KR100641800B1 - juice a matter method of the food waste - Google Patents

juice a matter method of the food waste Download PDF

Info

Publication number
KR100641800B1
KR100641800B1 KR1020030002226A KR20030002226A KR100641800B1 KR 100641800 B1 KR100641800 B1 KR 100641800B1 KR 1020030002226 A KR1020030002226 A KR 1020030002226A KR 20030002226 A KR20030002226 A KR 20030002226A KR 100641800 B1 KR100641800 B1 KR 100641800B1
Authority
KR
South Korea
Prior art keywords
food waste
honeycomb
stirring
ceramics
molecular sieve
Prior art date
Application number
KR1020030002226A
Other languages
Korean (ko)
Other versions
KR20040063737A (en
Inventor
김계숙
강광대
Original Assignee
박기호
김계숙
강광대
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 박기호, 김계숙, 강광대 filed Critical 박기호
Priority to KR1020030002226A priority Critical patent/KR100641800B1/en
Publication of KR20040063737A publication Critical patent/KR20040063737A/en
Application granted granted Critical
Publication of KR100641800B1 publication Critical patent/KR100641800B1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B2101/00Type of solid waste
    • B09B2101/02Gases or liquids enclosed in discarded articles, e.g. aerosol cans or cooling systems of refrigerators
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/20Waste processing or separation

Landscapes

  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

본 발명은 음식물 쓰레기의 수분 처리방법에 관한 것으로서, 더욱 구체적으로는 농업부산물인 섬유소 500g과, 규산알미늄 10g, 탄산칼슘 5g, 산화칼슘 2g, 산화규소 5g, 탄산나트륨 5g, 오산화바나듐 2g, 산화티탄 2g으로 이루어지는 금속산화물과, 무정형탄소 미세분말 700g과, 당밀100g을 일정형태의 반응기에 투입, 교반하면서 약100 - 120℃의 열을 가하여 알갱이 형태의 벌집형 유기성분자체 세라믹스를 만드는 제1공정과; 상기 제1공정에서 제조된 일정량의 벌집형 유기성 분자체 세라믹스에 수분을 포함한 음식물 쓰레기 분말을 벌집형 세라믹스 분자체 전량 대비 약 20%를 투입하여 약100℃ - 120℃ 열에서 약10 - 12분동안 교반시킴과 동시에 음파와 열풍을 공급하는 제2공정으로 수분이 제거되면서 화학변화된 음식물 쓰레기를 얻을 수 있도록 함으로써 음식물 쓰레기를 매립하더라도 토양 및 지하수 등의 오염이 방지되도록하고, 또 위 수분이 제거된 음식물 쓰레기를 소각하더라도 다이옥신 등과 같은 유해물질의 발생이 억제되도록 한 것이다.The present invention relates to a method for treating food waste water, and more specifically, 500 g of agricultural by-products, 10 g of aluminum silicate, 5 g of calcium carbonate, 2 g of calcium oxide, 5 g of silicon oxide, 5 g of sodium carbonate, 2 g of vanadium pentoxide, and 2 g of titanium oxide. A first step of producing a granular honeycomb-type organic self-contained ceramics by applying heat of about 100-120 ° C while stirring and stirring a metal oxide consisting of a metal oxide, 700 g of amorphous carbon fine powder, and 100 g of molasses into a predetermined type of reactor; About 20% of the total amount of the food waste powder containing water into the predetermined amount of honeycomb organic molecular sieve ceramics prepared in the first step is added to the total amount of the molecular sieves of the honeycomb ceramics for about 10-12 minutes in a heat of about 100 ℃-120 ℃ In the second process of stirring and supplying sound waves and hot air, the water is removed and chemically changed food waste can be obtained to prevent contamination of soil and groundwater even when the food waste is reclaimed. Even incineration of waste is to prevent the generation of harmful substances such as dioxin.

