KR100623069B1 - Manufacturing method of ceramic product - Google Patents

Abstract

The present invention relates to a method of manufacturing building materials and living magnetics using wave water, comprising 1.16 to 1.28 mg / 100 g of calcium, 3.33 to 3.44 mg / 100 g of potassium, and 3.57 to 4.41 mg in reduced pressure purified water. Wave minerals, talc, and clay obtained by spraying mineral mixtures obtained by mixing / 100 g sodium and 0.074 to 0.14 mg / 100 g magnesium, and then radiating 30 million to 300 million cycles of topical microwaves. , Feldspar, clay, kaolin, feldspar, earth, siliceous, dolomite, limestone or alumina are blended with raw materials used in the manufacture of porcelain, tiles, walls and floorings, and then molded into their respective shapes using blended bases. After sintering first, it is immersed in glaze mixed with wave water and roasted at high temperature to emit far infrared rays and anions, and it is used for building materials such as bathroom, kitchen, living room, wall, floor, etc. B, cups, utensils and cups, and how to make a porcelain, such as Goji.

Description

Manufacturing method of ceramic product

The present invention relates to a method of manufacturing a ceramic magnetic material using wave water, and more specifically, to a bathroom, a kitchen, a living room, a wall material, a floor tile, a tableware or a mug, a goggle, etc. It relates to a manufacturing method.

In general, building materials, specifically, building materials such as tile materials are mixed with water such as clay, kaolin, feldspar, earth and limestone, and then molded into a predetermined form and baked at 1,120 ?? It has been produced by heat treatment by coating with glaze and baking at 1020 ??

And, also known as living mugs, such as tea cups and goggles, such as clay, white clay, feldspar, silica, talc, earth, limestone, or alumina is formed by mixing with water and then the primary firing (pre-baking) 400 to 750? It has been produced through the process of baking at 800-1000 ?? by secondary firing after coating with?, Glaze.

By the way, in the case of the tile material or the living magnetic obtained by the above method, far infrared ray emission, anion emission, deodorizing action or antimicrobial action were insignificant, and thus it was not functional.

Accordingly, the present invention is to provide a method for manufacturing a building material or a living magnetic having a more functional, after spraying the mineral mixture solution obtained by mixing an appropriate amount of minerals in reduced pressure purified water, The number of waves obtained by radiating 30 million to 300 million cycles of local microwaves is used for the manufacture of building materials and household magnetics.

An object of the present invention is to provide a method for producing a ceramic magnetic material with improved emission performance of far infrared rays and anions, and excellent in deodorization and antibacterial performance.

Another object of the present invention is to provide a method of manufacturing a ceramic magnetic material such that the functionality does not disappear even after a long heat treatment, but the functionality is improved even in a long time of high heat treatment.

Method for producing a ceramic magnetic material of the present invention for achieving the above object is 1.16 ~ 1.28mg / 100g calcium, 3.33 ~ 3.84mg / 100g potassium, 3.57 ~ 4.11mg / 100g sodium and 0.074 ~ in reduced pressure purified water After spraying a mineral mixture solution obtained by mixing 0.14 mg / 100 g of magnesium, and then emitting 30 million to 300 million cycles of topical microwaves, talc, clay, feldspar, white clay, kaolin, feldspar, earth stone, A first step of preparing a blended base by mixing silica, dolomite, limestone or alumina; A second step of molding into a predetermined shape; A third step of primary firing for 14 to 24 hours with a heat of 600 to 800 ° C .; A fourth step of slowly cooling at room temperature for 6 to 10 hours; A fifth step of mixing the wave water with a glaze and coating the molded product; And a sixth step of secondary firing for 8 to 12 hours at 1,300 to 1,400 ??.

The present invention will be described in more detail as follows.

Power wave water used in the manufacture of ceramic magnetic materials, such as building materials or living magnetic materials of the present invention is produced by the method disclosed in the domestic patent No. 348473, which is the applicant's October 2003 It is a 25-character transfer of rights from the original applicant.

As disclosed herein, since the wave number used in the present invention is manufactured by using 30 to 300 million cycles of topical microwaves and natural minerals such as potassium and calcium, which have been researched and developed for medical treatment purposes, it is very useful for the human body. And safe. Therefore, it is harmless to the human body even if it is used for vegetables or fruits in addition to the life magnet.

In the method of preparing the wave water, the purified water is added to a stirrer, a certain amount of minerals are mixed, and then the mineral solution is sprayed at about 10,000 to 15,000 rpm, and then the microwave wave system radiates the microwaves emitted from the microwave generator. Is performed by.

