KR970001284A - 귀금속을 주성분으로 하는 촉매의 존재하에 염소를 주입하여 방향족 화합물을 수소첨가하는 방법 - Google Patents
귀금속을 주성분으로 하는 촉매의 존재하에 염소를 주입하여 방향족 화합물을 수소첨가하는 방법 Download PDFInfo
- Publication number
- KR970001284A KR970001284A KR1019960024371A KR19960024371A KR970001284A KR 970001284 A KR970001284 A KR 970001284A KR 1019960024371 A KR1019960024371 A KR 1019960024371A KR 19960024371 A KR19960024371 A KR 19960024371A KR 970001284 A KR970001284 A KR 970001284A
- Authority
- KR
- South Korea
- Prior art keywords
- feedstock
- process according
- aromatic compound
- weight
- hydrogenating
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B31/00—Reduction in general
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/44—Hydrogenation of the aromatic hydrocarbons
- C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
- C10G45/52—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing platinum group metals or compounds thereof
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
본 발명은 초기 비등점이 100℃ 이상이고 10중량% 이상의 방향족 화합물을 함유하는 공급원료내의 방향족 화합물을 수소첨가하기 위한 방법에 관한 것이다. 본 발명의 방법은 200∼450℃의 온도에서, 1MPa 내지 25MPa의 압력하에, 0.1-10h-1의 HSV 및 수소/공급원료 부피비 100∼2,000을 사용하여, 상기 공급원료에 대하여 0.5∼500 중량 ppm의 농도로 염소를 주입하는 것으로 구성된다. 사용되는 촉매는 귀금속 유형의 촉매이며 하나 이상의 할로겐 1중량% 이상을 함유한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 초기 비등점이 100℃ 이상이고 10중량5 이상의 방향족 화합물을 함유하는 공급원료내의 방향족 화합물을 수소첨가하기 위한 방법으로서, 하나 이상의 귀금속을 주성분으로 하며 하나 이상의 할로겐 1중량%이상을 함유하는 지지된 촉매의 존재하에, 200∼450℃의 온도에서, 1∼25MPa의 압력하에, 0.1∼10h-1의 HSV 및 수소/공급원료 부피비 100∼2,000을 사용하여, 수소 첨가반응 영역내로 상기 공급원료에 대하여 0.5∼500중량 ppm의 농도하에 주입된 염소의 존재하에서 수행하는 방법.
- 제1항에 있어서, 상기 공급원료가 5∼2,000중량 ppm의 황을 함유하는 방법.
- 제1항 또는 제2항에 있어서, 상기 공급원료가 50∼800중량 ppm의 황을 함유하는 방법.
- 제1항 내지 제3항 중 어느 한 항에 있어서, 상기 공급원료내의 방향족 화합물이 2∼6개의 방향족 고리를 함유하는 방법.
- 제1항 내지 제4항중 어느 한 항에 있어서, 상기 공급원료의 초기 비등점이 200℃ 이상인 방법.
- 제1항 내지 5항 중 어느 한 항에 있어서, 상기 공급원료가 대기 가스유 또는 진공 증류물인 방법.
- 제1항 내지 제6항 중 어느 한 항에 있어서, 디클로로메탄, 트리클로로메탄, 디클로로에탄, 트리클로로에탄, 테트라클로로에틸렌, 헥사클로로에탄, 및 클로로포름으로 이루어진 군중에서 선택된 염소화된 유기 화합물을 주입하는 방법.
- 제1항 내지 제7항 중 어느 한 항에 있어서, 상기 공급원료내로 염소를 주입하는 방법.
- 제1항 내지 제8항 중 어느 한항에 있어서, 상기 촉매가 염소화 및 플루오르화된 지지체를 함유하는 것을 특징으로 하는 방법.
