CN202594824U - Ultraviolet-and-ozone-combined (UV/O3) advanced oxidation reactor for treatment of micro-polluted water - Google Patents
Ultraviolet-and-ozone-combined (UV/O3) advanced oxidation reactor for treatment of micro-polluted water Download PDFInfo
- Publication number
- CN202594824U CN202594824U CN 201220085722 CN201220085722U CN202594824U CN 202594824 U CN202594824 U CN 202594824U CN 201220085722 CN201220085722 CN 201220085722 CN 201220085722 U CN201220085722 U CN 201220085722U CN 202594824 U CN202594824 U CN 202594824U
- Authority
- CN
- China
- Prior art keywords
- water
- reaction monomers
- micro
- reactor
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 230000003647 oxidation Effects 0.000 title claims abstract description 23
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 23
- 239000000178 monomer Substances 0.000 claims abstract description 37
- 238000006243 chemical reaction Methods 0.000 claims abstract description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000006385 ozonation reaction Methods 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract description 11
- 238000005273 aeration Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 238000005516 engineering process Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 5
- 239000002957 persistent organic pollutant Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- -1 hydroxyl radical free radical Chemical class 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 239000004912 1,5-cyclooctadiene Substances 0.000 description 1
- 208000005623 Carcinogenesis Diseases 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 208000031320 Teratogenesis Diseases 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000009303 advanced oxidation process reaction Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000036952 cancer formation Effects 0.000 description 1
- 231100000504 carcinogenesis Toxicity 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000002703 mutagenesis Methods 0.000 description 1
- 231100000350 mutagenesis Toxicity 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Images
Landscapes
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Physical Water Treatments (AREA)
Abstract
The utility model relates to an ultraviolet-and-ozone-combined (UV/O3) advanced oxidation reactor for treatment of micro-polluted water, belonging to the technical field of water treatment equipment. The reactor consists of a plurality of reaction monomers; each reaction monomer is of a cylindrical shell body, an UV lamp tube and a quartz glass tube sleeve are arranged at one end inside the shell body, and an O3 aeration head is arranged at the other end; and the two sides of each shell body are respectively provided with a water inlet and a water outlet, the reaction monomers are arranged in parallel, the water inlets and the water outlets of every two adjacent reaction monomers are communicated with one another so as to form a series structure, and the water inlet of the head reaction monomer and the water outlet of the tail reaction monomer are the water inlet and water outlet of the UV/O3 reactor. The reactor is applicable to the treatment of micro-polluted water, and has the advantages of high ozone utilization ratio, good treatment effect and the like compared with the existing reactor.
Description
Technical field
The utility model belongs to the water treating equipment technical field, particularly a kind of UV/O that is used for the micro-polluted water processing
3(ultraviolet associating ozone) advanced oxidation reactor drum.
Background technology
In general; Mainly comprise petroleum hydrocarbon, volatile phenol, ammonia nitrogen, agricultural chemicals, COD, heavy metal, arsenic, prussiate etc. in the contaminated rivers water body; These pollutant kinds are more, and character is complicated, but concentration ratio is lower; Especially those preferential control toxic organic pollutants that are difficult to degrade, be easy to biological accumulation and have mutagenesis, teratogenesis and carcinogenesis are poisoned very big to HUMAN HEALTH.
At present; China's confluent is not enough, water resource waste and seriously polluted, and the water quality standard of tap water is on the low side; Because the economic strength that China is present; Can't control pollution of waterhead within a short period of time, change the inferior present situation of source quality, thereby people have to adopt new treatment process to guarantee safety of drinking water and people's health.Research through decades is explored, and has developed many purification technologies.
Advanced oxidation processes is a kind of new life's a water technology; Different according to reaction system median surface characteristic in the high-level oxidation technology; Can high-level oxidation technology be divided into homogeneous phase high-level oxidation technology and heterogeneous high-level oxidation technology, the homogeneous phase high-level oxidation technology comprises Fenton oxidation, O
3, UV/O
3, O
3/ H
2O
2And UV/H
2O
2Systems such as (Fenton oxidation, ozone, ozone associating ultraviolet, ozone associating ydrogen peroxide 50 and ultraviolet associating ydrogen peroxide 50), heterogeneous oxidation comprises: UV/TiO
2(ultraviolet associating titanium oxide) etc.UV/O wherein
3Be a kind of in the homogeneous phase high-level oxidation technology, at O
3Behind the middle introducing UV, the generation efficient of hydroxyl radical free radical is higher, effectively raises the efficient of ozone oxidation degradation of organic substances.Because UV not only can excite O
3Molecule impels it to produce OH, also has very strong bactericidal property, so UV/O
3The technological potentiality that in various organic degradeds and tap water advanced treatment, are widely used.
