KR100472941B1 - A porous concrete composition having permeability, high strength and durability - Google Patents

A porous concrete composition having permeability, high strength and durability Download PDF

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KR100472941B1
KR100472941B1 KR10-2001-0030963A KR20010030963A KR100472941B1 KR 100472941 B1 KR100472941 B1 KR 100472941B1 KR 20010030963 A KR20010030963 A KR 20010030963A KR 100472941 B1 KR100472941 B1 KR 100472941B1
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water
weight
porous concrete
concrete
binder
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KR20010070730A (en
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최재진
김희덕
이용구
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(주)한길이엔씨
한국휴로드 (주)
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/14Waste materials; Refuse from metallurgical processes
    • C04B18/141Slags
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/0016Granular materials, e.g. microballoons
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/30Water reducers, plasticisers, air-entrainers, flow improvers
    • C04B2103/302Water reducers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/54Pigments; Dyes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • C04B2201/52High compression strength concretes, i.e. with a compression strength higher than about 55 N/mm2, e.g. reactive powder concrete [RPC]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
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  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Road Paving Structures (AREA)

Abstract

본 발명은 콘크리트를 구성하는 페이스트로 둘러싸인 골재입자 사이에 연속되는 많은 공극을 조성하여 물을 통과시키거나 공극내에 저류함으로써 자연 환경계나 생태계에 도움을 주며 다공성 콘크리트 포장면을 이용함으로써 이용자에게 쾌적한 환경을 주는 투수성 다공질 콘크리트를 제조하는 방법에 관한 것으로 투수기능을 가진 다공질 콘크리트의 강도와 내구성 저하의 문제점을 해결하기 위하여 혼화제로서 고성능 AE감수제를 적정량 사용하고 시멘트량에 대하여 광물질 혼화재인 고로슬래그 미분말을 적정량 치환 사용하여 단위수량(單位水量)을 저감함으로써 재령 28일 압축강도 150 내지 350 kgf/㎠ 및 높은 내구성을 가지며 투수계수 0.01 내지 0.5 cm/sec의 투수성을 갖는 다공질 콘크리트 조성물을 제공하는데 그 목적이 있다. 상기 목적을 달성하기 위하여 본 발명은 투수성 다공질 콘크리트 1㎥ 당 물 90 내지 110kg, 물-결합재의 비(W/(C+B.F))가 25 내지 33중량%, 고성능 AE감수제를 결합재에 대하여 0.5 내지 2.5중량%, 착색재를 결합재에 대하여 2 내지 5중량%, 골재는 최대치수 13mm 또는 10mm 골재 1500 내지 1750kg으로 구성하되 결합재로서 시멘트와 고로슬래그 미분말을 사용하는 것을 특징으로 하는 높은 강도와 내구성을 지니는 투수성 다공질 콘크리트 조성물에 관한 것이다.The present invention helps the natural environment or ecosystem by forming a large number of continuous voids between aggregate particles surrounded by the paste constituting the concrete to pass water or stored in the voids and to create a pleasant environment for the user by using a porous concrete pavement surface. The main method is to manufacture permeable porous concrete. In order to solve the problem of strength and durability degradation of porous concrete with permeability, an appropriate amount of high-performance AE water reducing agent is used as a admixture, and an appropriate amount of fine blast furnace slag powder, which is a mineral admixture, is used for cement content. The purpose of the present invention is to provide a porous concrete composition having a compressive strength of 150 to 350 kgf / cm 2, high durability and permeability of 0.01 to 0.5 cm / sec. have. In order to achieve the above object, the present invention provides 90 to 110 kg of water per 1 ㎥ of permeable porous concrete, water to binder ratio (W / (C + BF)) of 25 to 33% by weight, high performance AE water reducing agent 0.5 to the binder To 2.5% by weight, 2 to 5% by weight of the coloring material to the binder, the aggregate consists of 1500 to 1750kg of the maximum size 13mm or 10mm aggregate, but the cement and blast furnace slag fine powder as a binder, characterized in high strength and durability Genie relates to a permeable porous concrete composition.

Description

높은 강도와 내구성을 지니는 투수성 다공질 콘크리트 조성물{A porous concrete composition having permeability, high strength and durability} A porous concrete composition having permeability, high strength and durability

본 발명은 보도, 도로, 주차장 등 넓은 면적을 가지는 포장용 투수성 다공질 시멘트 콘크리트 조성물의 제조에 관한 것이다.The present invention relates to the production of permeable porous cement concrete composition for paving having a wide area such as sidewalks, roads, parking lots.

도로의 포장에는 불투수성인 아스팔트 포장과 콘크리트 포장이 주로 사용되고 있다. 그러나 불투수성 포장체들은 강우시, 배수시설이 없거나 배수가 완벽하지 못한 경우 물이 잘 빠지지 못하고 도로표면에 고임으로써 통행에 지장을 초래하며 미끄럼 저항성이 떨어지는 단점이 있다. 또한 물을 땅속에 침투시키지 못하고 포장체 표면으로 흐르게 하여 하수관과 하천 등으로 흘러 들어가면서 지하수가 고갈되고 폭우시 하천에의 물의 유입이 가속화됨에 따라 하천의 범람을 일으키며, 땅 속에 미생물이 서식하지 못하여 가로수가 잘 자라지 못하는 등 자연환경의 측면에서 여러가지 문제점이 있다. The pavement of the road is mainly used for asphalt pavement and concrete pavement. However, impervious pavements have a disadvantage in that when there is no drainage or incomplete drainage, the water is not drained well and the road surface is impregnated and the slip resistance is reduced. In addition, water does not penetrate into the ground and flows to the surface of the package, which flows into sewer pipes and streams, causing groundwater depletion and flooding of rivers as the inflow of water into the rivers accelerates during heavy rains. There are many problems in terms of natural environment, such as poor growth.

