KR100447068B1 - The components of funtional cleaning agent on the environmental affinity - Google Patents

Abstract

PURPOSE: A cleansing composition is provided to give antistatic, antibacterial and anticorrosive effects as well as cleaning effects without toxic effects on a human body, air and aqueous environment, thereby being safely used for kitchen, domestic or office appliances and improving work conditions, owing to the use of environmentally-friendly cleansing liquids. CONSTITUTION: The cleansing composition comprises: 2-15wt% of D-limonene, that is an orange extract; 2-15wt% of palm oil having natural fatty acids; 2-15wt% of an aqueous conductive polymer such as poly(3,4-ethylenedioxythiophene), polypyrrole, polyaniline; 0.01-2wt% of 5-chloro-2-methyl-4-isothiazolin-3-one; 0.01-2wt% of methyl-4-isothiazolin-3-one; 4-20wt% of sodium lauryl ether sulfate or sodium xylene sulfate as an anionic surfactant; 2-20wt% of ethyl alcohol; and 50-90wt% of water.

Description

The components of funtional cleaning agent on the environmental affinity}

The present invention provides an environmentally friendly functional detergent composition obtained using D-limonene, an excellent orange water extract, water-soluble conductive polymer having antistatic and anti-corrosion effect, isothiazoline, surfactant, alcohol, and water having high antibacterial activity. It is about a method.

Common cleaning agents for cleaning electronics, display monitors, electronics, electronics circuits, fibers, windows and floors are used only to remove contaminants from surfaces. The most contaminants attached to the surface are dust, oil contamination, oil contamination of protein components, oily pollution, etc. due to the accumulation of various dusts. Since the above contaminants are difficult to clean effectively with general surfactants, detergents, abrasives, or organic solvents have been added for effective cleaning effects.

Cleaning agents for kitchen, home appliances, office equipment, and indoor various pollutants are emphasized only by the use of unvalidated raw materials outside the country.They do not use environmentally friendly solvents such as alcohol and water. It causes air and water pollution. In addition, the neutrality of the detergent solution is emphasized, so that the detergent is inferior, and in most cases, an irritating fragrance for masking is used. In Korea, the use of irritating fragrances, there is a sense of rejection at the first use, and the use of alcohol, an environmentally friendly solvent, is low, often causing environmental and quality problems.

The removal of contaminants on surfaces is caused by a complex mechanism, which is cleaned by physical and chemical methods in the presence of contaminants that penetrate into the surface or by physical binding by adsorbent additives such as resins. The cleaning action by the surfactant may include the solubilization of the contaminant, the disturbance of the electrostatic force between the contaminant and the solid adduct by the surfactant, the degree of adsorption of the surfactant solution adsorbed with the contaminant, and the oiliness generated by the surfactant. It is heavily influenced by the mechanism determined by contamination and interfacial tension between surfactant solutions.

Since most pollutants are dust, fat, oil pollution, protein-based oil pollution and oil pollution, the general cleaning agents that remove contaminants are organic solvent-added cleaners. It not only has a problem of damaging and adversely affecting the natural environment and the human body, but also has a disadvantage in that the cleaning effect is somewhat reduced.

In particular, in the cleaning of electronic products, display monitors, electronic parts, and electronic component circuits, existing cleaners are often used with aqueous or alkaline hydroxide solutions. However, oily agents have a big problem in damaging the product itself. However, there is a problem of corrosion of metals other than silicon. In addition, the cleaning agent only gives a cleaning effect, the significant antistatic effect, anti-corrosion effect, antimicrobial effect was found to be very small in electronic products.

Electric charges can be generated on the surface of an object for various reasons, which are usually generated by static electricity generated between two friction objects or by an external strong electric field. In the state where the surface of such an object is charged, various harmful phenomena are generated by the electric field generated from the electric charge.

Such static electricity does not flow and accumulates on a surface of a certain object and is discharged momentarily upon contact with another object. In particular, when contacted with a human body, a significant electric shock is often applied to the human body, causing severe discomfort.

