CN104086034B - Environment-friendly type super oxidation depth purifying direct drinking processing method and processing device - Google Patents
Environment-friendly type super oxidation depth purifying direct drinking processing method and processing device Download PDFInfo
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- CN104086034B CN104086034B CN201410256837.2A CN201410256837A CN104086034B CN 104086034 B CN104086034 B CN 104086034B CN 201410256837 A CN201410256837 A CN 201410256837A CN 104086034 B CN104086034 B CN 104086034B
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- 239000003651 drinking water Substances 0.000 claims abstract description 53
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- Physical Water Treatments (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
The invention discloses environment-friendly type super oxidation depth purification direct-drinking water process reaches the method and device of direct drinking.Method comprises to make the drinking water in entrance tank body to form the full flow regime of overall maelstrom, locally little vortex, and drinking water is carried out with 6 processes such as disinfection by ultraviolet light process；Device includes the first water cavity and the second water cavity connected with the first water cavity, the overall flow spoiler of setting first in the first water cavity；Several first quartz socket tubes are encapsulated, in the first quartz socket tube, encapsulation wavelength is first quartz burner of 185nm in first water cavity；Setting first game portion flow spoiler outside first quartz socket tube；The outer surface of the inwall of the first water cavity, the first overall flow spoiler and the first local flow spoiler includes the electrodeposited coating of high grade oxidation catalytic agent, several second quartz socket tubes are encapsulated, in the second quartz socket tube, encapsulation wavelength is second quartz burner of 253.7nm in second water cavity；The inwall of the second water cavity is minute surface.Present configuration is simple, broad-spectrum high efficacy, thoroughly prevent secondary pollution, ensures water quality safety.
Description
Technical field
The present invention relates to a kind of processing method of drinking water, carry out super oxidation, deep purifying particularly to drinking water
Process the method reaching direct drinking, the invention still further relates to a kind of processing meanss of drinking water, surpass particularly to drinking water
Level oxidation, deep purifying process the device reaching direct drinking.
Background technology
The composition of the drinking water water supply system of resident living cell in China city：By water head site → tap water supply factory →
City water transfer pipe network → secondary water-supply equipment → terminal resident.
After waterworks carries out a series of purifying sterilizing process to water source, drinking water is sent into urban pipe network, in order to anti-
Only antibacterial invades the procreation growth of tap water water transfer pipe network, and tap water needs before dispatching from the factory to add certain density chlorine residue, carries out disinfection and kill
Go out antibacterial, therefore dosage that add harmful due to chlorine residue is few, to guarantee chlorine residue consumption or volatilization before reaching the user
Finish；But in reality, due to sparge pipe linear distance, the addition of chlorine residue and the bad control of residual volume；Further, sparge pipe
Linear distance is long, so that a large amount of dissolving of ferro-compound is constantly diffused in pipe network, so that iron content in water is greatly increased, cause
Tap water quality standard reduces, and defines polluter.And present China major part urban pipe network present situation is because quantities is great and money
The each side factor such as gold, road cannot be transformed, water quality heavily contaminated present situation sustainable development in pipe network, affects water quality safety.
On the other hand, pipe network water source reaches urban life residential area needs to carry out secondary water-supply, and traditional secondary supplies water and stores up
Wetting system is mainly supplied water to urbanite by tank, water storage box, water tank type frequency-changing water supply device, pipe network Pressure-superposed water supply equipment,
But due to needing drinking water to be stored and regulating pondage, and the voltage stabilizing in transmitting procedure and decompression demand, need to arrange
The tank such as water tank or water pot, because the delay of water, aeration, makes these tanks cause the second pollution to drinking water
Source, concrete way of supplying water and process are：Skyscraper is typically equipped with supply equipment in basement, is derived from break tank storage
The tap water of city planting ductwork, then taken out by water pump rise to roof elevated tank or intermediate water tank decompression after shunting deliver to each user, or
Each user is fed directly to using pump group pressurization by storage tank, tap water, in this storing process twice, have passed through double exposure,
Consume the chlorine residue in water, community resident resident population quantity cannot be fixed and be controlled in addition, cause cistern, water storage box long-term
Water-retention, leads to water quality severe contamination, deterioration, spoiled, variable color, fouling, grows harmful algae and antibacterial, water pollution once again is tight
Weight；This is the subject matter that secondary water-supply presently, there are.Another secondary water-supply equipment is no negative pressure and water distribution system flushing
Equipment, though these not standby tank-free, water tanks, these equipment are designed with current stabilization water storage boost pressure regulation tank, to the dirt from pipe network
Dye water source does not all have corresponding water treatment technology and sterilization safeguards technique, simply achieves pressurization for the needs in water level,
And can't resolve the problem of water pollution, do not ensure water quality safety.Relevant urban health department once had testing result to show, from
Come water factory and direct water supply network tip water quality qualification rate be more of a relatively high, and secondary water-supply water quality qualification rate be only 50%～
73%.According to statistics, there are about 80% disease relevant with drinking unsafe water, serious harm China urbanite body and mind be good for
Health.
