KR100666158B1 - Water treatment apparatus - Google Patents

Abstract

An object of the present invention is to provide an apparatus for producing microorganisms and physiologically active water. The present invention is an apparatus for producing water capable of maintaining physical properties even when the physical properties of the redox potential ORP (mV) and the O ¹⁷ -NMR half width are diluted 60,000 times or more, and water-permeable ceramics containing carbon are laminated in the flow path. And a tank (2) provided with a circulation pump in a circulation path (1) in which an active cylinder (20) formed in the air and an active cylinder (30) formed by filling a flow path with carbon-containing ceramics in a flow path are disposed. The water treatment apparatus characterized by the above-mentioned.

Microorganism, bioactive water

Description

Water treatment device {WATER TREATMENT APPARATUS}

1 is a schematic diagram of a bioactive water production system according to the present invention.

FIG. 2 is a cross-sectional schematic diagram illustrating an interior of a first active cylinder in the manufacturing system of FIG. 1. FIG.

3 is a cross-sectional schematic diagram illustrating an interior of a second active cylinder in the manufacturing system of FIG. 1.

4 is a front view of a partition wall used in the second active cylinder of FIG. 3.

FIG. 5 is a front view of the ceramic plate combination used in the second active cylinder of FIG. 3. FIG.

6 is a cross-sectional schematic diagram illustrating an interior of a third active cylinder in the manufacturing system of FIG. 1.

7A and 7B are micrographs of ceramics A and B used in the second and third active cylinders, respectively.

8 is a graph for explaining O ¹⁷ -NMR spectrum half width.

9 is a graph showing the relationship between ORP-pH of water.

*** Description of Major Reference Code ***

1: circulation path 2: circulation pump

10: first active barrel 15: stainless steel chain

20: second active cylinder 26: ceramic span

30: third active barrel 35: ceramics ball

The present invention relates to an apparatus for treating water excellent in microbial activity and physiological activity, and provides an apparatus capable of producing water capable of maintaining physical properties represented by redox potential and O ¹⁷ -NMR half width even when diluted to 60,000 times or more. It is characterized by.

Conventionally, various apparatuses, such as an ionized water generator, a water magnetization apparatus, and a ceramics treatment apparatus, are proposed as a water treatment apparatus. Particularly, ceramics are used to fill an ozone gas reaction layer with alumina ceramics to improve the contact area and to treat ozone (Japanese Patent Laid-Open No. 2001-121168), and to ionize water using bioceramic (Japan Patent Publication No. 2003-305464) has been proposed.

Conventional methods have been aimed at oxidizing, reducing, ionizing or minimizing water, but cannot be said to be a fundamental physical modification method of water. This is because such physical property is owned only by the water and is not propagated, and also the physical property easily changes with time or by heat treatment.

For example, a method of breeding microorganisms to create an environment or a symbiotic system for the microorganisms to work effectively has been proposed.However, in the sludge treatment method that effectively utilizes the microorganisms, how to provide an environment in which the microorganisms are easily activated is important It is a task. However, in order to create an environment in which microorganisms are easy to activate, inexpensively and extensively, the water to be added needs to have the ability to automatically correct the environment, which is not possible with conventional water.

Therefore, an object of the present invention is to provide a device capable of producing water having the ability to maintain and propagate desirable physical properties.

In the present invention, water is aged using fermentation enzymes such as Shiozyme (trade name), and then filtered or contacted with specific ceramics to form physical properties represented by specific redox potentials and O ¹⁷ -NMR half widths. The physical properties of the present invention have been completed in the face of an unpredictable effect of sustained propagation even when diluted at a magnification of 60,000 times or more.

The present invention is an apparatus for producing water capable of maintaining physical properties even when the physical properties of the redox potential and the O ¹⁷ -NMR half width are diluted to 60,000 times or more, wherein water-permeable ceramics containing carbon are laminated in a flow path. The tank 2 provided with a circulation pump is arrange | positioned in the circulation path 1 which arrange | positioned the active cylinder 20 and the active cylinder 30 which fills the flow path with the ceramics of particle shape containing no carbon in series. It is a water treatment apparatus characterized by the above-mentioned.