- 제1항 내지 제9항 중 어느 한 항에 있어서, 상기 촉매가 염소화 및 플루오르화된 알루미나상에 부착된 백금을 함유하는 것을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9507726 | 1995-06-27 | ||
| FR9507726A FR2736063B1 (fr) | 1995-06-27 | 1995-06-27 | Procede d'hydrogenation d'aromatiques avec injection de chlore sur des catalyseurs a base de metal noble |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR970001284A true KR970001284A (ko) | 1997-01-24 |
| KR100450474B1 KR100450474B1 (ko) | 2004-12-04 |
Family
ID=9480438
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019960024371A KR100450474B1 (ko) | 1995-06-27 | 1996-06-27 | 귀금속을주성분으로하는촉매의존재하에염소화제를주입하여방향족화합물을수소첨가하는방법 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US5789637A (ko) |
| EP (1) | EP0751204B1 (ko) |
| JP (1) | JP4178301B2 (ko) |
| KR (1) | KR100450474B1 (ko) |
| DE (1) | DE69615464T2 (ko) |
| ES (1) | ES2164851T3 (ko) |
| FR (1) | FR2736063B1 (ko) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2736063B1 (fr) * | 1995-06-27 | 1997-08-14 | Inst Francais Du Petrole | Procede d'hydrogenation d'aromatiques avec injection de chlore sur des catalyseurs a base de metal noble |
| EP0904482B2 (en) | 1996-06-10 | 2010-01-20 | Hitachi, Ltd. | Exhaust gas purification apparatus of an internal combustion engine and catalyst for purifying exhaust gas of an internal combustion engine |
| FR2765586B1 (fr) * | 1997-07-02 | 2003-09-05 | Inst Francais Du Petrole | Procede de transformation, par hydrogenation catalytique, d'une base huile en huile blanche medicinale |
| FR2778341B1 (fr) * | 1998-05-07 | 2000-06-09 | Inst Francais Du Petrole | Catalyseur a base d'un metal noble du groupe viii contenant du bore et/ou du silicium et son utilisation en hydrotraitement de charge hydrocarbonees |
| FR2778342B1 (fr) * | 1998-05-07 | 2000-06-16 | Inst Francais Du Petrole | Catalyseur utilisable dans l'hydrogenation des composes aromatiques dans une charge hydrocarbonnee contenant des composes soufres |
| US6013847A (en) * | 1998-12-31 | 2000-01-11 | Phillips Petroleum Company | Hydrogenation of benzene in the presence of water |
| FR2795420B1 (fr) * | 1999-06-25 | 2001-08-03 | Inst Francais Du Petrole | Procede d'hydrotraitement d'un distillat moyen dans deux zones successives comprenant une zone intermediaire de stripage de l'effluent de la premiere zone avec condensation des produits lourds sortant en tete du strippeur |
| FR2800638B1 (fr) * | 1999-11-10 | 2002-01-18 | Inst Francais Du Petrole | Catalyseur fluore comprenant un element du groupe viii et un element du groupe viib et son utilisation pour l'hydrogenation de composes aromatiques en presence de composes soufres |
| FR2800639B1 (fr) * | 1999-11-10 | 2002-01-18 | Inst Francais Du Petrole | Catalyseur bimetallique comprenant du fluor et son utilisation pour l'hydrogenation des composes aromatiques en presence de composes soufres |
| FR2800637B1 (fr) * | 1999-11-10 | 2002-01-18 | Inst Francais Du Petrole | Catalyseur fluore comprenant un metal du groupe viii et un metal du groupe ib et son utilisation pour l'hydrogenation de composes aromatiques en presence de composes soufres |
| EP1099476B1 (fr) | 1999-11-10 | 2006-11-08 | Institut Francais Du Petrole | Catalyseur fluoré et chloré comprenant un métal du groupe VIII et un métal additionnel et son utilisation pour l'hydrogénation de composés aromatiques |
| FR2800640B1 (fr) * | 1999-11-10 | 2002-01-18 | Inst Francais Du Petrole | Catalyseur fluore comprenant un metal du groupe viii et un metal du groupe iib et son utilisation pour l'hydrogenation de composes aromatiques en presence de composes soufres |
| CN1558927A (zh) | 2001-09-25 | 2004-12-29 | ����ɭ���ڻ�ѧר����˾ | 增塑聚氯乙烯 |
| US9828571B2 (en) | 2015-06-05 | 2017-11-28 | Illinois Tool Works, Inc. | Heavy duty laundry detergent |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3639227A (en) * | 1969-11-17 | 1972-02-01 | Chevron Res | Chloride addition during hydrogenation |
| US3816299A (en) * | 1973-04-30 | 1974-06-11 | Union Oil Co | Hydrogenation process |
| FR2240905B1 (ko) * | 1973-08-16 | 1980-01-04 | Inst Francais Du Petrole | |
| US4110198A (en) * | 1977-02-03 | 1978-08-29 | Uop Inc. | Process for hydrocracking hydrocarbons |
| FR2736063B1 (fr) * | 1995-06-27 | 1997-08-14 | Inst Francais Du Petrole | Procede d'hydrogenation d'aromatiques avec injection de chlore sur des catalyseurs a base de metal noble |
-
1995
- 1995-06-27 FR FR9507726A patent/FR2736063B1/fr not_active Expired - Lifetime
-
1996
- 1996-06-21 DE DE69615464T patent/DE69615464T2/de not_active Expired - Lifetime
- 1996-06-21 EP EP96401381A patent/EP0751204B1/fr not_active Expired - Lifetime
- 1996-06-21 ES ES96401381T patent/ES2164851T3/es not_active Expired - Lifetime
- 1996-06-27 US US08/671,501 patent/US5789637A/en not_active Expired - Lifetime
- 1996-06-27 KR KR1019960024371A patent/KR100450474B1/ko not_active IP Right Cessation
- 1996-06-27 JP JP16759096A patent/JP4178301B2/ja not_active Expired - Lifetime
-
1998
- 1998-06-26 US US09/105,002 patent/US5986154A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| FR2736063B1 (fr) | 1997-08-14 |
| US5986154A (en) | 1999-11-16 |
| KR100450474B1 (ko) | 2004-12-04 |
| JP4178301B2 (ja) | 2008-11-12 |
| EP0751204A1 (fr) | 1997-01-02 |
| FR2736063A1 (fr) | 1997-01-03 |
| EP0751204B1 (fr) | 2001-09-26 |
| ES2164851T3 (es) | 2002-03-01 |
| DE69615464T2 (de) | 2002-04-25 |
| US5789637A (en) | 1998-08-04 |
| DE69615464D1 (de) | 2001-10-31 |
| JPH0912486A (ja) | 1997-01-14 |
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