In the above, the mineral is used while varying the amount and type of sodium, potassium, selenium, manganese, zinc, calcium, magnesium, molybdenum, chromium or zinc according to the purpose of the use of the wave number, 1.16 ~ 1.28mg / 100g calcium, 3.33 to 3.84 mg / 100 g of potassium, 3.57 to 4.11 mg / 100 g of sodium and 0.074 to 0.14 mg / 100 g of magnesium are used.

On the other hand, the microwave generator in the synch wave system is not particularly limited, and uses a device capable of generating microwaves having 30 million to 300 million cycles of those commonly used in the art.

The method of manufacturing building materials and living porcelain using the wave water produced by the above method is, first, talc, clay, feldspar, clay, kaolin, leadstone, clay, quartz, dolomite The base is prepared by directly mixing, limestone or alumina in wave water.

At this time, the mixing amount of the wave water is not particularly limited, but is used in the same amount of water used to produce a general product. Specifically, it is preferable to mix the wave number according to the weight and humidity of the raw material of the ceramic magnetic material. If the mixing amount of the wave water is excessive, the original shape may be changed. If the mixing amount of the wave water is too small, not only the molding is difficult but also the functionality due to the addition of the wave water is difficult to exhibit.

When the base is to be used in a predetermined shape, for example, flooring, it is molded in the form of a square tile, or in the case of using as a living magnet, it is molded in the form of a mug, cup, tableware or the like. Since the shaping | molding method follows a conventional method, it is not specifically limited.

Such moldings are baked by primary firing at 600-800 ° C. for 14-24 hours. At this time, the temperature of primary firing is 600 ?? If it is lower, all functions are weak and easy to break. If it is higher than 800 °, the molding state may be changed or broken. If the primary firing time is out of the above range, not only the molding state changes but also a problem in which the functional state does not diverge normally may occur.

Then, the molded product after the primary firing is taken out, cooled to room temperature for 6 to 10 hours, and then glazed. At this time, apply a mixture of glaze and wave water. When mixing the glaze and the wave water, the mixing ratio is preferably 1: 1.5 to 1: 1.6. If the mixing amount of the wave water is too small, the flow of the glaze is not spread evenly, and the surface is uneven. If the functional state may be abnormal and the amount of wave water is excessively high, there may be a problem in that the flow of the glaze is wandering, the gloss is blurred, and the functional state may be abnormal.

The first firing is performed after glazing, and the conditions of the second firing are preferably performed at 1300 to 1400 ° for 8 to 12 hours. If the temperature of the secondary firing is lower than 1300 ??, the glaze of the glaze is lost and its function is weakened. If the temperature of the secondary firing is higher than 1400 ??, it is not only broken, but also fine gold is formed, thereby deteriorating the function. When the time required for the secondary firing is out of the above range, there may be a problem in that the product may not be released as well as the product may be damaged.

As such, the finished product after the second firing can maintain its functionality in any environment in daily use, and there is no alteration or change, and its function and effect are semi-permanent.

The term "functionality" herein refers to further improving the emission performance of the far-infrared rays owned by itself, generating anions, and deodorizing and antibacterial functions.

Hereinafter, although an Example is given and this invention is demonstrated in detail, this invention is not limited by an Example.

Preparation Example 1. Preparation of wave water (according to the method disclosed in Patent No. 348473)

1.2 mg / 100 g, potassium 3.50 mg / 100 g, sodium 38.4 mg / 100 g and magnesium 0.08 mg / 100 g were added to the purified water, and the mixture was mixed at 12,000 rpm to prepare a mineral mixed solution. Then, the mineral mixed solution was filtered through a 100 million cycle microwave generator to obtain a wave water in which microwaves were radiated.

Example 1 Preparation of Functional Tiles

Clay, kaolin, feldspar, earth stone, limestone mixed feldspar, silica, dolomite, talc, etc. were mixed and mixed in 1 ton at an appropriate ratio to prepare a base.

The base was poured into a mold made of iron or gypsum to form a square, rectangular, or triangular shaped article, which was then baked for 20 hours in a heat of 800 ° C. and then cooled at room temperature for 6 to 10 hours.

The number of waves obtained from Preparation Example 1 was mixed in the glaze in a ratio of 1: 1.5, and then coated on the first baked molding, and then secondarily baked at 1300 ?? for 10 to 12 hours to prepare a tile.

Example 2: Preparation of Functional Mug

Clay, kaolin, feldspar, earth stone, limestone mixed feldspar, silica, dolomite, talc and the like were mixed in 20 L of the wave number obtained in Preparation Example 1 to prepare a base by mixing 1 ton at an appropriate ratio.

The base was poured into a cast iron mold to form a cup or cup-shaped molding, and then roasted for 18 to 24 hours with a heat of 800 ° C., and then cooled at room temperature for 8 hours.

The number of waves obtained from Preparation Example 1 was mixed in a glaze in a ratio of 1: 1.5, and then coated on the first roasted molding, and then roasted again at 1300 ° for 10 hours to prepare a mug.

