KR100602161B1 - The Eco-environment composition and Manufacturing Process for the Inhibitory Function on a Chemical Material Hypersensitiveness - Google Patents

The Eco-environment composition and Manufacturing Process for the Inhibitory Function on a Chemical Material Hypersensitiveness Download PDF

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KR100602161B1
KR100602161B1 KR1020040064351A KR20040064351A KR100602161B1 KR 100602161 B1 KR100602161 B1 KR 100602161B1 KR 1020040064351 A KR1020040064351 A KR 1020040064351A KR 20040064351 A KR20040064351 A KR 20040064351A KR 100602161 B1 KR100602161 B1 KR 100602161B1
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wood vinegar
charcoal
composition
prepared
mixture
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KR20060015950A (en
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이상준
한성욱
김복조
추상호
윤말노미
한지훈
이광한
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주식회사 실버리아
한성욱
이상준
추상호
윤말노미
김복조
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/013Deodorant compositions containing animal or plant extracts, or vegetable material
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/014Deodorant compositions containing sorbent material, e.g. activated carbon
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20Method-related aspects
    • A61L2209/21Use of chemical compounds for treating air or the like

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  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
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  • General Health & Medical Sciences (AREA)
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  • Veterinary Medicine (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
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  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

본 발명은 환경적으로 문제가 되고 있는 화학물질 과민증 현상을 최소화할 수 있도록 한 친환경조성물 및 그 제조방법에 관한 것이다.The present invention relates to an environmentally friendly composition and a method of manufacturing the same to minimize the chemical hypersensitivity phenomenon which is an environmental problem.

상기 목적을 달성하기 위하여 본 발명은 항균과 살균, 악취 및 잡냄새 제거능력이 우수한 목초액과, 수많은 기공을 형성하면서 공기정화 및 흡착성, 원적외선 방사, 음이온 방출능력이 우수한 숯과, 탈취 및 흡착효과가 우수한 인조 제올라이트를 서로 합성하여 새로운 조성물을 얻고, 상기 조성물을 이용하여 화학물질 과민증 증상을 유발시킬 우려가 있는 곳에 도포하여 사용케 하므로서 이러한 현상을 최소화할 수 있도록 한 것이다.In order to achieve the above object, the present invention has excellent antibacterial and sterilization, odor and odor smell removal ability, charcoal excellent in air purification and adsorption, far-infrared radiation, anion releasing ability and forming numerous pores, and deodorization and adsorption effect Excellent artificial zeolites are synthesized with each other to obtain a new composition, and by using the composition to be applied to the place where there is a possibility of causing symptoms of chemical hypersensitivity to minimize this phenomenon.

Description

화학물질 과민증 억제기능을 갖는 친환경 조성물 및 그 제조방법{The Eco-environment composition and Manufacturing Process for the Inhibitory Function on a Chemical Material Hypersensitiveness}The eco-environment composition and manufacturing process for the inhibitory function on a chemical material hypersensitiveness

본 발명은 목초액과 숯 및 인조 제올라이트를 이용하여 제조한 화학물질 과민증 억제기능을 갖는 친환경 조성물 및 그 제조방법에 관한 것이다.The present invention relates to an environment-friendly composition having a chemical hypersensitivity inhibiting function prepared using wood vinegar and charcoal and artificial zeolite and a method for producing the same.

일반적으로 화학물질 과민증이란 특정 화학물질이 공기와 복합적으로 작용하여 오염되면서 인체에 유해한 영향을 미치는 증상으로서 최근 문제화되고 있는 새집증후군이 화학물질 과민증의 한 예이다.In general, chemical hypersensitivity is a symptom that has a harmful effect on the human body as a certain chemical compound is contaminated by the complex action with the air, the new house syndrome is an example of chemical hypersensitivity.

최근 문제화되고 있는 화학물질 과민증의 일종인 새집증후군 증상을 나타내는 사람의 경우 실내환경을 구성하고 있는 장식물로부터 발생하는 화학물질 냄새에 매우 민감하게 반응하여 심각한 건강장애를 일으킬 수 있으며, 이러한 현상은 새집이나 수리한 집에 입주하여 생활하면서 전에 없었던 두통이나 천식, 아토피성 피부염등의 알레르기성 질환에 걸리는 경우를 총칭하여 화학물질 과민증, 혹은 새집증후군이라고 하며 문제의 심각성이 자주 보도되면서, 규제와 관심을 갖기 시작하였다.A person with symptoms of sick house syndrome, a type of chemical hypersensitivity, which has recently become a problem, is very sensitive to the smell of chemicals generated from the decorations that make up the indoor environment, which can cause serious health problems. When living in a repaired house, allergic diseases such as headache, asthma, atopic dermatitis, etc. are called chemical hypersensitivity or sick house syndrome, and the seriousness of the problem is frequently reported. Started.