In terms of rural potable water, the vast drinking water in rural China pollution situation of China also allows of no optimist, in agricultural production
The use of long-term pesticide and chemical fertilizer in a large number, the superposition of domestic pollution and industrial pollution in addition, further, since rural residence dispersion,
The safeguard such as regulator dynamics and monitoring technology level is difficult to implement, and the water quality situation of vast rural area is all not as good as city
Area, the health of rural area Drinking Water, security issues become increasingly urgent, larger compared with urban drinking water matter gap.2007
Environment Green Book is pointed out：The whole nation there are about 3.2 hundred million rural populatioies drinking-water dangerous, 800,000,000 people's drinking water safeties are still on the hazard.Therefore
Rural potable water Disinfection Status are urgently to be resolved hurrily.
Water purifying equipment of drinking popular in the market is all based on greatly what principle of reverse osmosis was made, and reverse osmosiss are referred to as
RO, is a kind of membrane separation technique growing up in the sixties, can be gone thin in eliminating water using reverse osmosis membrane manufacture purified water
Bacterium, virus, colloid, Organic substance and dissolubility salt.But, reverse osmosis equipment haves the shortcomings that some are fatal, such as, qualified water
Water rate is low, and only 40%, cause 60% water resource waste, more seriously in going eliminating water while harmful substance,
Eliminate most of mineral necessary to health and trace element, this water of long-term drink can cause one to human body on the contrary
Fixed injury;Equipment needs frequently to change filter element, the artificial and material cost that the equipment that increased runs and safeguards, in addition, controlling the water circulation
Slow with going out water speed, efficiency is low, the shortcomings of do not catch up with user's moment water.
Further, disinfecting aspect, current drinking water technology also has the technology carrying out disinfection using Burdick lamp, its
Principle is：After the ultraviolet light glistening light of waves 253.7nm that the antibacterial in water, virus, algae bio etc. are subject to doses irradiates, it is thin
DNA, RNA of born of the same parents are destructurized, and cell regeneration cannot be carried out, thus reaching the sterilization of water and the purpose of purification.And wavelength
185nm spectral line produces ozone in atmosphere, and ozone can play the effect of sterilization, taste removal.The spectral line of 185nm can be with decomposition water
In organic molecule, produce hydroxyl radical free radical and the organic molecule in water be oxidized to carbon dioxide the most at last, reach removal
The purpose of Organic substance.Application No. 00117600.5, patent name are《A kind of disinfection system of high-quality direct drinking and method》, Shen
The Chinese patent for Guangzhou Geochemistry Inst., Chinese Academy of Sciences of asking someone just discloses this technology, and its process system is:Directly
Drinking-water blood circulation → direct drinking water butt → water pump pump water → ozonator and ozone injection device → contact tower【Ozone is equal
Even dissolve in water】→ ultraviolet device【Ultraviolet lighting jetting】→ direct drinking user → direct drinking blood circulation.But this technology
There is also certain problem in actual applications, such as：Need special ozonator, contact tower, occupation area of equipment is big,
Complex operation, ultraviolet light sterilization not thoroughly and sterilization has dead angle etc. defect, are especially the absence of high grade oxidation catalytic device,
Under conditions of output is larger, processing speed does not reach and uses water requirement.
Content of the invention
In order to solve the problems, such as above-mentioned prior art, the invention provides environment-friendly type super oxidation depth purification direct-drinking
The method that water process reaches direct drinking；In addition present invention also offers realizing the device of above-mentioned advanced treatment method for drinking water.