Experimental Example 1 Evaluation of Tiles Prepared from Example 1

The functional tiles obtained in Example 1 were commissioned by the Korea Institute of Construction Materials for deodorization tests, and the results are shown in Table 1 below.

Test Items Deodorization test (NH ₃ ) Elapsed time (minutes) Control concentration (ppm) Sample concentration (ppm) Deodorization rate (%) Test result 30 194 142 26.8 60 152 106 30.3 90 131 90 31.3 120 116 78 32.8 Test Methods KICM-FIR-1085

From the results in Table 1, it can be seen that the tiles obtained using the wave number has a deodorizing performance.

In addition, the far-infrared emission of the tile obtained from Example 1 was requested by the Korea Institute of Construction Materials Evaluation and Evaluation Center and the results are shown in Table 2 below. In addition, the amount of anion release was measured and the results are shown in Table 3 below.

Test Items Test result Test Methods Far infrared ray emission amount (40 ??) Emissivity (5 ~ 20㎛) 0.920 KICM-FIR-1005 Radiation energy (W / ㎡) 3.71 ㅧ 10 ²

Test Items Test result Test Methods Anion (ION / cc) Blank 75 KICM-FIR-1042 Example 1 425

Blank in Table 3 was prepared in the same manner as in Example 1, except that a tile prepared using water instead of wave water was used.

From the results of Tables 1 to 3, it can be seen that in the case of the tile manufactured using the wave water, not only the large amount of far infrared rays are emitted, but also the anion emission amount is higher than that produced without using the wave water.

Experimental Example 2: Evaluation of the mug prepared from Example 2

The cup obtained from Example 2 was commissioned by the Korea Institute of Construction Materials for deodorization test, and the results are shown in Table 4 below.

Test Items Deodorization test (NH ₃ ) Elapsed time (minutes) Control concentration (ppm) Sample concentration (ppm) Deodorization rate (%) Test result 30 194 149 23.2 60 152 113 25.7 90 131 96 26.7 120 116 84 27.6 Test Methods KICM-FIR-1085

From the results of Table 4, it can be seen that the mug obtained using the wave water has a deodorizing performance.

In addition, the mug obtained from Example 2 was requested to the far-infrared application evaluation center of the Korea Institute of Construction Materials Testing and the far-infrared emission is measured and the results are shown in Table 5 below. In addition, the amount of anion release was measured and the results are shown in Table 6 below.

Test Items Test result Test Methods Far infrared ray emission amount (40 ??) Emissivity (5 ~ 20㎛) 0.916 KICM-FIR-1005 Radiation energy (W / ㎡) 3.69 ㅧ 10 ²

Test Items Test result Test Methods Anion (ION / cc) Blank 73 KICM-FIR-1042 Example 1 76

Blank in Table 6 was prepared in the same manner as in Example 1, but using a mug prepared using water instead of wave water.

From the results of Tables 4 to 6, in the case of the mug prepared using the wave water not only emits a large amount of far-infrared rays, but also the anion release amount is more anion is released and deodorizing function is superior to that produced without using the wave water Able to know.

 As described in detail above, according to the present invention, a base is prepared by mixing the wave water with talc, clay, feldspar, clay, kaolin, feldspar, earth, silica, dolomite, limestone or alumina, and then forming the base into a predetermined shape. After the first firing at a constant temperature and time conditions, coated with a mixture of glaze and wave water, and then secondary firing at a high temperature to produce a deodorizing and antibacterial effect while emitting far-infrared rays and anions, It is useful for manufacturing general ceramic products such as construction materials, and household appliances such as tea cups and tableware.

Claims (4)

A mineral mixed solution obtained by mixing 1.16-1.28 mg / 100g calcium, 3.33-43.8 mg / 100g potassium, 3.57-44.1 mg / 100 g sodium and 0.074-0.14 mg / 100 g magnesium with reduced pressure After, the base water to make a blended base by mixing the wave water and talc, clay, feldspar, white clay, kaolin, feldspar, earth stone, silica, dolomite, limestone or alumina prepared by radiating local microwaves of 30 million to 300 million cycles First step; A second step of molding into a predetermined shape; A third step of primary firing with heat of 600 to 800 ° C. for 14 to 24 hours; A fourth step of slowly cooling at room temperature for 6 to 10 hours; A fifth step of mixing the wave water with a glaze and coating the molded product; And A method of manufacturing a ceramic magnetic material through a sixth step of secondary firing for 8 to 12 hours at 1,300 to 1,400 ??. The method of manufacturing a ceramic magnetic material using wave water according to claim 1, wherein the glaze and the wave water are mixed at a weight ratio of 1: 1.5 to 1: 1.6 in a fifth step. delete delete