음식물 쓰레기, 수분, 호정화액, 벌집형 분자체, 유기성 부유물Food waste, moisture, stabilization liquid, honeycomb molecular sieve, organic suspended solids

Description

음식물 쓰레기 수분 처리방법{juice a matter method of the food waste}Juice a matter method of the food waste

본 발명은 음식물 쓰레기의 수분 처리방법에 관한 것으로서 이를 좀더 구체적으로 설명하자면 음식물 쓰레기를 최종적으로 처리(매립, 소각 등)하기 전에 음식물 쓰레기에 포함된 수분을 제거할 수 있는 방법을 제공하여 음식물 쓰레기를 최종적으로 처리할 때 환경(지하수, 토양, 대기 등)오염의 발생이 방지되도록 함에 그 목적이 있는 것이다.The present invention relates to a water treatment method of food waste, which will be described in more detail. The food waste may be removed by providing a method for removing water contained in the food waste before finally processing the food waste (landfill, incineration, etc.). Its purpose is to prevent the generation of environmental (groundwater, soil, air, etc.) pollution during the final treatment.

현재까지 알려진 바에 의하면 음식물 쓰레기는 그 수분 함유량이 약70% 정도이여서 이를 그대로 매립할 경우에는 음식물 쓰레기의 수분으로 인한 지하수는 물론 토양까지 오염시키게 되어 2005년부터는 수분이 포함된 음식물 쓰레기의 매립이 전면 금지되게 되고, 또 음식물 쓰레기를 소각할 경우에는 이 역시 수분으로 인하여 다이옥신등과 같은 대기오염물질을 발생시키게 된다.As far as is known, food waste has about 70% of its water content, so when it is landfilled, it contaminates groundwater and soil due to moisture of food waste. When the food waste is incinerated, this also causes air pollutants such as dioxins due to moisture.

삭제delete

이와 같은 점을 해결하기 위해 현재 음식물 쓰레기를 재활용하는 방안이 다각적으로 제시되고는 있으나, 이러한 방법들은 또 다른 환경오염을 유발 시킴은 물론 처리비용 역시 많이 들어 매우 비현실적이고 또한 시장성도 거의 없는 문제점등으로 인하여 현재에는 외면당하고 있는 실정이다.In order to solve this problem, there have been various proposals for recycling food waste, but these methods not only cause other environmental pollution but also have high disposal costs, resulting in very unrealistic and almost no marketability. Due to the current situation is neglected.

즉, 음식물 쓰레기를 사료화할 경우에는 시설비 및 연료비 등이 많이 들어 경제성이 없고, 이를 퇴비화할 경우에는 염류자해 및 초산염 발생 그리고 토양의 물리성 악화와 같은 문제점이 있다.In other words, when food waste is fed into a large amount of facility costs and fuel costs, there is no economic feasibility, and when composted there are problems such as salt harm and acetate salt generation and soil physical deterioration.

삭제delete

삭제delete

본 발명은 위와 같이 음식물 쓰레기를 처리함에 있어 나타나는 종래의 문제점을 해결하기 위함에 그 기술적인 과제를 두고 발명한 것으로서, 특히 음식물 쓰레기를 최종적(소각, 매립 등)으로 처리하기 전에 수분을 제거할 수 있도록 함으로써 음식물 쓰레기의 최종적 처리로 인한 토양, 지하수, 대기 등의 오염이 방지되도록 한 것이다..The present invention has been invented with the technical problem to solve the conventional problems appearing in the treatment of food waste as described above, in particular, it is possible to remove the moisture before the final disposal (incineration, landfill, etc.) of food waste. This prevents the contamination of soil, groundwater and air from the final disposal of food waste.

이하에서는 본 발명의 음식물 쓰레기의 수분 처리방법을 설명하기로 한다.Hereinafter, a method of treating water in food waste of the present invention will be described.

<제 1공정><1st process>

농업부산물인(왕겨,옥수수줄기,짚등) 섬유소(Cellulose 입경5mm)500g과, 규산알미늄(Al2SiO3 )10g, 탄산칼슘(CaCO3 )5g, 산화칼슘(CaO) 2g, 산화규소(SiO2 ) 5g, 탄산나트륨(Na2CO3 )5g, 오산화바나듐(V2O5)2g, 산화티탄(TiO2 )2g으로 이루어지는 금속산화물과, 무정형탄소 미세분말(매탄,역전탄,무연탄등)700g과, 당밀100g을 일정형태의 반응기에 투입, 교반하면서 약100 - 120℃의 열을 가하여 알갱이 형태의 벌집형(hemeycomd)유기성분자체 세라믹스(이하 "분자체" 라 약칭함)를 만든다.Agricultural by-products (rice husk, corn stem, straw, etc.) 500g of fiber (Cellulose particle size 5mm), 10g of aluminum silicate (Al 2 SiO 3 ), 5g of calcium carbonate (CaCO 3 ), 2g of calcium oxide (CaO), silicon oxide (SiO 2 ) 5 g, sodium carbonate (Na 2 CO 3 ) 5 g, vanadium pentoxide (V 2 O 5 ) 2 g, metal oxide consisting of 2 g of titanium oxide (TiO 2 ), and amorphous carbon fine powder (methane, reverse carbon, anthracite, etc.) 700 g; 100 g of molasses is added to a reactor of a certain type, and heated to about 100-120 ° C. while stirring to form a granular honeycomb organic ceramics (hereinafter, abbreviated as “molecular body”).