In order to solve above-mentioned technical problem, the super oxidation depth purification direct-drinking water process of environment-friendly type of the present invention reaches direct drinking
Method comprise following process, this process not according to sequencing arrange：
A) make the drinking water in entrance tank body form the full flowing of overall maelstrom, locally little vortex by disturbing flow device
State is it is ensured that drinking water no stagnant water in tank body；
B) inner tank wall is carried out with mirror process such as polishing, plating, so that the impurity in water cannot be adhered to, deposit,
On the other hand uv reflectance can be played and then increase the effect of amount of ultraviolet irradiation；
C) using wavelength, for 185nm and wavelength, the ultraviolet for 253.7nm carries out disinfection by ultraviolet light process to drinking water,
And the dosage of ultraviolet is 4-800mJ/cm2；
D) for the ozone of 185nm ultraviolet induction, ozonization process is carried out to drinking water using wavelength；
E) there is senior oxygen for the ozone of 185nm ultraviolet induction using wavelength in the presence of multiphase slow release catalyst
Change（Also referred to as super oxidation, as follows）Reaction, the hydroxyl radical free radical of generation drops to the pollutant being difficult in drinking water degrade
Solution is processed；
F) using wavelength, the ultraviolet for 253.7nm has elimination to act on to ozone, and remaining ozone in water is eliminated
Process.
Above-mentioned f) step can also increase have slow-releasing ozone-eliminating catalyst come rapid, thoroughly eliminate residual
Remaining ozone.
This environment-friendly type super oxidation depth purification direct-drinking water treatment facilities, connects including the first water cavity 1 with the first water cavity
The second water cavity 2, be particular in that the inwall of the first water cavity 1 or be provided with the spiral helicine first overall flow-disturbing at the inwall
Device 3；Encapsulation several first quartz socket tubes 1-1 in first water cavity 1, in the first quartz socket tube 1-1, encapsulation wavelength is the of 185nm
One quartz burner 1-2；It is provided with spiral helicine first local flow spoiler 5 outside first quartz socket tube 1-1；First water cavity 1 interior
The outer surface of wall, the first overall flow spoiler 3 and the first local flow spoiler 5 includes the electrodeposited coating of high grade oxidation catalytic agent, this electricity
Coating can not only play the mirrored effect of uv reflectance, and the carrier as heterogeneous catalyst, plays gradually, at any time, persistently
The effect of release heterogeneous catalyst, can take the mode of dispersion plating to realize；Several second quartz of encapsulation in second water cavity 2
Sleeve pipe 2-1, in the second quartz socket tube 2-1, encapsulation wavelength is the second quartz burner 2-2 of 253.7nm；The inwall of the second water cavity 2
For minute surface, the mirrored effect of uv reflectance can be played, can realize in the way of using polishing or plating.
The spiral helicine second overall flow spoiler 4 can also be provided with the inwall of the second water cavity 2 or close inwall；Second is whole
The outer surface of body flow spoiler 4 can also be minute surface.The mirrored effect of uv reflectance can be played, can using polishing or plating
Mode is realized.
Spiral helicine second local flow spoiler 6 can also be set outside second quartz socket tube 2-1, and its outer surface can also be mirror
Face, can play the mirrored effect of uv reflectance, can realize in the way of using polishing or plating.
The minute surface of the inwall of the second water cavity 2 and the second overall flow spoiler 4 outer surface can be to include high grade oxidation catalytic
The electrodeposited coating of agent.
The minute surface of the second local flow spoiler 6 outer surface can also be the electrodeposited coating including high grade oxidation catalytic agent.
The minute surface of the inwall of the second water cavity 2 can also be the electrodeposited coating including ozone-eliminating catalyst, with more rapidly, more
Thoroughly bottom eliminates remaining ozone.
The minute surface of the second overall flow spoiler 4 outer surface can also be the electrodeposited coating including ozone-eliminating catalyst.
The minute surface of the second local flow spoiler 6 outer surface can also be the electrodeposited coating including ozone-eliminating catalyst.
Specifically, aforesaid high grade oxidation catalytic agent includes metal oxide catalyst and/or noble metal catalyst；Described
Metal-oxide be titanium dioxide, Mn oxide, iron oxides, cobalt/cobalt oxide, copper oxide, zinc oxide, barium oxide, oxidation
One or more of nickel, tin ash and ceria；Described noble metal is in ruthenium, platinum, palladium, rhenium, rhodium, iridium, silver and gold
One or more.