이와 같은 문제점을 해결하기 위한 방법으로 투수성 포장에 대한 관심을 갖고 1980년대부터 선진 외국에서는 투수성 아스팔트를 개발하여 보도를 중심으로 한 생활관련도로, 광장 및 주차장 등의 포장에 사용하고 있다. 그러나 투수성 아스팔트 포장은 여름철에 노면의 온도가 상승할 때 노면이 변형되어 투수기능이 상실되는 단점이 있기 때문에 투수성 콘크리트가 개발되게 되었고 현재는 주로 사람이 통행하는 보도, 자전거 도로나 주차장 등에 이용되고 있다.As a way to solve such problems, interest in permeable pavement has been developed, and since 1980, developed permeable asphalt has been used for pavement such as living-related roads, plazas and parking lots, mainly on sidewalks. However, permeable asphalt pavement has been developed due to the disadvantage of loss of permeability due to deformation of the road surface when the temperature of the road surface rises in the summer, and now permeable concrete has been developed. It is becoming.

투수성 콘크리트는 물이 투과할 수 있도록 하기 위하여 연속된 공극을 갖는 다공질 콘크리트로 제조되며, 일정 크기의 굵은 골재를 사용한다. 콘크리트의 강도는 공극률의 증가에 따라 감소하며 반대로 투수성은 공극률의 증가에 따라 증가된다. 이에 따라 적절한 수준의 투수성과 강도를 가지는 투수성 다공질 콘크리트를 제조하기 위한 연구가 활발히 진행되었다. 예로서 대한민국 공고 특허 제 90-4390호에서는 물 116kg/㎥, 시멘트 292kg/㎥, 잔골재 87kg/㎥, 굵은골재 1690kg/㎥, 안료 7kg/㎥, 혼화제 0.58kg/㎥로 혼합한 투수성 콘크리트를 제공하였고, 동 제 91-6894호에서는 콘크리트 1㎥ 당 300내지 400kg 의 포틀랜드시멘트, 시멘트 1 중량부에 대해 0.005 내지 0.1 중량부의 바인더와 0.35 내지 0.45중량부의 물 및 잔부를 이루는 골재로 이루어진 투수성 콘크리트를 제공하였으며, 대한민국 공개 특허 제 97-21018호에서는 물 120 내지 130kg/㎥, 시멘트 270 내지 340kg/㎥, 6 내지 10mm 크기의 골재 1530 내지 1920kg/㎥, 안료 14 내지 20kg/㎥에 지연제를 시멘트 사용량의 0.3% 이내로 혼합한 투수성 콘크리트를 제공하였다. Permeable concrete is made of porous concrete with continuous pores in order to allow water to permeate, using coarse aggregates of a certain size. The strength of concrete decreases with increasing porosity, while the permeability increases with increasing porosity. Accordingly, studies have been actively conducted to manufacture permeable porous concrete having appropriate levels of permeability and strength. For example, Korean Patent Publication No. 90-4390 provides water permeable concrete mixed with water 116kg / ㎥, cement 292kg / ㎥, fine aggregate 87kg / ㎥, coarse aggregate 1690kg / ㎥, pigment 7kg / ㎥, admixture 0.58kg / ㎥. In No. 91-6894, water-permeable concrete composed of 300 to 400 kg of Portland cement per m3 of concrete, 0.005 to 0.1 parts by weight of binder, and 0.35 to 0.45 parts of water and aggregates based on 1 part by weight of cement is used. In Korean Patent Laid-Open No. 97-21018, the amount of cement is added to 120 to 130 kg / m3 of water, 270 to 340 kg / m3 of cement, 1530 to 1920 kg / m3 of aggregates having a size of 6 to 10 mm, and 14 to 20 kg / m3 of pigment. Permeable concrete mixed to within 0.3% of.

한편, 미국 특허 제 3,870,422호(1975년 3월 11일 등록)에서는 골재는 약 1/4인치의 평균 직경을 가지며 시멘트, 모래 및 굵은 골재의 혼합물의 부피비가 1:0:3 또는 1:1/4:3으로 하고 접착제와 물의 혼합물의 부피비를 1:3으로 하여 높은 투수성(초당 1인치)을 지니는 투수성 포장 콘크리트를 제조하는 기술을 제시하였다. On the other hand, U.S. Patent No. 3,870,422 (registered Mar. 11, 1975) has an average diameter of about 1/4 inch and the volume ratio of the mixture of cement, sand and coarse aggregate is 1: 0: 3 or 1: 1 /. A technique for producing permeable pavement concrete having high permeability (1 inch per second) with a ratio of 4: 3 and a volume ratio of a mixture of adhesive and water is 1: 3.

