KR100626176B1 - Functional paint made using nano silver and charcoal - Google Patents

Functional paint made using nano silver and charcoal Download PDF

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KR100626176B1
KR100626176B1 KR1020040094821A KR20040094821A KR100626176B1 KR 100626176 B1 KR100626176 B1 KR 100626176B1 KR 1020040094821 A KR1020040094821 A KR 1020040094821A KR 20040094821 A KR20040094821 A KR 20040094821A KR 100626176 B1 KR100626176 B1 KR 100626176B1
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nano silver
charcoal
deodorizing
silver
paint
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KR20060055256A (en
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박진우
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박진우
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D129/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
    • C09D129/14Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/80Processes for incorporating ingredients

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

본 발명은 다공성 구조로 각종 유해가스에 대한 탈취력을 가진 숯 분말과 나노은의 특성인 강력한 살균력을 이용하여 탈취와 항균, 살균효과가 동시에 나타나면서 도포후 건조된 나노은, 숯 도료의 검은 표면이 나노 은의 입자에 의해 시각적으로 반짝이므로 귀금속인 은을 통한 피착면의 미적 부가가치도 부수적으로 누리게 되는 나노 은과 숯을 이용한 기능성 살균, 탈취도료에 관한 것이다.The present invention is a porous structure of the deodorizing, antimicrobial, and sterilizing effect simultaneously using the charcoal powder having a deodorizing power for various harmful gases and nano silver, while appearing at the same time deodorizing, antimicrobial, and sterilizing effect, the black surface of the charcoal paint is nano silver It is related to functional sterilization and deodorizing paint using nano silver and charcoal, which is visually sparkled by particles, and thus additionally enjoys the aesthetic added value of the deposited surface through the precious metal silver.

고속 교반기 속에 농도가 30%인 아크릴 에멀젼바인더와 농도가 30%가 되도록 수용액화한 폴리비닐부티랄(poly vinyl butyral)을 혼합한 혼합 수용액 1000㎖와 150nm ~ 250nm의 크기로 분산 시킨 나노 은 수용액 20㎖를 혼합하여 총량 대비 나노 은의 이온농도가 200ppm이 되게 한 다음, 입도 크기가 350 메쉬인 숯 250g과 입도 크기가 350 메쉬인 음 이온석 50g을 각각 투입하여 혼합하는 것에 의해 제조된 나노 은과 숯을 이용하여 제조한 기능성 도료를 제공하는 데 있다.1000 ml of mixed aqueous solution mixed with 30% acrylic emulsion binder and 30% polyvinyl butyral solution in a high speed stirrer and nano silver aqueous solution dispersed in the size of 150nm ~ 250nm The nano silver and charcoal were prepared by mixing ㎖ to make the ion concentration of nano silver to the total amount 200ppm, and then mixing by adding 250 g of char with a particle size of 350 mesh and 50 g of negative ion stone with a particle size of 350 mesh. It is to provide a functional paint prepared using.

숯 분말, 나노은, 음이온석,Charcoal powder, nano silver, anion stone,

Description

나노 은과 숯을 이용하여 제조한 기능성 도료{omitted}Functional paint made with nano silver and charcoal

본 발명은 나노 은과 숯을 이용하여 제조한 기능성 도료에 관한 것이다.
일반적으로 숯은 섭씨 1200도 이상의 고온에서 생산하여 숯 자체의 기공을 이용하여 탈취뿐만 아니라 다양한 크기로 분쇄한 숯 분말을 이용하여 정화 및 정수의 목적으로 사용하고도 있다.
The present invention relates to a functional paint prepared using nano silver and charcoal.
In general, charcoal is produced at a high temperature of more than 1200 degrees Celsius, and is used for purifying and purifying water by using charcoal powder crushed to various sizes as well as deodorization using pores of the charcoal itself.

그러나 습도가 높은 곳의 숯이나 침수된 숯은 시간이 경과됨에 따라 숯의 기공 속 환경조건이 세균이 번식하기 좋은 습도와 환경으로 인해 차츰 곰팡이가 발생하게 되는 것을 볼 수 있다.However, as charcoal in high humidity or submerged charcoal, as time passes, it can be seen that the environmental conditions in the pores of charcoal gradually grow mold due to the humidity and environment where bacteria can grow.

