KR100489195B1 - Recycling Method of Residual Castables for Teeming Ladle - Google Patents

Recycling Method of Residual Castables for Teeming Ladle Download PDF

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Publication number
KR100489195B1
KR100489195B1 KR10-2000-0080300A KR20000080300A KR100489195B1 KR 100489195 B1 KR100489195 B1 KR 100489195B1 KR 20000080300 A KR20000080300 A KR 20000080300A KR 100489195 B1 KR100489195 B1 KR 100489195B1
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thickness
ladle
slag
residual
inflow material
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KR10-2000-0080300A
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Korean (ko)
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KR20020050983A (en
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홍기곤
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주식회사 포스코
재단법인 포항산업과학연구원
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/02Linings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/005Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like with heating or cooling means

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)

Abstract

본 발명의 목적은 잔존 유입재를 재활용하고 신규 유입재의 시공시간 단축을 도모하기 위함에 있다.An object of the present invention is to recycle the remaining influent and to reduce the construction time of the new influent.

이에 본 발명은 용강배제후에 발생되는 레이들 슬래그를 이용하여 노체경동을 통하여 잔존 유입재의 두께가 통상적으로 50mm정도인 잔존 유입재의 표면에 슬래그 코팅층을 5~15mm 두께로 형성시킨 후 상온으로 냉각시키고, 신규유입재를 50~70mm 의 두께로 시공하고 통상의 조건인 1000℃에서 1200℃로 예열하는 것을 특징으로 하는 잔존 유입재 덧붙임 시공방법을 제공한다. Therefore, the present invention forms a slag coating layer on the surface of the residual inflow material having a thickness of about 50 mm using a ladle slag generated after the molten steel is removed to a thickness of 5 to 15 mm, and then cooled to room temperature. The new influent material is constructed with a thickness of 50 to 70 mm, and a residual inflow material addition method is provided, characterized in that preheating is performed at 1000 ° C to 1200 ° C under normal conditions.

Description

잔존 유입재 덧붙임 시공방법{Recycling Method of Residual Castables for Teeming Ladle}Recycling Method of Residual Castables for Teeming Ladle}

본 발명은 레이들(ladle)용 잔존 유입재의 재활용 방법에 관한 것으로, 더욱 상세하게는 레이들 슬래그(slag)를 잔존 유입재의 표면에 코팅(coating)한 후 신 유입재를 시공하는 잔존 유입재 덧붙임 시공방법에 관한 것이다.The present invention relates to a method of recycling residual influent for ladle, and more particularly, adding a residual influent for coating a ladle slag on the surface of the remaining influent and constructing a new influent. It is about a construction method.

일반적으로 레이들용 유입재는 사용후 두께 50mm 이상이 잔존 유입재로 발생되는데, 종래에는 주로 브레이커(breaker)를 사용하여 이를 전량 폐기처분하였다.In general, the inflow material for ladle is generated as a residual inflow material more than 50mm after use, in the prior art was mainly discarded by using a breaker (breaker).

또한, 일본특허공개공보 JP9280746호에서와 같이 슬래그(slag)가 부착된 용융 금속용기의 내장 내화물을 보수하는 방법에 있어서 부착 슬래그의 융점을 저하시키는 슬래그 개질재를 미리 내장 내화물의 표면에 도포한 후 부정형 내화물을 시공하는 것을 특징으로 하는 용융 금속용기 내장 내화물의 보수방법이 개시되어 있다.In addition, in the method for repairing the internal refractories of a molten metal container with slag as in Japanese Patent Application Laid-Open No. JP9280746, after applying a slag modifier to reduce the melting point of the attached slag on the surface of the internal refractories in advance A repairing method for a built-in refractory metal container containing molten refractory materials has been disclosed.

