KR100581547B1 - High-speed packaging enabled resin composition for snack-packaging and easy-peel film - Google Patents

Abstract

The present invention is a resin consisting of 20 to 90% by weight of ethylene vinyl acetate having a vinyl acetate content of 12 to 18%, 5 to 40% by weight polypropylene, and 5 to 40% by weight of elastomer mixed with one or two or more kinds. Low temperature heat sealing is possible when manufacturing a film made by adding 0.05 to 0.3 parts by weight of slip agent and 0.45 parts by weight of anti-blocking agent to 100 parts by weight of the resin blend as an additive to the blend. The present invention relates to a resin composition for easy peel film for snack packaging.

Description

HIGH-SPEED PACKAGING ENABLED RESIN COMPOSITION FOR SNACK-PACKAGING AND EASY-PEEL FILM}

The present invention relates to a resin composition for easy-fill film for snack packaging, and more particularly, the present invention is composed of ethylene vinyl acetate (EVA), polypropylene (PP), elastomer or a mixture of two or more kinds of film production The present invention relates to a resin composition for easy-fill film for snack packaging, which is capable of low-temperature heat sealing, and in particular, has high hot sealing strength and enables high-speed packaging.

The concept of food packaging until the early 90s was very important for the long-term preservation of food, but recently, with the advancement of the industrial structure, the concept of packaging is accompanied by the development of instant industry, the development of medicine industry, and the development of dessert industry. This unit packaging and the ease of opening is a trend that is particularly emphasized, what appeared as part of the easy peel film easy to open.

The easy-fill film is composed of polymers with different compatibility, and the core technology is to express the easy-filling property with proper adhesion by appropriate balance of compatibility and incompatibility between the substrate and the film when heat-sealing the adhesive base. Selection of appropriate polymers and blend ratios between them, morphology control technology for continuous and dispersed phases. In particular, when the use is for snack packaging, sealing should be possible at a low temperature, and the required peeling strength (peeling strength) is in the range of 0.8 to 1.6 kg / 15 mm. In addition, since the packaging itself is a sealing of the easy peel film instead of the sheet, since the heat transfer is made faster than when the sheet should be a temperature range that can express the easy peel.

Looking at the prior art, in Japanese Patent Laid-Open No. 63-114646 composed of ionomer / polybutene / polyethylene was prepared to have the easy-fill properties for ethylene vinyl acetate film, in this case peeling strength of about 140 ℃ The problem is that the peeling strength is too weak to be applied for snack packaging at 260g / 15㎜.

In addition, according to Japanese Patent Laid-Open No. 61-279552, the easy peel film was composed of polyethylene / polypropylene and applied to container packaging. The product has high heat resistance and can be sterilized at 200 ° C., and at the same time, can express easy peel properties. However, the problem is that the minimum sealing temperature is high when the films are heat-sealed.

Korean Patent Application No. 97-67235 also consists of polypropylene / polyethylene / polystyrene to secure the peeling strength of 1.0 ~ 1.5㎏ / 15㎜ in the range of 180 ~ 220 ℃ for the polypropylene container, When the temperature exceeds 140 ℃ sealing is possible, the peeling strength at this time shows a tendency to increase significantly as the temperature is difficult to use for snack packaging.

In order to improve this problem, it is possible to seal at 120 ℃, the product that can ensure the peeling strength of 0.8 ~ 1.6㎏ / 15mm level of ethylene vinyl acetate (EVA), polyethylene (PE) and polypropylene (PP) Developed through a melt blend. However, this product needs to slow down the production speed during automatic packing due to the weak hot sealing strength and needs to be improved in the packaging process due to the narrow temperature range indicating the hot sealing strength.

The object of the present invention is to improve the above problems and to be sealed at a temperature in the range of 110 ~ 150 ℃, wherein the peeling strength is 0.8 ~ 1.6 ㎏ / 15㎜, excellent hot sealing strength during automatic packaging and hot sealing It is to provide a resin composition for easy-fill film for snack packaging that can increase the productivity significantly due to the temperature range that can secure the strength.

The easy-fill film resin composition for snack packaging of the present invention is 20 to 90% by weight of ethylene vinyl acetate, polypropylene 5 to 40% by weight, 12 to 18% of vinyl acetate, elastomer 5 mixed with one or two or more It is characterized by consisting of 0.05 to 0.3 parts by weight of a slip agent and 0.45 parts by weight of an antiblocking agent with respect to 100 parts by weight of the resin blend and an additive of 40% by weight.