<제2공정><The second process>

상기 제1공정에서 제조된 일정량의 분자체에 수분을 포함한 음식물 쓰레기 분말(이하 "호정화액"이라 함)을 투입하여 약100℃ - 120℃열에서 약10 - 12분동안 교반시킬 때 음파(가청주파수)와 열풍을 공급한다.When the food waste powder containing water (hereinafter referred to as "stabilization liquid") was added to a predetermined amount of molecular sieve prepared in the first step and stirred for about 10-12 minutes at about 100-120 ℃ heat, Frequency) and hot air.

위에서 분자체에 투입되는 호정화(Dextrinization)액의 투입비율은 벌집형 세라믹스 분자체 전량 대비 약 20%비율로 한다.The ratio of dexterification liquid introduced into the molecular sieve is about 20% of the total amount of the honeycomb ceramic sieve.

이와 같이 된 본 발명은 제1공정에서 제조되는 분자체는 알갱이 형태이면서 벌집형이므로 흡장성 이온(ion)교환성이 강하게 되는데, 이는 호정화액의 수분을 흡장하는 반응이 뛰어나게 된다.In the present invention as described above, since the molecular sieve prepared in the first step is in the form of granules and honeycomb, the sorbent ion exchange ability is strong, which is excellent in the reaction of absorbing the water in the purified liquid.

즉, 분자체에 호정화액을 제2공정에서와 같이 적절한 비율로 투입한 후 일정시간 동안 교반하면 호정화액의 수분은 벌집형 분자체 표면의 모공을 통해 분자체 내로 흡수되게 되고, 수분이 제거된 호정화액의 유기성 부유물(음식물 쓰레기 분말과 수분내에 포함된 부유물)들은 분자체 표면에 흡착되게 된다.That is, when the purified liquid is added to the molecular sieve at an appropriate ratio as in the second step and stirred for a predetermined time, the moisture of the purified liquid is absorbed into the molecular sieve through the pores on the surface of the honeycomb molecular sieve, and the moisture is removed. Organic suspended solids (food waste powder and suspended solids in water) of the purified water are adsorbed onto the surface of the molecular sieve.

이때(음식물 쓰레기 분말과 분자체를 혼합 교반할 때)일정한 열을 가하게 되면 분자체 내로 흡수된 수분은 열에 의해 기화되어 비산하게 되고, 이로 인하여 분자체 표면에는 비산되는 수분 분자에 의해 모공이 발생하게 되며, 이 모공은 차기 수분이 흡수될 수 있게 한다.At this time (when mixing and stirring food waste powder and molecular sieves), if a certain amount of heat is applied, moisture absorbed into the molecular sieve is vaporized and scattered by heat, which causes pores to be generated by moisture molecules scattered on the surface of the molecular sieve. The pores allow the next moisture to be absorbed.

상기와 같은 반응(분자체 표면에 유기성 부유물의 흡착 반응과 분자체 내로의 수분 흡수와 기화 반응)을 반복하면 호정화액의 유기성 부유물과 그 수분을 처리할 수 있게되고, 이와 동시에 음파와 열풍을 공급하면 위 반응이 가속화 되어 반응시간이 단축되게 된다.By repeating the above reaction (adsorption reaction of organic suspended solids on the surface of the molecular sieve, absorption of water into the molecular sieve and vaporization reaction), the organic suspended solids of the purified liquid and its moisture can be treated, and at the same time, sound waves and hot air are supplied. This accelerates the reaction and shortens the reaction time.

