KR100478340B1 - Artificial Glass Marble having Elasticity - Google Patents

Artificial Glass Marble having Elasticity Download PDF

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Publication number
KR100478340B1
KR100478340B1 KR10-2002-0012334A KR20020012334A KR100478340B1 KR 100478340 B1 KR100478340 B1 KR 100478340B1 KR 20020012334 A KR20020012334 A KR 20020012334A KR 100478340 B1 KR100478340 B1 KR 100478340B1
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KR
South Korea
Prior art keywords
glass
layer
artificial marble
pvc
undercoat
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KR10-2002-0012334A
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Korean (ko)
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KR20020026917A (en
Inventor
김애숙
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김애숙
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Priority to KR10-2002-0012334A priority Critical patent/KR100478340B1/en
Publication of KR20020026917A publication Critical patent/KR20020026917A/en
Application granted granted Critical
Publication of KR100478340B1 publication Critical patent/KR100478340B1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165Functional features of the laminated safety glass or glazing
    • B32B17/10247Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
    • B32B17/10256Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques
    • B32B17/10266Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques on glass pane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10788Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing ethylene vinylacetate
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/72Decorative coatings

Abstract

유리(1)를 기재로 하고 그 이면에 인쇄층(30)과의 접착력 강화를 위하여 하도층(프라이머)(2)을 형성하고 그 하도층 이면에 대리석 무늬 인쇄층(4)을 형성한염화폴리비닐(PVC)시트(5)를 공지된 접착제층(3)를 매개로하여 부착한 것으로 구성된 인조대리석에 있어서, 상기 PVC시트층(5)이면에 에틸렌비닐아세테이트(EVA)발포패드(7)를 상기와 같은 공지된 접착제층(6)으로 접착한 것으로 구성된 탄성이 우수한 유리 인조대리석으로서, 유리에 직접 인쇄하지 않고 PVC시트에 대리석 무늬를 인쇄한 것을 접착제로 유리에 접착하고 또한 그 위에 다시 EVA패드(pad)를 부착하였으므로 유리가 잘 파손되지 않음은 물론 설사 유리가 충격에 의해 파손되드라도 파편이 튀거나 비산되지 않는 특징이 있으면서 유리의 취급이 쉽고 건축물에 부착시 작업이 용이한 특징이 있는 것이다.Polychlorinated polychlorine based on glass (1) and formed on the back side to form an undercoat (primer) 2 to enhance adhesion with the print layer 30 and on the backside of the undercoat In the artificial marble composed of a vinyl (PVC) sheet (5) attached via a known adhesive layer (3), the ethylene vinyl acetate (EVA) foam pad (7) on the back of the PVC sheet layer (5) Glass artificial marble having excellent elasticity composed of the adhesive layer 6 as described above, which is printed on a PVC sheet without printing directly on the glass, adheres to the glass with an adhesive, and again on the EVA pad It is easy to handle the glass and easy to attach it to the building because it has the feature that the pad is attached, so that the glass is not easily broken, and even if the glass is broken by the impact, the fragments are not splashed or scattered. to be.

Description

탄성이 있는 유리 인조대리석{Artificial Glass Marble having Elasticity} Artificial Glass Marble having Elasticity

본 발명은 유리로된 인조대리석으로서, 특히 유리의 이면에 도포된 통상의 프라이머상에 대리석 무늬등 다양한 입체무늬를 인쇄한 폴리염화비닐(PVC)시트와 탄성패드를 차례로 유리이면에 접착한 탄성이 우수한 유리 인조대리석에 관한 것이다.The present invention is an artificial marble made of glass, and in particular, a polyvinyl chloride (PVC) sheet, which has printed various three-dimensional patterns such as a marble pattern on a common primer applied to the back surface of glass, and an elastic pad, in turn, adheres to the back surface of the glass. It relates to an excellent glass artificial marble.