그러나 이들 기술은 물과 시멘트의 배합비를 높게 구성함으로써 강도나 내구성증진에는 한계를 보이고 있다. 일반적으로 콘크리트는 수밀한 구성일수록 높은 강도와 내구성을 가지는 콘크리트라고 말할 수 있다. 그러나 투수성의 다공질 콘크리트는 투수성능을 확보하기 위해 높은 연속 공극률을 가지도록 제조되기 때문에 강도나 내구성이 일반 콘크리트에 비해 크게 저하하는 것이므로 이러한 단점을 개선하기 위해서는 콘크리트의 단위수량을 최대한 낮추는 것이 가장 현실적인 수단되며 이를 통해 강도나 내구성이 향상되는 것이다. However, these technologies show a limitation in increasing strength and durability by forming a high mixing ratio of water and cement. In general, concrete can be said to be a concrete having a higher strength and durability the more dense configuration. However, since permeable porous concrete is manufactured to have high continuous porosity to secure permeability, strength and durability are greatly reduced compared to general concrete. Therefore, in order to remedy these disadvantages, it is most practical to lower the unit quantity of concrete as much as possible. This will improve strength or durability.

또한, 투수성 다공질 콘크리트는 투수성능에 의한 자연 환경친화성을 가지고 있는 반면, 다공성으로 인한 강도의 저하문제 및 내구성 저하의 문제 즉 연속공극으로 인한 대기중 유해물질에 의한 중성화 속도가 빠르게 진행되며, 공극내로 수분 유입에 따른 동결팽창에 대한 저항력의 저하 등 여러가지의 극심한 외부환경에 콘크리트 내부의 공극면이 노출됨으로써 콘크리트 구축물의 내구수명이 단축되는 단점을 가지고 있다. In addition, while permeable porous concrete has a natural environmental friendliness due to permeability, the problem of deterioration in strength due to porosity and durability deterioration, that is, the speed of neutralization by harmful substances in the air due to continuous pores is rapidly progressing. The durability of the concrete construction is shortened by exposing the void surface inside the concrete to various extreme external environments such as a decrease in the resistance to freezing expansion due to moisture inflow into the void.

본 발명은 이러한 문제점을 해결하기 위한 것으로서 콘크리트 배합시 혼화제로서 고성능 AE감수제를 적정량 사용하고, 광물성 혼화재로서 고로슬래그 미분말(Ground Granulated Blast-Furnace Slag : B.F)을 시멘트중량에 대하여 적정량 치환 사용하도록 하여, 물, 시멘트, 골재에 고성능 AE감수제와 고로슬래그 미분말을 배합하되 최적의 배합비를 도출함으로써 투수성 다공질 콘크리트의 강도나 내구성능을 종전보다 크게 향상된 재령 28일 압축강도 150 내지 350kgf/㎠와 높은 내구성을 갖고 투수계수 0.01 내지 0.5cm/sec를 갖는 투수성 다공질 콘크리트를 제공하는데 그 목적이 있다. The present invention is to solve this problem by using an appropriate amount of high performance AE reducing agent as admixture when mixing concrete, and by using an appropriate amount to replace the ground granulated Blast-Furnace Slag (BF) with respect to the cement weight as a mineral admixture, High-performance AE water-reducing agent and blast furnace slag fine powder are mixed with water, cement, and aggregate, and the optimum mixing ratio is derived. The strength and durability of permeable porous concrete are significantly improved than before, with 28-day compressive strength of 150 to 350kgf / ㎠ and high durability. It is an object to provide a permeable porous concrete having a permeability coefficient of 0.01 to 0.5 cm / sec.

이러한 목적을 달성하기 위하여 콘크리트 1㎥당 골재의 최대치수가 13mm 또는 10mm이며 5mm체의 통과중량백분율이 5 내지 30%인 골재 1500 내지 1750kg 을 사용하고, 물의 양이 90 내지 110kg이며 결합재는 시멘트와 시멘트에 대하여 분말도(粉末度) 2750 내지 8000㎠/g인 고로슬래그 미분말을 20 내지 50중량%로 치환 사용하고 결합재에 대한 물의 비(W/(C+B.F))가 25 내지 33중량%, 고성능 AE감수제를 결합재에 대하여 0.5 내지 2.5중량%, 착색재(着色材)를 결합재에 대하여 2 내지 5중량%로하는 것에 본 발명의 특징이 있다.In order to achieve this purpose, the maximum dimension of aggregate per 1m3 of concrete is 13mm or 10mm, and the aggregate weight is 1500-1750kg, which is 5-30% of the weight ratio of 5mm sieve, and the amount of water is 90-110kg, and the binder is cement and cement. 20 to 50% by weight of blast furnace slag fine powder having a powder degree of 2750 to 8000 cm 2 / g is used, and the ratio of water to binder (W / (C + BF)) is 25 to 33% by weight, high performance. The feature of the present invention is that the AE reducing agent is 0.5 to 2.5% by weight with respect to the binder, and the coloring material is 2 to 5% by weight with respect to the binder.