In addition, since the accumulated charge is adjacent to a precise circuit such as an IC circuit, and the electric field generated therein increases the probability that the circuit malfunctions, it is very important to quickly remove the charged charge.

Corrosion is an interaction between metal and its surroundings, where metal atoms leave the crystal lattice and cause a wide range of oxidation reactions. Corrosion of metals can be controlled in a variety of ways, including the use of corrosion inhibitors, changes in metals or corrosion media. Corrosion inhibitors can be single substances or mixtures that can control or reduce corrosion at certain concentrations. The most effective corrosion inhibitors are organic compounds (conductive polymers) with π-double bonds. The efficiency of an organic compound acting as a corrosion inhibitor is determined by the degree of adsorption of the organic compound on the metal surface and the ability of the organic compound to remove water from the metal surface. Adsorption of organic compounds is affected by functional groups such as = NH, -N = H-, -CHO, R-OH, and -R = R- in the molecular structure.

Existing antistatic agent is a detergent added with salt or surfactant, antistatic effect is not semi-permanent, and shows a very small antistatic effect, antibacterial and anti-corrosive detergent for sterilization and cleaning It is the same as Lax used mainly. It has good sterilizing power but it is not suitable for easy use due to strong irritant smell and toxicity to human body.

An object of the present invention was devised to solve the above-mentioned conventional problems, water-soluble poly (3,4-ethylenedi) having an antistatic effect with D-limonene, which is a fruit extract having excellent cleaning effect while being harmless to humans and the environment. Oxythiophene), water-soluble polypyrrole, polyaniline, anti-corrosion effect, isothiazoline with very effective antibacterial activity, environmentally friendly functional detergent composition obtained by using lauryl ether sulfate salt based on vegetable fat as a surfactant, alcohol and water The functional cleaner is a cleaning effect by using as a cleaning agent for various contaminants in electronics, display monitors, electronic components, electronic component circuits, fibers, windows, floors, kitchen, household appliances, office equipment and indoors It is to give antistatic, anticorrosive and antibacterial effect at the same time.

The present invention is a fruit extract D-limonene with excellent cleaning effect and water-soluble poly (3,4-ethylenedioxythiophene) with antistatic effect and water-soluble polypyrrole, polyaniline, antibacterial effect isothia very effective The present invention relates to a method for preparing an environmentally friendly functional detergent composition obtained by using chloromethylisothiazoline, methyl isothiazoline, which is a sleepy lauryl ether sulfate salt using alcohol as a raw material of a vegetable oil as a surfactant, alcohol and water, and the functional detergent It is used as a cleaning agent for various pollutants in electronic products, display monitors, electronic components, electronic component circuits, textiles, glass windows, floors, kitchen appliances, home appliances, office equipment, and indoors. Can be granted.

In order to achieve the object of the present invention, the present invention, orange extract D-Limonene (D-Limonene) 2-15% by weight, natural fatty acid palm oil (CDE) 2-15% by weight, water-soluble conductive polymer (poly (3,4- Ethylenedioxythiophene), polypyrrole, polyaniline) 2-15% by weight, 5-chloro-2-methyl-4-isothiazolin-3-one (5-Chloro-2-methyl-4-isothiazolin-3-one ) 0.01 to 2% by weight, methyl-4-isothiazolin-3-one 0.01 to 2% by weight, an anionic surfactant, lauryl ether sulfate salt (Sodium Lauryl Ether Sulfate: SLES) or xylene sulfate salt (Sodium Xylene Sulfate: SXS) is characterized by consisting of 4 to 20% by weight, ethyl alcohol 2 to 20% by weight, water 50 to 90% by weight.