Problems such as yet existing advanced oxidation equipment exists integrated level low, and floor space is big, and ozone utilization rate is low.
Micro-polluted water is meant generally and receives Organic pollutants that part water quality surpasses the water body of the III class water body requirement of " water environment quality standard ".The method of conventional process micro-polluted water has electrochemical process, and coagulating sedimentation Chlorination etc. can not effectively be removed the organism that exists with dissolved state, and all be laboratory scales, are difficult to apply.
The utility model content
The purpose of the utility model is in order to solve the above-mentioned deficiency that existing advanced oxidation equipment exists, a kind of UV/O that micro-polluted water is handled that is used for to be provided
3The advanced oxidation reactor drum has the oxidation susceptibility height, and ozone utilization rate is high, good effectiveness.
The utility model is realized through following technical scheme:
The described UV/O that is used for the micro-polluted water processing
3The advanced oxidation reactor drum is characterized in that: said reactor drum is made up of shell and a plurality of reaction monomers; Each reaction monomers is a cylindrical shell, and enclosure interior one end is provided with ultraviolet lamp tube and is placed in the outer silica glass pipe box of this ultraviolet lamp tube, and the other end is provided with ozonation aerated head.The housing both sides are set up water-in and water outlet separately, and all reaction monomers are arranged in parallel within shell of reactor inside, the water-in of adjacent two reaction monomers formation cascaded structure that is connected with water outlet, and head and the tail two reaction monomers water-ins, water outlets are UV/O
3The entery and delivery port of reactor drum.
Technical scheme by above-mentioned the utility model provides can be found out: the utility model can be realized UV and O
3Combined action, the monomeric series connection of reactor drum has prolonged water by the time of uviolizing and and O
3Effect, make hydroxyl radical free radical give full play to oxygenizement, remove the organic pollutant in the water, improve effluent quality; Floor space is little, and integrated level is high, and oxidation susceptibility improves, and ozone utilization rate is high, and is effective, is applicable to the processing of micro-polluted water.
Description of drawings
Fig. 1 is the UV/O of the utility model
3The composition of the embodiment of reactor drum and connection synoptic diagram.
Fig. 2 is the UV/O of present embodiment
3The monomer structure synoptic diagram of reactor drum.
Device number is among each figure: 1. total water inlet, the monomeric pipe connecting of 2.3# and 4#, 3. total water outlet, 4.2# monomer water-in, 5.2# monomer water outlet, 6.2# monomer O
3Aeration head, 7.2# monomer silica glass pipe box, 8.2# monomer housing, 9.2# monomer ultraviolet lamp tube, 10. spring.
Embodiment
Below in conjunction with practical implementation the utility model is described further.
A kind of UV/O that is used for the micro-polluted water processing of the utility model
3The advanced oxidation reactor drum, as shown in Figure 1, said reactor drum is made up of a plurality of (being shown as 6 embodiment among the figure) reaction monomers.Each reaction monomers is a cylindrical shell, and enclosure interior one end is established ultraviolet lamp tube 9 and silica glass pipe box 7, and the other end is established ozonation aerated 6.The housing both sides are set up water-in 4 and water outlet 5 separately, and all reaction monomers are arranged in parallel, adjacent two reaction monomers water-ins formation cascaded structure that is connected with water outlet, and two reaction monomers water-ins, water outlets are UV/O from beginning to end
3The entery and delivery port of reactor drum.
Shell in the utility model, ultraviolet lamp tube 9, silica glass pipe box 7, ozonation aerated 6 all can be adopted the conventional ripening product; Uv lamp power, quartz glass sleeve size are by concentration of wastewater, and factors such as sewage quantity are confirmed.