본 발명에서는 콘크리트 1㎥당 최대치수 13mm의 골재 또는 최대치수 10mm인 골재를 1500kg 내지 1750kg을 사용하고 물의 양이 90 내지 110kg이며, 물-결합재의 비(W/(C+B.F))가 25 내지 33중량%, 고성능 AE감수제를 결합재에 대하여 0.5 내지 2.5중량%, 착색재(着色材)를 결합재에 대하여 2 내지 5중량%로 하되 일반적으로 투수성 다공질 콘크리트의 투수도와 강도 특성은 상반되므로 강도를 높이려면 투수도가 저하되는 반면 투수도를 높이려면 강도가 낮아지는 경향이 있으므로 최적의 투수콘크리트를 제공하기 위해서는 콘크리트 배합 구성요소들에 대해 최적의 배합비를 선정하여야 한다. In the present invention, the aggregate of the maximum dimension 13mm or aggregate size of 10mm maximum 1500mm to 1750kg is used in the present invention and the amount of water is 90 to 110kg, water-binder ratio (W / (C + BF)) of 25 to 33% by weight, 0.5 to 2.5% by weight of the high-performance AE water reducing agent and 2 to 5% by weight of the binder in the colorant, but generally the permeability and strength characteristics of the permeable porous concrete are incompatible with each other. To increase the permeability, while the permeability is lowered, the strength tends to be lowered. Therefore, in order to provide an optimal permeable concrete, an optimal mixing ratio should be selected for the concrete mixing components.

본 발명에서 골재는 일반쇄석으로서 5mm체의 통과중량백분율이 5 내지 30%인 골재를 사용하는데 5mm체의 통과중량백분율이 5%미만인 경우는 투수성은 좋으나 강도저하의 문제점이 있고 30%를 초과하는 경우에는 강도는 증대하나 투수성이 저하한다. 따라서 사용 골재는 한국산업규격(KSF2527)에 따라 골재크기 13 내지 2.5mm인 골재는 19mm체를 전부 통과하고 13mm체의 통과중량백분율 90 내지 100%, 10mm체의 통과중량백분율 40 내지 75%, 5mm체의 통과중량백분율 5 내지 25%, 2.5mm체의 통과중량백분율 0 내지 10%, 1.2mm체의 통과중량백분율 5%이하인 것을 사용하며 골재크기 10 내지 2.5mm 골재는 13mm체를 전부 통과하고 10mm체의 통과중량백분율 85 내지 100%, 5mm체의 통과중량백분율 10 내지 30%, 2.5mm체의 통과중량백분율 0 내지 10%, 1.2mm체의 통과중량백분율 5%이하인 것을 사용한다. In the present invention, aggregate is 5 to 30% of the aggregate weight percentage of the 5mm sieve as a general crushed aggregate, but when the percent by weight of the 5mm sieve is less than 5%, the water permeability is good but there is a problem of reduced strength and exceeds 30%. In this case, the strength increases, but the water permeability decreases. Therefore, the aggregate used is aggregate of 13 ~ 2.5mm of aggregate according to Korean Industrial Standard (KSF2527), all the 19mm sieve passes through 90mm of the total weight of 13mm sieve, 40 ~ 75% of the passing weight percent of 10mm sieve, 5mm The through weight percentage of the sieve is 5 to 25%, the through weight percentage of the 2.5mm sieve is 0 to 10%, and the passing weight percentage of the 1.2 mm sieve is 5% or less. The through weight percentage of the sieve is 85 to 100%, the through weight percentage of the 5 mm sieve is 10 to 30%, the passing weight percentage of the 2.5 mm sieve is 0 to 10%, and the passing weight percentage of the 1.2 mm sieve is 5% or less.

투수성 콘크리트에는 결합재로서 보통포틀랜드 시멘트만을 일반적으로 사용해 오고 있으나 본 발명에서는 결합재의 구성비를 시멘트 80 내지 50중량%와 분말도(粉末度) 2750 내지 8000㎠/g인 고로슬래그 미분말 20 내지 50중량%로 하여 사용하는데 고로슬래그 미분말이 혼입되지 아니한 것에 비하여 콘크리트의 압축강도가 5 내지 15%가 증진되는 효과를 나타낸다. Although only Portland cement has been generally used as a binder in water-permeable concrete, in the present invention, the composition ratio of the binder is 80 to 50 wt% of cement and 20 to 50 wt% of blast furnace slag powder having a powder degree of 2750 to 8000 cm2 / g. In comparison with the use of blast furnace slag fine powder, the compressive strength of concrete is increased by 5 to 15%.

