KR100672880B1 - 개선된 동결 안정성을 갖는 액체 mdi 부가물 - Google Patents

개선된 동결 안정성을 갖는 액체 mdi 부가물 Download PDF

Info

Publication number
KR100672880B1
KR100672880B1 KR1020010005540A KR20010005540A KR100672880B1 KR 100672880 B1 KR100672880 B1 KR 100672880B1 KR 1020010005540 A KR1020010005540 A KR 1020010005540A KR 20010005540 A KR20010005540 A KR 20010005540A KR 100672880 B1 KR100672880 B1 KR 100672880B1
Authority
KR
South Korea
Prior art keywords
weight
isomer
group content
nco group
mdi
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020010005540A
Other languages
English (en)
Korean (ko)
Other versions
KR20010078337A (ko
Inventor
피터 에이치. 마쿠쉬
리차드 에스. 판톤
랄프 구에터
윌리엄 이. 슬랙
Original Assignee
바이엘 코포레이션
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 바이엘 코포레이션 filed Critical 바이엘 코포레이션
Publication of KR20010078337A publication Critical patent/KR20010078337A/ko
Application granted granted Critical
Publication of KR100672880B1 publication Critical patent/KR100672880B1/ko
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/80Masked polyisocyanates
    • C08G18/8003Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8006Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
    • C08G18/8009Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
    • C08G18/8012Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with diols
    • C08G18/8019Masked aromatic polyisocyanates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
    • C08G18/667Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/7806Nitrogen containing -N-C=0 groups
    • C08G18/7818Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7837Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing allophanate groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020010005540A 2000-02-07 2001-02-06 개선된 동결 안정성을 갖는 액체 mdi 부가물 Expired - Fee Related KR100672880B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/499,603 2000-02-07
US09/499,603 US6242556B1 (en) 2000-02-07 2000-02-07 Liquid MDI adducts with improved freeze stability

Publications (2)

Publication Number Publication Date
KR20010078337A KR20010078337A (ko) 2001-08-20
KR100672880B1 true KR100672880B1 (ko) 2007-01-23

Family

ID=23985920

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020010005540A Expired - Fee Related KR100672880B1 (ko) 2000-02-07 2001-02-06 개선된 동결 안정성을 갖는 액체 mdi 부가물

Country Status (11)

Country Link
US (1) US6242556B1 (enExample)
EP (1) EP1122270B1 (enExample)
JP (1) JP2001220422A (enExample)
KR (1) KR100672880B1 (enExample)
AR (1) AR030047A1 (enExample)
AT (1) ATE266052T1 (enExample)
BR (1) BR0100365A (enExample)
CA (1) CA2331469C (enExample)
DE (1) DE60103090T2 (enExample)
ES (1) ES2219442T3 (enExample)
MX (1) MXPA01001362A (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040077773A1 (en) * 2002-07-12 2004-04-22 Tavares Manuel J Low viscosity, flexible, hydrolytically stable potting compounds
US7790907B2 (en) * 2006-07-21 2010-09-07 Basf Corporation Method of producing a uretonimine-modified isocyanate composition
US20080085987A1 (en) * 2006-10-05 2008-04-10 Thomas Savino Method of producing a uretonimine-modified isocyanate composition
US7666971B2 (en) * 2006-11-14 2010-02-23 Bayer Materialscience Llc Amide/urea-modified liquid diphenylmethane diisocyanates
US7632911B2 (en) * 2006-11-14 2009-12-15 Bayer Materialscience Llc Liquid modified diphenylmethane diisocyanates
US20080227878A1 (en) * 2007-03-14 2008-09-18 James Garrett Trimer and allophanate modified isocyanates, a process for their production, foams comprising these modified isocyanates, and a process for the production of these foams
US20090030161A1 (en) * 2007-07-27 2009-01-29 Bayer Materialscience Llc Allophanate modified diphenylmethane diisocyanates, prepolymers thereof, and their use in the preparation of polyureas and polyurethanes
DE102008045223A1 (de) 2007-11-20 2009-05-28 Bayer Materialscience Ag Polyurethan-/Polyharnstoff-Elastomere auf Basis von 2,4'-Diphenylmethandiisocyanat-Prepolymeren und ihre Herstellung
US20090156777A1 (en) * 2007-12-17 2009-06-18 Nodelman Neil H Freeze-stable aromatic diisocyanates and processes for the preparation of these freeze-stable products
CN103502296B (zh) 2011-04-15 2015-11-25 H.B.富勒公司 改性的二苯甲烷二异氰酸酯基粘合剂
EP3438158B1 (de) * 2017-08-01 2020-11-25 Evonik Operations GmbH Herstellung von sioc-verknüpften polyethersiloxanen