First water cavity 1 and the second water cavity 2 are collectively forming a tank body.
First water cavity 1 and the second water cavity 2 can also independently form two tank bodies.
The axial direction of the first quartz socket tube 1-1 or the second quartz socket tube 2-1 is parallel with water inlet direction.
The axial direction of the first quartz socket tube 1-1 or the second quartz socket tube 2-1 can also be vertical with water inlet direction.
Compared with prior art, the invention has the beneficial effects as follows：
1. disinfection by ultraviolet light, ozonization, advanced oxidation sterilization, residual ozone eliminate four kinds of water process modes and are used in combination, and make
The effect of water process is more preferable.
2. overall flow-disturbing is used in combination with local flow-disturbing, makes the drinking water in entrance tank body form overall maelstrom, locally little whirlpool
The full flow regime of stream, it is ensured that each dripping all have passed through the process of four kinds of modes, has been truly realized advanced treating, thorough nothing extremely
Angle.
3. using electrodeposited coating as the carrier of catalyst, so that the impurity in water cannot be adhered to, deposit, on the other hand may be used
Play uv reflectance so that increase amount of ultraviolet irradiation effect, also act as gradually, at any time, the work of sustained release catalyst
With, killing three birds with one stone, whole equipment structure is simple, broad-spectrum high efficacy, thoroughly prevent secondary water pollution, improves and ensure water quality peace
Entirely.
Brief description
Fig. 1 is the structural representation that a kind of single tank body indulges fraction drinking water advanced treatment device.
Fig. 2 is a kind of structural representation of single tank body horizontal fraction drinking water advanced treatment device.
Fig. 3 is a kind of structural representation of a kind of pair of tank body drinking water advanced treatment device the first water cavity.
Fig. 4 is a kind of structural representation of a kind of pair of tank body drinking water advanced treatment device the second water cavity.
Fig. 5 is a kind of water inlet direction double tank body double vertical drinking water deeps axially vertical with the first or second quartz socket tube
The structural representation of processing meanss.
Fig. 6 is a kind of water inlet direction double tank body double vertical drinking water deeps axially in parallel with the first or second quartz socket tube
The structural representation of processing meanss.
Fig. 7 is a kind of water inlet direction double tank body dual horizontal drinking water deeps axially vertical with the first or second quartz socket tube
The structural representation of processing meanss.
Fig. 8 is a kind of water inlet direction with second quartz socket tube axially in parallel double tanks axially vertical with the first quartz socket tube
Body crouches the structural representation of vertical drinking water advanced treatment device.
Embodiment
With reference to the accompanying drawings, describe specific embodiment in detail：
Specific embodiment 1：
This example referring to the drawings 1.
The dividing plate that tank body carries hole with bottom is longitudinally divided into two, and left part is divided into the first water cavity 1, and right part is divided into the second water
Chamber 2, is evenly arranged with four the first quartz socket tube 1-1 in the middle part of the left end face of the first water cavity 1, close in the first quartz socket tube 1-1
Envelope has the first quartz burner 1-2 that wavelength is 185nm；Spiral first entirety is provided with the inwall of the first water cavity 1 disturb
Stream device 3；First overall flow spoiler 3 is made up through torsive of the rustless steel steel disc of wide 20mm thickness 2mm；Each first quartz
It is socketed with first game portion flow spoiler 5 outside sleeve pipe 1-1, be made up through torsive of the rustless steel steel disc of wide 10mm thickness 1mm；The
The inwall of one water cavity 1 and spiral first overall flow spoiler 3, the outer surface of the first local flow spoiler 5 are made using dispersion plating
Its electrodeposited coating has direct reflection effect while including high grade oxidation catalytic agent.Wherein here high grade oxidation catalytic agent
It is the manganese oxide catalyst of one-component（It can in addition contain using iron oxides, cobalt/cobalt oxide, copper oxide, zinc oxide, vanadium oxygen
The metal oxide catalyst of the one-components such as compound, nickel oxide, tin ash and ceria）；The water inlet of the first water cavity 1
In tank body above left end face centre, outlet centre below its right end face in tank body.