고로슬래그 미분말을 결합재의 일부로 사용함으로써 단위수량의 절감, 장기강도의 증진, 폐자원의 활용과 원가절감 그리고 콘크리트 색조가 약간 흰색을 띠게되므로 착색에 유리한 점 등 장점이 있는 반면, 응결시간이 길어져 포장면의 개방이 지연(특히 저온일 경우 양생기간이 길어짐)되고 초기강도가 낮아지는 단점이 있으므로 10℃이상의 기후조건하에서 양생기간, 단위수량 저감효과 및 강도증진효과를 고려하여 시멘트에 대한 고로슬래그 미분말의 치환률의 범위를 20 내지 50중량%로 정한다. 본 발명의 구성인 물-결합재의 비(W/(C+B.F)) 25 내지 33중량%의 범위에 있어서, 고로슬래그의 치환율이 20 중량%미만인 경우 단위수량 저감효과가 적으며 치환율을 50중량%로 한 경우에는 고로슬래그 미분말을 혼입하지 아니한것에 비하여 단위수량이 5 내지 10% 저감되나 치환율 50중량%를 초과하는 경우에는 강도증진 효과가 작아진다. By using blast furnace slag powder as part of the binder, it has advantages such as reduction of unit quantity, improvement of long-term strength, utilization of waste resources and cost reduction, and the color tone of concrete that is slightly white, which is advantageous for coloring. Since the opening of the cotton is delayed (especially at low temperatures, the curing period is long) and the initial strength is lowered. Therefore, the blast furnace slag fine powder for cement is considered in consideration of curing period, unit quantity reduction effect and strength enhancement effect under the climatic condition of 10 ℃ or higher. The range of substitution rate of is set to 20 to 50% by weight. In the range of 25 to 33% by weight of the water-binding material (W / (C + BF)), which is the constituent of the present invention, when the substitution rate of the blast furnace slag is less than 20% by weight, the effect of reducing the unit quantity is small and the substitution rate is 50%. In the case of%, the amount of unit is reduced by 5 to 10% as compared with the case where no fine blast furnace slag is mixed, but when the substitution rate exceeds 50% by weight, the effect of increasing strength is reduced.

또한, 투수성 다공질 콘크리트가 일반 콘크리트에 비해 강도가 매우 낮은 것을 감안할 때 투수성 다공질 콘크리트제조시 시멘트를 고로슬래그 미분말로 일정량 치환하여 사용하면 단위수량 저감은 물론 장기강도의 발현에 매우 유리하므로 고성능 AE감수제와 함께 사용하는 경우 강도나 내구성지수를 증진시킬 수 있다. In addition, considering that permeable porous concrete is much lower than general concrete, when permeable porous concrete is replaced by a certain amount of cement with blast furnace slag, it is very advantageous to reduce unit quantity and develop long-term strength. When used in combination with a water reducing agent, the strength or durability index can be enhanced.

특히, 기온이 높은 여름철에는 콘크리트의 응결이 촉진되어 시공성이 떨어지는 문제점이 있는데 고로슬래그 미분말의 혼입량에 따른 응결시간 지연 특성을 이용하면 콘크리트의 운반과 포설에 소요되는 시간을 연장할 수 있어서 투수성 다공질 콘크리트의 품질향상을 도모할 수 있다. In particular, in the summer when the temperature is high, the condensation of concrete is accelerated, and the workability is inferior. The use of the delay time of condensation according to the amount of blast furnace slag powder can be used to extend the time required for transporting and laying concrete. The quality of concrete can be improved.

한편, 투수성 다공질 콘크리트는 투수성능을 확보하기 위하여 높은 공극률을 가지도록 제조되기 때문에 강도와 내구성이 일반 콘크리트에 비하여 저하되며 이에 대한 대응책으로서는 기존의 감수제보다 감수성능이 우수한 화학혼화제의 사용으로 콘크리트의 물-결합재의 비(W/(C+B.F))를 낮추는 것이 가장 현실적인 수단이 된다. On the other hand, permeable porous concrete is manufactured to have high porosity in order to secure permeability, so strength and durability are lowered compared to general concrete. As a countermeasure, chemical admixtures having superior water-resistance performance than conventional water reducing agents are used as a countermeasure. Lowering the water-binder ratio (W / (C + BF)) is the most realistic means.

본 발명에서의 콘크리트 배합에는 화학혼화제인 고성능 AE감수제를 사용한다. In the present invention, a high performance AE water reducing agent, which is a chemical admixture, is used for concrete mixing.

콘크리트용 화학혼화제의 역사를 보면, 1940년경 감수제와 AE제의 개발을 시작으로 하여 본격적인 개발이 이루어졌으며, 1970년경에는 독일에서 고성능 감수제 또는 유동화제의 개발이 이루어져 현재는 이 혼화제가 고강도 콘크리트의 제조 또는 시공성이 좋은 콘크리트의 제조에 널리 사용되고 있다. 그러나 고성능 감수제 또는 유동화제는 단위수량을 크게 감소시키며, 비교적 많은 양을 사용하여도 응결지연이나 공기포의 과잉연행 등의 악영향이 없다는 장점이 있는 반면 혼합 후 경과시간에 따라 급격한 슬럼프 손실이 초래되는 결점이 있어서 믹싱 후 조속한 시간 내에 콘크리트 치기를 마쳐야 하는 사용상의 제약이 있다. The history of chemical admixtures for concrete began with the development of water sensitizers and AEs around 1940, and the development of high performance water sensitizers or glidants in Germany in 1970. Or it is widely used for the manufacture of concrete with good workability. However, high-performance water-reducing agent or fluidizing agent greatly reduces the unit quantity, and even if a relatively large amount is used, there is an advantage that there is no adverse effect such as condensation delay or excessive entrainment of air bubbles, whereas rapid slump loss occurs depending on the elapsed time after mixing. There are drawbacks to the use constraints of finishing the concrete stroke within the fast time after mixing.

