KR100468430B1 - Preparation method of pure sludge or pure liquid for resource recovery - Google Patents

Abstract

The present invention relates to a method for producing clean sludge or a clean liquid for recycling sludge, and more particularly, harmful heavy metals, harmful volatile organic matter (VOC), odors and pathogens (viruses, bacteria, parasites, etc.) contained in the sludge. Sludge treatment method to reduce and remove the sludge by treating the sludge with a small amount of strong acid and chlorine dioxide at low temperature and then filtering it to clean sludge for manufacturing compost, and aeration with a large amount of strong acid, water vapor or air at high temperature. Clean liquid used for the purpose of soil improver, liquid fertilizer, feed for livestock and fish farming, additives such as freshwater and seawater biological nutrients obtained by treating with peroxides such as chlorine dioxide and making alkaline with calcium hydroxide and then neutralizing the filtrate. By manufacturing, sludge can be efficiently processed.

Description

Preparation method of pure sludge or pure liquid for resource recovery

The present invention relates to a method for producing clean sludge or a clean liquid for recycling sludge, and more particularly, harmful heavy metals, harmful volatile organic matter (VOC), odors and pathogens (viruses, bacteria, parasites, etc.) contained in the sludge. Sludge treatment method to reduce and remove the sludge by treating the sludge with a small amount of strong acid and chlorine dioxide at low temperature and then filtering it to clean sludge for manufacturing compost, and aeration with a large amount of strong acid, water vapor or air at high temperature. Clean liquid used for the purpose of soil improver, liquid fertilizer, feed for livestock and fish farming, additives such as freshwater and seawater biological nutrients obtained by treating with peroxides such as chlorine dioxide and making alkaline with calcium hydroxide and then neutralizing the filtrate. By manufacturing, sludge can be efficiently processed.

Domestically and internationally, sludge treatment technology is used to remove only heavy metals or odors individually for the purpose of recycling sludge, and to produce compost only.In addition to heavy metals or odors, sludges treated in this way are not only volatile organic matter (VOC) and pathogens , Viruses, parasites, etc.), and has not been applied to composting, except animal sludge. However, until now, the technology capable of simultaneously reducing and eliminating these harmful factors (heavy metals, odors, VOCs, pathogens, etc.) has not been invented in our country or around the world.

In addition, the invention has not yet been made regarding the use of liquid fertilizer by manufacturing, additives for livestock and fish farming, useful freshwater and seawater nutrients, etc. in high value-added clean raw materials rich in amino acids by the decomposition of sludge. to be.

Recently, the US Environmental Protection Agency reported on the necessity of evaluating and reducing pathogens in sludge for recycling sludge (Control of Pathogens and Vector Attraction in Sewage Sludge, 1999), and devising useful methods of using sludge for public health and environmental conservation. (Policy on Sewage Sludge Management, 1984), and the Standards for the Use or Disposal of Sewage Sludge, 40 CFR Part 503, to protect the environment and human health from pathogens in sludge recycling. Has announced.

Domestic and internationally, sludge treatment methods include landfill, ocean dumping, incineration and recycling. First of all, recycling is used for livestock sludge due to the lack of recycling technology.In case of sludge incineration, economical facilities are 100 ~ 150 tons / day, and the construction cost is not only 10 ~ 15 billion won, but also huge amount of funds. Due to incomplete combustion, emissions of toxic carcinogenic substances such as formaldehyde, acrolein, butadiene, etc. due to incomplete combustion [EPA / 600R-98 / 076, June 1998] are not only a threat to human health but also a fuel cost for incineration. Water content 80%) It costs 50,000 won (Bangka C) to 70,000 won (L & G) per ton.Including management costs such as depreciation cost, the incineration cost per ton exceeds 100,000 won.In case of landfill, sludge from Nanjido, Seoul When using the Gimpo metropolitan landfill site, it is about 27,000 won / ton (wet state) .In case of ocean dumping, it is about 70,000 ~ 80,000 won / ton when using the west coast on Nanjido. It is not only costly, but also has problems such as bad smell, leachate, delayed sanitation and stabilization of landfill and land pollution, pollution of marine ecosystem and fish, etc. Due to severe health threats and tax burdens, local residents have been unable to reclaim landfills and build incinerators. In Korea, it is difficult to secure landfills in narrow lands such as Korea, and since 2001, since landfilling has been banned, some sludge composting and solidification of incineration ash, a by-product of incineration, has been carried out. The use of is virtually impossible.

In addition, the sludge compost contains harmful factors such as heavy metals, odors, harmful volatile organic substances and pathogens, and is threatened by the Ministry of Agriculture, Forestry and Fisheries due to the threat of farmers' health and land pollution. The prepared compost is in an unusable state. As a result, there is no special countermeasure at this time, and until July 2003, the provisional extension of the landfill and the gradual review of the sludge treatment facility are specified, but there are no special measures.

On the other hand, international dumping of sludge is banned on the basis of the London Treaty on the Prevention of Marine Dumping of Sludge, which is an urgent situation for Korea to comply with the Convention.