일반적으로 유리로된 인조대리석은 유리의 이면에 각종 합성수지로된 인쇄잉크로 다양한 무늬의 대리석 인쇄층을 형성한 것으로 구성되어 있으나 그렇게 형성된 인쇄층은 탄력성이 거의 없으므로 외부 충격이나 눌림에 의하여 유리 인조대리석은 쉽게 파손되고 그 파손된 파편이 멀리까지 튀거나 퍼져서 공해 문제는 물론 인체에 위해를 끼칠 수도 있게 된다.Generally, the artificial marble made of glass is composed of various kinds of marble printing layers formed by printing inks made of various synthetic resins on the back side of the glass. However, the printed layers have almost no elasticity. Is easily broken, and the broken fragments can splatter or spread far, causing harm to humans as well as pollution problems.

이와같은 유리 인조대리석의 결점을 보완 개량하여 2001.10.31로 "제조와 가공이 쉬운 유리 인조대리석"이 선출원된 바 있는데 그 요지는 불소수지에 다목적 실란 카프링을 첨가한 것을 프라이머층으로 하고 통상의 폴리우레탄 수지와 에폭시수지의 혼합물에 접착보강제로 아크릴레이트올리고머와 자외선 흡수제를 혼합한 것을 인쇄층으로하여 유리 이면에 차례로 도포하여 유리 인조대리석을 제조한 것이었으나 이 역시 프라이머층과 인쇄층의 탄성이 약하여 제조 및 취급과 설치과정에서 파손되트 쉬운 결점이 있었다.또한 투명기판, 프라이머층, 인쇄층, 인쇄층 보호막, 유리섬유매트 및/또는 유리섬유강화플라스틱층을 차례로 적층하여 파편보호막을 형성하도록 구성된 칼라무늬 인조대리석이 있으나, 이 경우 파편보호막용으로 적층한 유리섬유매트나 유리섬유강화 플라스틱층은 잘 파손되지는 않지만 경화되면 너무 단단하여 쿳션력이 전혀 없고 제조 및 절단도 쉽지 않고 제조비용도 많이 소요되는 등의 불편이 있었다.As a result of supplementing and improving the shortcomings of the glass artificial marble, the “glass artificial marble which is easy to manufacture and process” was pre- filed on October 31, 2001. The main point is to add a multipurpose silane capping to the fluorine resin as a primer layer. A mixture of a urethane resin and an epoxy resin was used as a printing layer by mixing an acrylate oligomer and an ultraviolet absorber as an adhesive reinforcement to apply to the back surface of the glass in order to produce a glass artificial marble. It is easy to be damaged during manufacturing, handling and installation. It is also a color configured to form a debris protection film by laminating a transparent substrate, a primer layer, a printing layer, a printing layer protective film, a glass fiber mat and / or a glass fiber reinforced plastic layer in sequence. Patterned marble, but in this case laminated glass fiber Or glass fiber reinforced plastic layers are cured, but if the damage was not well, such as the inconvenience of too hard and not at all a cushion force and manufacturing is not easy and it takes a lot of also cutting manufacturing costs.

본 발명은 상기한 바와같은 종래의 유리 인조대리석의 결점을 개선하여 유리의 이면에 인쇄층이나 필름과의 접착력 강화를 위한 통상적인 하도층(프라이머)을 도포 형성한 다음 그 하도층 위에 탄성이 우수한 합성수지 시트에 각종 대리석 무늬를 다양하게 인쇄하여 유리이면에 부착하고 그 시트의 이면에 발포패드를 부착하여 왠만한 충격이나 하중에도 탄성이 강하고 휨강도가 우수하며 왠만한 충격이나 눌림에도 잘 파손되지 않고 설사 파손이 되드라도 파편이 튀거나 휘산되지 않고 크랙만 가게되어 폐기처리하기가 쉽고 인체에 위해를 주지 않는 특징을 가진 유리 인조대리석을 제공코저하는 것으로서 이를 첨부된 도면을 참조하면서 상세히 설명하면 다음과 같다.The present invention improves the drawbacks of the conventional glass artificial marble as described above by coating a conventional undercoat (primer) for strengthening the adhesion to the printing layer or film on the back of the glass and then excellent elasticity on the undercoat Various marble patterns are printed on the synthetic resin sheet and attached to the back of the glass, and foam pads are attached to the back of the sheet so that they are highly elastic against bending and load, and have excellent bending strength. Even if the fragments are not splashed or volatilized, only cracks are stored, so that they are easy to dispose of and provide a glass artificial marble having a feature that does not harm the human body, which will be described in detail with reference to the accompanying drawings.

