KR100611631B1 - Prepation Method of Deodorant for Sewage - Google Patents

Prepation Method of Deodorant for Sewage Download PDF

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KR100611631B1
KR100611631B1 KR1020030077111A KR20030077111A KR100611631B1 KR 100611631 B1 KR100611631 B1 KR 100611631B1 KR 1020030077111 A KR1020030077111 A KR 1020030077111A KR 20030077111 A KR20030077111 A KR 20030077111A KR 100611631 B1 KR100611631 B1 KR 100611631B1
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deodorant
particle size
calcium carbonate
prepation
sewage
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KR20040051496A (en
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정청식
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(주)지엔씨글로텍
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/16Disinfection, sterilisation or deodorisation of air using physical phenomena
    • A61L9/18Radiation
    • A61L9/20Ultraviolet radiation
    • A61L9/205Ultraviolet radiation using a photocatalyst or photosensitiser
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/39Photocatalytic properties
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20Method-related aspects
    • A61L2209/22Treatment by sorption, e.g. absorption, adsorption, chemisorption, scrubbing, wet cleaning

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Veterinary Medicine (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Epidemiology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

본 발명은 천연 광물질에서 갖고 있는 특성중 부분적인 기능을 극대화하여 물리적 흡착 및 화학적 흡착을 동시에 갖을 수 있도록 하는 한편 사용중에나 사용후에 인, 축에 해가 없도록 한 것이다.The present invention maximizes the partial function of the properties of natural minerals so as to have physical adsorption and chemical adsorption at the same time, while preventing the phosphorus, axis during use or after use.

소취, 광촉매Deodorant, Photocatalyst

Description

동물분뇨 냄새흡착제 제조방법{Prepation Method of Deodorant for Sewage}Production method of animal manure odor adsorbent {Prepation Method of Deodorant for Sewage}

본 발명은 소취제, 특히 동물 분뇨의 냄새를 흡착 제거하는 냄새 흡착제의 제조방법에 관한 것이다. The present invention relates to a method for producing a deodorant, in particular an odor adsorbent for adsorbing and removing odors of animal manure.

각종의 동물들로부터 쏟아지는 오물들은 우리 인간들의 호흡기에 적지 않은 피해를 주기도 하고 또한 이로 인한 폐해 역시 매우 심각한 경지에 이르고 있다.Dirt from various kinds of animals can cause a lot of damage to our human respiratory system, and the damage caused by this is very serious.

각종 동물 사육장에서 발생되는 강한 악취와 각종 바이러스균류 번식 등으로 그 주변에는 주거가 불가능한 경지에 이른다.Due to the strong odor generated in various animal breeding grounds and the breeding of various virus fungi, it is impossible to live in the surrounding area.

더욱이 사계절 대량으로 사육하고 있는 사육장 주변의 주거지는 물론 하절기에는 원거리에 있는 곳까지 심각하게 썩는 냄새가 주거환경의 피해를 주고 있으나 이를 방지할만한 대책안이 매우 미진한 상태이며 이에 고심하고 있다.Moreover, severe rotting odors in residential areas around the kennels, which are being reared in four seasons, as well as in remote areas in summer, are damaging to the residential environment, but there are very few measures to prevent them.

그러나, 화학적 공법으로 만들어진 유기질 소취제를 사용하였을 시에는 퇴비화 하는데에는 불가능하고 혹여 사용하였을 시에는 심각한 피해를 초래함으로 원천적으로 사용을 할 수 없다.However, the use of organic deodorant made by the chemical process is impossible to compost, and when used, it can not be used inherently because it causes serious damage.

또, 분뇨를 드라이시키는 방법을 사용하는 것과 기계적 성질을 이용하여 미 생물로 처리방법 등이 있으나 이러한 방법은 고비용 저 효율성의 문제점들을 수반하고 있으며 영세의 농가에서는 이러한 방법을 사용하기에는 여러 가지의 문제점들을 가지고 있을 뿐만 아니라 우리 나라에서는 불가능할 수밖에는 없다.In addition, there is a method of drying manure and treating it with microorganisms using mechanical properties. However, this method has problems of high cost and low efficiency, and it is difficult to use this method in small farms. Not only do we have it, but it is impossible in our country.