삭제delete

여기서 호정화액과 분자체의 반응은 아래의 그림과 같이 이루어지게 되는데, 일반적으로 수분은 대체로 상온에서 이온결합체이며 이온성 상태에서 액체로 존재하여 100℃에서 비등하여 단일분자로 증발하게 된다.Here, the reaction between the purified liquid and the molecular sieve is made as shown in the figure below. In general, the water is generally an ionic bond at room temperature and is present as a liquid in the ionic state, and boils at 100 ° C. to evaporate into a single molecule.

Figure 112003502402291-pat00001
Figure 112003502402291-pat00001

한편 수분이 포함된 음식물 쓰레기를 호정화액으로 만들어 분자체와 반응시키는 이유는 각종 음식물 쓰레기에는 수분함량 및 함유성분등이 일정하지 않기 때문이다.On the other hand, food waste containing water is made into a purified liquid and reacted with molecular sieves because various food wastes have a constant moisture content and content.

따라서 본 발명은 상기한 바와 같이 제1공정에 의거하여 흡장성 벌집형 분자체를 만들고, 이를 제2공정에서 얻어진 호정화액과 혼합,교반시킴과 함께 호정화액의 유기성 부유물은 분자체 표면에 반복적으로 흡착되도록 하여 농축되게 하고, 호정화액의 수분은 분자체 내로 흡수되도록 한 후 기화 되도록 함으로써 수분이 제거되면서 화학변화된 음식물 쓰레기를 얻을 수 있으므로 이를 매립하더라도 토양 이나 지하수 등의 오염이 방지될 뿐만 아니라 위 수분이 제거된 음식물 쓰레기를 소각하더라도 다이옥신 등과 같은 유해물질은 제1공정에서 투입되는 금속산화물에 의해 그 발생이 억제되게되며, 한편 위 수분이 제거된 음식물 쓰레기를 경화제와 일정비율로 혼합,교반하면 유기성 고체연료로 제조할 수 있게되어 연간 다량으로 배출되는 음식물 쓰레기를 연료화 할 수 있게 되는 효과도 있는 것이다.Therefore, according to the present invention, the absorbent honeycomb molecular sieve is prepared according to the first step, and mixed with the stabilization solution obtained in the second step, and the organic suspended solids of the stabilization solution are repeatedly added to the surface of the molecular sieve. It is concentrated by adsorption, and the water of the purified water is absorbed into the molecular sieve, and then vaporized to obtain chemically changed food waste by removing water. Even if the removed food waste is incinerated, harmful substances such as dioxin are suppressed by the metal oxide introduced in the first step, and the organic matter is mixed and stirred at a predetermined ratio with the food waste from which the above water is removed. Food can be produced in solid fuel, which is emitted in large quantities annually. Effect which can be yeonryohwa group would in.

Claims (3)

농업부산물인 섬유소 500g과, 규산알미늄 10g, 탄산칼슘 5g, 산화칼슘 2g, 산화규소 5g, 탄산나트륨 5g, 오산화바나듐 2g, 산화티탄 2g으로 이루어지는 금속산화물과, 무정형탄소 미세분말 700g과, 당밀100g을 일정형태의 반응기에 투입, 교반하면서 100 - 120℃의 열을 가하여 알갱이 형태의 벌집형 유기성분자체 세라믹스를 만드는 제1공정과; 상기 제1공정에서 제조된 일정량의 벌집형 유기성 분자체 세라믹스에 수분을 포함한 음식물 쓰레기 분말을 벌집형 세라믹스 분자체 전량 대비 약 20%를 투입하여 100℃ - 120℃ 열에서 약10 - 12분동안 교반시킴과 동시에 음파와 열풍을 공급하는 제2공정으로 이루어짐을 특징으로 하는 음식물쓰레기 수분 처리방법.500 g of agricultural by-products, 10 g of aluminum silicate, 5 g of calcium carbonate, 2 g of calcium oxide, 5 g of silicon oxide, 5 g of sodium carbonate, 2 g of vanadium pentoxide, 2 g of titanium oxide, 700 g of amorphous carbon fine powder, and 100 g of molasses A first step of producing granular honeycomb-type organic constituent ceramics by applying heat at 100-120 ° C. while stirring and stirring into a reactor of a type; Food waste powder containing water was added to a predetermined amount of honeycomb organic molecular sieve ceramics prepared in the first step by adding about 20% of the total amount of molecular sieves of honeycomb ceramics and stirred for 10-12 minutes at 100 ° C-120 ° C heat. Food waste water treatment method comprising a second step of supplying sound waves and hot air at the same time. 삭제delete 삭제delete
KR1020030002226A 2003-01-08 2003-01-08 juice a matter method of the food waste KR100641800B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020030002226A KR100641800B1 (en) 2003-01-08 2003-01-08 juice a matter method of the food waste