유리(1)를 기재로 하고 그 이면에 인쇄층과의 접착력 강화를 위하여 불소수지와 같은 공지된 하도층(프라이머층)(2)을 도포하고 그 하도층(2) 이면에 대리석 무늬를 인쇄한 인쇄층(4)을 가진 염화폴리비닐(PVC)시트층(5)을 공지된 접착제층(3)을 매개로 하여 부착한 것으로 구성된 인조대리석에 있어서, 상기 PVC시트층(5)이면에 에틸렌비닐아세테이트(EVA)발포패드(7)를 상기와 같은 공지된 접착제층(6)으로 접착한 것으로 구성된 것이다.It is based on the glass (1), and coated with a known undercoat (primer layer) 2, such as a fluororesin, to enhance adhesion with the print layer on the back side thereof, and a marble pattern is printed on the underside of the undercoat layer 2 In the artificial marble consisting of a polyvinyl chloride (PVC) sheet layer (5) having a printing layer (4) attached via a known adhesive layer (3), ethylene vinyl on the back of the PVC sheet layer (5) The acetate (EVA) foam pad 7 is constructed by adhering the above known adhesive layer 6.

이상과 같이 구성되는 본 발명의 탄성이 있는 유리 인조대리석은 유리(1)에 직접 인쇄하지 않고 대리석 무늬의 인쇄층(4)이 인쇄된 PVC시트층(5)을 유리(1)이면에 도포된 프라이머층(2)의 이면에 접착제층(3)으로 부착하고 다시 그 PVC시트층(5) 이면에 EVA발포패드(7)를 접착제층(6)으로 접착하였으므로 유리가 PVC와 EVA시트에 의해 여간한 충격이나 압력에 의해서도 잘 파손되지 않게되고 쿳션성이 좋아서 취급하기가 좋고 제조공정도 간편하여 제조원가도 저렴한 특징이 있으며 설사 파손되드라도 파편이 분산되어 공해의 원인이 되거나 인체에 위해를 주는 일이 없이 폐기할 수 있는 특징이 있다.The elastic glass artificial marble of the present invention constituted as described above is coated with a PVC sheet layer 5 having a marble-printed printing layer 4 printed thereon without being directly printed on the glass 1. It was attached to the back of the primer layer 2 with the adhesive layer 3, and again the EVA foam pad 7 was attached to the back of the PVC sheet layer 5 with the adhesive layer 6, so that the glass was separated by the PVC and the EVA sheet. It is not easy to be damaged by shock or pressure, and it has good cushioning property, which is easy to handle, and the manufacturing process is simple, and its manufacturing cost is inexpensive, and even if it is broken, fragments are dispersed and cause pollution or harm to human body. There is a feature that can be discarded without.

여기에서 상기와 같은 방법으로 인조타일을 제작할 수도 있다.Here, the artificial tile may be manufactured in the same manner as described above.

본 발명 유리 인조대리석은 PVC시트(5)와 EVA발포패드(7)에 의해 탄성이 우수하여 파손이 잘 안되는 효과가 있고 따라서 취급이 용이한 효과도 있다.Glass artificial marble of the present invention is excellent in elasticity by the PVC sheet (5) and EVA foam pad (7) has an effect that is not easily broken, and thus there is an effect that is easy to handle.

도 1 은 본 발명에 따른 유리 인조대리석의 요부 단면도.1 is a cross-sectional view of the main portion of the glass artificial marble according to the present invention.

