JP2012086207A - Material for purifying water bottom sludge by oxygen generating material and method of manufacturing the same - Google Patents

Material for purifying water bottom sludge by oxygen generating material and method of manufacturing the same Download PDF

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JP2012086207A
JP2012086207A JP2010246818A JP2010246818A JP2012086207A JP 2012086207 A JP2012086207 A JP 2012086207A JP 2010246818 A JP2010246818 A JP 2010246818A JP 2010246818 A JP2010246818 A JP 2010246818A JP 2012086207 A JP2012086207 A JP 2012086207A
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sludge
oxygen generating
nitrogen
environment
zeolite
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Shoji Sawada
昌治 澤田
Yoshihiro Sawada
吉宏 澤田
Yoshiko Takeda
佳子 武田
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Abstract

PROBLEM TO BE SOLVED: To provide a material for purifying water bottom sludge by an oxygen generating material, which is a material for purifying/decomposing the water bottom sludge without requiring advanced equipment cost, and purifies/decomposes environmental pollution caused by garbage, domestic sludge, agricultural sludge, industrial sludge, sewage sludge and the like to provide odor elimination, protection of fishes, and environment where plants can live.SOLUTION: Components of a peroxide and wood vinegar are made to be contained in and adsorbed by porous materials of diatomaceous earth, burned oyster shells, zeolite, wood chips, sawdust, and a plant extract, thereby removing chlorine and carrying out an oxidation catalytic reaction. Odorants are oxidatively decomposed, whereby odorants which undergo the oxidation catalytic reaction are decomposed. The habitat environment of effective microorganisms is prepared by decomposition of a putrid odor of protein and of animal excrement, adsorption and decomposition of pesticide residues such as nitrogen and phosphorus, adsorption of harmful substances such as spilled oil, bacteriostatic action, and acidity control, thereby exhibiting an excellent effect. The superfine and superporous natural materials adsorb and decompose the pesticide residues and heavy metals. Growth of various germs, which is a secondary source of smell, is prevented to provide deodorizing effect. Zeolite removes ammonia and nitrogen. Adsorptive removal of heavy metal ions, decolorization and purification of dye wastewater, treatment of radioactive waste water, softening of hard water are carried out. Ammonia gas is adsorbed, and oxygen and nitrogen are separated as separation of gas. Deodorizing effect due to adsorption of ammonia, nitrogen and phosphorus improves the environment to contribute to protection and preservation of the environment.

Description

本発明は、酸素発生材による水底ヘドロ分解に係わる浄化処理技術により環境改善、保護、保全に寄与に関する。
水底ヘドロを微生物の多孔質物質に含浸させ生息させることにより水底ヘドロの有機物を炭酸ガスと水に分解低減する。
The present invention relates to contribution to environmental improvement, protection, and maintenance by a purification treatment technique related to water bottom sludge decomposition using an oxygen generating material.
By submerging the bottom sludge in a porous material of microorganisms and inhabiting it, the organic matter in the bottom sludge is decomposed and reduced to carbon dioxide and water.

水底ヘドロは、生ゴミ、生活汚泥、農業汚泥、産業汚泥、下水汚泥により環境悪化が進んでいることから、水底の酸素が消費され、漁業や生活環境に被害が発生している。
水底ヘドロの汚染から、悪臭・魚類・植物の生息等に問題が起きている。
対策として設備、機材が投入されているものの、十分な水底ヘドロの処理対策に至っていない。
Underwater sludge has been aggravated by raw garbage, domestic sludge, agricultural sludge, industrial sludge, and sewage sludge, so that oxygen in the bottom is consumed, causing damage to the fishery and living environment.
Contamination of bottom sludge has caused problems such as bad odor, fish and plants.
Although equipment and equipment have been introduced as countermeasures, they have not been able to deal with sufficient sludge treatment.

本発明は同発明者の特願2005−365886を活用し、汚れ、化学物質、重金属、リン、チッソ、アンモニアを多孔質体が、重金属など、汚れを吸着し微生物、細菌類を自然分解させることにより微生物担体の栄養分に変えることにより水質浄化し自然環境を復元させる。  The present invention makes use of Japanese Patent Application No. 2005-365886 of the same inventor to adsorb dirt, chemical substances, heavy metals, phosphorus, nitrogen, ammonia, porous materials, heavy metals and other dirt, and to naturally decompose microorganisms and bacteria. By changing to nutrients of microbial carrier, water quality is purified and the natural environment is restored.