이러한 문제를 해결하기 위하여 유동화제의 경우 공사현장에서 애지테이터드럼 속에 혼화제를 추가로 첨가하여 사용하는 예가 많은데 공사현장에서의 유동화작업은 유동화제의 투입관리, 베이스콘크리트와 유동화콘크리트 양자의 품질확인과 관리, 레미콘 차의 배기가스, 소음 등의 많은 문제를 야기한다. In order to solve this problem, in the case of the fluidizing agent, there are many examples in which the admixture is added to the agitator drum at the construction site. The fluidization work in the construction site includes the management of the input of the fluidizing agent, the quality confirmation of both the base concrete and the fluidizing concrete. It causes a lot of problems such as management, ready-mixed car exhaust, noise, etc

특히 투수성 다공질 콘크리트의 경우는 된반죽으로 제조되어 덤프트럭으로 운반되기 때문에 운반시간에 따라 반죽질기가 크게 변화할 수 있으며 이와 같은 경우 다짐작업이 불충분하게 됨으로써 품질저하를 초래할 수 있다. In particular, the permeable porous concrete is made of dough and transported to the dump truck, so the dough kneading can be changed greatly according to the transport time, and in this case, the compaction work may be insufficient, resulting in quality deterioration.

이에 반하여 비교적 최근에 개발된 고성능 AE감수제를 사용하는 경우는 운반시간에 따른 슬럼프 손실이 매우 적기 때문에 다른 재료와 함께 배치 플랜트에서 동시에 혼합한 다음 현장까지 운반하여 사용하는 것이 가능하다는 큰 장점이 있다.On the other hand, the use of a relatively high performance AE water reducing agent, which has been developed recently, has a great advantage that it is possible to simultaneously mix in different batching plants together with other materials and then transport them to the site because the slump loss is very small.

고성능 AE감수제로는 폴리카르본산계, 멜라민계, 나프탈린계 등 다양한 혼화제가 시판되고 있으며 시멘트에 대하여 0.5중량% 미만이 첨가되는 경우에는 공기연행효과 및 감수효과가 발휘되지 못하여 콘크리트 강도증진을 기대하기 어렵고 2.5중량%를 초과하여 첨가시는 경과시간에 따른 슬럼프의 손실이 크고 공기량을 과잉으로 연행시켜 콘크리트의 강도를 저하시키게 되므로 본 발명에서는 고성능 AE감수제의 량을 결합재에 대하여 0.5 내지 2.5중량%를 첨가하는 것으로 하였는데, 고로슬래그 미분말의 혼입량이 증가하면 고성능 AE감수제의양도 증가하는 것을 고려하였다.As a high performance AE reducing agent, various admixtures such as polycarboxylic acid, melamine, and naphthalin are commercially available, and when less than 0.5% by weight of cement is added, air entraining and water-reducing effects are not exhibited and concrete strength is expected to be increased. It is difficult to do so, when the addition of more than 2.5% by weight, the loss of slump over the elapsed time and entraining the air amount excessively to reduce the strength of the concrete, in the present invention, the amount of high-performance AE water reducing agent 0.5 to 2.5% by weight relative to the binder When the amount of the blast furnace slag fine powder was increased, the amount of the high performance AE reducing agent was also considered.

한편, 고성능 AE감수제의 사용에 의한 물-결합재의 비(W/(C+B.F))를 낮춤으로써 나타나는 다른 효과는 내동해성, 중성화에 대한 저항성 및 마모저항성 등의 내구성이 향상된다는 것이다.On the other hand, another effect of lowering the water-binding ratio (W / (C + B.F)) by the use of a high performance AE reducing agent is improved durability such as freeze resistance, resistance to neutralization and abrasion resistance.

[표 1]은 일반 AE감수제를 최적 사용표준량인 시멘트에 대하여 0.3중량% 사용한 경우와 고성능 AE감수제를 시멘트에 대하여 1.0중량% 사용한 경우의 투수성 콘크리트 배합에 따른 재령 28일 압축강도와 투수계수를 시험한 실시예이다. [Table 1] shows the 28-day compressive strength and coefficient of permeability according to the permeable concrete mix when 0.3% by weight of general AE water reducing agent is used with respect to cement which is the optimum standard amount and 1.0% by weight of high performance AE water reducing agent is used. It is an Example tested.

[표 1] AE감수제와 고성능 AE감수제를 사용한 투수성 콘크리트의 물성 [Table 1] Properties of Permeable Concrete Using AE Reducing Agent and High Performance AE Reducing Agent

실험결과Experiment result

No. No. 물-시멘트의 비W/C(%) Water-Cement Ratio W / C (%) 단위량(kg/㎥) Unit weight (kg / ㎥) 실험결과 Experiment result 물(W) Water (W) 시멘트(C) Cement (C) 골재 aggregate AE감수제 AE Supervisor 고성능AE감수제 High performance AE water reducer 압축강도(kgf/㎠) Compressive strength (kgf / ㎠) 투수계수(cm/sec) Permeability coefficient (cm / sec) 1 One 38 38 115 115 300 300 1562 1562 0.9 0.9 - - 165 165 0.31 0.31 2 2 34 34 120 120 350 350 1546 1546 1.05 1.05 - - 190 190 0.21 0.21 3 3 31 31 125 125 400 400 1529 1529 1.2 1.2 - - 229 229 0.14 0.14 4 4 32 32 95 95 300 300 1562 1562 - - 3.0 3.0 189 189 0.42 0.42 5 5 29 29 100 100 350 350 1546 1546 - - 3.5 3.5 227 227 0.29 0.29 6 6 26 26 105 105 400 400 1529 1529 - - 4.0 4.0 266 266 0.15 0.15

