KR100431028B1 - Manufacturing method of electrolyzed peroxyfulvic acid complexed mineral salts and application method - Google Patents

Abstract

The present invention makes mineral complexes of pulvic acid electrolytic oxidized water (ORP) value of + 1100mv or more to prevent crop disease and spray it on the place where odor occurrence is severe such as barn or compost. The purpose is to economically and efficiently control the growth and suppression of harmful microorganisms such as microorganisms, rot and perishable microorganisms.

To this end, fulvic acid is applied in an electrolytic oxidation tank (3) to produce a fulvic acid electrolytic oxidation water with an ORP value of +1100 mv or more, followed by pellets (9) and pumice (active corrosive material). 10) Growth of useful microorganisms, which receive useful minerals from the mineral reaction tank (8) in which the mineral reaction tower (8) is filled, inhibits the growth of pathogenic microorganisms, decayed and perishable microorganisms, and plays a useful role in the growth of animals and plants. Producing mineral complex salt of fulvic acid electrolyzed water, which is a mineral complex of peroxyfulvic acid, helps spraying on crops or barn compost to suppress the growth of harmful microorganisms such as pathogenic microorganisms, rot and decaying microorganisms. As the growth of useful microorganisms, which are useful for the growth of animals and plants, which are antagonistic with microorganisms, becomes active, the growth of harmful microorganisms is suppressed.

Therefore, the mineral complex salt of fulvic acid electrolyzed water developed in the present invention is expected to be applied to various fields such as feed additives, soil improvers, etc. in addition to crop pest control and suppression of odor occurrence in barns or compost.

Description

Manufacturing method and method of using fulvic acid electrolytic water mineral complex salt {Manufacturing method of electrolyzed peroxyfulvic acid complexed mineral salts and application method}

The present invention is a peat (Peat) produced by the deposition of marine animals and plants such as marine diatoms, Plankton, seaweed with a high content of Fulvic acid (also known as peat (Peat)) by the acid treatment after alkali (Alkali) treatment Extracts liquid Fulvic acid and uses it to produce Fulvic Acid Electrolytic Oxidized Water (ORP) of + 1100mv or more in electrolytic oxidation tanks as pesticides and livestock disinfectants. It's about doing.

When the aqueous solution of NaCl, KCl, etc. is injected into the electrolytic oxidation tank equipped with a diaphragm, and a direct current is applied, an alkali solution, which is an electrolytic reduction water, is produced at the cathode, and the technology using the sterilization effect of an aqueous solution of HClOχ, which is an acidic electrolytic oxidation water, is used at the anode. In Japanese Patent Laid-Open Publication Nos. Hei 5-163101, Hei 7-187931 and Hei 2000-159618, it was found that when electrolytic oxidation water of anode was sprayed on the leaves and fruits, etc., to control the pathogenic microorganisms. · Stable control of crops, but it did not help the growth of useful microorganisms that are antagonistic to harmful pathogenic microorganisms while helping plant growth.

In the present invention, by applying a DC current in an electrolytic oxidation tank with an acidic solution of fulvic acid having a pH of 2 or less, an oxidized reduction potential (ORP) value of + 1100mv or more is a pulve which is peroxyfulvic acid (Peroxyfulvic acid). Oxygen peroxide is supplied from a mineral reaction tank containing calcite or dacite pumice and activated corrosive pellets filled with active minerals. Mineral complex salt of fulvic acid electrolyzed water in the form of mineral complex salt (also called liquid active corrosive material) is made and sprayed on crops or barns to suppress the sterilization or growth of harmful microorganisms such as harmful pathogenic microorganisms, rot and decaying microorganisms. By activating the growth of useful microorganisms, which are useful for plant growth, Static and continually prevents pests of crops, and sprays on crops by producing mineral complex salts of Fulvic acid electrolyzed water, which have the effect of removing odors when spraying on barns or composts, while improving the disinfection efficiency of pathogenic microorganisms. When it was sprayed on the barn or compost, the odor was reduced and the sterilization efficiency of harmful microorganisms such as pathogenic microorganisms, rot and decay microorganisms was improved.