It is evenly arranged with four the second quartz socket tube 2-1 in the middle part of second water cavity 2 right side, close in the second quartz socket tube 2-1
Envelope has the second quartz burner 2-2 that wavelength is 253.7nm;It is provided with spiral second overall on the inwall of the second water cavity 2
Flow spoiler 4；Second overall flow spoiler 4 is made up of the rustless steel steel disc of a width of 20mm thickness 2mm, the inwall and second of the second water cavity 2
It is anti-that overall flow spoiler 4 outer surface makes its electrodeposited coating have minute surface while including high grade oxidation catalytic agent using dispersion plating
Penetrate effect.Wherein here high grade oxidation catalytic agent is the manganese oxide catalyst using one-component.Each second quartz sleeve
Be socketed with second game's portion's flow spoiler 6 outside pipe 2-1, by wide 10mm thickness 1mm rustless steel steel disc through helical form distort and polished or
Common platings are made.First water cavity 1 two ends are respectively adopted ring flange with the second water cavity 2 both ends of the surface and are connected with tank body.First water
Chamber 1, the quartz burner axially direction of the second water cavity 2 and water (flow) direction are perpendicular.
Operationally, water with pressure enters the first water cavity 1 by the water inlet positioned at the first water cavity 1, and the first water cavity 1 is installed
Quartz burner sends, by quartz pipe sleeve, the ultraviolet that wavelength is l85nm;Spiral, appearance is installed in the first water cavity 1
The overall flow spoiler 4 of the first of the mirror reflection effect that face has, the first local flow spoiler 5 and the first water cavity 1 inner surface have
Under the collective effect of direct reflection, so that sent ultraviolet is fully reflected in tank body, be uniformly distributed, so that amount of radiation is reached
200mJ/cm2.Because most of Hydrocarbon have stronger absorbability to the ultraviolet of these high-energy, in ultraviolet
In the presence of, these Organic substances resolve into the states such as ion, free state ion, excited molecule, reach disinfective action.
Oxygen molecule can produce ozone molecule and elemental oxygen in wavelength under the ultraviolet for 185nm irradiates simultaneously, spiral
The spiral carrying on first overall flow spoiler 3 makes water body that maelstrom is integrally formed, and spiral first local flow spoiler 5 makes water body
It is partially formed little vortex, so that the whole violent disturbance of water body, enable the ozone molecule of generation to be more fully dissolved into water
In stream.The catabolic process of active ozone molecule also functions to disinfective action to the organic molecule in current.
Further, wavelength is the ozone producing under the ultraviolet irradiation of 185nm can induce a certain amount of hydroxyl of generation certainly
By base, and the ultraviolet of this wavelength and the first water cavity 1 inwall, the first overall flow spoiler 3, the first local flow spoiler 5 outer surface
Produce advanced oxidation catalytic reaction ozonisation in the presence of plating in the layer high grade oxidation catalytic agent, produce substantial amounts of hydroxyl
Free radical, instantaneous sterilization, and the harmful substance such as moment decomposing pesticide, chemical combination precipitation of heavy metals ion, hormone, oxidation is all of to be had
Machine thing.Research shows, free-radical oxidation does not have selectivity, generally the noxious pollutant in water can be oxidized to CO2With letters such as water
Single inorganic matters, to realize the functions such as strength efficient water purifying and disinfection decontamination.Through above disinfecting process current in pressure
The second water cavity 2 is entered from the hole of the first water cavity 1 lower right side under effect.
The water body entering the second water cavity 2 is fully irradiated by the ultraviolet of 253.7nm, and the uviol lamp of these high-energy is to second
Current in water cavity 2 continue sterilization, and meanwhile, the ozone molecule that is dissolved in current has strong to the ultraviolet of 253.7nm
Absorption, in the presence of the ultraviolet of this wavelength, ozone molecule is more promptly decomposed into elemental oxygen and oxygen molecule, wherein
The liveness of elemental oxygen is extremely active, in the presence of it, remains in the carbon in water body and the analyte of Hydrocarbon continues
Resolve into CO2And water, the further disinfecting detergent to water body;Eliminate further after the ultraviolet of 273.5nm wavelength irradiates
Remain in ozone in water body, the second overall flow spoiler 4 can make smelly to the common perturbation action of current and the second local flow spoiler 6
Oxygen more thoroughly decomposes.
Water body by positioned at the second water cavity outlet be cleaning, aseptic, contamination-free can direct drinking, can by pipe
Road is transported to required user's drinking-water point.