이러한 것은 숯 자체의 성분은 곰팡이를 발생시키지 않지만 기공 속에 흡착된 유기물질을 먹이로 하는 세균과 곰팡이가 다수 발생함으로 숯의 기공 속에 세균이 번식하게 되고 그 부산물의 부패로 인해 숯의 고유기능인 탈취력이 급격하게 떨어지는 부작용이 나타남으로써 통상 이를 폐기하거나 세균을 분리시키기 위하여 물로 씻어내고 건조시키는 과정을 거치는 번거로움이 발생하게 되는 것이다.This is because the charcoal itself does not generate mold, but many bacteria and molds feed on organic substances adsorbed in the pores, causing bacteria to multiply in the pores of the char. As a sudden dropping side effect appears, the hassle of washing and drying with water in order to discard it or to separate the bacteria is generated.

또한 기존의 수성용 도료는 물을 대량 포함하고 있으므로 부패의 위험에 항상 노출되어 있다고 할 수 있는데. 기존 수성 도료는 자체부패를 막기 위하여 포르말린이 주성분인 각종 화학방부제, 유기항균제를 사용하고 있으며 이는 제품의 화 학적 안전성, 내산성을 일으켜 제품의 질을 떨어뜨리고 있다.In addition, existing waterborne paints contain large amounts of water, which means that they are always exposed to the risk of corruption. Existing water-based paints use various chemical preservatives and organic antimicrobial agents, the main component of which is formalin, in order to prevent its own decay.

특히 각종 화학적 방부제는 독소작용으로 인해 인체와 자연 생태계를 위협하고 우리의 거주환경에 치명적 악영향을 초래할 수 있으므로 그 사용을 최대한 억제 하여야 한다.In particular, various chemical preservatives should be suppressed as much as possible because they can threaten the human body and natural ecosystem due to toxin action and cause fatal adverse effects on our living environment.

본 발명은 상기와 같은 문제점을 해결하기 위함에 있다.
이러한 목적을 달성하기 위하여 본 발명에서는 숯과 나노 은 및 음이온석 광물을 주원료로 이용하여 우리의 일상생활 속 각종 건축물이나 가구류 등에서 발생하는 유해가스나 악취등 유해성분의 탈취, 공기정화, 각종 세균에 대한 살균, 탈취 등의 제거 효율이 우수하게 나타나는 친환경 기능성 수성용 도료를 제공하고자 하는데 있다.
이러한 본 발명의 도료는 실내건축물에 도포한 다음 건조시키면 주원료인 숯과 나노 은등이 첨가된 기능성 물질의 작용과 효과로 공기정화작용, 항균작용, 음이온방출, 원적외선방출, 온혈작용 등을 하여 각종 건축물에서 발생하는 유해가스를 제거하고, 공기를 정화시키며 공기 중의 부유세균까지 흡착, 살균하므로 우리의 생활주거공간을 좀 더 안전하고 쾌적한 공간으로 제공할 수 있다.
The present invention is to solve the above problems.
In order to achieve the above object, in the present invention, charcoal, nano silver and anion stone minerals are used as main raw materials for deodorization, air purification, and various bacteria of harmful components such as harmful gases or odors generated in various buildings and furniture in our daily lives. It is intended to provide an environmentally friendly functional water-based paint that exhibits excellent removal efficiency such as sterilization and deodorization.
When the paint of the present invention is applied to indoor buildings and dried, the air purification, antibacterial action, anion emission, far infrared ray emission, warm blood action, etc. are performed by the action and effect of the functional materials added with charcoal and nano silver as the main raw materials. By eliminating harmful gases generated in buildings, purifying the air, and adsorbing and sterilizing suspended bacteria in the air, we can provide our living space as a safer and more comfortable space.

본 발명은 다공성 구조로 탈취력을 가진 숯 분말과 나노은의 특성인 강력한 살균력을 이용하여 공기정화와 더불어 기공 속에 흡착된 세균을 효과적으로 살균하는 기능성 도료를 제공하는 것으로서 이를 구체적으로 설명하면 다음과 같다.The present invention provides a functional paint that effectively sterilizes bacteria adsorbed in pores with air purification by using strong sterilizing properties of charcoal powder and nano silver having a deodorizing power with a porous structure.