In such a water treatment apparatus, it is preferable to arrange the auxiliary active cylinder 10 having a flow path wound with a stainless chain upstream of the active cylinder 20 in view of physical properties of the water to be produced.

It is not clear how the physical properties of the redox potential of the raw water and the O ¹⁷ -NMR half width can be maintained even by diluting 60,000 to 3.6 million times by the above apparatus.

It is not clear whether this property indicates a relationship with the cluster size of water, but the signal width of at least O ¹⁷ -NMR is the spectral half-width of the NMR (nuclear magnetic resonance) signal of the nucleus of the quadrupole moment (see FIG. 8). Because of the change in chemical bonds to the observed nuclei and the ligands, they reflect the observed nucleus, that is, the electronic state constituting the water, which is thought to contribute to the high activity of the water and to the reaction and absorption. On the other hand, ORP (redox potential) of water is represented as shown in FIG. 9 as a function of pH. That is, based on the formula of Nernst, the oxidative decomposition of water: O ₂ + 4H ⁺ + 4e ⇔ 2H ₂ O is represented by ORP = 1.23-0.059pH in formula 1, and the reductive decomposition of water: 2H ⁺ + 2e ⇔ H ₂ is represented by ORP = -0.059pH in Equation 2, but in relation to this the equilibrium ORP-pH relation of water is experimentally given as ORP = 0.84-0.047pH in Equation 3 In the region, it is considered to be an index indicating the presence of active hydrogen. Therefore, in a reduction system having a pH of 7 or higher and an oxidation-reduction potential ORP (mV) of 840-47 pH or less, the physical property of O ¹⁷ -NMR half width of 100 Hz or less is a physical property index indicating the microbial activity and the physiological activity of the water of interest. It is considered to be suitable as.

Due to such physical properties, dilution water obtained by diluting the raw water having the above-described physical property retention ability to 60,000 to 3.6 million times is useful as sludge decomposition water because it has activity against microorganisms including fermented bacteria. Therefore, the stream can be purified by continuously dropping or intermittently administering to the stream. Moreover, in the sludge treatment plant, microorganisms can be activated by continuous dropwise or intermittent administration to decompose sludge. The same applies to household septic tanks.

On the other hand, since the dilution water has a physiological activity, it is particularly used as a beverage, and as a result of having excellent penetration into the cells of the body, it exhibits various constitution improvement effects. Therefore, when used as a solution for oral or injectable drug delivery, and extracts such as collagen and ginseng, various minerals, and various drugs are used, the cellular absorption in the body is increased, which is effective for improving the drug efficacy. In addition, the cosmetic product containing dilution water obtained by diluting the raw water having the above-described physical property maintaining ability to 60,000 to 3.6 million times is excellent in the skin penetration function of the drug using the dilution water as a medium. Therefore, it is useful as a support | carrier of the cosmetic mask agent which makes water-soluble collagen an essential component, and the transdermal adhesive agent which makes an essential component a transdermal agent an essential component.

Hereinafter, the present invention will be described in detail according to a preferred embodiment.

It is preferable to manufacture the active water which has the said physical property by the following method, and the following manufacturing apparatus is used.

The method comprises the steps of mixing the fermentation enzyme in a ratio of 10: 1 to 5 by weight with respect to water, retaining and aging under UV light or sunlight irradiation for 5 to 10 days,

The aged water is filled by filling the flow path with the first active cylinder 10 having a flow path wound with a stainless chain, the second active cylinder 20 formed by laminating an equilateral triangle plate ceramics in the flow path, and the granular ceramics. A process of treating with a processing apparatus (see FIG. 1) formed by disposing a tank 2 having a circulation pump in a circulation path 1 in which the third active cylinder 30 is arranged in series;

The process water is diluted to 60,000-3 million times using raw water obtained.