Specific embodiment 2：
This example referring to the drawings 2.
Tank body is laterally divided into two with the pertusate dividing plate of right side band, and top is divided into the first water cavity 1, and bottom is divided into the second water
Chamber 2, is evenly arranged with two the first quartz socket tube 1-1 in the middle part of the left end face of the first water cavity 1, close in the first quartz socket tube 1-1
Envelope has the first quartz burner 1-2 that wavelength is 185nm；Spiral first entirety is provided with the inwall of the first water cavity 1 disturb
Stream device 3；First overall flow spoiler 3 is made up through torsive of the rustless steel steel disc of wide 20mm thickness 2mm；Each first quartz
It is socketed with first game portion flow spoiler 5 outside sleeve pipe 1-1, be made up through torsive of the rustless steel steel disc of wide 10mm thickness 1mm；The
The inwall of one water cavity 1 and spiral first overall flow spoiler 3, the outer surface of the first local flow spoiler 5 are made using dispersion plating
Its electrodeposited coating has direct reflection effect while including high grade oxidation catalytic agent.Wherein here high grade oxidation catalytic agent
It is the bicomponent catalyst of copper oxide and ceria composition（It can in addition contain using two or more Mn oxides, iron oxides,
The double-component of the compositions such as cobalt/cobalt oxide, zinc oxide, barium oxide, nickel oxide, tin ash or multi-component metal-oxide are urged
Agent）.The water inlet of the first water cavity 1 centre above left end face in tank body, outlet is in following central part
Position.
It is evenly arranged with two the second quartz socket tube 2-1 in the middle part of second water cavity 2 right side, close in the second quartz socket tube 2-1
Envelope has the second quartz burner 2-2 that wavelength is 253.7nm;It is provided with spiral second overall on the inwall of the second water cavity 2
Flow spoiler 4；Second overall flow spoiler 4 is made up of the rustless steel steel disc of a width of 20mm thickness 2mm, the inwall and second of the second water cavity 2
Overall flow spoiler 4 outer surface makes it have direct reflection effect using electroplating processes.Need not be socketed with outside second quartz socket tube 2-1
Second local flow spoiler 6（In figure is shown with, only reference）.First water cavity 1 two ends and the second water cavity 2 both ends of the surface are respectively adopted flange
Disk is connected with tank body.First water cavity 1, the quartz burner axially direction of the second water cavity 2 and water (flow) direction are perpendicular.
Work process is similar to Example 1, and it will not go into details.
Specific embodiment 3：
This example referring to the drawings 3,4,5.
First water cavity 1 individually becomes vertical tank with the second water cavity 2, and is connected by pipeline, is provided with flow-disturbing in the second water cavity 2
Device.Water inlet direction and the first quartz socket tube 1-1's of the first water cavity 1 is axially in parallel, the water inlet direction of the second water cavity 2 and the second stone
English sleeve pipe 2-1's is axially vertical.Spiral first overall flow spoiler 3 is provided with the inwall of the first water cavity 1；First entirety is disturbed
Stream device 3 is made up through torsive of the rustless steel steel disc of wide 30mm thickness 2mm；It is socketed with outside each first quartz socket tube 1-1
First local flow spoiler 5, is made up through torsive of the rustless steel steel disc of wide 15mm thickness 1.5mm；The inwall of the first water cavity 1
And spiral first overall flow spoiler 3, the outer surface of the first local flow spoiler 5 make its electrodeposited coating comprise using dispersion plating
There is while having high grade oxidation catalytic agent direct reflection effect.Wherein here high grade oxidation catalytic agent is Mn oxide, oxygen
Change nickel, three component catalysts of tin ash composition.Other are similar to Example 1.
Specific embodiment 4：
This example referring to the drawings 3,4,6.
Substantially similar to Example 3, the water inlet direction of the first water cavity 1 is axially in parallel with the first quartz socket tube 1-1's, and second
The water inlet direction of water cavity 2 is axially also parallel with the second quartz socket tube 2-1's.The inwall of the first water cavity 1 and spiral first whole
Body flow spoiler 3, the outer surface of the first local flow spoiler 5 make its electrodeposited coating include high grade oxidation catalytic agent using dispersion plating
While there is direct reflection effect.Wherein here high grade oxidation catalytic agent is the precious metal iridium of one-component.
