KR100654059B1 - Hair shining compositions comprising alkyl phosphatidyl PG-dimonium chloride - Google Patents

Abstract

      The present invention relates to a hair gloss cosmetic composition comprising the alkyl phosphatidyl dizimonium chloride of the formula (1).

(1)

(One)

 Where x + y = 3 and R represents Coco, Lioleamido-propyl, Cocamidopropyl, Steramidopropyl or Borageamidopropyl it means.

 Hair gloss cosmetic composition according to the present invention provides a long lasting gloss effect without shine on the hair.

Hair Gloss Cosmetic Composition, Alkylphosphatidylfijidimonium Chloride

Description

   Hair shining compositions comprising alkyl phosphatidyl PG-dimonium chloride}

      The present invention relates to a hair gloss composition having excellent hair gloss effect, and more particularly, to alkyl phosphatidyl PG-dimonium chloride, and optionally to alkyl dimethicone cocopolyol or cationic hydrolysis keratin. It relates to a hair gloss cosmetic composition further comprising.

      Alkylphosphatidyl fijidimonium chloride is a compound whose preparation method and manufacturing process are known in US Patent No. 4,503,002, Canadian Patent No. 1132990, Japanese Patent No. 59-4478, European Patent No. 0013713, etc. And as a conditioner for hair, it provides excellent gloss to hair and is designed to be similar to the natural lipids present in the epidermal layer of the skin, and thus has a high affinity for the human body and exhibits a wide range of antimicrobial activities.

      In general, the preferred gloss after using the hair cosmetic is obtained by uniformly coating the surface of the oil or oil-based components or various organic compounds contained in the cosmetic to reduce the diffuse reflection of light. The hair may be cracked by physical force such as excessive combing, the cuticle may be out of order, and the hair may be broken by chemical treatment such as permanent wave and hair dye or by heat of the hair dryer. It is easily damaged by daily hair care, such as rough skin. This damage causes the hair to appear crumbly and matte.

      Therefore, for the purpose of enhancing the gloss of the hair, it can be seen that the treatment of an oily component having a high refractive index, a treatment of a compound having a good adsorption power to the hair, and the like are essential requirements.

      However, most of the oil-based ingredients used to provide gloss to the hair can be easily removed from the hair in the case of cosmetics applied to the hair, or in the case of the cosmetics used in the manner of washing with water after being treated with excess hair. Due to the shortcomings and the like has been somewhat limited in its utilization. In addition, the inclusion of an oily component or silicone oil having a high refractive index tends to adversely affect the stability of the emulsion over time in the treatment formulation, and in the case of a product which is washed after treatment on the hair, it is adsorbed on the hair. It is difficult to provide a favorable gloss effect for a long time in the hair after being poorly dried.

      In addition, the use of cationic compounds may be considered for adsorption to hair for hair gloss. These cationic compounds, through simple electrical adsorption, provide long term desirable hair conditioning effects, unlike simple physical adsorption, but not all cationic compounds provide the desired gloss.                         

      As such, examples of the hair cosmetic composition for the purpose of enhancing the gloss of hair include a hair gloss enhancer containing one or two or more saturated or unsaturated fats and fatty acids having a melting point of -5 to 42 ° C (European Patent No. 9902121). ), A hair cosmetic composition (European Patent No. 9531173) by double dispersion of a polysiloxane conditioning component and a polysiloxane shine component, and a specific silicone copolymer obtained by radical copolymerization of N-vinylpyrrolidone with acrylic modified silicone Hair cosmetic compositions (Japanese Patent JP-0036218), hair conditioner compositions containing organopolysiloxane modified from polyoxyalkylene (Japanese Patent JP-0136214), and the like.

      However, these components perform relatively well as hair conditioning components, but there is a problem that there is no condition for enhancing the gloss of hair, that is, no shine or foreign matter, and that their use is limited for the purpose of giving a long lasting gloss. .

      Accordingly, the inventors of the present invention, while investigating a material having excellent hair adsorption power while having a hair protection effect in order to solve the above problems, the inventors focus on the fact that the alkyl phosphatidyl-digimonium chloride has excellent hair conditioning effect, and provides an emollient effect without grease. The present invention was completed.

      Accordingly, it is an object of the present invention to provide a hair treatment cosmetic composition which is excellent in biocompatibility and can continuously provide a gloss-free and conditioning effect to hair.

      The present invention relates to a hair gloss cosmetic composition comprising an alkyl phosphatidyl dizimonium chloride of the formula (1).