주로 이 증상은 건축내장재로부터 방출되는 포름알데히드, 유기용제, 가스 및 먼지등의 환경오염물질을 비롯하여 화장품, 담배, 세탁된 의복, 염화비닐, 인쇄물의 잉크등에서 배출되는 가스상 물질등이 주요원인으로 제시되고 있다.This symptom is mainly caused by environmental pollutants such as formaldehyde, organic solvent, gas and dust emitted from building interior materials, as well as gaseous substances emitted from cosmetics, tobacco, washed clothes, vinyl chloride, and ink of printed materials. It is becoming.

이러한 원인을 해결하기 위하여 여러 화합물로 조성한 조성물들이 제공되고 있으나 만족할만한 바는 아닌 것이었다.In order to solve this cause, compositions provided with various compounds have been provided, but were not satisfactory.

본 발명은 화학물질 과민증과 같은 실내환경오염문제를 효과적으로 최소화하고 억제할 수 있는 새로운 조성물을 얻고, 상기 조성물을 실내인테리어작업시 바닥이나 벽체등에 도포하거나 자동차, 에어컨필터등과 같은 산업전분야에 걸쳐 사용케 함으로서 환경오염물질을 흡착, 살균 및 중화시켜 오염없는 쾌적한 실내환경을 제공하고자 하는 것이다.The present invention obtains a new composition that can effectively minimize and suppress indoor environmental pollution problems such as chemical hypersensitivity, and apply the composition to the floor or wall during indoor interior work, or to be used in all industrial fields such as automobiles, air conditioner filters, etc. By adsorbing, disinfecting and neutralizing environmental pollutants, we aim to provide a pleasant indoor environment without pollution.

상기 목적을 달성하기 위하여 본 발명은 항균과 살균작용은 물론 악취분해능력이 탁월한 목초액과, 다공질로서 공기정화효과 및 흡착성이 우수하고, 원적외선과 음이온 방출기능을 갖는 숯과, 흡착능력이 탁월한 인조 제올라이트를 주재료로 합성하여 화학물질 과민증 억제기능을 갖는 친환경 조성물을 제조사용케 한 것이다.In order to achieve the above object, the present invention has excellent antibacterial and bactericidal action as well as odor degrading ability of wood vinegar, porous air purifying effect and adsorption ability, far infrared rays and anion releasing ability, and excellent adsorption ability of artificial zeolite It was synthesized as a main material to manufacture and use an environmentally friendly composition having a function of inhibiting chemical hypersensitivity.

이하 본 발명에서 제공하고자 하는 화학물질 과민증 억제기능을 갖는 친환경 조성물의 제조방법을 상세히 설명한다.Hereinafter, a method for preparing an environmentally friendly composition having a chemical hypersensitivity inhibiting function to be provided by the present invention will be described in detail.

본 발명 조성물의 제조는 연기가 응고된 결정체인 목초액와, 숯화합물과, 인 조 제올라이트를 적절한 비율로 혼합하여 제조하게 된다.The composition of the present invention is prepared by mixing wood vinegar, a charcoal compound, and artificial zeolite in an appropriate ratio.

상기 제조과정을 실시예에 따라 공정별로 상세히 설명하면 아래와 같다.The manufacturing process will be described in detail by process according to the embodiment as follows.

<제1공정><Step 1>

본 공정은 목초액을 얻는 공정이다.This step is a step of obtaining wood vinegar.

목초액의 제조는 일반화되어 있으나, 개략적인 과정을 설명하면, 목재를 숯가마에 넣고 불을 붙여 350~400℃ 정도로 붙여 가열하면 탄화현상이 일어나면서 목재는 숯으로 되고, 이과정에서 연기가 발생하게 되고, 상기 연기를 채취하여 냉각, 액화시켜 조목초액을 얻는다.The production of wood vinegar is generalized, but when explaining the schematic process, if the wood is put in a charcoal kiln, put on fire and heated to about 350 ~ 400 ℃, carbonization occurs and the wood becomes charcoal, and smoke occurs in this process. The smoke is collected, cooled and liquefied to obtain crude wood vinegar.