Specific embodiment 5：
This example referring to the drawings 3,4,7.
Substantially similar to Example 4, but water inlet direction and the first quartz socket tube 1-1's of the first water cavity 1 is axially vertical, the
The water inlet direction of two water cavities 2 is axially also vertical with the second quartz socket tube 2-1's.The inwall of the first water cavity 1 and spiral first
Overall flow spoiler 3, the outer surface of the first local flow spoiler 5 make its electrodeposited coating include high grade oxidation catalytic using dispersion plating
There is while agent direct reflection effect.Wherein here high grade oxidation catalytic agent is the double of noble silver and titanium dioxide composition
Component catalyst.The inwall of the second water cavity 2 makes it include ozone-eliminating catalyst by disperseing plating.Second water cavity 2 is close
It is provided with the second overall flow spoiler 4, the second overall polished process of flow spoiler 4 outer surface at inwall.
Specific embodiment 6：
This example referring to the drawings 3,4,8.
Substantially similar to Example 4, but water inlet direction and the first quartz socket tube 1-1's of the first water cavity 1 is axially vertical, the
The water inlet direction of two water cavities 2 is axially in parallel with the second quartz socket tube 2-1's.The inwall of the first water cavity 1 and spiral first whole
It is anti-that the outer surface of body flow spoiler 3 makes its electrodeposited coating have minute surface while including high grade oxidation catalytic agent using dispersion plating
Penetrate effect.Wherein here high grade oxidation catalytic agent is the iron oxides of one-component；First local flow spoiler 5 outer surface first passes through
Blasting treatment is then again through making it include the catalyst of the barium oxide of one-component by dispersion plating.The work of blasting treatment
With being the surface area improving the first local flow spoiler 5, be conducive to the contact that more multi-catalyst is with water body.The inwall of the second water cavity 2
It is made to include ozone-eliminating catalyst by disperseing plating.Second overall flow spoiler 4 is provided with the second water cavity 2 inwall, the
Two overall flow spoiler 4 outer surfaces are dispersed through electroplating processes the high grade oxidation catalytic agent containing barium oxide, the second local flow-disturbing
The polished process of device.
According to above-mentioned principle, the present invention can also carry out suitable change and modification to above-mentioned specific embodiment.Therefore,
The invention is not limited in specific embodiment disclosed and described above, some modifications and changes of the present invention be should also be as
Enter in the scope of the claims of the present invention.Although additionally, employing some specific terms in this specification, these
Term merely for convenience of description, does not constitute any restriction to the present invention.
Claims (14)
1. environment-friendly type super oxidation depth purification direct-drinking water treatment facilities, including the first water cavity（1）And connect with the first water cavity
Second water cavity（2）It is characterised in that the first water cavity（1）Inwall or be provided with the spiral helicine first overall flow-disturbing at the inwall
Device（3）；First water cavity（1）Interior several first quartz socket tubes of encapsulation（1-1）, the first quartz socket tube（1-1）Interior encapsulation wavelength be
First quartz burner of 185nm（1-2）；First quartz socket tube（1-1）It is provided with outward spiral helicine first local flow spoiler
（5）；First water cavity（1）Inwall, the first overall flow spoiler（3）With the first local flow spoiler（5）Outer surface include senior
The electrodeposited coating of oxidation catalyst；Second water cavity（2）Interior several second quartz socket tubes of encapsulation（2-1）, the second quartz socket tube（2-1）
Interior encapsulation wavelength is second quartz burner of 253.7nm（2-2）；Second water cavity（2）Inwall be minute surface.
2. the super oxidation depth purification direct-drinking water treatment facilities of environment-friendly type according to claim 1 is it is characterised in that described
The second water cavity（2）Inwall or be provided with the spiral helicine second overall flow spoiler at the inwall（4）And its outer surface is mirror
Face.
3. the super oxidation depth purification direct-drinking water treatment facilities of environment-friendly type according to claim 1 is it is characterised in that described
The second quartz socket tube（2-1）It is provided with outward spiral helicine second local flow spoiler（6）, its outer surface is minute surface.
4. the super oxidation depth purification direct-drinking water treatment facilities of environment-friendly type according to claim 1 is it is characterised in that described
The second water cavity（2）The minute surface of inwall be the electrodeposited coating including high grade oxidation catalytic agent.