[표 1]의 실험결과를 비교하면 고성능 AE감수제를 사용한 경우는 종래의 AE감수제를 사용한 콘크리트와 비교하여 투수계수가 약간 향상되었으며 단위수량(單位水量)이 20kg정도 감소되고, 압축강도가 15 내지 20% 정도 증가되어 고성능 AE감수제는 투수성 다공질 콘크리트의 강도 향상에 매우 효과적인 것을 알 수 있다. Comparing the experimental results of [Table 1], when the high performance AE water reducing agent is used, the coefficient of permeability is slightly improved compared to the concrete using the conventional AE water reducing agent, the unit water quantity is reduced by about 20 kg, and the compressive strength is 15 to 20% increase in high performance AE reducing agent is very effective in improving the strength of permeable porous concrete.

물-결합재의 비를 25 내지 33중량%의 범위로 한 이유는 25중량% 미만인 경우는 시멘트풀과 골재와의 부착이 충분히 되지 않고 다짐작업이 불량해지며 33중량%를 초과하는 경우는 시멘트풀의 유동성이 너무 커서 골재입자 사이를 흘러 내림으로써 밑면의 공극을 막으며 재료분리의 경향이 커서 투수콘크리트 강도에 결점이 생긴다. 시멘트풀의 양은 그것이 골재를 둘러싸 금속과 같은 빛을 띠는 막을 형성하도록 하는 것이 적당하며 시멘트풀이 흘러내리지 않은 범위로 정해야 한다. The reason why the ratio of water-bonding material is in the range of 25 to 33% by weight is less than 25% by weight of cement paste and aggregates, and the compaction work is poor. Because of its high fluidity, it flows down between the aggregate particles, blocking pores at the bottom, and the tendency of material separation is high, resulting in a defect in permeable concrete strength. The amount of cement paste should be in such a way that it will surround the aggregate to form a film that shines like metal and the cement paste should not be allowed to flow down.

한편 투수성 다공질 콘크리트는 다량의 연속된 공극이 존재하므로 이 공극내로 수분이 쉽게 유입되어 동결팽창함으로써 일반 콘크리트에 비해 동결융해 저항성이 낮은 것으로 알려져 있다. 그러나 한냉지의 옥외 폭로시험결과에 의하면 물-결합재의 비가 낮다면 투수콘크리트의 내구성도 양호한 것으로 나타나 있고 이런 구조의 콘크리트에서도 고성능 AE감수제 및 고로슬래그 미분말의 사용으로 동결융해 저항성이 향상되는 결과를 얻을 수 있다. On the other hand, permeable porous concrete is known to have low freeze-thawing resistance compared to general concrete by freeze-expansion because water is easily introduced into the pores because a large amount of continuous pores exist. However, according to the results of the outdoor exposure test of the cold district, the permeability of the concrete is good if the ratio of water-binder is low and the freeze-thawing resistance can be improved by using high performance AE reducing agent and blast furnace slag powder in concrete of such structure. have.

포장용 투수성 다공질 콘크리트는 안료를 사용하여 여러가지 색을 연출할 수 있다. 안료의 종류와 사용량이 모르타르의 물성에 크게 영향을 미치며 녹색과 청색의 경우는 투수성 다공질 콘크리트의 강도를 저하시킬수 있음을 [표 2]의 실시예에서 나타낸다. 그래서 본 발명에서는 무기질안료의 사용량을 결합재에 대하여 2 내지 5중량%의 범위로 하였다. 또한 색을 보다 선명하게 하고 그 색이 장시간 지속되는 색마감 효과를 위하여 아크릴 또는 우레탄계 수지와 산화철 피그먼트 등의 안료를 포함하는 표면처리제를 브러쉬나 스프레이를 이용하여 1mm 이내의 두께로 바르는 것으로 하였다. Pavement-permeable porous concrete can produce various colors using pigments. The type and amount of pigments greatly affect the physical properties of the mortar, and in the examples of [Table 2], green and blue colors can reduce the strength of the permeable porous concrete. Therefore, in the present invention, the amount of the inorganic pigment is used in the range of 2 to 5% by weight based on the binder. In addition, the surface treatment agent containing a pigment such as acrylic or urethane-based resin and iron oxide pigment in order to make the color more clear and the color lasts for a long time was applied to a thickness of less than 1mm using a brush or a spray.

착색재(着色材)로 사용되는 안료로는 합성산화철, 산화크롬, 프탈록시안계 등과 같은 안료들이 일반적으로 사용되고 있다.As a pigment used as a coloring material, pigments such as synthetic iron oxide, chromium oxide, and phthaloxyan series are generally used.