       Where

       x + y = 3

   R means Coco, Lioleamidopropyl, Cocamidopropyl, Stearamidopropyl or Borageamidopropyl.

       More specifically, the present invention will be described below.

      Hair cosmetic composition according to the present invention comprises 0.1 to 30% by weight, preferably 0.1 to 15% by weight of the alkyl phosphatidyl sedimonium chloride which is an essential ingredient for the desired gloss effect relative to the total weight of the composition. When used at less than 0.1% by weight, the desired gloss effect cannot be obtained sufficiently, and when it exceeds 30% by weight, the stability of the formulation is lowered.

      On the other hand, the hair gloss cosmetic composition according to the present invention, in addition to the alkyl phosphatidyl sedimonium chloride, and optionally further comprises 0.1 to 20% by weight of alkyl dimethicone copolyol or quaternary cationic hydrolysis keratin to further improve the hair gloss effect You can get it.

     The alkyl dimethicone polyol is a water-soluble silicone derivative, which has a property such as combing property, anti-tangling, softening effect, gloss effect, etc. by using adsorption property on the hair surface. Dimethicone bis-hydroxypropyl copolyol, methyl eugenyl di One or two or more compounds selected from methicone copolyol, stealconium dimethicone copolyol phthalate or cetyl triethylmonium dimethicone copolyol can be used.

    Quaternary cationic hydrolysis keratin is a compound having excellent hair affinity with hair keratin, which is generally used as a humectant, an antistatic agent, etc., and is used as a cocodimonium hydroxypropyl hydrolyzed keratin and hydroxypropyltrimonium. It means one or two or more compounds selected from hydrolyzed keratin, lauryldimonium hydroxypropyl hydrolyzed keratin or steardimonium hydroxypropyl hydrolyzed keratin.

      In the present invention, a surfactant selected from cationic, nonionic and amphoteric surfactants is used in an amount of 5 to 60% by weight, preferably 5 to 40% by weight, based on the total weight of the composition. If not enough and exceeds 60% by weight, the viscosity is excessively high, it is inconvenient to take the contents from the container, and there is a disadvantage in that the spread of the contents in the hair is bad.

     Cationic surfactants that can be used in the present invention include quaternary alkylammonium salts having an alkyl group having 16 to 22 carbon atoms, and nonionic surfactants include alcohols having 8 to 18 carbon atoms, alkanolamides, and HLB 9 to 16 carbon atoms. And polyoxyethylene alkyl ether having 12 to 18 carbon atoms having an alkyl group. The amphoteric surfactant includes alkyl betaine or alkyl amidopropyl betaine having an alkyl group having 8 to 18 carbon atoms and an alkoxy group. The aforementioned surfactants may be used alone or in combination in the hair gloss cosmetic composition of the present invention.

      Meanwhile, in the composition of the present invention, thickeners, preservatives, pH adjusters, flavoring agents, dyes, water and the like can be used in addition to the above components.

      Hair gloss cosmetic composition according to the present invention may have a conventional formulation, for example, it may be formulated as a cream, lotion, liquid hair treatment agent. In addition, in the case of creams and lotions, it is applicable to both the use of the hair after treatment and to wash the hair, and the number of times of use may vary depending on the user's hair and scalp condition or taste.

Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited thereto.

Examples 1-5 and Comparative Examples 1-4

To the hair gloss cosmetic composition (cream formulation) having a composition as shown in Table 1 below was prepared by the following method.

     The raw materials 1 to 3 were added to the aqueous phase (raw material 13) to dissolve and warmed to 75 ° C., the oil phase (raw materials 4 to 6) was heated to 75 ° C., and the oil phase was added to the aqueous phase to emulsify, and then the raw materials 7 to 12 were sequentially The mixture was added and mixed uniformly and cooled to obtain a composition.

Example 1 Example 2 Example 3 Example 4 Example 5 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 One Cetyltrimethylammonium Chloride 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 2 Polyquaternium-10 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 3 Hydroxyethyl Cellulose 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 4 Cetostearyl alcohol 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 5 Mineral oil 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 6 Glyceryl Stearate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 7 Alkylphosphatidylfijidimonium chloride 0.10 0.50 1.00 0.50 0.50 - - - - 8 Alkyl Dimethicone Copolyol - - - 0.50 - - 0.50 - 0.50 9 Quaternary Cationic Hydrolysis Keratin - - - - 0.50 - - 0.50 0.50 10 Spices 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 11 Citric acid 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 12 antiseptic 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 13 Purified water Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount

      The hair gloss effect is applied to 30 men and women aged 20 to 35 years, using a conventional shampoo, and then applying the product to wet hair for about 40 seconds. The results are shown in Table 2.