5. the super oxidation depth purification direct-drinking water treatment facilities of environment-friendly type according to claim 2 is it is characterised in that described
The second overall flow spoiler（4）The minute surface of outer surface is the electrodeposited coating including high grade oxidation catalytic agent.
6. the super oxidation depth purification direct-drinking water treatment facilities of environment-friendly type according to claim 3 is it is characterised in that described
The second local flow spoiler（6）The minute surface of outer surface is the electrodeposited coating including high grade oxidation catalytic agent.
7. the super oxidation depth purification direct-drinking water treatment facilities of environment-friendly type according to claim 1 is it is characterised in that described
The second water cavity（2）The minute surface of inwall be the electrodeposited coating including ozone-eliminating catalyst.
8. the super oxidation depth purification direct-drinking water treatment facilities of environment-friendly type according to claim 2 is it is characterised in that described
And the second overall flow spoiler（4）The minute surface of outer surface is the electrodeposited coating including ozone-eliminating catalyst.
9. the super oxidation depth purification direct-drinking water treatment facilities of environment-friendly type according to claim 3 is it is characterised in that described
The second local flow spoiler（6）The minute surface of outer surface is the electrodeposited coating including ozone-eliminating catalyst.
10., according to the super oxidation depth purification direct-drinking water treatment facilities of the arbitrary described environment-friendly type of claim 1,4,5,6, it is special
Levy and be that described high grade oxidation catalytic agent includes metal oxide catalyst and/or noble metal catalyst；Described metal oxygen
Compound is titanium dioxide, Mn oxide, iron oxides, cobalt/cobalt oxide, copper oxide, zinc oxide, barium oxide, nickel oxide, dioxy
Change one or more of stannum and ceria；Described noble metal is ruthenium, platinum, palladium, rhenium, rhodium, iridium, one of silver-colored and golden or
Multiple.
The super oxidation depth purification direct-drinking water treatment facilities of 11. environment-friendly types according to claim 1 is it is characterised in that described
The first water cavity（1）With the second water cavity（2）It is collectively forming a tank body.
The super oxidation depth purification direct-drinking water treatment facilities of 12. environment-friendly types according to claim 1 is it is characterised in that described
The first water cavity（1）With the second water cavity（2）Independently form two tank bodies.
The super oxidation depth purification direct-drinking water treatment facilities of 13. environment-friendly types according to claim 1 is it is characterised in that described
The first quartz socket tube（1-1）Or second quartz socket tube（2-1）Axial direction with water inlet direction parallel.
The super oxidation depth purification direct-drinking water treatment facilities of 14. environment-friendly types according to claim 1 is it is characterised in that described
The first quartz socket tube（1-1）Or second quartz socket tube（2-1）Axial direction with water inlet direction vertical.
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| CN201410256837.2A CN104086034B (en) | 2014-06-11 | 2014-06-11 | Environment-friendly type super oxidation depth purifying direct drinking processing method and processing device |
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| CN201410256837.2A CN104086034B (en) | 2014-06-11 | 2014-06-11 | Environment-friendly type super oxidation depth purifying direct drinking processing method and processing device |
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| CN104086034B true CN104086034B (en) | 2017-03-01 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6274484A (en) * | 1985-09-30 | 1987-04-06 | Toshiba Corp | Apparatus for purifying liquid |
| CN1228251C (en) * | 2003-01-23 | 2005-11-23 | 翰信科技股份有限公司 | Sterilizing unit of ultraviolet rediationa nd ozone with improved sterukuzubg effect |
| CN2712359Y (en) * | 2003-09-24 | 2005-07-27 | 郑行健 | Vortex type air sterilization and oxidation device |
| CN2723882Y (en) * | 2004-08-16 | 2005-09-07 | 深圳清华大学研究院 | Air sterilizing device for central air conditioner |
| CN201182765Y (en) * | 2008-03-06 | 2009-01-21 | 东海县驼峰友伟电光源厂 | Two-band ultra-violet sterilization and disinfection lamp |
| CN102101052B (en) * | 2011-01-28 | 2013-01-09 | 河北亚太环境科技发展股份有限公司 | Ozone-eliminating catalyst using active carbon as carrier |
| CN103482731B (en) * | 2013-09-11 | 2015-10-28 | 吴正新 | Flow-disturbing purifier |
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