D-limonene is a substance extracted from orange peels that are easily encountered in ordinary homes. It is a by-product of citrus juice making. It is called terpen. The terpene is used for steam distillation of citrus peel and pulp from citrus juice production. Obtained in the 94-98% oil phase. D-limonene contains a dark citrus scent to prevent odor, which is a disadvantage of solvent-based detergents. It also has a strong self-cleaning ability to prevent re-contamination and softening effect. D-limonene has 1-methyl- 4 (1-methylethenyl) cyclohexene is the main component and the chemical formula of 1-methyl-4 (1-methylethenyl) cyclohexene is shown in FIG. 1.

1

Poly (3,4-ethylenedioxythiophene) is a kind of conductive polymer. In particular, poly (3,4-ethylenedioxythiophene) is obtained in a dispersed form in an aqueous solution using polystyrene sulfonate as a dopant as a derivative of polythiophene. Poly (3,4-ethylenedioxythiophene) in an aqueous solution state, unlike other conductive polymers, has excellent transparency, chemical resistance, heat resistance and excellent conductivity. In particular, it is a water-soluble solution, which is very harmless to the environment and human body, and is suitable for industrialization. The structural formula of poly (3,4-ethylenedioxythiophene) using polystyrene sulfonate as a dopant is shown in FIG. 2.

[Figure 2]

Polypyrrole, a kind of water-soluble conductive polymer, is obtained in the form of dispersed in an aqueous solution using polystyrene sulfonate as a dopant, like poly (3,4-ethylenedioxythiophene). Polypyrrole in aqueous solution shows excellent conductivity and is suitable for industrialization as a solution that is very harmless to the environment and human body. In particular, the polyaniline in the aqueous state, unlike other conductive polymers, it is easy to chemically control the oxidation state, intermediate oxidation state, reduced state process. Due to the control of the redox has shown excellent function in the corrosion protection effect. The structural formulas of water-soluble polypyrrole and polyaniline using polystyrene sulfonate as a dopant are shown in FIGS. 3 and 4.

3

[Figure 4]

Isothiazolin, an antimicrobial agent, is biologically and physically stable with anionic surfactants and can be inactivated by a reducing agent. In particular, even in small amounts and low concentrations, fungi and bacteria including fungi, yeast growth control and sterilization effect is continuous, and even when used in a wide pH range (pH 2.0 ~ 9.0) it is not only stable but also chemically compatible with water Have Since it does not affect the growth and development of the surrounding plants after use, it is a very stable material for the environment. 5-Chloro-2-methyl-4-isothiazolin-3-one and methyl-4-isothiazolin in isothiazolin 3-one (Methyl-4-isothiazolin-3-one) is shown in FIGS. 5 and 6.

5

6

Sodium Lauryl Ether Sulfate (SLES), an anionic surfactant, is a high-grade alcohol based on vegetable oils such as palm oil and palm oil, which has a short biodegradation period, removes surface activation and general time, and is stable to cleaning agents. It gives a role. Sodium Lauryl Ether Sulfate (SLES), an anionic surfactant, has a structure of CH _3- (CH ₂ ) ₁₀ -CH _2- (CH ₂ CH ₂ O) ₃ -O-SO ₃ Na, Soluble in water, pH 6.0-7.0.

The present invention as described above will be described with reference to Examples.

Example 1

The blending ratio of the environmentally friendly functional detergent composition manufacturing method prepared by the present invention is as follows.

D-Limonene: 2 to 3% by weight,

Natural Fatty Palm Oil (C.D.E): 2-3 wt%

Water-soluble poly (3,4-ethylenedioxythiophene): 4 to 5 wt%

5-chloro-2-methyl-4-isothiazolin-3-one: 0.01 to 0.05% by weight,

Methyl-4-isothiazolin-3-one: 0.005 to 0.01% by weight,

Water-soluble polyaniline: 2-3 wt%,

Lauryl ether sulfate salt (SLES): 4-5% by weight,

Magnesium Salt: 0.05 ~ 0.1 wt%

Ethyl alcohol: 2-3 wt%,

Water: 80 ~ 85 wt%

By the above blending ratio, natural fatty palm oil (C.D.E) is slowly stirred and mixed with water at room temperature. D-limonene is added to a natural fatty oil (C.D.E) solution with gentle stirring at room temperature. Ethyl alcohol is added to the solution to which D-Limonene is added, and water-soluble poly (3,4-ethylenedioxythiophene) and polyaniline are added and stirred. A cloudy solution is produced, but the addition of lauryl ether sulfate salt (SLES) results in a clear stable solution. To the solution are added 5-chloro-2-methyl-4-isothiazolin-3-one, methyl-4-isothiazolin-3-one and magnesium salts.