그러나, 사용후 발생되는 잔존 유입재를 전량 폐기하는 방법은 폐기물의 발생량 및 신유입재의 시공량을 증가시키는 단점이 있으며, 일본특허공개공보JP9280746호와 같은 방법은 개질재를 필요로 할 뿐만 아니라 개질재를 도포하는데 시간이 소요되므로 단가상승 및 시공시간 증가라는 단점이 있다.However, the method of discarding the total amount of residual influent generated after use has the disadvantage of increasing the amount of waste generated and the amount of new influent input, and methods such as Japanese Patent Application Laid-Open No. JP9280746 require not only reforming but also reforming. Since it takes time to apply the ash has the disadvantages of unit cost rise and construction time increase.

이에 본 발명은 상기와 같은 단점을 극복하기 위하여 안출된 것으로, 잔존 유입재를 재활용하고 신규 유입재의 시공시간 단축을 도모하기 위하여 용강배제후에 발생되는 레이들 슬래그를 이용하여 노체경동을 통하여 잔존 유입재의 표면에 슬래그 코팅층을 5~15mm 두께로 형성시킨후 상온으로 냉각시키고, 신규유입재를 50~70mm 의 두께로 시공하고 통상의 조건인 1000℃ ~ 1200℃로 예열하는 것을 특징으로 하는 잔존 유입재 덧붙임 시공방법을 제공함에 그 목적이 있다.Accordingly, the present invention has been made to overcome the above disadvantages, to recycle the remaining influent and to reduce the construction time of the new influent, using the ladle slag generated after the molten steel excretion through After the slag coating layer is formed on the surface of 5 ~ 15mm thickness, it is cooled to room temperature, and the new inflow material is constructed to a thickness of 50 ~ 70mm and the residual inflow material is added, which is preheated to 1000 ℃ ~ 1200 ℃ under normal conditions. The purpose is to provide a construction method.

상기한 바와 같은 목적을 달성하기 위한 본 발명의 잔존 유입재 덧붙임 시공방법은, 용강배제작업 후 슬래그를 레이들의 잔존 유입재 표면에 코팅시키는 단계와, 슬래그가 코팅된 레이들을 상온으로 냉각시키는 단계, 레이들 내부의 슬래그 코팅층에 신규유입재를 시공하는 단계를 포함한다.Residual inlet material addition method of the present invention for achieving the object as described above, the step of coating the slag on the surface of the residual inlet material of the ladle after the molten steel removal operation, the step of cooling the slag coated ladle to room temperature, And constructing a new inflow material into the slag coating layer inside the ladle.

슬래그 코팅은 노체경동을 통하여 이루어지며, 잔존 유입재의 표면에 슬래그 코팅층을 5~15mm 두께로 형성시킨후 상온으로 냉각시키고, 신규유입재를 50~70mm 의 두께로 시공하고 통상의 조건인 1000℃~1200℃로 예열하여 시공하게 된다.The slag coating is made through the furnace sloping, and the slag coating layer is formed on the surface of the remaining inflow material to a thickness of 5 to 15 mm, then cooled to room temperature, and the new inflow material is constructed to a thickness of 50 to 70 mm, and the general conditions are 1000 ℃ ~ It is preheated at 1200 ℃ and installed

본 발명에서는 유입재 및 레이들 슬래그의 조성으로서 특별히 한정하는 것은 없으며, 통상의 레이들용 유입재 및 레이들 슬래그를 사용하여도 무방하다.In the present invention, the composition of the inflow material and ladle slag is not particularly limited, and an ordinary inflow material for ladle and ladle slag may be used.

본 발명에서 잔존유입재의 표면에 형성되는 슬래그 코팅층의 두께는 5~15mm 이어야 한다. 슬래그 코팅층의 두께가 5mm 이하가 되면 잔존 유입재와 신규 유입재의 접착계면력이 미약하여 사용시에 잔존 유입재와 신규 유입재의 접촉면을 통하여 지금이 침투되어 신규 유입재가 탈락을 초래한다. 슬래그 코팅층의 두께가 15mm 이상이 되면 잔존 유입재와 신규 유입재의 경계면에 생성되는 접착층의 내화도가 미약하여 경계면이 용강에 노출시 급격한 내용성의 저하를 초래한다.In the present invention, the thickness of the slag coating layer formed on the surface of the residual inflow material should be 5 ~ 15mm. When the thickness of the slag coating layer is less than 5mm, the adhesive interface between the remaining inflow material and the new inflow material is weak, and the new inflow material is now infiltrated through the contact surface between the remaining inflow material and the new inflow material. When the thickness of the slag coating layer is 15 mm or more, the fire resistance of the adhesive layer formed on the interface between the remaining inflow material and the new inflow material is low, resulting in a sharp drop in the resistance when the interface is exposed to molten steel.