       Hair gloss effect test result Example 1 Example 2 Example 3 Example 4 Example 5 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Shiny and glossy after drying ○ ○ ○ ◎ ◎ Χ Χ Χ △

◎: very good, ○: good, △: normal, Χ: bad

As shown in Table 2, the hair gloss effect was excellent in Examples 1 to 5 using the alkyl phosphatidyl dizimomonium chloride, together with the alkyl phosphatidyl dizimomonium chloride and the alkyl dimethicone cocopolyol or quaternary cationic hydrolysis keratin. Best in Examples 4 and 5 used.

Examples 6-10 and Comparative Examples 5-8

     To the hair gloss cosmetic composition (bilayer type conditioning agent) having a composition as shown in Table 3 was prepared by the following method.

The raw materials 1 and 2 were added and dissolved in the raw material 13, the raw materials 3-6 were mixed, it was added to the raw materials 1,2 and 13, it mixed at high speed, and the raw materials 7-12 were added and mixed, and the composition was obtained.

Example 6 Example 7 Example 8 Example 9 Example 10 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 One Polyquaternium-11 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 2 Polyquaternium-6 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 3 Polyoxyethylene Cured Castor Oil 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 4 Cyclomethicone 10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 5 Methyl Polysiloxane 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 6 Dimethicone Copolyol 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 7 Alkylphosphatidyl sebum- dimonium chloride 0.10 0.50 1.00 0.50 0.50 - - - - 8 Alkyl Dimethicone Copolyol - - - 0.50 - - 0.50 - 0.50 9 Quaternary Cationic Hydrolysis Keratin - - - - 0.50 - - 0.50 0.50 10 Spices 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 11 Lactic acid 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 12 antiseptic 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 13 Purified water Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount

      The hair gloss effect was evaluated for the gloss and gloss effect after spraying the composition on the hair for 30 men and women aged 20 to 35 years, and the results contained alkylphosphatidyl pyzidimonium chloride as shown in Table 4. The hair gloss effect was excellent in Examples 6 to 10, and the most excellent in Examples 9 and 10 using alkyl phosphatidyl sedimonium chloride and alkyl dimethicone copolyol or quaternary cationic hydrolysis keratin.

Example 6 Example 7 Example 8 Example 9 Example 10 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Glittery and polished ○ ○ ○ ◎ ◎ Χ Χ Χ △

◎: very good, ○: good, △: normal, Χ: bad

As described above, in the hair gloss cosmetic composition according to the present invention, alkylphosphatidyl sedimonium chloride provides a long lasting gloss effect without bleeding on the hair, and in particular, using alkyldimethicone cocopolyol or quaternary cationic hydrolysis keratin. As a result, synergistic hair gloss effect can be obtained.

Claims (6)

      A hair gloss cosmetic composition comprising one or two or more compounds selected from alkylphosphatidylphysidimomonium chlorides of the general formula (1).

(One)        Where        x + y = 3       R means coco, lioleamidopropyl, cocamidopropyl, stearamidopropyl or borazamidopropyl.       The hair gloss cosmetic composition according to claim 1, further comprising an alkyldimethicone cocopolyol or quaternary cationic hydrolysis keratin in addition to the alkyl phosphatidyl dizimomonium chloride.       The hair gloss cosmetic composition according to claim 1, wherein the alkyl phosphatidyl fijidimonium chloride is 0.1 to 30% by weight based on the total weight of the composition.       The method of claim 2, wherein the alkyl dimethicone copolyol is selected from dimethicone bisaminohydroxypropyl copolyol, methyl eugenyl dimethicone copolyol, stealconium dimethicone copolyol phthalate or cetyl triethylmonium dimethicone copolyol. A hair gloss cosmetic composition, characterized in that the compound is two or more species.       The method of claim 2, wherein the quaternized cationic hydrolysis keratin is cocodimonium hydroxypropyl hydrolyzed keratin, hydroxypropyltrimonium hydrolide keratin, lauryldimonium hydroxypropyl hydrolide keratin or steardimonium hydroxide A hair gloss cosmetic composition, characterized in that the compound is one or two or more selected from oxypropyl hydrolyzed keratin.       The hair gloss cosmetic composition according to claim 2, wherein the alkyldimethicone cocopolyol or quaternary cationic hydrolysis keratin is 0.1 to 20% by weight based on the total weight of the composition.