The easy-fill film resin composition for snack packaging of the present invention uses ethylene vinyl acetate (EVA) as a base resin, and the EVA used has a content of vinyl acetate (VA) of 12 to 18%, and 20 to 90 weight based on the total resin blend. % Is used. If the content of VA is less than 12%, the lowest sealing temperature is increased to lower the low temperature sealing property, and if the content of VA is more than 18%, the quality is reduced by the acetic acid smell. When the EVA is less than 20% by weight, the peeling strength is too weak to be applied for snack packaging, and when the content of EVA exceeds 90% by weight, the peeling strength is too strong and not suitable for snack packaging.

In the present invention, the polypropylene (PP) is a factor that gives peeling properties when applied to snack packaging (about 130 ° C) requiring low-temperature sealing at a sealing temperature of 170 ° C. or higher required when heat sealing the films. It will work. The polypropylene used in the present invention preferably has an isotactic index of at least 96%, particularly preferably homopropylene.

The use of the present invention is generally used for snack packaging by dry laminating an aluminum foil or an aluminum deposited film in consideration of moisture permeability and gas burry. Recently, high-density polyethylene is used as a snack packaging outer layer for cost reduction. In this case, the stiffness of the packaging material is lower than that of aluminum. The stiffness of the film was increased after film molding by using polypropylene having a high isotactic index as a method to solve this problem. PP is used in the range of 5 to 40% by weight based on the total resin blend.When the content of PP is less than 5% by weight, the peeling strength is so strong that it is difficult to express easy peel properties, and when the PP content exceeds 40% by weight It is weak and not suitable for snack packaging.

In the present invention, it is preferable that the elastomer mixed with one or two or more kinds is amorphous or has a density of 0.91 g / cm 3 or less.

The elastomer refers to an alpha olefin copolymer in which the comonomer is ethylene, propylene, butene and octene, and the reason for limiting the density of the elastomer is that the physical properties depending on the density are hot sealing strength, so that the To achieve the desired hot sealing strength at temperature.

Elastomers use 5 to 40% by weight of the total resin blend, but when the elastomer is less than 5% by weight, it cannot exhibit hot sealing strength, and when the content of the elastomer exceeds 40% by weight, hot sealing Strength can be secured sufficiently, but the ease-filling characteristics are deteriorated due to the increase in manufacturing cost and peeling strength.

In the present invention, the additive uses a slip agent or an anti-blocking agent. When the additive is not used, the film may not be wound due to blocking when the film is formed for the blown film, and the film may be wrinkled even if it is forcibly wound. This increases the failure rate during post-processing, such as printing or dry lamination.

The slip agent used in the present invention is used 0.05 to 0.3 parts by weight based on 100 parts by weight of the resin blend of ethylene vinyl acetate / polypropylene / elastomer, most preferably 0.2 parts by weight.

The antiblocking agent used in the present invention uses 0.45 parts by weight or less based on 100 parts by weight of the resin blend of ethylene vinyl acetate / polypropylene / elastomer, and most preferably 0.2 part by weight.

When the content of the additive is less than 0.5 parts by weight, there is a concern that a problem may occur in the film winding process due to blocking during film forming.

The present invention can be understood in more detail through the following examples and comparative examples, the following examples and comparative examples are not intended to limit the scope of the present invention but are described for illustrative purposes.

The peeling strength and the hot sealing strength of the films according to the Examples and Comparative Examples were evaluated as follows.

1. Peeling strength

The peeling strength was thermally fused between films in a size of 25 mm x 10 mm, and then cut into 15 mm x 10 mm in size, and the maximum value of the measured strength was measured as the peeling strength. Tensile speed was measured at a speed of 20 mm / min. In this case, when the peeling strength is too strong, the film may be stretched or torn, and it is important to maintain an appropriate level of peeling strength. Generally, peeling strength that an adult can open is 2.0 kg / 15 mm or less, and a peeling strength of 0.8 to 1.6 kg / 15 mm is suitable for snack packaging.

2. Hot sealing strength

The peeling strength is the strength that occurs when the film is separated at room temperature after heat sealing, but the hot sealing strength is the peeling strength immediately after the heat sealing. This falling problem occurs. In addition, when the temperature range for securing the hot sealing strength is narrow, the temperature of the heat sealer may change according to the change in the working environment, which may cause a defect. In general, the hot sealing strength is not less than 2.0N / INCH, the temperature range is about 20 ℃ compared to the reference working temperature is known to be no problem.