*도면 중 주요부분에 대한 부호의 설명** Description of the symbols for the main parts of the drawings *

20 : 하도층(프라이머층) 30 : 인쇄층20: undercoat (primer layer) 30: printed layer

1 : 유리 2 : 프라이머층1: glass 2: primer layer

3 : 접착제층 4 : 인쇄층3: adhesive layer 4: printed layer

5 : PVC시트 6 : 접착제층5: PVC sheet 6: adhesive layer

7 : EVA발포패드7: EVA foam pad

Claims (1)

유리(1)를 기재로 하고 그 이면에 인쇄층과의 접착력 강화를 위하여 불소수지와 같은 공지된 하도층(프라이머층)(2)을 도포하고 그 하도층(2) 이면에 대리석 무늬를 인쇄한 인쇄층(4)을 가진 염화폴리비닐(PVC)시트층(5)을 공지된 접착제층(3)을 매개로 하여 부착한 것으로 구성된 인조대리석에 있어서, 상기 PVC시트층(5)이면에 에틸렌비닐아세테이트(EVA)발포패드(7)를 상기와 같은 공지된 접착제층(6)으로 접착한 것으로 구성됨을 특징으로하는 탄성이 있는 유리 인조대리석.It is based on the glass (1), and coated with a known undercoat (primer layer) 2, such as a fluororesin, to enhance adhesion with the print layer on the back side thereof, and a marble pattern is printed on the underside of the undercoat layer 2 In the artificial marble consisting of a polyvinyl chloride (PVC) sheet layer (5) having a printing layer (4) attached via a known adhesive layer (3), ethylene vinyl on the back of the PVC sheet layer (5) An elastic glass artificial marble, characterized in that it is composed of the acetate (EVA) foam pad (7) adhered to the above known adhesive layer (6).
KR10-2002-0012334A 2002-03-08 2002-03-08 Artificial Glass Marble having Elasticity KR100478340B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR10-2002-0012334A KR100478340B1 (en) 2002-03-08 2002-03-08 Artificial Glass Marble having Elasticity

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Application Number Priority Date Filing Date Title
KR10-2002-0012334A KR100478340B1 (en) 2002-03-08 2002-03-08 Artificial Glass Marble having Elasticity

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KR20020026917A KR20020026917A (en) 2002-04-12
KR100478340B1 true KR100478340B1 (en) 2005-03-24

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR910009589A (en) * 1989-11-27 1991-06-28 류상균 Composite Glazed Artificial Marble
WO1996000886A1 (en) * 1994-06-30 1996-01-11 Aerospatiale Societe Nationale Industrielle Optoelectronic camera
JPH08157239A (en) * 1994-11-29 1996-06-18 Asahi Glass Co Ltd Sandwich glass
KR19990046117A (en) * 1998-05-08 1999-06-25 주덕중 Artificial color marble and a process for preparation thereof
KR20000064529A (en) * 1997-01-13 2000-11-06 이즈하라 요조 Method of manufacturing laminated glass
JP2002180019A (en) * 2000-12-18 2002-06-26 Bridgestone Corp Adhesive film and film-reinforced glass

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR910009589A (en) * 1989-11-27 1991-06-28 류상균 Composite Glazed Artificial Marble
WO1996000886A1 (en) * 1994-06-30 1996-01-11 Aerospatiale Societe Nationale Industrielle Optoelectronic camera
JPH08157239A (en) * 1994-11-29 1996-06-18 Asahi Glass Co Ltd Sandwich glass
KR20000064529A (en) * 1997-01-13 2000-11-06 이즈하라 요조 Method of manufacturing laminated glass
KR19990046117A (en) * 1998-05-08 1999-06-25 주덕중 Artificial color marble and a process for preparation thereof
JP2002180019A (en) * 2000-12-18 2002-06-26 Bridgestone Corp Adhesive film and film-reinforced glass

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