An object of the present invention is to inhibit or sterilize the growth of phytopathogens such as powdery mildew, anthrax and rice blasting of horticultural crops, while maintaining a stable control of mineral complex salts of fulvic acid electrolyzed water to help the growth environment of microorganisms useful for agricultural crops. Let's develop a way to produce it.

1 is a manufacturing process of the electrolytic oxidized water mineral complex salt when the mineral reaction tower is installed inside the mineral reactor after electrolytic oxidation of fulvic acid (Fulvic acid) in the electrolytic oxidation tank

2 is a manufacturing process diagram of the electrolytic oxidation mineral mineral salt of fulvic acid when the mineral reaction tower is installed outside the mineral reaction tank after electrolytic oxidation of fulvic acid in the electrolytic oxidation tank

[Description of Code for Major Parts of Drawing]

1: Fulvic acid storage tank 2: Fulvic acid transfer pump

3: electrolytic oxidation tank 4: cathode

5: positive pole 6: rectifier

7: Mineral reaction tank 8a: Mineral reaction tower (when installed inside the mineral reaction tank)

8b: Mineral reaction tower (when installed outside the mineral reactor)

9: Pellet (Active Corrosive)

10: pumice 11: fulvic acid electrolytic water mineral complex salt storage tank

12: Fulvic acid electrolytic water mineral complex salt transfer pump

13: fulvic acid electrolytic water circulation pump

The characteristics and characteristics of the fulvic acid electrolyzed hydrochloride complex developed in the present invention are as follows.

Dacite-quality volcanic ash produced by marine fauna and flora such as marine diatoms, plankton, and seaweeds from the nearby Unzen active volcanoes in the Kago Wetlands of Nagasaki Prefecture, Japan. In the case of humus (peat) deposited by mixing with activated silicic acid and alumina component, hydrogen ions (H ⁺ ) are released by hydrolysis reaction with water to become strong acidity (pH = 2.0 ~ 2.5). It was oxidized in the form of peroxyfulvic acid by hydrogen peroxide (H ₂ O ₂ ) produced in the corrosive process while being induced in the glass state. It exists in the form of fulbrate-oxidized mineral complex salt which is almost the same as mineral complex salt, and it is also called active corrosive material.

The corrosive substance in which the fulvic acid is oxidized and activated in the form of mineral and complex salts has the following characteristics.

1) Corrosive microorganisms and microorganisms that convert organic matter into corrosive substances among soil microorganisms with a lot of minerals in the cell membrane or nucleus, while suppressing the growth of harmful microorganisms such as pathogenic microorganisms, which are protein membranes, and decayed and decaying microorganisms. Microorganisms in symbiotic relationship with most of them promote the growth of useful microorganisms, which are useful for growing animals and plants.

2) Peroxyfulvic acid, oxidized fulvic acid, plays a catalytic role in the reaction of corrosive organic materials to corrosive substances and suppresses odor.

Microorganisms involved in the corrosive reaction excrete polyphenol compounds as metabolites, and polyphenol compounds react with oxygen in the air by the catalysis of oxidase produced in fulvic acid oxidized water. It is oxidized to (Quinone) compound, which is ammonia (NH ₃ ), hydrogen sulfide (H ₂ S), volatile amine, volatile alcohol, volatile organic acid, mercaptan It is insoluble in water by the odor generating substance and the polycondensation reaction, and it is immobilized to a nonvolatile corrosion precursor. It has a function of suppressing the occurrence of odor.

3) It has the function of promoting the corrosive reaction of organic materials.

As organic substances are decomposed by corrosive microorganisms, polyphenol compounds excreted as metabolites should be oxidized to quinone compounds. Fulvic acid oxidized water has a function of oxidizing pulley phenol compounds to quinone compounds. Because it oxidizes quickly, polycondensation reaction with other organic materials promotes the formation of corrosive substances.

4) Excellent mineral supply function for growing animals and plants.

Since most minerals exist in the form of chelate mineral complex salts, it is easy to supply minerals not only to animals and plants but also to soil microorganisms.