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020030002226A KR100641800B1 (en) 2003-01-08 2003-01-08 juice a matter method of the food waste

Publications (2)

Publication Number Publication Date
KR20040063737A KR20040063737A (en) 2004-07-14
KR100641800B1 true KR100641800B1 (en) 2006-11-13

Family

ID=37354620

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020030002226A KR100641800B1 (en) 2003-01-08 2003-01-08 juice a matter method of the food waste

Country Status (1)

Country Link
KR (1) KR100641800B1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100849672B1 (en) 2007-12-04 2008-08-01 주식회사 아이파워 Organic waste treatment apparatus

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100849672B1 (en) 2007-12-04 2008-08-01 주식회사 아이파워 Organic waste treatment apparatus

Also Published As

Publication number Publication date
KR20040063737A (en) 2004-07-14

Similar Documents

Publication Publication Date Title
CN100569400C (en) The processing method of combustion ash
Phan et al. Preparation of rice husk hydrochar as an atrazine adsorbent: Optimization, characterization, and adsorption mechanisms
CN108927109B (en) Method for modifying biochar by using phosphogypsum and application of biochar
CN105854805A (en) Modified charcoal microballoon, and preparation method and application thereof
Zhao et al. Tetracycline adsorption mechanisms by NaOH-modified biochar derived from waste Auricularia auricula dregs
CN107867688A (en) A kind of preparation method for the shaddock peel activated carbon for being used for purification of air and sewage disposal
KR20130023198A (en) A buoyant multifunctional composite material for effective removal of organic compounds in water and wastewater
CN109956483A (en) A kind of innoxious and method of resource of chemical industry abraum salt
Zhang et al. A comparative study on adsorption of cadmium and lead by hydrochars and biochars derived from rice husk and Zizania latifolia straw
KR100641800B1 (en) juice a matter method of the food waste
US7157000B2 (en) Catalytic bioconversion of petroleum-contaminated wastes/wastewaters using kenaf core powder
JP3397304B2 (en) Sewage treatment method using sludge carbonization system
CN105771576B (en) A kind of technique removing bioxin using modified activated carbon
JP2005263521A (en) Zeolite combined carbonized material and method for manufacturing the same
JP3663685B2 (en) Method for producing activated carbon
Shivayogimath et al. Treatment of biomethanated distillery spent wash by adsorption process on bagasse activated carbon
JP3663682B2 (en) Production method of granulated activated carbon
KR101464195B1 (en) Method for regenerating porous phosphorus adsorbent
JP2000262848A (en) Treatment of exhaust gas
JP3663679B2 (en) Method for producing activated carbon
JP2951299B2 (en) Method and apparatus for using adsorbent produced from waste
JP2002059001A (en) Anion adsorbent
JP2004181336A (en) Composition for capturing environmental hormone
JP2000288386A (en) Filter medium for removing environmental pollutant and recovering useful substance
CA2553489C (en) Catalytic bioconversion of petroleum-contaminated wastes/wastewaters using kenaf core powder

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
N231 Notification of change of applicant
E902 Notification of reason for refusal
E601 Decision to refuse application
J201 Request for trial against refusal decision
N231 Notification of change of applicant
J301 Trial decision

Free format text: TRIAL DECISION FOR APPEAL AGAINST DECISION TO DECLINE REFUSAL REQUESTED 20050901

Effective date: 20060830

Free format text: TRIAL NUMBER: 2005101005877; TRIAL DECISION FOR APPEAL AGAINST DECISION TO DECLINE REFUSAL REQUESTED 20050901

Effective date: 20060830

S901 Examination by remand of revocation
GRNO Decision to grant (after opposition)
N231 Notification of change of applicant
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20090826

Year of fee payment: 4

LAPS Lapse due to unpaid annual fee