상기 조목초액을 용기에 저장한 다음 일정기간 숙성하고, 정제하여 정제된 목초액을 얻고, 정제된 목초액을 약900~1100㎖ 준비한다.The crude wood vinegar is stored in a container and then aged for a certain period of time, and purified to obtain purified wood vinegar, and about 900 to 1100 ml of purified wood vinegar is prepared.

<제2공정><Step 2>

본 공정은 숯화합물을 제조하는 공정이다.This process is a process for producing a charcoal compound.

1000℃에서 구운 숯을 잘게 분쇄하여 숯가루를 얻고, 상기 숯가루 190~210g과, 알미늄분말 90~110g과, 전기석 분말 45~55g을 수용성 아크릴 바인더 900~1100㎖에 혼입하고, 충분히 교반하여 숯화합물을 얻는다.Finely pulverize the charcoal baked at 1000 ℃ to obtain charcoal, and the charcoal powder 190 ~ 210g, aluminum powder 90 ~ 110g, tourmaline powder 45 ~ 55g is mixed in 900 ~ 1100ml of water-soluble acrylic binder, and thoroughly stirred to charcoal Obtain the compound.

<제3공정><Step 3>

본 공정은 인조 제올라이트를 제조하는 공정으로서 통상의 제조방법과 같이 제조한다.This process is a process of manufacturing artificial zeolite, and it manufactures it like a normal manufacturing method.

위 제조공정의 일예를 들면 pH13인 수산화나트륨수용액 900~1100㎖에 알미늄 분말 90~110g을 첨가하여 교반, 반응시키고, 반응시키면서 발생되는 가스를 배기시 킨 혼합물을 얻는다.As an example of the above manufacturing process, 90 to 110 g of aluminum powder is added to 900 to 1100 ml of sodium hydroxide aqueous solution having a pH of 13, stirred, and reacted to obtain a mixture in which the gas generated while reacting is evacuated.

상기 혼합물에 규산나트륨 90~110g을 혼입시킨 다음 충분히 교반하고, 상기 혼합물을 건조기에 넣고, 100℃로 가열, 건조시켜 분말상태의 인조 제올라이트를 얻는다.90-110 g of sodium silicate is added to the mixture, followed by stirring sufficiently. The mixture is placed in a dryer, heated to 100 ° C, and dried to obtain a powdery artificial zeolite.

<제4공정><Step 4>

본 공정은 본 발명에서 얻고자 하는 조성물 제조공정이다.This step is a composition manufacturing step to be obtained in the present invention.

즉 제1공정에서 얻어진 목초액과, 제2공정에서 얻어진 숯화합물과, 제3공정에서 얻어진 인조 제올라이트를 혼합하므로서 본 발명에서 제공하고자 하는 화학물질 과민증 억제기능을 갖는 친환경 조성물을 제조하게 되는 것이다.That is, by mixing the wood vinegar obtained in the first step, the char compound obtained in the second step, and the artificial zeolite obtained in the third step, to prepare an environmentally friendly composition having a chemical hypersensitivity inhibiting function to be provided in the present invention.

상기에서 제조된 조성물의 주성분이 목초액과, 숯화합물 및 인조 제올라이트로서, 목초액의 특성인 항균, 살균 및 탁월한 악취분해기능과, 숯의 특성인 공기정화 및 우수한 흡착성, 원적외선 및 음이온 방출기능과, 인조 제올라이트의 특성인 흡착력을 동시에 만족하게 된다.The main components of the composition prepared above are wood vinegar, charcoal compound and artificial zeolite, antibacterial, bactericidal and excellent odor degrading function of wood vinegar, air purification and excellent adsorption, far infrared and anion releasing function of charcoal, and artificial The adsorption force, which is a characteristic of the zeolite, is simultaneously satisfied.