It is preferable to use the same kind as the fermentation enzyme mixed in order to ferment the clay and the fermentation enzyme used in the aging step. As the fermentation enzyme, a pineapple enzyme such as shiozyme supported on zeolite can be appropriately used.

As shown in FIG. 2, the 1st active cylinder 10 used at the said process process consists of the longitudinally long inner cylinder 11 and the outer cylinder 12, The inlet 13 is provided at one end and the other end. In the flow passage 16 having an outlet 14 in the inner and outer cylinders, stainless chains 316L and 15 are wound around the inner cylinder 11 so as to be in contact with the treated water flowing through the flow passage.

As shown in FIG. 3, the second active cylinder 20 has a partition plate 24 having a plurality of perforations showing the inlet portion 22 and the outlet portion 23 at both ends of the longitudinally long outer cylinder 21. And a central axis 25 extending in the longitudinal direction, in which the equilateral triangular ceramic plate 26 is rotated by 60 ° as shown in FIG. Then, several sheets are stacked and arranged in the longitudinal direction to form six flow paths 27 around the periphery.

The ceramic plate 26 is a mixture of carbon particles and fermentation enzymes 3: 1: 1 in Japanese Hiroshimaken Saizo fatty acid clay and fermented for about one week, and then formed into an equilateral triangle having a thickness of 10 mm, at around 500 to 600 ° C. It is prepared by heating and sintering.

Such ceramics have a fine porous structure and are excellent in water permeability (micrograph of FIG. 7A), and contain the elements shown in Table 1 below (except for carbon content).

Table 1

SiO ₂ : 71.4 wt% Al ₂ O ₃ : 22.9 wt%

K ₂ O: 2.32 wt% CaO: 1.11 wt%

Fe ₂ O ₃ : 1.02wt% TiO ₂ : 0.452wt%

Na ₂ O: 0.414 wt% MgO: 0.119 wt%

V ₂ O ₅ : 0.0718wt% P ₂ O ₅ : 0.0704wt%

SO ₃ : 0.0639wt% Cr ₂ O ₃ : 0.0241wt%

MnO: 0.0155wt% NiO: 0.0135wt%

Cl: 0.0116 wt% ZrO ₂ : CuO: SrO: ZnO: Rb ₂ O: Trace

As shown in FIG. 6, the third active cylinder 30 is partitioned by a partition plate 34 having a plurality of perforations shown in FIG. 4 at both ends of the longitudinally long outer cylinder 31 to form an inlet portion 32 and an outlet. Part 33 is provided, and in the middle thereof is partitioned by partition plates 34 having a plurality of perforations as described above, and granular ceramics BRC-22 (diameter 10 mm) manufactured by J. BIA Co., Ltd. 35). The photomicrograph is shown in FIG. 7B. The ceramics contain the elements shown in Table 2 below.

TABLE 2

SiO ₂ : 57.6wt% Al ₂ O ₃ : 34.7wt%

K ₂ O: 4.16 wt% Na ₂ O: 1.21 wt%

CaO: 0.918 wt% Fe ₂ O ₃ : 0.491 wt%

TiO ₂ : 0.407wt% MgO: 0.217wt%

P ₂ O ₅ : 0.185wt% ZnO: 0.0743wt%

ZrO ₂ : 0.0562wt% Rb ₂ O: 0.0167wt%

SrO: Trace

As the water to be treated, 50 to 150 ml of the aged water is added per 20 liters of water, and the water is circulated in the circulation passage 1 having the first to third active cylinders for 30 minutes to 1 hour for treatment. Let this be your enemy.

This raw water is contacted to prepare raw water, which is diluted 60,000 to 3.6 million times.

As the dilution water, chlorine-treated tap water may be used, but in order to maintain and store the active hydrogen in the dilution water, it is preferable that the chlorine-treated ground water or mineral water is used.

(Example 1)

When the raw water treated in the first, second and third active cylinders is diluted with groundwater, O ¹⁷ -NMR half width 100 Hz in a reducing system having a pH of 7 or more and an oxidation-reduction potential ORP (mV) of 840-47 pH or less. It shows the physical properties before and after, and can maintain the said physical properties even if it dilutes 60,000 times-3.6 million times, and the half value width may obtain the favorable value by dilution.

