 올려주는 장치.Reduction reaction chamber (9) A device in which the waste oil inlet pipe wound outside of the cooling chamber cools the heat of the reduction reaction chamber and receives the heat of the reduction reaction chamber to raise the heat of the inflow waste oil entering the ultrasonic vibration chamber. 회전분사장치(3)에 있어서 회전분사장치와 막대관으로 형성되어 여러개의 구멍으로 형성된 형태.In the rotary spraying device (3) is formed of a rotary spraying device and a rod tube formed of a plurality of holes.
KR1020060112009A 2006-11-14 2006-11-14 weste oil by microbialbioprocessing synthesis producer. KR100693829B1 (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4056483A (en) 1975-07-18 1977-11-01 Metallgesellschaft Aktiengesellschaft Process for producing synthesis gases
KR870011229A (en) * 1986-05-08 1987-12-21 박만철 Method and apparatus for producing flammable synthetic fuel gas from water and oil
CN1065923A (en) 1992-05-06 1992-11-04 四川康迪技术实业公司 Gasification stove
KR20040020893A (en) * 2001-04-27 2004-03-09 데이비드 시스템즈 앤드 테크놀로지, 에스. 엘. Method for plasma catalytic conversion of fuels usable in an internal combustion engine of gas turbine into a synthesis gas and the plasma catalytic converter therefor
KR20050015077A (en) * 2003-08-01 2005-02-21 김현영 Method of gasifying carbonaceous material and apparatus therefor
KR100636853B1 (en) 2002-05-08 2006-10-19 로우 에드먼드 킨 온 Hazardous waste treatment method and apparatus

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4056483A (en) 1975-07-18 1977-11-01 Metallgesellschaft Aktiengesellschaft Process for producing synthesis gases
KR870011229A (en) * 1986-05-08 1987-12-21 박만철 Method and apparatus for producing flammable synthetic fuel gas from water and oil
CN1065923A (en) 1992-05-06 1992-11-04 四川康迪技术实业公司 Gasification stove
KR20040020893A (en) * 2001-04-27 2004-03-09 데이비드 시스템즈 앤드 테크놀로지, 에스. 엘. Method for plasma catalytic conversion of fuels usable in an internal combustion engine of gas turbine into a synthesis gas and the plasma catalytic converter therefor
KR100636853B1 (en) 2002-05-08 2006-10-19 로우 에드먼드 킨 온 Hazardous waste treatment method and apparatus
KR20050015077A (en) * 2003-08-01 2005-02-21 김현영 Method of gasifying carbonaceous material and apparatus therefor

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