The functional detergent prepared above is a weak alkaline detergent of pH 7.5, there is no layer separation in a stable solution at 50 ℃. Excellent cleaning, charging, corrosion and antibacterial effect.

Example 2

The blending ratio of the environmentally friendly functional detergent composition manufacturing method prepared by the present invention is as follows.

D-Limonene: 2 to 3% by weight,

Natural Fatty Palm Oil (C.D.E): 2-3 wt%

Water-soluble poly (3,4-ethylenedioxythiophene): 4 to 5 wt%

5-chloro-2-methyl-4-isothiazolin-3-one: 0.01 to 0.05% by weight,

Methyl-4-isothiazolin-3-one: 0.005 to 0.01% by weight,

Water-soluble polypyrrole: 2-3 wt%,

Lauryl ether sulfate salt (SLES): 4-5% by weight,

Magnesium Salt: 0.05 ~ 0.1 wt%

Ethyl alcohol: 2-3 wt%,

Water: 80 ~ 85 wt%

By the above blending ratio, natural fatty palm oil (C.D.E) is slowly stirred and mixed with water at room temperature. D-limonene is added to a natural fatty oil (C.D.E) solution with gentle stirring at room temperature. Ethyl alcohol is added to the solution to which D-Limonene is added, and water-soluble poly (3,4-ethylenedioxythiophene) and polypyrrole are added and stirred. A cloudy solution is produced, but the addition of lauryl ether sulfate salt (SLES) results in a clear stable solution. To the solution are added 5-chloro-2-methyl-4-isothiazolin-3-one, methyl-4-isothiazolin-3-one and magnesium salts.

The functional detergent prepared above is a weak alkaline detergent of pH 7.3, and there is no layer separation in a stable solution state at 50 ℃. Excellent cleaning, charging, corrosion and antibacterial effect.

Example 3

The blending ratio of the environmentally friendly functional detergent composition manufacturing method prepared by the present invention is as follows.

D-Limonene: 2 to 3% by weight,

Natural Fatty Palm Oil (C.D.E): 2-3 wt%

Water-soluble poly (3,4-ethylenedioxythiophene): 4 to 5 wt%

Lauryl ether sulfate salt (SLES): 4 to 5% by weight

Xylene sulfate salt (SXS): 10-15% by weight,

Ethyl alcohol: 2-3 wt%,

Water: 70 ~ 75 wt%

First, by mixing the mixture of natural fatty acid palm oil (C.D.E) slowly at room temperature by water. D-limonene is added to a natural fatty oil (C.D.E) solution with gentle stirring at room temperature. Ethyl alcohol is added to the solution to which D-Limonene is added, and water-soluble poly (3,4-ethylenedioxythiophene) is added and stirred. At this point, a cloudy solution is produced but the xylene sulfate salt (SXS) is added and the lauryl ether sulfate salt (SLES) is added to form a clear stable solution.

The functional detergent prepared above is a weak alkaline detergent of pH 9.0, and there is no layer separation in a stable solution state at 50 ℃. Excellent cleaning power and antistatic effect.

Example 4

The blending ratio of the environmentally friendly functional detergent composition manufacturing method prepared by the present invention is as follows.