따라서 본 발명에서 얻어진 조성물을 아파트나 주택, 상가와 같은 신축건물의 실내인테리어 공사시 바닥이나 벽체에 먼저 도포건조시킨 다음 그위에 벽지나 바닥시공등 인테리어 작업케 하므로서 각종 내장재나 시멘트로부터 방출되는 유해성분을 흡수제거, 완화시키거나 중화시켜 새집증후군과 같은 화학물질 과민증 증상을 현저히 줄일 수 있게 될 뿐 아니라, 자동차나 에어컨필터등 화학물질 과민증 증상이 나타날 우려가 있는 산업전분야에 적용사용할 수도 있다.Therefore, the composition obtained in the present invention is first applied to the floor or wall during the interior construction of new buildings, such as apartments, houses, malls, and then applied to the interior work such as wallpaper or floor construction on the harmful components emitted from various interior materials and cement Absorption, mitigation, or neutralization of chemicals can significantly reduce the symptoms of chemical hypersensitivity, such as sick house syndrome, and can be used in all industrial fields where chemical hypersensitivity symptoms, such as automobile or air conditioner filters, may occur.

본 발명 조성물에 함유된 숯은 수많은 기공(1g당 약300㎡)으로 이루어져 있 을 뿐 아니라 숯의 기공에는 미생물이 서식하기에 매우 적합하여 미생물의 서식이 활성화되므로 미생물이 세균과 잡냄새를 흡착제거하고, 흡착된 세균은 목초액이 갖는 강한 항균 및 살균작용에 의해 사멸시키게 되므로 유해세균과 악취를 분해, 제거시키게 된다.Charcoal contained in the composition of the present invention not only consists of a number of pores (about 300㎡ per 1g) but also the pores of the char is very suitable for microorganisms to inhabit the microorganisms are activated, so the microorganisms adsorption and removal of bacteria and odor And, since the adsorbed bacteria are killed by the strong antibacterial and sterilizing action of wood vinegar solution, the harmful bacteria and odors are decomposed and removed.

또한 숯이 발생시키는 음이온은 시멘트성분으로부터 다량방출되는 양이온을 중화시켜 실내공기를 맑게 정화시키는 기능을 하게 될 뿐 아니라, 숯으로부터 방사되는 원적외선은 혈액순환 및 신진대사를 촉진시켜 실내에 거주하는 사람의 인체에 유익하게 작용하게 된다.In addition, the anion generated by charcoal not only functions to neutralize the cations released from the cement component to clear indoor air, but the far-infrared radiation emitted from charcoal promotes blood circulation and metabolism, It will be beneficial to the human body.

본 발명 조성물에 함유된 인조 제올라이트는 뛰어난 흡착 및 탈취능력에 의해 각종 화학물질의 냄새 및 유해성분을 흡착제거시키는 기능을 하게 된다.The artificial zeolite contained in the composition of the present invention has a function of adsorbing and removing odors and harmful components of various chemicals by excellent adsorption and deodorizing ability.

이상 설명한 바와 같이 본 발명은 항균, 살균 및 악취분해능력이 탁월한 목초액과, 공기정화 및 흡착성, 원적외선 방사, 음이온방출기능이 우수한 숯과, 탈취 및 흡착능력이 우수한 인조 제올라이트를 서로 혼합하여 새로운 조성물을 얻고, 상기 조성물을 건축물의 실내인테리어 작업전에 바닥이나 벽체등에 도포하여 사용케 하므로서 최근 문제가 되고 있는 새집증후군과 같은 화학물질 과민증 증상을 최소화하여 쾌적한 실내환경을 조성할 수 있게 될 뿐 아니라, 자동차나 에어컨 필터등 산업전분야에 적용하여 위와 같은 현상을 방지할 수 있게 되는 등의 효과가 있는 것이다. As described above, the present invention provides a new composition by mixing a wood vinegar solution having excellent antibacterial, bactericidal and malodorous decomposing ability, charcoal having excellent air purification and adsorption ability, far-infrared radiation and anion release function, and artificial zeolite having excellent deodorizing and adsorption ability. It is possible to create a comfortable indoor environment by minimizing the symptoms of chemical hypersensitivity, such as sick house syndrome, which has recently become a problem by applying the composition to a floor or a wall before the interior work of a building. It is effective to prevent the above phenomenon by applying to industrial field such as air conditioner filter.