따라서, 본 발명의 목적은 모재( Matrix )를 천연 광물을 이용하여서 인간에게는 피해를 주지 않도록 하는 한편 악취가 발생되는 곳에 적은 양만을 사용하여도 강력한 냄새의 흡착력을 갖는 냄새흡착제의 제조방법을 제공하는 것이다. Accordingly, an object of the present invention is to provide a method for preparing an odor adsorbent having a strong odor adsorption power even when only a small amount is used in a place where odor is generated while preventing the human body by using a matrix as a natural mineral. will be.

본 발명의 다른 목적은 소취제로 사용 후 다시 퇴비화시 토양의 개선의 효과가 매우 뛰어나고 토양에서의 삼대요소인 질소, 인산, 칼륨 (N, P, K)는 물론이거니와 토양의 미량요소인 마그네슘(Mg)의 성분을 보충하여 주어 각종 여러 식물들에게 필수적인 성분을 공급하여 줄 수 있는 냄새흡착제를 제공하는 것이다.
Another object of the present invention is very good effect of improving the soil when composting again after use as a deodorant and nitrogen, phosphoric acid, potassium (N, P, K) of the three major elements of the soil, as well as magnesium (Mg) as a trace element of the soil By supplementing the ingredients of) to provide a variety of plants essential ingredients to provide an odor adsorbent.

상기 본 발명의 목적은 탄산칼슘과 EDTA-2Na를 물에 부가하여 슬러리 상태로 만든 다음, 광촉매 입자 졸을 부가하여 광촉매 입자를 탄산칼슘에 코팅시킨 후, 다시 마그네슘 졸을 부가하여 코팅시키는 것을 특징으로 하는 냄새흡착제의 제조방법에 의해 달성된다. The object of the present invention is to add calcium carbonate and EDTA-2Na to the water to make a slurry, and then add the photocatalyst particles sol to coat the photocatalyst particles on calcium carbonate, and then add magnesium sol to coat again It is achieved by a method for producing an odor adsorbent.

탄산칼슘의 입자크기는 75㎛ 이하의 미립자로 형성하며, 천연광물인 방해석인 것과 6방정계의 결정구조를 갖는 것을 선별하여 사용한다. 또, 미분쇄 분말을 1000℃로 가열한 다음 급냉시키는 방법으로 공극을 형성하여 흡척 성능을 향상시킨다. The particle size of calcium carbonate is formed into fine particles of 75 μm or less, and the calcite which is a natural mineral and the one having a hexagonal crystal structure are selected and used. In addition, the pulverized powder is heated to 1000 ° C. and then quenched to form voids to improve the suction performance.

광촉매는 이산화 티탄(TiO2)이며 입자크기 20nm∼35nm와 고형분(NOV)값이 10%인 졸 형태로 사용한다. The photocatalyst is titanium dioxide (TiO 2 ) and is used in the form of a sol having a particle size of 20 nm to 35 nm and a solid content (NOV) value of 10%.

마그네슘(Mg)은 순도 99.9%이상, 고형분값(Nov)3% 이상의 졸을 사용한다. Magnesium (Mg) uses a sol having a purity of 99.9% or more and a solid content value (Nov) 3% or more.

상기한 목적을 달성하기 위한 본 발명을 실시함에 따라 상세히 설명하면 다음과 같다.When described in detail according to the present invention for achieving the above object is as follows.

실시예 1 Example 1

분자량 100.09의 값을 가지고 있는 것과 순도 98% 이상의 것인 탄산칼슘(CaCO3)을 엄선하여, 큰돌을 분쇄하는 죠크락샤 기계에 넣어 입자크기 200매쉬(75㎛) 이내로 잘게 분쇄하여 탄산칼슘(CaCO3)으로서 천연광물인 방해석인 것과 6방정계의 결정구조인 것을 엄선하였다. 얻어진 분말을 1000℃의 자연 분위기 고온로에서 5시간 가열 후 급랭 시켰다. Calcium carbonate (CaCO 3 ), which has a molecular weight of 100.09 and a purity of 98% or more, is carefully selected and placed in a jaw crusher that grinds large stones and finely pulverized to within 200 mesh (75 μm) in particle size. 3 ) selected as calcite which is a natural mineral and crystalline structure of 6 tetragonal system. The obtained powder was quenched after heating for 5 hours in a natural atmosphere high temperature furnace at 1000 ° C.