A kind of embodiment of the utility model is as shown in Figure 1, and each reaction monomers structure is identical, and size is Φ * H=24mm * 1100mm, and overall reactor is of a size of L * H=674mm * 1100mm.
Be processed sewage from UV/O
3Reactor drum total water inlet 1 (i.e. the water-in of first reaction monomers) gets into; Flow in first reaction monomers; First reaction monomers is handled the back water outlet and is got into second reaction monomers; So connection is final through after the 6th the reaction monomers processing, discharges through total water outlet 3 (i.e. the water outlet of the 6th reaction monomers).
The described UV/O that is used for the micro-polluted water processing of the utility model
3The method that the advanced oxidation reactor drum carries out water treatment is following: the O of reactor drum is received in the air outlet that (1) will regulate the ozonizer of ozone concn in advance
3Inlet mouth, the effect through aeration head makes O in the reactor drum
3Be evenly distributed; (2) former water gets into reactor drum through the water-in of reactor shell, under the irradiation of uv lamp, flows to monomer 6 by reactor drum monomer 1, reaches higher purification efficiency for guaranteeing in the present embodiment, and the residence time of former water in reactor drum is 3～15min.
Claims (1)
1. one kind is used for the UV/O that micro-polluted water is handled
3The advanced oxidation reactor drum is characterized in that: said reactor drum is made up of a plurality of reaction monomers; Each reaction monomers is a cylindrical shell, and enclosure interior one end is provided with ultraviolet lamp tube and is placed in the outer silica glass pipe box of this ultraviolet lamp tube, and the other end is established ozonation aerated head; The housing both sides are arranged with water-in and water outlet, and all reaction monomers are arranged in parallel, adjacent two reaction monomers water-ins formation cascaded structure that is connected with water outlet, and head and the tail two reaction monomers water-ins, water outlets are UV/O
3The entery and delivery port of reactor drum.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201220085722 CN202594824U (en) | 2012-03-08 | 2012-03-08 | Ultraviolet-and-ozone-combined (UV/O3) advanced oxidation reactor for treatment of micro-polluted water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201220085722 CN202594824U (en) | 2012-03-08 | 2012-03-08 | Ultraviolet-and-ozone-combined (UV/O3) advanced oxidation reactor for treatment of micro-polluted water |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN202594824U true CN202594824U (en) | 2012-12-12 |
Family
ID=47312382
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201220085722 Expired - Fee Related CN202594824U (en) | 2012-03-08 | 2012-03-08 | Ultraviolet-and-ozone-combined (UV/O3) advanced oxidation reactor for treatment of micro-polluted water |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN202594824U (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104730267A (en) * | 2015-03-31 | 2015-06-24 | 烟台大学 | Continuous, synchronous and online monitoring method and instrument for concentration and total quantity of TOC (total organic carbon), TN (total nitrogen) and TP (total phosphorus) |
| CN104764740A (en) * | 2015-03-31 | 2015-07-08 | 烟台大学 | Method and instrument for synchronously, continuously and automatically measuring total organic carbon and total phosphorus |
| CN104792704A (en) * | 2015-03-31 | 2015-07-22 | 烟台大学 | Continuous synchronous real-time on-line determination method and instrument for three indexes of TOC, TN and TP |
| CN106430524A (en) * | 2016-11-28 | 2017-02-22 | 程中和 | Ozone oxidation reactor pipe network with circuitous horizontal curve |
| CN108246221A (en) * | 2018-03-29 | 2018-07-06 | 睦化(上海)流体工程有限公司 | Micropore is vortexed casing mixing reactor and its application |
| CN108502970A (en) * | 2018-05-02 | 2018-09-07 | 清华大学深圳研究生院 | A kind of integrated ultraviolet irradiation algal-inhibition device |
-
2012
- 2012-03-08 CN CN 201220085722 patent/CN202594824U/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104730267A (en) * | 2015-03-31 | 2015-06-24 | 烟台大学 | Continuous, synchronous and online monitoring method and instrument for concentration and total quantity of TOC (total organic carbon), TN (total nitrogen) and TP (total phosphorus) |