섭씨 1200도 이상의 고온에서 생산된 활성숯이나 참숯을 325메쉬의 크기를 가지도록 분쇄한 숯 분말을 사용한다.
이때 상기한 숯 분말은 주성분이 탄소로 된 숯 자체의 성분은 곰팡이를 발생시키지 않지만 숯의 특성인 다공성 구조로 인해 각종 기체 및 각종 유기화합물이 자연 흡착된다.
Use charcoal powder pulverized to have a size of 325 mesh activated charcoal or true charcoal produced at a high temperature of more than 1200 degrees Celsius.
At this time, the charcoal powder as the main component of the charcoal itself of carbon does not generate mold, but due to the porous structure of the charcoal, various gases and various organic compounds are naturally adsorbed.

이 흡착된 유기물질을 먹이로 하는 곰팡이가 숯의 기공 속에 다수 발생할 수 있는데, 이때 기공 속에 흡착된 유기물질을 먹이로 하는 세균과 곰팡이가 다수 발생함으로 숯의 기공 속에 세균이 번식하게 되고 그 부산물의 부패로 인해 숯의 고유기능인 탈취성능이 현저히 떨어지는 결과가 나타나게 되는데 이런 세균류를 근본적으로 효과 있게 제거하기 위하여 숯을 항균 처리할 필요가 있게 된다.A large number of molds feeding the adsorbed organic materials may occur in the pores of the char. At this time, bacteria and molds that feed the organic substances adsorbed in the pores are generated, causing bacteria to multiply in the pores of the char. Due to decay, the deodorizing performance, which is a unique feature of charcoal, is markedly degraded. In order to effectively remove these bacteria, charcoal needs to be treated with antibacterial treatment.

이런 유해세균은 숯 자체의 능력으로 어느 정도 감소시킬 수 있지만 많은 유기물이 흡착되었거나 습도가 높은 곳에서는 전혀 효과를 기대할 수 없다.These harmful bacteria can be reduced to some extent by the ability of the charcoal itself, but no effect can be expected at all where many organic substances are adsorbed or in high humidity.

따라서 인위적으로 좀 더 강력하고 효과적으로 살균, 항균 능력을 부여해야 할 필요성이 있다고 할 수 있다.Therefore, there is a need to give artificially more powerful and effective sterilization and antibacterial ability.

일반적으로 은은 전도성이 뛰어나고 정전기 및 전자파를 차단하며 수맥차단 효과가 있으며 인체에 무해하여 고대로부터 독성감지 및 항균, 살균효과가 반영구적으로 나타나는 무기 물질임이 각종 실험을 통해 알려지고 있다.In general, silver has excellent conductivity, blocks static electricity and electromagnetic waves, has water vein blocking effect, and is harmless to human body.

통상 은을 통해서 각종 세균에 대한 항균력을 가지게 하려면 약200ppm의 은 이온 농도를 확보해야 하는데 이를 손쉽게 정량화하기 위하여 본 기능성 도료는 나노은을 사용한다.
나노 은은 순도 99.99%의 은을 고전압을 통해 폭발시킬 때 발생하는 250나노 크기로 분해된 은 입자를 모은 것으로 순수 은 입자이므로 이를 계량하여 균일한 농도비를 손쉽게 얻을 수 있다.
In general, in order to have antibacterial activity against various bacteria through silver, it is necessary to secure a silver ion concentration of about 200 ppm. In order to easily quantify this functional coating, nano silver is used.
Nano silver is a collection of 250 nanoparticles of silver decomposed to a high purity of 99.99% of silver, which is generated when exploding through high voltage. Pure silver particles can be easily measured to obtain a uniform concentration ratio.

인체에 전혀 무해하면서도 강력한 살균, 항균성을 가진 순수 은궤를 수용성 액화하기 위하여 다음과 같이 실시하였다.In order to liquefy pure silver ace, which is harmless to human body and has strong sterilization and antibacterial effect, it was carried out as follows.