1) water diluted 1000 times with groundwater, 2) magnetized water, 3) water of heater, 4) tap water, 5) water diluted 1.5 million times with raw water, 6) 60,000 times with raw water The redox potentials and O ¹⁷ -NMR half-value widths of 8 types of water of dilute water, 7) groundwater, and 8) AC5 (adding 10-30% of quicklime to raw water and diluting 60,000 times) were as follows.

Water 1), 5) and 6), which were diluted with groundwater, were almost neutral and had a redox potential of 160 to 300 mV. In particular, water diluted 60,000 times of 6) showed the lowest redox potential. This value was almost equal to or lower than that of other natural waters, overwhelmingly lower than that of other treated waters, and also 600 mV in tap water.

On the other hand, the O ¹⁷ -NMR half-width was 100 Hz or less for water 1), 5) and 6), which were the raw water diluted with groundwater, and 6) 60,000-fold dilution water showed values around 60 Hz. In other waters, the water in the heater showed a value around 100 Hz, but the other values were almost 120 to 130 Hz.

When the dilution water was changed to tap water (redox potential 250 mV), the redox potential was 200-250 mV, which was not significantly different from this tap water, but most of the O ¹⁷ -NMR half-value width measurements were 100 Hz or less. Considering that the half width of the tap water is 125 to 130 Hz, it was confirmed that even if the tap water was diluted 60,000 to 3.6 million times, there was no change in physical properties and desirable properties were maintained.

In the reduction system is a water diluting the raw water of the present invention from the above, pH 7 or higher and oxidation-reduction potential ORP (mV) represented by the following 840-47pH, O ¹⁷ -NMR 100Hz full width at half maximum of less than the physical properties, 6 million times - It was found that it can be maintained even after diluting 3.6 million times.

As will be apparent from the above description, according to the production apparatus according to the present invention, water having a physical property retention function can be produced.

Claims (7)

A device capable of producing water capable of maintaining physical properties even after diluting from 60,000 times or more to 360 million times or less, comprising: an active cylinder 1 having a flow path wound with a stainless chain 15 and ceramics having a porous structure containing carbon. The tank 2 provided with a circulation pump is arrange | positioned in the circulation path 1 which arrange | positioned the active cylinder 20 laminated | stacked on the flow path, and the active cylinder 30 which fills the flow path with ceramics containing no carbon in a flow path. Water treatment apparatus, characterized in that consisting of. delete The method of claim 1, The active cylinder 20 is installed by partitioning the inlet portion 22 and the outlet portion 23 into the partition plate 24 having a plurality of perforations at both ends of the longitudinally long outer cylinder 21, in the middle of the longitudinal direction The central axis 25 extending in the direction is provided, and the combination of the equilateral triangular ceramic plate 26 in a state rotated by 60 ° is provided, and a plurality of sheets are stacked in the longitudinal direction, whereby six flow paths 27 Water treatment device formed by forming a). The method of claim 3, wherein The ceramic plate (26) is a water treatment apparatus which is prepared by mixing carbon particles and fermentation enzymes in clay and fermenting them, followed by heating and sintering at around 500 to 600 ° C. The method of claim 1, The active cylinder 30 is partitioned by partition plates 34 having a plurality of perforations at both ends of the longitudinally long outer cylinder 31 to install the inlet portion 32 and the outlet portion 33, in the middle of the plurality of The water treatment apparatus which divides into the partition plate 34 which has a perforation, and is filled with the ceramics 35 in each compartment. The method of claim 1, The active cylinder 10 is composed of a vertically long inner cylinder 11 and an outer cylinder 12, having an inlet 13 at one end and an outlet 14 at the other end thereof, The water treatment apparatus 16 is arrange | positioned by winding the stainless chain 15 in the inner cylinder 11, and contacting the to-be-processed water which flows through a flow path. delete

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