KR100487735B1 - The method for manufacturing and combustible of solid fuel - Google Patents
The method for manufacturing and combustible of solid fuel Download PDFInfo
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- KR100487735B1 KR100487735B1 KR10-2002-0053686A KR20020053686A KR100487735B1 KR 100487735 B1 KR100487735 B1 KR 100487735B1 KR 20020053686 A KR20020053686 A KR 20020053686A KR 100487735 B1 KR100487735 B1 KR 100487735B1
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/10—Treating solid fuels to improve their combustion by using additives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/06—Firelighters or wicks, as additive to a solid fuel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
본 발명은 경유 80중량부, 2-부타놀 8중량부, 메타-크레졸 10중량부 및 산화마그네슘 2중량부로 조성됨을 특징으로 하는 가연성 폐기물을 연료로 하는 고체연료의 조연제 및 그 제조방법에 관한 것이다.The present invention relates to a solid fuel retarder comprising a flammable waste fuel and a method for producing the same, comprising 80 parts by weight of diesel, 8 parts by weight of 2-butanol, 10 parts by weight of meta-cresol, and 2 parts by weight of magnesium oxide. will be.
Description
본 발명은 가연성 폐기물을 연료로 하는 고체연료의 조연제 및 그 제조방법에 관한 것으로서, 상세히 설명하면, 가연성 폐기물을 가공성형하여 만든 고체연료의 발열량을 향상시켜 연료로서의 가치를 증대시키는 촉매제로 사용하는 가연성 폐기물을 연료로 하는 고체연료의 조연제 및 그 제조방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a fuel refining agent for solid fuels and a method for producing the same, which are used as catalysts for improving the calorific value of solid fuels produced by processing and composing flammable wastes. The present invention relates to a solid fuel retardant using a flammable waste as a fuel, and a method of manufacturing the same.
폐합성수지등을 이용한 고체연료 제조는 산업폐기물 등의 공해물질의 재활용과 자원절약의 장점이 있어 오래 전부터 다양한 형태로 개발되어 왔으나, 단순한 수지와 섬유소 물질의 혼합체에 불과한 단순 혼련제품이므로 연소가 불완전하며 다량의 유독성 기체가 발생하므로 실용화가 어려워 조연제를 첨가하여 대체 고체연료로 사용하고자 많은 연구가 있어 왔다.Solid fuel manufacturing using waste synthetic resin has been developed in various forms for a long time because of the advantages of recycling pollutants such as industrial waste and resource saving, but it is incomplete combustion because it is a simple kneading product which is just a mixture of resin and fiber materials. Since a large amount of toxic gas is generated, it has been difficult to be commercialized, and there have been many studies to use it as an alternative solid fuel by adding a supporting agent.
대한민국공개특허공보 공개번호 특 1992-0014733호에는 산업폐기물과 프라스틱을 이용하여 인조석과 조연제로 폴리에치렌, 폴리스치렌, 폴리프로필렌 등을 분쇄하여 제오라이트와 탄산석회, 무연저질탕을 혼합하여 가열하여 제조된 조연제를 첨가하여 재생하는 방법이 기재되어 있고,Korean Laid-Open Patent Publication No. 1992-0014733 is prepared by grinding polyethylene, polystyrene and polypropylene with artificial stone and softener using industrial waste and plastics, and mixing zeolite with lime carbonate and smokeless low temperature hot water. A method of regenerating by addition of a precoated flame retardant,