In addition, there is an earthquake treatment method to reduce sludge sludge, but the amount of sludge that can be treated is extremely small, and commercialization is not possible due to the accumulation of organic mercury in earthworm individuals and mercury in fecal soil.

As a harmful factor contained in the sludge, a technology for simultaneously reducing and removing harmful heavy metals, odors, harmful volatile organic compounds (VOCs) and pathogens (microorganisms, viruses, parasites, etc.) has not been developed.

Therefore, the present inventors simultaneously remove all harmful factors in the sludge by physical and chemical methods such as decomposition, oxidation, aeration, and filtration to reduce sludge, as well as agriculture, fishing, forestry, animal husbandry, land improver, and The present invention has been completed by developing a method for treating sludge that can be recycled with additives such as nutrients for fresh water and seawater, and compost.

Accordingly, an object of the present invention is to provide a method for producing a clean sludge or a clean liquid for recycling the sludge.

Figure 1 shows the manufacturing process of the clean sludge in the sludge treatment method according to the present invention.

Figure 2 shows the manufacturing process of the clean liquid of the sludge treatment method according to the present invention.

The present invention is characterized by a method of producing a clean sludge or a clean liquid for the recycling of sludge.

The sludge includes sewage sludge, septic tank sludge, industrial wastewater sludge, building wastewater sludge, apartment complex wastewater sludge, livestock waste sludge and other sludges generated during water treatment.

The present invention will be described in more detail as follows.

Clean sludge that simultaneously reduces or removes all harmful factors in organic sludge (hereinafter referred to as sludge) containing harmful heavy metals, harmful volatile organic substances, odors, and pathogenic microorganisms and parasites (including eggs) (hereinafter referred to as harmful factors). And technology for manufacturing clean liquids containing amino acids by the decomposition of sludge and using environmentally sustainable clean compost and clean liquids to improve land use, liquid fertilizer, livestock and fish farming, useful fresh water and seawater. Development of additive manufacturing technology such as nutritional sources of living organisms and methods for the development of treatment chemicals for odor removal are presented as follows.

1. Sludge treatment chemical: Chlorine dioxide is selected and used as treatment chemical that can be used to remove odors in sludge or odor by decomposition of inorganic and organic heavy metals and to reduce or remove heavy metals.

2. Sludge Treatment

A) Manufacture of clean sludge

Clean air for 5 minutes to 10 hours at room temperature to 100 DEG C while injecting 0.01 to 1 parts by weight of peroxide into a mixture of 0.1 to 20 parts by weight of hydrochloric acid, nitric acid, or a mixture of hydrochloric acid and nitric acid with respect to 100 parts by weight of sludge. After aeration, the filtered and washed acidic sludge is suspended again in water, neutralized with 0.05 to 10 parts by weight of calcium hydroxide, and then filtered to reduce, sterilize and kill odors, heavy metals, volatile organics and pathogens. Clean sludge can be obtained which can be used for the purpose. After combining the filtrate containing the heavy metal and the wash solution to pH 12 with calcium hydroxide and then filtered to remove the heavy metal in a solid form.

B) Preparation of clean liquid

Suspension of 2 to 40 parts by weight of aqueous solution of hydrochloric acid, nitric acid or hydrochloric acid and nitric acid mixture with respect to 100 parts by weight of sludge is followed by sterilization, insecticidal and decomposition at 100 to 300 ° C. for 5 minutes to 10 hours, and then aerated with steam or air. And harmful volatile organics are discharged and removed. The remaining solution (degradation product of sludge) is completely sterilized and killed by pathogens (microorganisms and parasites), and if there is residual odor, it can remove odor by adding 0.01 ~ 1 parts by weight of peroxide at room temperature to 100 ℃. . Heavy metals in the solution remaining after treatment can be precipitated by filtration by adjusting to pH 10-12 with 0.8-16 weight part of calcium hydroxide, etc., and can be removed by filtration. Neutralizing the filtrate back to pH 6-8 with hydrochloric acid, nitric acid, phosphoric acid or mixtures thereof yields a clean liquid suitable for the manufacture of additives such as soil modifiers, liquid fertilizers, feed for livestock and fish farming, and nutrient sources for freshwater and seawater organisms. Depending on the application, it can be recycled as a consumer demand type such as dilution, concentration, or solidification (granulation, etc.).

Hereinafter, the present invention will be described in more detail based on Examples, but the present invention is not limited to the following Examples.

Example 1 Preparation of Clean Sludge

100 parts by weight of fresh sludge (wet state) and 1 part by weight of a mixture of nitric acid and hydrochloric acid (nitric acid: hydrochloric acid = 1: 3) are adjusted to pH 1.5 or lower, and then 0.05 part by weight of chlorine dioxide oxidizing agent is added at 35 ° C. Stirring for a time was performed to extract heavy metals and remove odor by oxidizing agent. After that, aeration with clean air discharged and removed harmful volatile organics. Then, the heavy metals were discharged and removed by the filtrate and the washing solution by filtration and washing, and the sludge obtained by filtration was suspended in clean water again, neutralized to pH 7 with 0.4 parts by weight of calcium hydroxide, and the solid clean sludge obtained by filtration was stored. Clean sludge produced is used for clean composting by removing odors, heavy metals, pathogens and volatile organics.