본 발명에서 신규 유입재의 시공두께는 50~70mm이어야 한다. 시공두께가 50mm 이하가 되면 슬래그 코팅층에 의한 신규 유입재의 변질층 두께의 증가로 내용성이 저하되며, 70mm 이상이 되면 예열시 열전달의 미약으로 잔존 유입재와 신규 유입재의 접착계면력이 저하되므로 잔존 유입재와 신규 유입재의 계면으로 지금이 침투되어 신규 유입재의 탈락을 초래한다.In the present invention, the construction thickness of the new inflow material should be 50 ~ 70mm. If the construction thickness is less than 50mm, the contents are degraded due to the increase in the thickness of the deteriorated layer of the new inflow material by the slag coating layer, and if it is more than 70mm, the adhesion interface between the remaining inflow material and the new inflow material decreases due to weak heat transfer during preheating. The current penetrates into the interface between the influent and the new inlet, resulting in the dropping of the new inlet.

본 발명에서는 예열조건으로 특별히 한정하는 것은 없으며, 용강수강시 열적 스폴링(spalling)의 발생을 방지하기 위하여 통상적으로 사용하는 예열조건인 1000℃에서 1200℃면 충분하다.In the present invention, there is no particular limitation to the preheating condition, and it is sufficient that 1200 ° C to 1200 ° C, which is a preheating condition commonly used to prevent the occurrence of thermal spalling during molten steel, is sufficient.

이하, 실시예를 통하여 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail through examples.

실시예Example 비교예Comparative example 1One 22 1One 22 33 44 슬래그 코팅층의 두께(mm)Thickness of slag coating layer (mm) 55 1515 22 2020 1010 55 신규 유입재의 시공두께(mm)Construction thickness of new incoming materials (mm) 5050 7070 7070 5050 4040 8080 120ch 사용후 신규유입재의 잔존두께(mm)Residual thickness of new influent after use of 120ch (mm) 1010 1515 없음none 없음none 없음none 없음none 60ch 사용후 잔존 유입재와 신규유입재 계면으로의 지금침투Now penetrates the interface between remaining influent and new influent after 60ch 없음none 없음none 발생Occur 없음none 없음none 발생Occur

260ch 사용후 잔존 두께가 평균 50mm인 300톤 용량의 레이들을 용강출강직후에 15회 경동시켜 잔존 유입재에 형성되는 슬래그 코팅층의 두께가 5~15mm가 되도록 한 후, 잔류 슬래그를 배제시키고 레이들을 상온으로 냉각시켰다.여기서 상기 ch 는 charge의 약어로 쇳물을 레이들에 담은 다음에 원하는 공정을 처리하고 다음 공정으로 넘기는 1번의 과정을 의미하는 단위로 정의한다.After using 260ch, the ladle of 300 ton capacity with average thickness of 50mm is tilted 15 times immediately after molten steel to make the thickness of slag coating layer formed on residual inflow material to be 5 ~ 15mm. Here, ch is an abbreviation for charge, and is defined as a unit which means one step of processing a desired process after lapping the waste water in a ladle, and then transferring to the next process.

레이들의 냉각이 완료된 후에 통상의 알루미나-마그네시아질 유입재를 50~70mm의 두께로 시공하고 1100℃로 예열하여 120ch까지 사용한 다음 실시예 1~2를 얻었다. After the cooling of the ladle was completed, a conventional alumina-magnesia inflow material was applied to a thickness of 50 to 70 mm, preheated to 1100 ° C., used up to 120 ch, and then Examples 1 to 2 were obtained.