동 공보 특2000-0036903호에는 분쇄공정과, 상기 분쇄된 폐합성수지에 첨가제를 0.3~0.5중량부 혼합하여 열분해시켜 혼합 유기체를 제조한 다음 혼합유로 전환시키는 용해공정과, 촉매 크래킹하는 반응공정과, 생성된 휘발유, 디젤유, 가스등으로 분리시키는 분류공정과 상기 분리된 휘발유, 디젤유를 추출 여과 정류시킨 다음 저장하는 정류 및 저장공정으로 이루어진 폐합성수지의 유화방법 및 유화설비장치가 기재되어 있으며,Japanese Patent Application Laid-Open No. 2000-0036903 discloses a crushing step, a dissolution step of mixing the pulverized waste resin with 0.3 to 0.5 parts by weight of an additive to thermally decompose to prepare a mixed organism, and then converting it into a mixed oil, a reaction step of catalytic cracking, Emulsification method and emulsification equipment device of the waste synthetic resin comprising a sorting process for separating the generated gasoline, diesel oil, gas, etc. and the rectification and storage process of the separated gasoline, diesel oil extracted and filtered and stored therein,
동 공보 공개번호 특2002-0057254호에는 폐기물을 종류별로 파쇄하고 이를 건조시킨 후 열량을 조절하면서 적당히 건조된 슬러지와 혼합시키고 압축성형하여 제조된 폐합성수지를 이용한 고체연료의 제조방법 및 고체연료가 기술되어 있고,Publication No. 2002-0057254 discloses a method for producing solid fuel and solid fuel using waste synthetic resins prepared by crushing waste by type, drying it, mixing it with moderately dried sludge and compressing it while controlling calories. It is,
대한민국 특허공보 등록번호 특1999-0002831호에는 폐합성수지를 건류탄화시킨 섬유소물질, 저급 무연탄 및 각종 조연제등을 균질 혼합하여 임의의 형태로 성형한 폐기물을 주원료로 이용한 고체연료가 기재되어 있으며, Korean Patent Publication No. 1999-0002831 describes solid fuels using wastes formed into arbitrary forms by homogeneously mixing fibrous materials, low anthracite coals, and various auxiliaries, which are carbonized with waste synthetic resins.
기타 폐합성수지, 섬유소, 조연제등을 혼합겔화하여 분말상, 입상의 고체연료제조가 특허출원번호 1973-580호에, 목분,왕겨,볏짚 폐설지를 이용한 인조연탄에 관한 기술이 특허출원번호 제1974-2848호, 1945-1580호등에 각각 기술되어 있으나,Manufacture of powdered and granular solid fuel by mixing and gelling other synthetic synthetic resins, cellulose, and coagulant, etc., to patent application No. 1973-580, and a technology related to artificial briquettes using wood flour, rice husk, and straw straw snowy paper. -2848 and 1945-1580, respectively,
상기와 같은 종래의 기술들은 폐합성수지를 고온 건류탄화시킨 후에 섬유소물 또는 조연제를 혼합하였기 때문에 저칼로리 연료로 이용하지 못하는 문제점이 있어 왔다. The prior art as described above has a problem that can not be used as a low-calorie fuel because the high-temperature dry carbonization of the waste synthetic resin and then mixed with the fibrous material or the supporting agent.
본 발명은 상기와 같은 문제점을 해결하고자, 경유 80중량부, 2-부타놀 8중량부, 메타-크레졸 10중량부 및 산화마그네슘 2중량부로 조성되어 다른 고형 연료에 비하여 높은 발열량을 갖게 되어 대체 에너지로서 사용할 수 있는 가연성 폐기물을 연료로 하는 고체연료의 조연제 및 그 제조방법을 제공하는 것을 목적으로 한다. In order to solve the above problems, the present invention is composed of 80 parts by weight of diesel, 8 parts by weight of 2-butanol, 10 parts by weight of meta-cresol, and 2 parts by weight of magnesium oxide to have a high calorific value compared to other solid fuels, and thus alternative energy. It is an object of the present invention to provide a fuel-coating agent for a solid fuel which can be used as a fuel, and a method for producing the same.
상기 목적을 달성하기 위하여, 본 발명은 경유 80중량부, 2-부타놀 8중량부, 메타-크레졸 10중량부 및 산화마그네슘 2중량부로 조성됨을 특징으로 하는 가연성 폐기물을 연료로 하는 고체연료의 조연제 및 그 제조방법에 관한 것이다.In order to achieve the above object, the present invention is composed of 80 parts by weight of diesel, 8 parts by weight of 2-butanol, 10 parts by weight of meta-cresol and 2 parts by weight of magnesium oxide, the support of solid fuel as a fuel It relates to an agent and a manufacturing method thereof.