Claims (2)

숯과 목초액 및 제올라이트를 포함하는 화학물질 과민증 억제기능을 갖는 친환경 조성물에 있어서, 목재의 탄화과정에서 발생하는 연기를 채취하여 냉각, 액화시켜 조목초액을 얻고, 상기 조목초액을 숙성, 정제하여 정제된 목초액을 얻고, 상기 정제된 목초액을 900~1100㎖ 준비하는 공정과, 숯가루 190~210g과, 알미늄분말 90~110g과, 전기석 분말 45~55g을 수용성 아크릴 바인더 900~1100㎖에 혼입, 교반하여 숯화합물을 얻는 공정과, 수산화나트륨 수용액 900~1100㎖에 알미늄분말 90~110g을 첨가, 교반, 반응시켜 혼합물을 얻고, 상기 혼합물에 규산나트륨 90~110g을 혼입, 교반한 다음 건조시켜 분말상태의 인조 제올라이트를 제조하는 공정과, 상기 각 공정에서 제조된 목초액과 숯화합물 및 인조 제올라이트를 혼합하여 제조함을 특징으로 하는 화학물질 과민증 억제기능을 갖는 친환경 조성물.In an environmentally friendly composition having a chemical hypersensitivity suppression function including charcoal, wood vinegar and zeolite, smoke generated during carbonization of wood is collected, cooled and liquefied to obtain crude wood vinegar, and the crude wood vinegar is aged and purified. Obtaining wood vinegar, and preparing 900 ~ 1100ml of the purified wood vinegar, 190 ~ 210g of charcoal powder, 90 ~ 110g of aluminum powder, 45 ~ 55g of tourmaline powder is mixed and stirred in 900 ~ 1100ml of water-soluble acrylic binder The process of obtaining a charcoal compound, and 90-110 g of aluminum powder to 900-1100 ml of sodium hydroxide aqueous solution, and stirring and reacting to obtain a mixture, incorporating and stirring 90-110 g of sodium silicate in the mixture, drying and Process for preparing artificial zeolite, inhibiting chemical hypersensitivity, characterized in that the wood vinegar prepared in each process and the charcoal compound and artificial zeolite are mixed and prepared Environmentally friendly composition having the capability. 숯과 목초액 및 제올라이트를 화학물질 과민증 억제기능을 갖는 친환경 조성물의 제조방법에 있어서, 목재의 탄화과정에서 발생하는 연기를 채취하여 냉각, 액화시켜 조목초액을 얻고, 상기 조목초액을 숙성, 정제하여 정제된 목초액을 얻고, 상기 정제된 목초액을 900~1100㎖ 준비하는 공정과, 숯가루 190~210g과, 알미늄분말 90~110g과, 전기석 분말 45~55g을 수용성 아크릴 바인더 900~1100㎖에 혼입, 교반하여 숯화합물을 얻는 공정과, 수산화나트륨 수용액 900~1100㎖에 알미늄분말 90~110g을 첨가, 교반, 반응시켜 혼합물을 얻고, 상기 혼합물에 규산나트륨 90~110g을 혼입, 교반한 다음 건조시켜 분말상태의 인조 제올라이트를 제조하는 공정과, 상기 각 공정에서 제조된 목초액과 숯화합물 및 인조제올라이트를 혼합하여 제조함을 특징으로 하는 화학물질 과민증 억제기능을 갖는 친환경 조성물의 제조방법.In the method for producing an environmentally friendly composition having a function of suppressing chemical hypersensitivity of charcoal, wood vinegar and zeolite, the smoke generated during carbonization of wood is collected, cooled and liquefied to obtain crude wood vinegar, and the crude wood vinegar is aged and purified. To obtain the prepared wood vinegar, 900 ~ 1100ml of the purified wood vinegar, charcoal powder 190 ~ 210g, aluminum powder 90 ~ 110g, tourmaline powder 45 ~ 55g mixed into 900 ~ 1100ml water-soluble acrylic binder, stirring To obtain a mixture by adding 90-110 g of aluminum powder to 900-1100 ml of sodium hydroxide aqueous solution, stirring and reacting to obtain a mixture, and mixing and stirring 90-110 g of sodium silicate in the mixture, followed by drying. Process of manufacturing artificial zeolite of, and hypersensitivity of chemical substance, characterized in that it is prepared by mixing wood vinegar and charcoal compound and artificial zeolite prepared in each step Process for producing a composition having environmentally-friendly features.
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