Example 2 Preparation of Clean Liquid

20 parts by weight of a mixture of nitric acid and hydrochloric acid (nitric acid: hydrochloric acid = 1: 3) is added to 100 parts by weight of fresh sludge (wet state), sterilized, killed and decomposed at 150 ° C. for 30 minutes with mixing and agitation. Volatile organics were discharged and removed. The remaining solution (decomposition of the sludge) was adjusted to pH 12 with 8 parts by weight of calcium hydroxide to precipitate and precipitate heavy metals by precipitation, and then filtered to neutralize the filtrate from which heavy metals were removed to pH 7 with hydrochloric acid, nitric acid or phosphoric acid. The solution was stored as a final clean solution free of harmful factors such as heavy metals, odors, volatile organics and pathogens (microorganisms, viruses, parasites, etc.), and the clean solution was diluted with water, concentrated in vacuum, or spray dried to facilitate use. Commercialize.

Test Example 1

The protein contained in the sewage sludge [Wonju-si Sewage Treatment Plant] is Stutzer method [sanitary test method, 1990, Japan Pharmacy Society]. Heavy metal among harmful factors is atomic spectrophotometer Model 2380 Perkin-Elmer (USA) ), Odors and volatile organics were analyzed by gas chromatography, and E. coli, a representative pathogen of pathogens, was analyzed by EPA's 2540G method [Standard Methods for the Examination of Water and Wastewater 18th edition]. Shown in

Test Example 2

Analysis of harmful factors in the clean sludge and the clean liquid prepared in Examples 1 and 2 was carried out by the analysis method of Test Example 1 and the results are shown in Table 2 below.

Test Example 3

Proteins in the clean liquid prepared in Example 2 were analyzed by Stutzer method [Hygiene test method, Japanese Pharmacy Society of 1990] and amino acid content by Van Slyke method [Hygiene test method, Japanese Society of Pharmacy 1990] The results are shown in Table 3 below.

As described above, the present invention can largely have environmental technical value and socioeconomic value. Environmental technical values include the reduction of sludge efficiently, preventing air, soil and water pollution from landfilling, pollution of marine and fish by marine dumping, as well as hazardous substances (heavy metals, harmful volatile organics / odors, and pathogenic microorganisms). ), It is possible to propose an alternative to domestic and international environmental regulations. Socio-economic values include the creation of employment, the production of protein and amino acid solutions for additives such as feed using sludge, the production of compost sludge, the fertilization of the land through the expansion of the clean composting of sludge, the enhancement of agricultural productivity, and the utilization of facility crops by the clean amino acid fertilization. Increasing agricultural income through increased production, improving income by increasing fishery productivity by supplying cheap fish farming, expanding water resources such as fish by developing cheap nutrient source for freshwater and seawater, and maximizing export maximization and competitiveness by preoccupying overseas market by international patent For example, resolving civil complaints by securing public health rights through sanitary sludge reduction, and reducing the tax burden on the public by reducing sludge disposal costs.

Claims (9)

delete delete delete A) To remove odor by heavy metal extraction and oxidant by injecting and stirring 0.01∼1 parts by weight of peroxide to the mixture suspended by adding 0.1-20 parts by weight of hydrochloric acid, nitric acid or hydrochloric acid and nitric acid mixture to 100 parts by weight of sludge. ; B) aeration for 5 minutes to 10 hours at room temperature to 100 ° C. with air to discharge and remove harmful volatile organics; C) filtration and washing to discharge and remove heavy metals; D) suspending the filtered sludge in water and neutralizing with 0.05 to 10 parts by weight of calcium hydroxide; And E) filtration again; Clean sludge manufacturing method comprising a. The method of claim 4, wherein the peroxide is chlorine dioxide. A) adding 2-40 parts by weight of nitric acid, hydrochloric acid or a mixture of nitric acid and hydrochloric acid to 100 parts by weight of sludge, followed by mixing and stirring; B) sterilizing, killing and decomposing at 100 to 300 ° C. for 5 minutes to 10 hours and then aeration with water vapor or air to discharge and remove odors and volatile organics; C) the remaining sludge decomposition product is adjusted to pH 10-12 with 0.8-16 parts by weight of calcium hydroxide to precipitate and precipitate heavy metals by precipitation; D) filtering to remove heavy metals; And E) neutralizing the filtrate to pH 6-8 with nitric acid, hydrochloric acid, phosphoric acid or a mixture thereof; Method for producing a clean liquid, characterized in that it comprises a. 7. The method of claim 6, wherein if there is a residual odor after step b), a peroxide is added at room temperature to 100 deg. 8. The method of claim 7, wherein the peroxide is chlorine dioxide. delete