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3152162A (en) 1959-07-29 1964-10-06 Bayer Ag Polyisocyanate-carbodiimide adducts and process for the production thereof
GB994890A (en) 1961-12-18 1965-06-10 Ici Ltd New organic polyisocyanates and their manufacture
US3384653A (en) 1965-03-31 1968-05-21 Upjohn Co Compositions of methylenebis (phenyl isocyanate) with trihydrocarbyl phosphates and preparation thereof
US3449256A (en) 1966-01-19 1969-06-10 Upjohn Co Methylenebis(phenyl isocyanate) compositions and preparation thereof
DE1618380C3 (de) 1967-03-08 1975-09-11 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung eines bei Raumtemperatur flüssigen Diphenylmethan-diisocyanatpräparates
GB1194050A (en) 1967-12-12 1970-06-10 Ici Ltd Liquid Diphenylmethane Diisocyanate Compositions
GB1200432A (en) 1968-01-25 1970-07-29 Bayer Ag Process for the preparation of polyisocyanates which contain a carbodiimideisocyanate adduct
US3701796A (en) 1970-09-29 1972-10-31 Upjohn Co Storage stable methylenebis (phenyl isocyanate) compositions
NL178871C (nl) 1972-09-26 Ici Ltd Werkwijze voor het bereiden van een vloeibaar difenylmethaandiisocyanaatproduct en voor het bereiden of vervaardigen van een polyurethaan onder toepassing van een dergelijk isocyanaatproduct.
GB1476088A (en) 1975-04-03 1977-06-10 Ici Ltd Carbodiimides
GB1483957A (en) 1975-05-19 1977-08-24 Ici Ltd Diphenylmethane diisocyanate compositions
US4055548A (en) 1976-09-17 1977-10-25 The Upjohn Company Storage-stable liquid polyisocyanate composition
US4118411A (en) * 1977-02-09 1978-10-03 Mobay Chemical Corporation Low-temperature storage stable liquid diphenylmethane diisocyanates
DE4403233A1 (de) * 1994-02-03 1995-08-10 Bayer Ag Oberhalb 5 DEG C flüssige Polyisocyanatmischungen
CA2207468A1 (en) * 1996-07-15 1998-01-15 Edmund J. Madaj Water blown polyurethane integral skin foam having improved abrasion resistance
US5874485A (en) * 1997-11-10 1999-02-23 Bayer Corporation Flexible foams and flexible molded foams based on allophanate-modified diphenylmethane diisocyanates and processes for the production of these foams

Also Published As

Publication number Publication date
DE60103090D1 (de) 2004-06-09
ES2219442T3 (es) 2004-12-01
JP2001220422A (ja) 2001-08-14
CA2331469A1 (en) 2001-08-07
KR20010078337A (ko) 2001-08-20
EP1122270B1 (en) 2004-05-06
CA2331469C (en) 2009-04-07
DE60103090T2 (de) 2009-10-01
AR030047A1 (es) 2003-08-13
EP1122270A1 (en) 2001-08-08
US6242556B1 (en) 2001-06-05
MXPA01001362A (es) 2002-08-06
BR0100365A (pt) 2001-10-02
ATE266052T1 (de) 2004-05-15

Similar Documents

Publication Publication Date Title
US4031026A (en) Diphenylmethane diisocyanate compositions
EP0013487B2 (en) Modified diisocyanate compositions and polyurethanes thereof
EP0998509B1 (en) Improved water blown polyurethane soling systems
US4332742A (en) Low temperature storage stable liquid diphenylmethane diisocyanates
US6784219B2 (en) Polyurethane cast elastomers based on durene diisocyanate
AU650134B2 (en) Polyisocyanate composition
CA1234830A (en) Liquid diphenylmethane diisocyanate compositions
FR2488897A1 (fr) Procede de preparation d'un elastomere de polyurethane par moulage par injection avec reaction et article faconne obtenu par ce procede
KR100672880B1 (ko) 개선된 동결 안정성을 갖는 액체 mdi 부가물
JPH0238583B2 (enExample)
US5686042A (en) Rim process using liquid methylene diphenyl diisocyanate
HUP0301393A2 (hu) Difenil-metán-diizocianát kompozíciók
US6277943B1 (en) One-shot polyurethane elastomers with very low compression set
JPH07149857A (ja) 液体ジフェニルメタンジイソシアネート並びにその製造および使用方法
EP1122271B1 (en) Process for the preparation of polyisocyanate compositions based on MDI with improved freeze stability
EP0819715A1 (en) Water blown polyurethane integral skin foam having improved abrasion resistance
US20020123594A1 (en) Polyurethane prepolymers and polyurethane elastomers based on 1,4-naphthalene diisocyanate
US5753750A (en) Toluene diisocyanate residue-based compositions as fillers for polyisocyanates
US5789497A (en) Hexamethylene diisocyanate residue-based compositions as fillers for polyether polyols
US5739207A (en) Hexamethylene diisocyanate residue-based compositions as fillers for polyisocyanates
US6583314B2 (en) Stable isocyanate formulations
FR2475456A1 (fr) Procede de fabrication de polyurethanes moules par injection avec reaction presentant un rendement catalytique ameliore
JPH10504299A (ja) 4,4’−メチレン−ビス(3−クロロ−2,6−ジアルキルフェニルイソシアネート)
MXPA97005224A (en) Comprehensive foam for polyurethane skin insuffled with water that has better abrasive resistance

Legal Events

Date Code Title Description
PA0109 Patent application

St.27 status event code: A-0-1-A10-A12-nap-PA0109

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U11-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

FPAY Annual fee payment

Payment date: 20110111

Year of fee payment: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20120117

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20120117