순도99.99%인 은선(Silver Wire)의 양쪽 끝 즉 양극에 변압기를 통해 저장된 전기에너지를 펄스로 압축한 후 고전압 스위치를 통하여 15만 볼트의 고밀도전류를 순간적으로 은선에 인가하면 극히 높은 온도 상태인 플라즈마가 발생하게 된다.
이렇게 생성된 저항 발열을 통해 은을 기화 또는 이온화시켜 150nm- 250nm크기로 분해된 나노 은 입자를 얻는다.
After compressing the electric energy stored through the transformer at both ends of the silver wire (99.99% purity), the anode with pulse, and applying high density current of 150,000 volts to the silver wire momentarily through the high voltage switch, the plasma is in extremely high temperature state. Will occur.
Through the generated resistance heating, the silver is vaporized or ionized to obtain nano silver particles decomposed to a size of 150 nm to 250 nm.

또한 얻어진 나노 은 입자를 포집하여 물에 분산시킴으로 나노 은이 포함된 수용액을 제조한다.In addition, the obtained nano silver particles are collected and dispersed in water to prepare an aqueous solution containing nano silver.

이렇게 전기플라즈마 법으로 얻어진 나노은 은 기존의 극약성 질산염과 가성소다를 첨가하여 추출하는 물리적, 화학적 방법으로 얻는 콜로이드 은용액이나 포르말린이 주성분인 방부제나 유기 항균제를 첨가하여 제품화 했을 때 발생하는 인체에 대한 유해성과 제품 속에 내재된 오염원의 잠재 환경 위험성을 피하면서도 강력한 살균과 항균 작용을 하는 바람직한 방법으로 순수 은 을 친환경적으로 이용하는 차별적인 나노 은 기술인 것이다.The nano silver obtained by the electroplasmic method is a colloidal silver solution obtained by the physical and chemical method of extracting by adding the existing ultra weak nitrate and caustic soda or the formalin-based preservative or organic antibacterial agent. It is a differentiated nano silver technology that uses pure silver in an environmentally friendly way as a powerful way of sterilizing and antibacterial, while avoiding the hazards and potential environmental hazards of the pollutants inherent in the product.

음이온이 대량 발생하는 음이온 전기석 광물을 첨가하였는데 음이온 광물의 특성과 효과는 성문 화학사전 (삼광 인쇄사 편저)에 잘 나타나있다.
1880년 노벨 물리학상을 수상했던 퀴리부부 중 남편 피에르 퀴리씨가 형 자크와 함께 전기석 결정에서 끊임없이 0.06m의 미약전류인 음이온이 항상 방출되는 것을 발견하였는데 본 발명은 350 메쉬 크기로 분말화한 전기석을 첨가하여 음이온을 대량 방출하는 기능성 살균, 탈취제를 제조하였다.
Anion tourmaline minerals with large anions are added, and the characteristics and effects of anion minerals are well represented in Sungmun Chemical Dictionary (ed by Samkwang Printing Company).
Among the Curie couples, who won the Nobel Prize in Physics in 1880, their husband, Pierre Curie, found out that with Jacques, he constantly released 0.06 m of weak currents in the tourmaline crystals. To prepare a functional sterilization, deodorant to release a large amount of anions.

본 기능성 도료에 사용하는 수용성 바인더는 아크릴 에멀젼바인더와 수용액화한 폴리비닐부티랄(poly vinyl butyral)을 서로 교반하여 혼합한 수용액을 사용한다.
이때 상기한 아크릴 에멀젼의 농도가 30%인 것을 사용하고, 폴리비닐부티랄의 농도도 30%로 수용액화한 것을 사용한다.
이때 상기한 폴리비닐부티랄(poly vinyl butyral)은 중합체, 수산기, 지방족화합물이며 산업안전보건규정(MSDS)에서 흡입, 피부접촉, 눈 접촉, 섭취, 에 대한 부작용과 반응성이 없고 유럽연합(EC)과 미국산업안전보건청 분류에도 발암성, 유해위험성=0 인 미규정 물질로, 물성이 안정된 수용성이며 접착력이 있으나 상호 밀도가 낮음으로 인해 기체 투과력이 있는 폴리비닐부티랄 을 이용하여 숯과 은을 피착 면에 부착시키는 접착제로 사용함으로 숯의 기공성을 확보하여 각종 실내건축자재 및 생활공간에서 발생하는 유해가스가 숯의 기공 속으로 원활하게 침투, 흡착되는 구조를 가지게 하여 숯의 고유기능인 탈취력을 저해 하지 않았다.
The water-soluble binder used for this functional paint uses the aqueous solution which stirred and mixed the acrylic emulsion binder and the polyvinyl butyral which was made into aqueous solution, mutually.
At this time, the above-mentioned acrylic emulsion has a concentration of 30%, and the polyvinyl butyral concentration is also used as an aqueous solution at 30%.
At this time, the polyvinyl butyral is a polymer, a hydroxyl group, and an aliphatic compound, and has no side effect and reactivity with inhalation, skin contact, eye contact, ingestion, etc. in the Industrial Safety and Health Regulation (MSDS). The carcinogen and the US Occupational Safety and Health Administration have also classified the charcoal and silver by using polyvinyl butyral with gas permeability due to its stable water solubility and adhesion but low mutual density. It is used as an adhesive to adhere to the adhered surface to secure the porosity of charcoal, so that harmful gas generated in various indoor building materials and living spaces can be easily penetrated and adsorbed into the pores of charcoal. Did not inhibit.