[표 2] 무기질 안료를 사용한 모르타르의 재령 28일의 압축강도(kgf/㎠) 실험결과 [Table 2] Compressive strength (kgf / ㎠) test results of the mortar age of 28 days using inorganic pigments

안료사용량(C×%) Pigment Usage (C ×%) 압축강도(kgf/㎠) Compressive strength (kgf / ㎠) 적색(산화철) Red (iron oxide) 황색(산화철) Yellow (iron oxide) 녹색(phthalocyanine green) Phthalocyanine green 청색(phthalocyanine blue) Phthalocyanine blue 흑색(산화철) Black (iron oxide) 0 0 391 391 391 391 391 391 391 391 391 391 2 2 385 385 394 394 202 202 200 200 389 389 4 4 392 392 393 393 132 132 174 174 387 387 6 6 422 422 430 430 130 130 146 146 374 374 8 8 440 440 418 418 126 126 134 134 413 413 10 10 425 425 433 433 126 126 158 158 398 398

주) ()내는 안료의 명칭Note) Name of Pigment

투수성 다공질 콘크리트의 특성은 일반 콘크리트와는 달리 물-결합재비(W/(C+B.F))뿐만아니라 다짐의 영향을 많이 받는다. 공극률이 증가하면 투수성이 좋아지는데 대하여 비례적으로 강도가 작아지기 때문에 강도와 투수성에 대한 요구조건이 충족되도록 다짐을 할 필요가 있다. 본 발명에서 투수성 다공질 콘크리트는 5 내지 25%의 공극률과 0.01 내지 0.5cm/sec의 투수계수를 갖도록 다짐을 한다. Unlike ordinary concrete, permeable porous concrete is affected by compaction as well as water-binder ratio (W / (C + B.F)). As the porosity increases, the strength decreases in proportion to the increase in the permeability. Therefore, it is necessary to ensure that the requirements for strength and permeability are met. In the present invention, the permeable porous concrete is compacted to have a porosity of 5 to 25% and a permeability coefficient of 0.01 to 0.5 cm / sec.

종래의 투수성 다공질 콘크리트에서 나타나는 강도나 내구성 저하의 문제점은 본 발명의 특징적인 구성요소인 고성능 AE감수제와 고로슬래그 미분말을 기본으로 하고 각 배합요소별 최적 배합비를 결정한 후 전압다짐에 의하여 공극률을 조절함으로써 높은 강도와 내구성 및 소요의 투수성을 갖는 콘크리트를 제공할 수 있다.Problems in strength and durability deterioration in conventional permeable porous concrete are based on high performance AE water reducing agent and blast furnace slag powder, which are the characteristic components of the present invention, and after determining the optimum mixing ratio for each mixing element, the porosity is adjusted by voltage compaction. By doing so, it is possible to provide concrete having high strength, durability, and permeability required.

본 발명은 종래의 투수성 다공질 콘크리트에서 나타나는 강도와 내구성저하의 문제점을 해결하기 위하여 고성능 AE감수제를 적정량 사용하고, 물, 결합재, 골재의 배합요소를 최적으로 조절함으로써 높은 강도와 내구성은 물론 소요의 투수계수를 갖는 투수성 다공질 콘크리트 조성물을 제조할 수 있고, 시멘트에 대하여 고로슬래그 미분말을 일정량 치환 사용하도록 하여 장기강도의 증진 및 시공성 향상은 물론 폐자원의 재활용과 원가절감을 실현할 수 있다. The present invention uses a high-performance AE water reducing agent in an appropriate amount to solve the problems of strength and durability deterioration in conventional permeable porous concrete, and by adjusting the mixing elements of water, binder, aggregate, high strength and durability as well as required Permeable porous concrete composition having a permeability coefficient can be prepared, and by using a certain amount of blast furnace slag fine powder substituted for cement, it is possible to improve long-term strength and constructability as well as to recycle waste resources and reduce costs.

Claims (1)

골재, 물, 결합재, 고성능 AE감수제 및 착색재로 구성되는 투수성 다공질 콘크리트조성물에 있어서, 투수콘크리트 1㎥당 최대치수 13mm 이하로서 5mm체의 통과중량백분율이 5 내지 30%인 골재 1500 내지 1750kg을 사용하고, 물은 90 내지 110kg을 사용하며, 결합재의 구성비를 시멘트 80 내지 50중량%와 고로슬래그 미분말 20 내지 50중량%로 하여 사용하고, 결합재에 대한 물의 비(W/(C+B.F))가 25 내지 33중량%, 고성능 AE감수제를 결합재에 대하여 0.5 내지 2.5중량%, 착색재를 결합재에 대하여 2 내지 5중량%로 사용하는 것을 특징으로 하는 높은 강도와 내구성을 지니는 투수성 다공질 콘크리트 조성물.In permeable porous concrete composition composed of aggregate, water, binder, high performance AE water reducing agent and coloring material, 1500-1750 kg of aggregate having 5-30% by weight of 5mm sieve with a maximum dimension of 13 mm or less per 1m3 of permeable concrete 90 to 110 kg of water, and the composition ratio of the binder to 80 to 50% by weight of cement and 20 to 50% by weight of blast furnace slag fine powder, the ratio of water to the binder (W / (C + BF)) The water-permeable porous concrete composition having a high strength and durability of 25 to 33% by weight, 0.5 to 2.5% by weight of the high-performance AE reducing agent, and 2 to 5% by weight of the coloring material.
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