D-Limonene: 2 to 3% by weight,

Natural Fatty Palm Oil (C.D.E): 2-3 wt%

Water Soluble Polypyrrole: 4 ~ 5 wt%

Lauryl ether sulfate salt (SLES): 4 to 5% by weight

Xylene sulfate salt (SXS): 10-15% by weight,

Ethyl alcohol: 2-3 wt%,

Water: 70 ~ 75 wt%

By the above blending ratio, natural fatty palm oil (C.D.E) is slowly stirred and mixed with water at room temperature. D-limonene is added to a natural fatty oil (C.D.E) solution with gentle stirring at room temperature. Ethyl alcohol is added to the solution to which D-Limonene is added, and water-soluble polypyrrole is added and stirred. At this point, a cloudy solution is produced but the xylene sulfate salt (SXS) is added and the lauryl ether sulfate salt (SLES) is added to form a clear stable solution.

The functional detergent prepared above is a neutral detergent of pH 6.9, there is no layer separation in a stable solution at 50 ℃. Excellent cleaning power and antistatic effect.

Example 5

The blending ratio of the environmentally friendly functional detergent composition manufacturing method prepared by the present invention is as follows.

D-Limonene: 2 to 3% by weight,

Natural Fatty Palm Oil (C.D.E): 2-3 wt%

Poly (3,4-ethylenedioxythiophene): 10-15% by weight,

Lauryl ether sulfate salt (SLES): 2-3 wt%

Isobutyl alcohol (isobutylalcohol): 10 to 15% by weight,

Water: 65 ~ 70 wt%

By the above blending ratio, natural fatty palm oil (C.D.E) is slowly stirred and mixed with water at room temperature. D-limonene is added to a natural fatty oil (C.D.E) solution with gentle stirring at room temperature. Isobutyl alcohol is added to the solution to which D-Limonene was added, and poly (3, 4- ethylene dioxythiophene) is added and stirred. A cloudy solution is produced, but the addition of lauryl ether sulfate salt (SLES) results in a clear stable solution.

The functional detergent prepared above is a neutral detergent of pH 7.0 ~ 7.5, there is no layer separation in a stable solution state at 50 ℃. Excellent cleaning power and antistatic effect.

Example 6

The blending ratio of the environmentally friendly functional detergent composition manufacturing method prepared by the present invention is as follows.

D-Limonene: 10 to 15% by weight,

Poly (3,4-ethylenedioxythiophene): 4-5% by weight,

Lauryl ether sulfate salt (SLES): 2-3 wt%

Xylene sulfate salt (SXS): 10-15% by weight,

Butyldiglycol: 10 to 15% by weight,

Water: 60 ~ 65 wt%

By the above mixing ratio, D-limonene (D-Limonene) is first added to water while stirring slowly at room temperature. Butyl dicholol is added to the solution to which D-Limonene is added, and poly (3, 4- ethylene dioxythiophene) is added and stirred. The turbid solution then turns into a stable solution with transparency. The addition of xylene sulfate salt (SXS), lauryl ether sulfate salt (SLES) results in a clearer, stable solution.

The functional detergent prepared above is a neutral detergent of pH 6.8 ~ 7.2, there is no layer separation in a stable solution state at 50 ℃. Very good cleaning power. Excellent antistatic effect.

Example 7

The blending ratio of the environmentally friendly functional detergent composition manufacturing method prepared by the present invention is as follows.

D-Limonene: 10 to 15% by weight,

Poly (3,4-ethylenedioxythiophene): 10-15% by weight,

Lauryl ether sulfate salt (SLES): 2-3 wt%

Butyldiglycol: 10 to 15 wt%

Isobutylalcohol: 10 ~ 15 wt%

Water: 45 to 50 wt%

By the above mixing ratio, D-limonene (D-Limonene) is first added to water while stirring slowly at room temperature. Butyl di glycol is added to the solution to which D-Limonene is added, and poly (3,4-ethylenedioxythiophene) and isobutyl alcohol (isobutylalcohol) are added and stirred. The turbid solution then turns into a stable solution with transparency. The addition of lauryl ether sulfate salt (SLES) forms a clearer, stable solution.

The functional detergent prepared above is a weak acidic detergent of pH 6.3 ~ 6.8, there is no layer separation in a stable solution state at 50 ℃. Very good washing power, excellent antistatic effect.