상기 각 물질을 합성하고 혼합한 본 기능성 나노은, 숯 도료의 적용 실시예는 다음과 같다.Examples of application of the present functional nano silver and charcoal paints synthesized and mixed with each material are as follows.

(실시예)(Example)

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고속 교반기속에 농도가 30%인 아크릴 에멀젼바인더와 농도가 30%인 액상화한 폴리비닐부티랄(poly vinyl butyral)을 혼합하여 수용액화한 혼합수용액 1000㎖와 150nm ~ 250nm의 크기로 분산 시킨 나노 은 수용액 20㎖를 혼합하여 총량 대비 나노 은의 이온농도가 200ppm이 되게 한 다음, 입도 크기가 350 메쉬인 숯 250g과 입도 크기가 350 메쉬인 음 이온석 50g을 각각 투입한다.
이러한 상태에서 고속 교반기를 작동하여 1000rpm의 속도로 교반하여 혼합한 다음, 준비된 용기에 담고 밀봉한다.
An aqueous solution of 30% acrylic emulsion binder and 30% liquefied polyvinyl butyral was mixed in a high speed stirrer to disperse the aqueous solution into 1000 ml and the nano silver solution dispersed in the size of 150 nm to 250 nm. After mixing 20ml to make the ion concentration of nano silver to the total amount 200ppm, 250g of charcoal having a particle size of 350 mesh and 50g of anionic stone having a particle size of 350 mesh are added thereto.
In this state, a high speed stirrer is operated to stir at a speed of 1000 rpm, mixed, and then placed in a prepared container and sealed.

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상기 기능성 나노 은, 숯 도료의 시편을 한국과학기술 연구소(KIST) 대기자원연구소에서 탈취 시험한 결과 벤젠과 포름알데히드를 흡착 제거하는 탈취효율이 대단히 우수하다고 기재된 논문을 공식 공문으로 수령하였으며 상기 기능성 나노은, 숯 도료의 세균에 대한 살균력 시험을 위해 한국 원사직물 연구원에 의뢰한 결과 99.9%의 살균력을 나타내고 있는 시험 성적서를 교부 수령 받은바 이는 본 기능성 나노은, 숯 도료의 효과를 객관적으로 증명한다 하겠다.As a result of the deodorization test of the functional nano silver and charcoal paint specimens at the Korea Institute of Science and Technology (KIST) Air Resources Research Institute, the official document received a paper stating that the deodorization efficiency of adsorption and removal of benzene and formaldehyde was very excellent. In order to test the bactericidal power of charcoal paints, we received a test report showing 99.9% of bactericidal power, and this objectively proves the effect of this functional nano silver and charcoal paint.