珪藻土は、秋田県北秋田市より産出する多孔質珪藻土。ゼオライトは秋田県能代市二ツ井より産出する鉱物。これらを混合することが望ましい。木酢液については、北秋田市産地品を活用し、日本木酢液協会の方法で分析し、木酢液の企画に定めされた品質でもっての使用であり、フェノール類を含む効果から消毒、消臭、脱臭、防菌等に効果がある。(木酢液は日本木酢液協会の認定協議会の認定品を使用)
この新技術は、環境ホルモンを含む処理用途に汎用拡大ができる。
Diatomaceous earth is a porous diatomaceous earth produced from Kitaakita City, Akita Prefecture. Zeolite is a mineral produced from Futatsui, Noshiro City, Akita Prefecture. It is desirable to mix these. For wood vinegar, use local products from Kitaakita City, analyze it using the method of Japan Wood Vinegar Association, and use it with the quality specified in the plan for wood vinegar. , Effective in deodorizing, antibacterial and the like. (For the wood vinegar, use the certified products of the Japan Wood Vinegar Association)
This new technology can be widely used in processing applications involving environmental hormones.

本発明は、木酢液の機能、性能と珪藻土、ゼオライト、おがくずの有用性の組み合わせを環境改善材としての提供を目的とする。An object of the present invention is to provide a combination of the function and performance of wood vinegar and the usefulness of diatomaceous earth, zeolite, and sawdust as an environmental improvement material.

水底ヘドロの処理については、数多くの提案がなされ実用化されているものの、設備投資額と多大なる費用と人力を必要としたが、生態系に汚染を引き起こしていた。
また、水質汚水及び重金属の水質浄化が河川に放出され自然汚染や二次製品による環境破壊、水質汚染、悪臭に問題があった。
焼成カキ殻・珪藻土・ゼオライトを粉砕し800度以上で焼成する処理方法。粉砕物質60〜80重量%混合物20〜40重量%を混合し、多孔質構造の機能を向上させたものを特徴とする。
本発明の酸素発生材による水底ヘドロの浄化材は生ゴミ、汚泥を分解し、消臭を吸収分解する環境浄化材であり環境汚染はなく、維持管理費の少ない生ゴミ、汚泥栄分解材を特徴とする。
焼成カキ殻・珪藻土、ゼオライトの粒体1〜5mmと炭素源としての、おがくず、木質破片、籾殻の粒子、植物抽出物との組み合わせに、木酢液を浸潤する。汚染の原因であるチッソやリン吸着などの物質浄化と水質浄化において酸素発生材を含む微生物作用によりヘドロ分解作用がある。
農業廃棄物・林業廃棄物・産業廃棄物等の活用資源循環型社会のゼロエミッションを推進とする。
Although many proposals have been made and put into practical use for the treatment of submerged sludge, it required capital investment and a large amount of money and manpower, but it caused pollution to the ecosystem.
In addition, water sewage and purification of heavy metals were released into rivers, causing problems with natural pollution, environmental destruction caused by secondary products, water pollution, and foul odors.
A treatment method in which calcined oyster shells, diatomaceous earth, and zeolite are pulverized and calcined at 800 ° C. or higher. It is characterized by mixing 60 to 80% by weight of the pulverized substance and 20 to 40% by weight of the mixture to improve the function of the porous structure.
The bottom sludge purification material by the oxygen generating material of the present invention is an environmental purification material that decomposes raw garbage and sludge and absorbs and deodorizes deodorant. Features.
The wood vinegar is infiltrated into a combination of calcined oyster shell / diatomaceous earth, 1-5 mm of zeolite particles and sawdust, wood debris, rice husk particles and plant extract as a carbon source. There is sludge decomposing action due to the action of microorganisms containing oxygen generating materials in purification of substances such as nitrogen adsorption and phosphorus adsorption and water purification that are the cause of pollution.
Utilize agricultural waste, forestry waste, industrial waste, etc. Promote zero emissions in a resource recycling society.

前記資源の組成分析結果を[表1]・[表2]に示す。The results of the composition analysis of the resources are shown in [Table 1] and [Table 2].

天然素材の焼成カキ殻・珪藻土、ゼオライト、おがくず、木質破片、籾殻、植物抽出物の有用な特徴と細孔部に吸着保持された酸素発生材による、微生物の相乗効果から環境改善材を得ることができた。
天然資源が有する特性から、独自効果の大きい作用が発見された。
To obtain environmental improvement materials from the synergistic effect of microorganisms by the useful characteristics of natural baked oyster shells / diatomaceous earth, zeolite, sawdust, wood fragments, rice husks, plant extracts and the oxygen generating material adsorbed and retained in the pores I was able to.
Due to the characteristics of natural resources, a unique action was discovered.

さらに環境改良材として、持続的効果の得られることが発見された。Furthermore, it was discovered that a sustainable effect can be obtained as an environmental improvement material.