Example 8

The blending ratio of the environmentally friendly functional detergent composition manufacturing method prepared by the present invention is as follows.

D-Limonene: 4 to 5% by weight,

5-chloro-2-methyl-4-isothiazolin-3-one: 0.01 to 0.05% by weight,

Methyl-4-isothiazolin-3-one: 0.005 to 0.01% by weight,

Water-soluble polyaniline: 2-3 wt%,

Xylene sulfate salt (SXS): 4-5% by weight,

Magnesium Salt: 0.05 ~ 0.1 wt%

5-6% by weight of ethyl alcohol,

Water 80 ~ 85 wt%

By the above mixing ratio, natural D-limonene (D-Limonene) is first added to water while stirring slowly at room temperature. Ethyl alcohol was added to the solution to which D-Limonene was added, and 5-chloro-2-methyl-4-isothiazolin-3-one, methyl-4-isothiazolin-3-one, magnesium Add salt. Water-soluble polyaniline is added to the solution and stirred. At this point, a cloudy solution is produced, but the addition of xylene sulfate salt (SXS) forms a clear stable solution.

The functional detergent prepared above is a weak alkaline detergent of pH 9.3, and there is no layer separation in a stable solution state at 50 ℃. Excellent cleaning, corrosion and antibacterial effect

Example 9

The blending ratio of the environmentally friendly functional detergent composition manufacturing method prepared by the present invention is as follows.

D-Limonene: 2 to 3% by weight,

5-chloro-2-methyl-4-isothiazolin-3-one: 0.05-0.1 wt%,

Methyl-4-isothiazolin-3-one: 0.01 to 0.05% by weight,

Water-soluble polyaniline: 2-3 wt%,

Lauryl ether sulfate salt (SLES): 4-5% by weight,

Magnesium Salt: 0.1 ~ 0.5 wt%

5-6% by weight of ethyl alcohol,

Water 80 ~ 85 wt%

By the above mixing ratio, natural D-limonene (D-Limonene) is first added to water while stirring slowly at room temperature. Ethyl alcohol was added to the solution to which D-Limonene was added, and 5-chloro-2-methyl-4-isothiazolin-3-one, methyl-4-isothiazolin-3-one, magnesium Add salt. Water-soluble polyaniline is added to the solution and stirred. A cloudy solution is produced, but the addition of lauryl ether sulfate salt (SLES) results in a clear stable solution.

The functional detergent prepared above is a weak alkaline detergent of pH 10.0, and there is no layer separation in a stable solution state at 50 ℃. Excellent corrosion and antibacterial effect

Example 10

The blending ratio of the environmentally friendly functional detergent composition manufacturing method prepared by the present invention is as follows.

D-Limonene: 2 to 3% by weight,

5-chloro-2-methyl-4-isothiazolin-3-one: 0.01 to 0.05% by weight,

Methyl-4-isothiazolin-3-one: 0.005 to 0.01% by weight,

Water-soluble polyaniline: 5 to 6% by weight,

Lauryl ether sulfate salt (SLES): 4-5% by weight,

Magnesium Salt: 0.05 ~ 0.1 wt%

5-6% by weight of ethyl alcohol,

Water 80 ~ 85 wt%

By the above mixing ratio, natural D-limonene (D-Limonene) is first added to water while stirring slowly at room temperature. Ethyl alcohol was added to the solution to which D-Limonene was added, and 5-chloro-2-methyl-4-isothiazolin-3-one, methyl-4-isothiazolin-3-one, magnesium Add salt. Water-soluble polyaniline is added to the solution and stirred. A cloudy solution is produced, but the addition of lauryl ether sulfate salt (SLES) results in a clear stable solution.

The functional detergent prepared above is a neutral detergent of pH 7.5, there is no layer separation in a stable solution state at 50 ℃. Excellent corrosion protection and antibacterial effect

Example 11

The blending ratio of the environmentally friendly functional detergent composition manufacturing method prepared by the present invention is as follows.