본 발명의 기능성 도료는 실내 마감재 시공 전의 천장, 벽면, 바닥 등의 표면에 분포하므로 시멘트의 강알칼리 독성을 중화 차폐하며 실내의 각종 건축자재에서 발생하는 유해가스를 흡착 제거함으로 별도의 탈취제와 살균제가 필요 없게 하였고, 또한 강한 자극취 발생 장소 등에도 활성 숯의 기공이 넓은 면적에 도포, 노출됨으로 정화기능이 탁월하게 나타나고 있으며 숨 쉬는 다수의 숯 기공과 나노 은과 음 이온석 등의 작용에 의해 유기 산화 화합물의 탈취는 물론이고 각종 생활 악취, 기체매연, 부유성 먼지 등을 흡착, 정화, 탈취하며 나노 은에 의한 공기살균과, 전기석 광물로 인한 음이온, 원적외선방출 등 습도조절, 세포활성작용 등의 효능이 일체적이고, 반영구적으로 나타나게 하였으며 친환경적이고 인체에 유익하여 쾌적한 생활환경을 손쉽게 누릴 수 있게 한 삶의 질을 향상 시킬 수 있는 새로운 개념의 기능성 살균, 탈취 도료이다.The functional paint of the present invention is distributed on the surface of the ceiling, wall, floor, etc. before construction of the interior finishing material neutralizes the strong alkali toxicity of cement, and requires a separate deodorant and disinfectant by adsorption and removal of harmful gases generated from various building materials in the room. In addition, the pores of activated charcoal are applied to a large area and exposed to strong irritant odors, resulting in excellent purification and organic oxidation compounds by the action of many breathing char pores and nano silver and negative ion stones. As well as deodorizing, it adsorbs, purifies and deodorizes various odors, gaseous smoke and floating dusts, and it is effective in controlling humidity and cellular activity such as air sterilization by nano silver, anion due to tourmaline minerals, and far infrared emission. It is integrated, semi-permanent, eco-friendly and beneficial to the human body. It is a new concept of functionality sterilization, deodorizing coatings that may be able to enjoy an improved quality of life.

본 도료의 응용으로는 실내건축재료 및 콘크리트 바닥, 합판, 실내인테리어, 산업제품, 생활용품, 초배지, 벽지 등의 각종 형상의 안팎 표면에 부착되어 각종 악취차폐, 공기정화, 음이온방출 등의 목적으로 사용할 수 있으며 각종 캐릭터 상품 속에 부착 동봉함으로써 차량이나 실내의 공기 정화와 담배냄새탈취, 살균, 음이온, 원적외선, 방출을 위한 용도로 사용되어질 수 있다.The application of this paint is applied to the interior and exterior surfaces of various shapes such as interior building materials, concrete floor, plywood, interior decoration, industrial products, household goods, grass paper, wallpaper, etc. It can be used and enclosed in various character products, and can be used for air purification and deodorization of cigarettes, sterilization, negative ion, far infrared ray and emission in vehicle or indoor.

특히 건조된 나노은, 숯 도료의 검은 표면이 나노은 입자(150nm- 250nm 크기) 에 의해 시각적으로 반짝이게 됨으로 살균, 탈취와 더불어 귀금속인 은을 통한 고급스런 시각적 느낌을 강하게 줌으로 피착면의 미적 부가가치도 크게 높일 수 있다.In particular, the black surface of dried nano silver and charcoal paint is visually shimmered by nano silver particles (150nm-250nm size), so as to sterilize and deodorize, and give a high-quality visual feeling through silver, which is a precious metal. It can be greatly increased.

Claims (1)

고속 교반기 속에 농도가 30%인 아크릴 에멀젼바인더와 농도가 30%가 되도록 수용액화한 폴리비닐부티랄(poly vinyl butyral)을 혼합한 혼합 수용액 1000㎖와 150nm ~ 250nm의 크기로 분산 시킨 나노 은 수용액 20㎖를 혼합하여 총량 대비 나노 은의 이온농도가 200ppm이 되게 한 다음, 입도 크기가 350 메쉬인 숯 250g과 입도 크기가 350 메쉬인 음 이온석 50g을 각각 투입하여 혼합하는 것에 의해 제조된 나노 은과 숯을 이용하여 제조한 기능성 도료.1000 ml of mixed aqueous solution mixed with 30% acrylic emulsion binder and 30% polyvinyl butyral solution in a high speed stirrer and nano silver aqueous solution dispersed in the size of 150nm ~ 250nm The nano silver and charcoal were prepared by mixing ㎖ to make the ion concentration of nano silver to the total amount 200ppm, and then mixing by adding 250 g of char with a particle size of 350 mesh and 50 g of negative ion stone with a particle size of 350 mesh. Functional paint prepared using.
KR1020040094821A 2004-11-16 2004-11-16 Functional paint made using nano silver and charcoal KR100626176B1 (en)

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