(Measuring method of hot sealing strength)

After film molding, the molded film was laminated with a polyethylene terephthalate (PET) film and a polyethylene (PE) film, and then cut into a size of 25.4 mm x 300 mm and used as a specimen for measuring hot sealing strength. The measuring method is to measure the peeling strength by separating two specimens at a speed of 200mm / min immediately after heat sealing for 1 second with a 25.4mm × 10mm area under a pressure of 2㎏f / ㎠. The peeling strength at seconds is called the heat-sealing strength. The measurement temperature was 90 degreeC, 100 degreeC, and 110 degreeC.

Examples 1-5, Comparative Examples 1-6

The resin composition of Table 1 was melt-blended and pelletized at 140-180 degreeC by the 30-φ twin screw extruder, and this was shape | molded to the thickness of 30 micrometers by the casting film machine. After measuring the transparency of the molded film, the peeling strength and the hot sealing strength were measured through heat fusion of PET films having a thickness of 12 µm and 30 µm, respectively, and easy-fill films laminated with normal PET. Each measurement result is shown in Table 1.

(Thermal fusion method for measuring the peeling strength)

1. Film Size: 5㎝ × 30㎝

2. Adhesive base: Bond the same films (Size: 5cm × 30cm)

3. Heat Fusion Temperature: The temperature was in the range of 20 ° C in the range of 110 ° C to 150 ° C.

4. Heat Fusion Area: 25㎜ × 10㎜

5. Heat Fusion Time: 1 second

6. Heat Fusion Pressure: 2㎏f / ㎠

division Resin composition (% by weight) Product performance EVA PP Era Stormer Metallocene PE additive Peeling Strength (㎏ / 15㎜) Hot sealing strength (N / 25.4㎜) 110 ℃ 130 ℃ 150 ℃ 90 ℃ 100 ℃ 110 ℃ Example 1 75 15 10 - 0.3 1.0 1.2 1.3 3.3 4.3 2.7 Example 2 45 15 40 - 0.3 1.5 1.5 1.6 4.8 5.4 5.9 Example 3 90 5 5 - 0.3 1.5 1.6 1.6 2.0 2.2 2.1 Example 4 55 40 5 - 0.3 0.8 0.9 0.9 2.0 2.8 3.2 Example 5 20 40 40 - 0.3 1.3 1.4 1.4 4.0 5.9 6.3 Comparative Example 1 35 15 50 - 0.3 1.7 1.9 1.9 5.5 5.7 5.8 Comparative Example 2 81 15 4 - 0.3 1.5 1.7 1.7 1.8 2.0 2.0 Comparative Example 3 40 50 10 - 0.3 0.4 0.5 0.8 2.0 3.0 3.5 Comparative Example 4 90 - 10 - 0.3 2.0 Not peeling Not peeling 2.8 3.5 3.2 Comparative Example 5 95 5 - - 0.3 1.9 2.3 2.3 1.1 1.2 1.2 Comparative Example 6 75 15 - 10 0.3 0.8 0.8 0.9 2.4 0.8 0.4

* In Table 1,

-Elastomer: Ethylene Alpha Olefin Copolymer (Trade Name: TAFMER)

-Slipper as additive: ERUICAMIDE

Antiblocking Agent: Silica

As can be seen in Table 1, the embodiment of the present invention was superior in both peeling strength and hot sealing strength compared to the comparative example outside the composition range of the present invention.

As described above, the easy-fill film resin composition of the present invention is capable of sealing at 110-150 ° C., has excellent peeling strength, and also has a temperature range in which hot sealing strength is excellent and automatic sealing strength at the time of automatic packaging. It also has a wider productivity, which is particularly suitable for snack packaging.

Claims (3)

100 weight of resin blend consisting of 20 to 90% by weight of ethylene vinyl acetate having 12 to 18% of vinyl acetate, 5 to 40% by weight of polypropylene, and 5 to 40% by weight of elastomer mixed with one or two or more kinds The resin composition for easy-filling film for snack packaging characterized by adding 0.05-0.3 weight part of slip agents which are additives, and 0.45 weight part or less of additives with respect to a part. The resin composition of claim 1, wherein the polypropylene is a homo polypropylene having an isotactic index of 96%. The resin composition for a snack packaging easy peel film according to claim 1, wherein the elastomer is amorphous or has a density of 0.91 g / cm 3 or less.