또한, 실시예의 범위에서 벗어난 범위에서 비교예 1~4를 얻었다. 용강배제후에 발생되는 레이들 슬래그를 이용하여 노체경동을 통하여 잔존 유입재의 표면에 슬래그 코팅층을 5~15mm 두께로 형성시킨후 상온으로 냉각시키고, 신규유입재를 50~70mm의 두께로 시공하고 통상의 조건인 1000℃~1200℃로 예열한 실시예 1~2는 본 발명의 목적이 달성되었으나, 본 발명의 범위를 벗어난 비교예 1~4는 신규유입재의 내용성 저하 및 지금침투로 인한 탈락 등이 발생되었다.Moreover, Comparative Examples 1-4 were obtained in the range outside the Example. Ladle slag generated after molten steel is used to form a slag coating layer on the surface of the remaining influent material by 5 to 15mm thickness through furnace sloping and then cooled to room temperature, and the new inflow material is constructed to a thickness of 50 ~ 70mm. Examples 1 to 2 preheated to 1000 ℃ ~ 1200 ℃ condition was achieved the object of the present invention, Comparative Examples 1 to 4 out of the scope of the present invention is the fall of the content of the new inlet material and dropping out due to the current penetration Occurred.

이상 설명한 바와 같은 본 발명에 따른 잔존 유입재 덧붙임 시공방법에 의하면, 잔존 유입재를 재활용하므로 폐기물 저감에 기여할 뿐만 아니라 노체 경동에 의한 단순 작업만으로도 잔존 유입재와 신규 유입재의 접착 계면력을 증진시켜 시공비 및 시공시간을 단축하는 효과를 얻을 수 있다.According to the method of adding the residual inflow material according to the present invention as described above, the remaining inflow material is recycled, thereby not only contributing to the reduction of waste, but also by improving the adhesive interface between the remaining inflow material and the new inflow material by simple work by rolling the furnace. And it is possible to obtain the effect of shortening the construction time.

Claims (3)

용강배제작업 후 레이들을 경동시켜 레이들 내의 슬래그를 레이들 내에 잔존하는 잔존 유입재 표면에 코팅시키는 단계;Tilting the ladle after molten steel to coat the slag in the ladle on the remaining inlet surface remaining in the ladle; 상기 슬래그가 코팅된 레이들의 코팅층을 상온에서 냉각시키는 단계;Cooling the slag-coated ladle at room temperature; 상기 레이들 내부의 슬래그 코팅층에 신규유입재를 시공하는 단계Constructing a new inflow material into the slag coating layer inside the ladle 를 포함하는 잔존 유입재 덧붙임 시공방법.Residual influent addition construction method comprising a. 제 1 항에 있어서, 상기 슬래그 코팅층의 두께가 5~15mm인 것을 특징으로 하는 잔존 유입재 덧붙임 시공방법.The method of claim 1, wherein the slag coating layer has a thickness of 5 to 15 mm. 제 1 항에 있어서, 상기 신규유입재는 두께가 50~70mm이고, 1000℃ ~ 1200℃로 예열하여 시공되는 것을 특징으로 하는 잔존 유입재 덧붙임 시공방법.The method according to claim 1, wherein the new inflow material has a thickness of 50 to 70 mm and is preheated to 1000 ° C to 1200 ° C.
KR10-2000-0080300A 2000-12-22 2000-12-22 Recycling Method of Residual Castables for Teeming Ladle KR100489195B1 (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6240307A (en) * 1985-08-13 1987-02-21 Nippon Kokan Kk <Nkk> Method for protecting refractory in converter
JPS6328816A (en) * 1986-07-22 1988-02-06 Nippon Steel Corp Coating method of converter slag
JPH0559423A (en) * 1991-08-29 1993-03-09 Nkk Corp Slag coating method for melting and refining furnace

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6240307A (en) * 1985-08-13 1987-02-21 Nippon Kokan Kk <Nkk> Method for protecting refractory in converter
JPS6328816A (en) * 1986-07-22 1988-02-06 Nippon Steel Corp Coating method of converter slag
JPH0559423A (en) * 1991-08-29 1993-03-09 Nkk Corp Slag coating method for melting and refining furnace

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