D-Limonene: 2 to 3% by weight,

5-chloro-2-methyl-4-isothiazolin-3-one: 0.01 to 0.05% by weight,

Methyl-4-isothiazolin-3-one: 0.005 to 0.01% by weight,

Water-soluble polypyrrole: 5 to 6% by weight,

Lauryl ether sulfate salt (SLES): 4-5% by weight,

Magnesium Salt: 0.05 ~ 0.1 wt%

5-6% by weight of ethyl alcohol,

Water 80 ~ 85 wt%

By the above mixing ratio, natural D-limonene (D-Limonene) is first added to water while stirring slowly at room temperature. Ethyl alcohol was added to the solution to which D-Limonene was added, and 5-chloro-2-methyl-4-isothiazolin-3-one, methyl-4-isothiazolin-3-one, magnesium Add salt. Water-soluble polypyrrole is added to the solution and stirred. A cloudy solution is produced, but the addition of lauryl ether sulfate salt (SLES) results in a clear stable solution.

The functional detergent prepared above is a neutral detergent of pH 7.3, and there is no layer separation in a stable solution at 50 ℃. Excellent corrosion protection and antibacterial effect

The main composition ratio of the present invention was determined by measuring the composition of the same composition as Examples (1 to 11) described above with respect to the cleaning agent, antibacterial effect, antistatic effect, anticorrosive effect, environmental (fish toxicity), skin irritation and solution stability. The result of Examples 8-11 which have is shown in [Table 1].

TABLE 1

From the results of the above [Table 1], it can be seen that the environmentally friendly functional detergent composition according to the present invention has excellent cleaning power and functionality such as antibacterial, corrosion, charging, environmental, skin irritation, and stability of the solution.

As described above, the environmentally friendly functional detergent composition according to the present invention is a fruit extract having excellent cleaning effect, D-limonene, an antistatic effect of water-soluble poly (3,4-ethylenedioxythiophene), and an anticorrosive effect of water-soluble. Polypyrrole, polyaniline, chloromethylisothiazoline, methylisothiazoline, isothiazoline, which is very effective antimicrobial activity The functional cleaner is a cleaning effect and antistatic by using as a detergent of various contaminants in electronics, display monitors, electronic components, electronic component circuits, fibers, windows, floors, kitchen, home appliances, office equipment and indoors It can give anti-corrosion and antibacterial effect at the same time. The cleaning agent of the present invention can be processed into various types of cleaning agents, such as the cleaning agent used as the liquid itself or the spraying agent, or by using a liquid cleaning agent in a paper or textile material manufactured to a predetermined size. By using environmentally friendly cleaning liquid and water-soluble polymer, it is not harmful to the air, water environment and human body, and can improve working environment, and can simultaneously provide cleaning effect, antistatic effect and corrosion inhibitory effect.

Claims (9)

Orange extract D-Limonene 2-15%, natural fatty acid palm oil (CDE) 2-15% by weight, water-soluble conductive polymer (poly (3,4-ethylenedioxythiophene), polypyrrole, polyaniline) 2-15 wt%, 5-Chloro-2-methyl-4-isothiazolin-3-one 0.01--2 wt%, methyl-4- Methyl-4-isothiazolin-3-one 0.01 to 2% by weight, an anionic surfactant, sodium lauryl ether sulfate (SLES) or xylene sulfate salt (sodium xylene sulfate) : SXS) 4 to 20% by weight, ethyl alcohol 2 to 20% by weight, water 50 to 90% by weight functional detergent composition delete The functional detergent composition according to claim 1, further comprising a polythiophene derivative, a poly (3,4-ethylenedioxythiophene), a water-soluble polypyrrole, and a water-soluble polyaniline as a water-soluble conductive polymer. The functional detergent according to claim 1, further comprising 5-chloro-2-methyl-4-isothiazolin-3-one and methyl-4-isothiazolin-3-one as isothiazoline. Composition delete delete delete delete delete