반응기에 순수 60중량%를 넣고 EDTA-2Na인 촉매제(Catalyst)를 0.1%넣은 후 10분동안 용해가 잘되도록 RPM300의 속도로 저어 주었다. 60% by weight of pure water was added to the reactor, and 0.1% of a catalyst (Catalyst), which was EDTA-2Na, was stirred at a speed of RPM300 to dissolve well for 10 minutes.

균질한 공극이 발달된 상기에서 제조된 탄산칼슘 파우더를 반응기 통에 넣어 30분동안 300RPM의 속도로 교반시키어 묽은 상태의 슬러리(Slurry)를 만든 다음, 상기의 공정에서 얻어진 슬러리(Slurry)상태의 현탁액의 입자(200매쉬:75㎛)들의 표면에 20nm∼35nm크기로 형성된 것들을 코팅 시키기 위하여 무기질 항균제인 광촉매(TiO2)졸 입자크기 20nm∼35nm와 고형분(NOV)값이 10%인 것으로 엄선된 것을 3중량%를 넣었다. The calcium carbonate powder prepared above, which had developed the homogeneous pores, was stirred in a reactor vessel at a speed of 300 RPM for 30 minutes to form a thin slurry, and then the slurry suspension obtained in the above process. In order to coat 20 nm to 35 nm of particles formed on the surface of the particles (200 mesh: 75 μm), the inorganic antimicrobial photocatalyst (TiO 2 ) sol particle size of 20 nm to 35 nm and solid content (NOV) value of 10% were carefully selected. 3 weight percent was added.

상기의 공정에서 얻어진 것을 마그네슘(Mg) 순도 99.9%이상의 것을 엄선을 한후 마그네슘(Mg)을 고형분값(Nov)3% 이내의 졸(Sol)을 엄선하여 이를 다시 슬러리(Slurry)상태의 100RPM의 속도로 교반시키는 현탁액에 위에서 만들어진 마그네슘(Mg), 고형분값(Nov)3% 의 용질액을 3중량% 서서히 첨가시켜 주었다. After selecting the magnesium (Mg) purity more than 99.9% obtained in the above process, carefully select the magnesium (Mg) and the sol (Solu) within 3% of solid content value (Nov), and then again the rate of 100RPM in the slurry state 3% by weight of the solute solution of magnesium (Mg) and solid content (Nov) 3% prepared above was slowly added to the suspension stirred with.

상기공정을 모두 마친 것을 40℃의 온도로 24시간 동안 열을 가해주어 코팅층이 형성하도록 하였다. After completing the above process, the coating layer was formed by applying heat at a temperature of 40 ° C. for 24 hours.

위의 공정에서 얻어진 물질을 이를 다시 반응기에서 꺼내어 300℃이내의 건조기에 넣은후 30분동안 수분을 충분하게 건조시켰다. The material obtained in the above process was again taken out of the reactor and placed in a drier within 300 ° C., and then sufficiently dried for 30 minutes.

이를 다시 주먹만한 덩어리들을 회쇄기에 넣어 회쇄를 시키어 원하는 크기로 포장시켰다. This was again put into a lump lump into the crusher was crushed and packed in the desired size.

시험예 1Test Example 1

상기의 모든 공정으로 얻어진 물질을 시험하기 위하여 다음과 같은 방법으로시험을 하였다.In order to test the material obtained by all the above process was tested by the following method.

돼지를 사육하는 양돈장의 오물 집하장에서 수집을 한 후 수분이 증발되지 않도록 비이커 위에 비닐 덮개를 해주었다.After collecting the pigs in the pig house where they raise pigs, a plastic cover was placed on the beaker to prevent moisture from evaporating.