有用な微生物を多孔質体に付着、植え付け、浸透させることにより水底に酸素発生を促しヘドロ有機物を分解する。
本発明による水底ヘドロ浄化材は、安全性・経済性ともに優れ、低コストでしかも実用に優れた硫化水素・リン吸着等の機能を特徴とする環境用材に関する。
By attaching, planting, and penetrating useful microorganisms to the porous body, oxygen is generated at the bottom of the water, and sludge organic matter is decomposed.
The bottom sludge purifying material according to the present invention relates to an environmental material characterized by hydrogen sulfide / phosphorus adsorption and the like, which are excellent in safety and economy, low in cost and excellent in practical use.

焼成カキ殻・珪藻土・ゼオライト・おがくず・木質破片・籾殻・植物抽出物・木酢液の混合物から成り、水底ヘドロ物質を分解する。It consists of a mixture of calcined oyster shell, diatomaceous earth, zeolite, sawdust, wood debris, rice husk, plant extract, and wood vinegar.

本発明の水底ヘドロ浄化材は、過酸化物質・天然多孔質物質の廃棄物のゼロエミッション物質から選ばれる一種類以上の発生材を含むことを特徴とする。The water bottom sludge purification material of the present invention is characterized in that it contains one or more kinds of generating materials selected from zero emission materials of wastes of peroxide materials and natural porous materials.

本発明に係る酸素発生材による水底ヘドロ浄化材を散布することにより、生ゴミ、生活汚泥、農業汚泥、産業汚泥、下水汚泥等に微生物の有機物の酸化分解作用が働き、ヘドロを低減分解する。

Figure 2012086207
Figure 2012086207
By spraying the water bottom sludge purification material by the oxygen generating material according to the present invention, the oxidative decomposition action of the organic matter of microorganisms acts on raw garbage, domestic sludge, agricultural sludge, industrial sludge, sewage sludge, etc., and sludge is reduced and decomposed.
Figure 2012086207
Figure 2012086207

Claims (4)

酸素発生材による水底ヘドロ浄化材として、焼成カキ殻・多孔質のシリカ構造に木酢液の成分を浸透させ、ゼオライト、おがくず、木質破片、籾穀、植物抽出物の醗酵、分解構造に微生物を浸透、または、過酸化物質から選ばれる一種類以上の酸素発生材を含むことを特徴とする。Oxygen generating material is used to purify water-flooded sludge. The components of pyroligneous acid are infiltrated into the baked oyster shell and porous silica structure, and the microorganisms are infiltrated into zeolite, sawdust, wood debris, cereals, plant extract fermentation, and decomposition structure. Or one or more oxygen generating materials selected from peroxide materials. 焼成カキ殻・珪藻土、ゼオライト、おがくず、木質破片、籾殻、植物抽出物に微生物を吸着、接着、植え付け、発生促進または炭酸カルシュウム酸化物であることを特徴とする酸素発生材。Oxygen generating material characterized by adsorbing, adhering, planting, promoting generation or promoting calcium carbonate to baked oyster shell / diatomaceous earth, zeolite, sawdust, wood debris, rice husk, plant extract. 請求項1から2のいずれかに記載の酸素発生材を水底に添加することを特徴とする硫化水素・リン吸着機能等による水底ヘドロの酸化方法。A method for oxidizing bottom sludge by hydrogen sulfide / phosphorus adsorption function or the like, wherein the oxygen generating material according to claim 1 is added to the bottom of the water. 上記記載において素材・化合・配分等において、本発明の趣旨を逸脱しない範囲の変更は、本発明に含まれる。In the above description, changes in a range not departing from the gist of the present invention in the material, compound, distribution, etc. are included in the present invention.
JP2010246818A 2010-10-15 2010-10-15 Material for purifying water bottom sludge by oxygen generating material and method of manufacturing the same Pending JP2012086207A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110342756A (en) * 2019-08-15 2019-10-18 杭州珊瑚环境科技有限公司 A kind of ecological restoring method in situ of Sediments
CN112798704A (en) * 2020-12-28 2021-05-14 江西省食品检验检测研究院(江西国家果蔬产品及加工食品质量监督检验中心) Method for detecting pesticide residue in plant-derived agricultural products

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110342756A (en) * 2019-08-15 2019-10-18 杭州珊瑚环境科技有限公司 A kind of ecological restoring method in situ of Sediments
CN112798704A (en) * 2020-12-28 2021-05-14 江西省食品检验检测研究院(江西国家果蔬产品及加工食品质量监督检验中心) Method for detecting pesticide residue in plant-derived agricultural products

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