본 발명은 가연성 폐기물을 파쇄 건조 압축하는 과정에 본 조연제를 첨가하여 성형된 고체연료는 조연제를 첨가하지 않은 다른 고형 연료에 비하여 높은 발열량을 갖게 되어 대체 에너지로서 사용할 수 있는 것이다.In the present invention, the solid fuel formed by adding the present coagulant in the process of crushing and drying the combustible waste has a higher calorific value than other solid fuels without adding the coagulant, and thus can be used as an alternative energy.
본 발명에서 사용되는 조연제는 경유와, 2-부타놀, 메타크레졸, 산화마그네슘을 사용하는 것으로서, 이들은 발열량을 증대시키고 착화를 원활히 하기 위하여 사용하는 것이다.The fuel retardant used in the present invention uses light oil, 2-butanol, methacresol, and magnesium oxide, and these are used to increase the calorific value and facilitate complexation.
이하 본 발명을 실시예를 통하여 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to the following Examples.
실시예Example
경유 80g 넣은 프로펠라가 부착된 교반기에 2-부타놀 8g 넣고 20분간 골고루 섞이도록 교반한 다음, 상기 혼합액에 메타-크레졸 10g를 다시 투입하여 30분간 재 교반한 후에, 상기 혼합액에 산화마그네슘 2g을 첨가하여 충분히 교반하여 조연제를 제조하였다.8 g of 2-butanol was added to a stirrer containing 80 g of diesel fuel, and stirred for 20 minutes, and then 10 g of meta-cresol was added to the mixed solution and stirred again for 30 minutes. Then, 2 g of magnesium oxide was added to the mixed solution. The mixture was sufficiently stirred to prepare a crude agent.
실험예Experimental Example
상기 실시예에 의해 제조된 조연제를 배합하지 않은 고체연료와 배합한 고체연료를 비교하여 발열량을 실험하였다.The calorific value was tested by comparing the solid fuel that was not blended with the solid fuel prepared by the above embodiment and the blended solid fuel.
표1Table 1
시험항목 ; 발열량Test Items ; Calorific value
시험기기 : Parr 1241 CalorimeterTester: Parr 1241 Calorimeter
시료기준 도착기준Sample criteria Arrival criteria
상기와 같이 본 발명은 가연성 폐기물을 이용하여 제조된 고체연료의 발열량을 증대시켜, 적은량을 연소로 많은 량의 열을 얻게 하여 경제적이며, 제조비용이 저렴하고, 경질의 고열량 제품으로서 착화가 대단히 용이하며, 연소후 잔류하는 재의 량도 극소화하였고, 연소시 유독한 기체 또는 자극성 냄새도 없는 우수한 장점이 있는 것이다 As described above, the present invention increases the calorific value of the solid fuel produced by using the combustible waste, obtains a large amount of heat by burning a small amount, and is economical, low in manufacturing cost, and very easy to ignite as a hard high calorie product. In addition, the amount of ash remaining after combustion is minimized and there is no toxic gas or irritating odor during combustion.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101101185B1 (en) | 2009-02-26 | 2012-01-03 | 부국산업주식회사 | Solid Fuel |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR920009957A (en) * | 1990-11-12 | 1992-06-25 | 전병연 | Solid fuel using combustible waste |
KR930016528A (en) * | 1992-01-23 | 1993-08-26 | 전병연 | Manufacturing method of solid fuel using combustible waste |
US6102975A (en) * | 1999-10-01 | 2000-08-15 | Marr; Wesley D. | Fuel conditioner and improver compositions |
KR20010054340A (en) * | 1999-12-06 | 2001-07-02 | 김재창 | Fuel additive compositions as combustion catalysts |
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2002
- 2002-09-06 KR KR10-2002-0053686A patent/KR100487735B1/en not_active IP Right Cessation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR920009957A (en) * | 1990-11-12 | 1992-06-25 | 전병연 | Solid fuel using combustible waste |
KR930016528A (en) * | 1992-01-23 | 1993-08-26 | 전병연 | Manufacturing method of solid fuel using combustible waste |
US6102975A (en) * | 1999-10-01 | 2000-08-15 | Marr; Wesley D. | Fuel conditioner and improver compositions |
KR20010054340A (en) * | 1999-12-06 | 2001-07-02 | 김재창 | Fuel additive compositions as combustion catalysts |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101101185B1 (en) | 2009-02-26 | 2012-01-03 | 부국산업주식회사 | Solid Fuel |
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