2L의 비이커에 각각IL의 걸죽한 상태의 분뇨를 5개로 나뉘어서 아래의 g량을 넣은 후 냄새 탈취력을 시험하였다.In 2L beakers, each of the thick manure of IL was divided into five, the following amount of g was added, and the odor deodorizing power was tested.

상기의 모든 공정으로 얻어진 물질을 실험 내용물이 담겨진 각 비이커 속에 분말을 영점저울에 10g, 30g, 50g, 70g, 90g, 을 나열의 순서대로 7일간 비교시험을 하였다.The materials obtained by all the above processes were compared to powder in each beaker containing the contents of the experiment in a zero balance of 10g, 30g, 50g, 70g, 90g, 7 days in the order listed.

Figure 112003041282734-pat00001
Figure 112003041282734-pat00001

상기의 표1과 같은 결과를 얻을 수 있었다.The same result as in Table 1 was obtained.

주) 상기의 결과는 개인 연구기관에서 테스트 결과치임.Note) The above results are test results from individual research institutes.

본 발명의 제조방법에 의해 제조된 냄새흡착제는 유기성 소취제와는 근본적으로 다르며 처음시작하는 모재( Matrix )의 성격부터 달리하여 냄새의 소취제로 사용을 한후 이를 다시 퇴비화시 토양의 개선의 효과가 매우 뛰어나고 토양에서의 삼대요소인 질소, 인산, 가리 (N, P, K)는 물론이거니와 토양의 미량요소인 마그네 슘(Mg)의 성분을 보충하여 주어 각종 여러 식물들에게 필수적인 성분을 공급하여 주는 효과가 있다. The odor adsorbent prepared by the manufacturing method of the present invention is fundamentally different from the organic deodorant, and is different from the nature of the matrix starting from the beginning. Nitrogen, phosphoric acid, girly (N, P, K), which are the three major elements in the soil, as well as magnesium (Mg), which is a trace element in the soil, are supplemented to supply essential ingredients to various plants. have.

또한, 본 발명의 냅새 흡착제는 사람이나 가축에 무해하고 입자 하나 하나 마다 공극(Pore)을 주고 항균제(Anti Baterial)를 부착시키는 공법을 이용하여 항균력이 매우 뛰어나 가축들로부터 발생되는 각종 바이러스 균들로부터 생명을 보호를 할 수 있도록 하는 것이며, 냄새흡착 조건에 알맞는 물성을 조성시켜 우리 인간에게 매우 유용하게 하는 한편 동물사육장의 환경을 개선시켜 주고 주변의 환경을 개선시켜 주어 여러사람들로부터 혐오감이 없도록 하므로 우리 인간 및 동물에게 매우 유용한 발명이다.In addition, the synapse adsorbent of the present invention is harmless to humans and livestock, and is very effective in antibacterial activity by giving a pore to each particle and attaching an antibacterial agent (Anti Baterial). It is to protect the environment, and to make the physical properties suitable for the odor adsorption conditions to be very useful to us humans, to improve the environment of the animal husbandry and to improve the environment around us so that there is no aversion from many people It is a very useful invention for humans and animals.

Claims (3)

입자크기는 75㎛ 이하인 탄산칼슘 분말을 1000℃에서 5시간 가열 후 급냉시키고, 탄산칼슘과 EDTA-2Na를 물에 부가하여 슬러리 상태로 만든 다음, 입자크기 20nm∼35nm의 이산화티탄을 부가하여 탄산칼슘에 코팅시킨 후, 다시 마그네슘을 부가하여 코팅시킨 다음, 건조하는 것을 특징으로 하는 냄새흡착제의 제조방법.The particle size of calcium carbonate powder having a particle size of 75 μm or less is rapidly quenched after heating at 1000 ° C. for 5 hours, and calcium carbonate and EDTA-2Na are added to water to make a slurry, followed by addition of calcium dioxide with a particle size of 20 nm to 35 nm. After coating on, and then coated with magnesium again, the method for producing an odor adsorbent, characterized in that the drying. 삭제delete 삭제delete
KR1020030077111A 2002-12-12 2003-11-01 Prepation Method of Deodorant for Sewage KR100611631B1 (en)

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