| CN104764740A (en) * | 2015-03-31 | 2015-07-08 | 烟台大学 | Method and instrument for synchronously, continuously and automatically measuring total organic carbon and total phosphorus |
| CN104792704A (en) * | 2015-03-31 | 2015-07-22 | 烟台大学 | Continuous synchronous real-time on-line determination method and instrument for three indexes of TOC, TN and TP |
| CN104730267B (en) * | 2015-03-31 | 2016-10-05 | 烟台大学 | TOC, TN, TP concentration and total amount continuous synchronization on-line monitoring method and instrument |
| CN104792704B (en) * | 2015-03-31 | 2017-04-05 | 烟台大学 | Tri- index continuous synchronization real-time online determining instrument of TOC, TN, TP |
| CN104764740B (en) * | 2015-03-31 | 2017-04-26 | 烟台大学 | Method and instrument for synchronously, continuously and automatically measuring total organic carbon and total phosphorus |
| CN106430524A (en) * | 2016-11-28 | 2017-02-22 | 程中和 | Ozone oxidation reactor pipe network with circuitous horizontal curve |
| CN108246221A (en) * | 2018-03-29 | 2018-07-06 | 睦化(上海)流体工程有限公司 | Micropore is vortexed casing mixing reactor and its application |
| CN108246221B (en) * | 2018-03-29 | 2023-05-26 | 睦化(上海)流体工程有限公司 | Microporous vortex sleeve mixing reactor and application thereof |
| CN108502970A (en) * | 2018-05-02 | 2018-09-07 | 清华大学深圳研究生院 | A kind of integrated ultraviolet irradiation algal-inhibition device |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN202594824U (en) | Ultraviolet-and-ozone-combined (UV/O3) advanced oxidation reactor for treatment of micro-polluted water | |
| CN204874213U (en) | Petrochemical industry waste water is with synthesizing water treatment facilities | |
| CN103613254B (en) | The deep treatment method of fine chemistry industry garden sewage work organic wastewater with difficult degradation thereby | |
| CN104787924A (en) | Caprolactam sewage advanced treatment method using ozone catalytic oxidation | |
| CN110228898A (en) | A kind of technique of catalytic ozonation-MBR Combined Treatment coal chemical industrial waste water | |
| CN205382045U (en) | Degradation system of aquatic antibiotic | |
| CN105253964A (en) | Iron aeration and photocatalysis organic wastewater degrading device | |
| CN104817215A (en) | Ozone photocatalysis advanced wastewater treatment technology and treatment equipment | |
| CN102363549A (en) | Deep treatment system of membraneless industrial organic wastewater | |
| CN103011517A (en) | Device and control method for safety guarantee of municipal sewage recycling | |
| CN102583695B (en) | Ozone and hydrogen peroxide combination system for realizing slightly polluted water treatment | |
| CN108675545A (en) | A kind for the treatment of process of civil engineering sanitary sewage | |
| CN204342609U (en) | A kind of refractory organic industrial sewage treatment system | |
| CN204265481U (en) | A kind of ultraviolet joint ozone equipment for micro-polluted water treatment | |
| CN101817616B (en) | Biologic unit combined treatment method for improving biological stability of drinking water quality | |
| CN108423883B (en) | Method and device for degrading and mineralizing quinolone antibiotics by hydroxyl radicals | |
| CN108128925B (en) | Method for simultaneously removing COD (chemical oxygen demand) and total phosphorus | |
| CN103420528A (en) | Multi-stage bubbling oxidizing tower-type sewage treatment reactor | |
| CN202594883U (en) | Ozone combined hydrogen peroxide advanced oxidation reactor used for micro-polluted water treatment | |
| CN105174611A (en) | Efficient energy-saving sewage treatment apparatus applied to sewage treatment | |
| CN102583850A (en) | Ultraviolet joint ozone system for realizing micro-polluted water treatment | |
| CN117023766A (en) | Wastewater treatment system of ultra-fine bubble coupling ozone generator | |
| CN205387494U (en) | Secondary biochemical sewage ozone catalytic oxidation processing system | |
| CN205222876U (en) | Multistage fenton processing apparatus of high COD waste water of high salt | |
| CN105060586B (en) | A kind of coating waste-water processing unit |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20121212 Termination date: 20190308 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |