KR100450474B1 - 귀금속을주성분으로하는촉매의존재하에염소화제를주입하여방향족화합물을수소첨가하는방법 - Google Patents
귀금속을주성분으로하는촉매의존재하에염소화제를주입하여방향족화합물을수소첨가하는방법 Download PDFInfo
- Publication number
- KR100450474B1 KR100450474B1 KR1019960024371A KR19960024371A KR100450474B1 KR 100450474 B1 KR100450474 B1 KR 100450474B1 KR 1019960024371 A KR1019960024371 A KR 1019960024371A KR 19960024371 A KR19960024371 A KR 19960024371A KR 100450474 B1 KR100450474 B1 KR 100450474B1
- Authority
- KR
- South Korea
- Prior art keywords
- feedstock
- weight
- chlorine
- catalyst
- ppm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 25
- 150000001491 aromatic compounds Chemical class 0.000 title claims abstract description 18
- 229910000510 noble metal Inorganic materials 0.000 title claims abstract description 12
- 239000012320 chlorinating reagent Substances 0.000 title description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 6
- 239000001257 hydrogen Substances 0.000 claims abstract description 6
- 238000009835 boiling Methods 0.000 claims abstract description 4
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 4
- 150000002367 halogens Chemical class 0.000 claims abstract description 4
- 239000000460 chlorine Substances 0.000 claims description 36
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 27
- 229910052801 chlorine Inorganic materials 0.000 claims description 27
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 14
- 239000011593 sulfur Substances 0.000 claims description 14
- 229910052717 sulfur Inorganic materials 0.000 claims description 14
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 238000005984 hydrogenation reaction Methods 0.000 claims description 9
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 5
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 4
- 229960001701 chloroform Drugs 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 150000002894 organic compounds Chemical class 0.000 claims description 4
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 claims description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims description 2
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 claims description 2
- 229950011008 tetrachloroethylene Drugs 0.000 claims description 2
- 230000000694 effects Effects 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000003921 oil Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000001802 infusion Methods 0.000 description 4
- 239000003350 kerosene Substances 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000006477 desulfuration reaction Methods 0.000 description 3
- 230000023556 desulfurization Effects 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 102000003964 Histone deacetylase Human genes 0.000 description 1
- 108090000353 Histone deacetylase Proteins 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002140 halogenating effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- -1 polycyclic aromatic compound Chemical class 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B31/00—Reduction in general
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/44—Hydrogenation of the aromatic hydrocarbons
- C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
- C10G45/52—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing platinum group metals or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9507726 | 1995-06-27 | ||
| FR9507726A FR2736063B1 (fr) | 1995-06-27 | 1995-06-27 | Procede d'hydrogenation d'aromatiques avec injection de chlore sur des catalyseurs a base de metal noble |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR970001284A KR970001284A (ko) | 1997-01-24 |
| KR100450474B1 true KR100450474B1 (ko) | 2004-12-04 |
Family
ID=9480438
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019960024371A Expired - Lifetime KR100450474B1 (ko) | 1995-06-27 | 1996-06-27 | 귀금속을주성분으로하는촉매의존재하에염소화제를주입하여방향족화합물을수소첨가하는방법 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US5789637A (enExample) |
| EP (1) | EP0751204B1 (enExample) |
| JP (1) | JP4178301B2 (enExample) |
| KR (1) | KR100450474B1 (enExample) |
| DE (1) | DE69615464T2 (enExample) |
| ES (1) | ES2164851T3 (enExample) |
| FR (1) | FR2736063B1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2736063B1 (fr) * | 1995-06-27 | 1997-08-14 | Inst Francais Du Petrole | Procede d'hydrogenation d'aromatiques avec injection de chlore sur des catalyseurs a base de metal noble |
| DE69730539T2 (de) | 1996-06-10 | 2005-06-23 | Hitachi, Ltd. | Abgasreinigungsanlage einer Brennkraftmaschine und Katalysator zum Reinigen des Abgases einer Brennkraftmaschine |
| FR2765586B1 (fr) * | 1997-07-02 | 2003-09-05 | Inst Francais Du Petrole | Procede de transformation, par hydrogenation catalytique, d'une base huile en huile blanche medicinale |
| FR2778341B1 (fr) * | 1998-05-07 | 2000-06-09 | Inst Francais Du Petrole | Catalyseur a base d'un metal noble du groupe viii contenant du bore et/ou du silicium et son utilisation en hydrotraitement de charge hydrocarbonees |
| FR2778342B1 (fr) | 1998-05-07 | 2000-06-16 | Inst Francais Du Petrole | Catalyseur utilisable dans l'hydrogenation des composes aromatiques dans une charge hydrocarbonnee contenant des composes soufres |
| US6013847A (en) * | 1998-12-31 | 2000-01-11 | Phillips Petroleum Company | Hydrogenation of benzene in the presence of water |
| FR2795420B1 (fr) * | 1999-06-25 | 2001-08-03 | Inst Francais Du Petrole | Procede d'hydrotraitement d'un distillat moyen dans deux zones successives comprenant une zone intermediaire de stripage de l'effluent de la premiere zone avec condensation des produits lourds sortant en tete du strippeur |
| FR2800638B1 (fr) * | 1999-11-10 | 2002-01-18 | Inst Francais Du Petrole | Catalyseur fluore comprenant un element du groupe viii et un element du groupe viib et son utilisation pour l'hydrogenation de composes aromatiques en presence de composes soufres |
| FR2800640B1 (fr) * | 1999-11-10 | 2002-01-18 | Inst Francais Du Petrole | Catalyseur fluore comprenant un metal du groupe viii et un metal du groupe iib et son utilisation pour l'hydrogenation de composes aromatiques en presence de composes soufres |
| ES2274771T3 (es) | 1999-11-10 | 2007-06-01 | Institut Francais Du Petrole | Catalizador clorado y fluorado que comprende un metal del grupo viii y un metal adicional y su uso en la hidrogenacion de composiciones aromaticas. |
| FR2800639B1 (fr) * | 1999-11-10 | 2002-01-18 | Inst Francais Du Petrole | Catalyseur bimetallique comprenant du fluor et son utilisation pour l'hydrogenation des composes aromatiques en presence de composes soufres |
| FR2800637B1 (fr) * | 1999-11-10 | 2002-01-18 | Inst Francais Du Petrole | Catalyseur fluore comprenant un metal du groupe viii et un metal du groupe ib et son utilisation pour l'hydrogenation de composes aromatiques en presence de composes soufres |
| EP1432758B1 (en) | 2001-09-25 | 2008-11-26 | ExxonMobil Chemical Patents Inc. | Plasticised polyvinyl chloride |
| US9828571B2 (en) | 2015-06-05 | 2017-11-28 | Illinois Tool Works, Inc. | Heavy duty laundry detergent |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3639227A (en) * | 1969-11-17 | 1972-02-01 | Chevron Res | Chloride addition during hydrogenation |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3816299A (en) * | 1973-04-30 | 1974-06-11 | Union Oil Co | Hydrogenation process |
| FR2240905B1 (enExample) * | 1973-08-16 | 1980-01-04 | Inst Francais Du Petrole | |
| US4110198A (en) * | 1977-02-03 | 1978-08-29 | Uop Inc. | Process for hydrocracking hydrocarbons |
| FR2736063B1 (fr) * | 1995-06-27 | 1997-08-14 | Inst Francais Du Petrole | Procede d'hydrogenation d'aromatiques avec injection de chlore sur des catalyseurs a base de metal noble |
-
1995
- 1995-06-27 FR FR9507726A patent/FR2736063B1/fr not_active Expired - Lifetime
-
1996
- 1996-06-21 DE DE69615464T patent/DE69615464T2/de not_active Expired - Lifetime
- 1996-06-21 ES ES96401381T patent/ES2164851T3/es not_active Expired - Lifetime
- 1996-06-21 EP EP96401381A patent/EP0751204B1/fr not_active Expired - Lifetime
- 1996-06-27 JP JP16759096A patent/JP4178301B2/ja not_active Expired - Lifetime
- 1996-06-27 US US08/671,501 patent/US5789637A/en not_active Expired - Lifetime
- 1996-06-27 KR KR1019960024371A patent/KR100450474B1/ko not_active Expired - Lifetime
-
1998
- 1998-06-26 US US09/105,002 patent/US5986154A/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3639227A (en) * | 1969-11-17 | 1972-02-01 | Chevron Res | Chloride addition during hydrogenation |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2736063B1 (fr) | 1997-08-14 |
| EP0751204A1 (fr) | 1997-01-02 |
| FR2736063A1 (fr) | 1997-01-03 |
| EP0751204B1 (fr) | 2001-09-26 |
| DE69615464T2 (de) | 2002-04-25 |
| JP4178301B2 (ja) | 2008-11-12 |
| KR970001284A (ko) | 1997-01-24 |
| JPH0912486A (ja) | 1997-01-14 |
| US5986154A (en) | 1999-11-16 |
| ES2164851T3 (es) | 2002-03-01 |
| US5789637A (en) | 1998-08-04 |
| DE69615464D1 (de) | 2001-10-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19960627 |
|
| PG1501 | Laying open of application | ||
| A201 | Request for examination | ||
| PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 20010612 Comment text: Request for Examination of Application Patent event code: PA02011R01I Patent event date: 19960627 Comment text: Patent Application |
|
| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
Comment text: Notification of reason for refusal Patent event date: 20031129 Patent event code: PE09021S01D |
|
| E701 | Decision to grant or registration of patent right | ||
| PE0701 | Decision of registration |
Patent event code: PE07011S01D Comment text: Decision to Grant Registration Patent event date: 20040629 |
|
| GRNT | Written decision to grant | ||
| PR0701 | Registration of establishment |
Comment text: Registration of Establishment Patent event date: 20040917 Patent event code: PR07011E01D |
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| PR1002 | Payment of registration fee |
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