As the mineral complex salt of folic acid is sprayed on the leaves or berries of soil or plant, the growth of corrosive microorganisms that actively metabolize when minerals are supplied sufficiently and the useful microorganisms which are mutually symbiotic with these microorganisms become active. Growth of harmful microorganisms, such as pathogenic microorganisms, which are antagonistic to microorganisms, and decaying microorganisms, is inhibited.

In order to achieve the above object in the present invention, a manufacturing method and a method of using the fulvic acid electrolytic water mineral complex salt will be described with reference to the accompanying drawings.

Caustic soda (NaOH) is added to peat formed by depositing marine animals and plants such as marine diatoms, plankton, and seaweeds with high fulvic acid content.Then, it is dissolved by heating and stirring to 80-90 ℃ at pH 14 and then insoluble Humin. ) Precipitate and remove the components.

When hydrochloric acid (HCl) is added to the dissolved solution and stirred under a pH of 2.5 or less, the humic acid solidifies and precipitates, and liquid fulvic acid is extracted.

The liquid fulvic acid is sent to the electrolytic oxidation tank (3), and a direct current is applied from the rectifier (6) to oxidize the redox potential (ORP) to + 1100mv or more.

At this time, the cathode (4) plate of the electrolytic oxidation tank (3) is made of a plated platinum electrode with a low hydrogen generation overvoltage, the positive electrode (5) is a titanium plate of high oxygen and chlorine generation overvoltage When electrolytic reaction is performed using a Dimmensionally Stable Anode (DSA) electrode coated with TiO ₂ -RuO ₂ -SnO ₂ , the electrolytic solution becomes an oxidizing atmosphere, and the liquid fulvic acid is oxidized to fulbric peroxide. .

The electrode reaction occurring at this time is as follows.

2H ₂ O 2H ^{+ +} 2OH ^- ----------------- ①

Cathodic reaction

_{^{2H + + 2e - → H 2}} (g) ↑ ----------------- ②

Anode reaction

_{^{2OH - → H 2 O + [}} O] ------------------ ③

Solution reaction

^{Cl - + [0] → ClO} - ------------------ ④

^{R - COOH + ClO - → R} -CO · OOH + Cl - ----------- ⑤

Fulvic Acid Peroxide

R-R-CO · OOH → → Oxidase -------------- ⑥

When fulvic acid is oxidized to fulbric peroxide by the above electrolytic reaction in electrolytic oxidation tank (3), luteum or large stone pumice (10), chelating mineral complex salt and other copper and Fulves in the form of mineral complex salts of fulbrate peroxide are sent to the mineral reaction tank (7) with the mineral reaction tower (8) filled with active corrosive pellets (9) filled with physiologically active substances in plant growth. An acid electrolytic oxidation mineral complex salt is prepared.

Mineral reaction tower (8a) is installed in the mineral reaction tank (7) to inject air into the bottom air-lifting (Air-Lifting) while the peroxide acid together with the pumice (10) layer and the active corrosion material pellets (9) layer While passing through the minerals to produce the peroxide mineral complex salt or the mineral reaction tower (8b) is installed outside the mineral reaction tank (7) and the fulvic acid electrolytic oxidation water circulation by the fulvic acid electrolytic oxidation water circulation pump (13) pumice ( 10) Passes the layer and the active corrosive pellet (9) layer and receives minerals to produce fulbrate peroxide mineral complex salt, fulbrate peroxide mineral complex.

When lateral vesicle electrolytic oxidation mineral complex salts are sprayed sideways with a dilute aqueous solution of 0.0006% to 0.06% on crops such as strawberries, cucumbers, peppers, rice, apples, and pears, the pathogenic microorganisms are sterilized and the pathogenic microorganisms interact with each other. As the growth of useful microorganisms that help to grow crops is active, there is a preventive effect against diseases.

Spraying 0.01% of aqueous solution of fulvic acid electrolytic oxidation mineral complex to the odor-prone barn or composting corrodes the metabolic activity of microorganisms that corrode organic substances and microorganisms in mutual symbiosis. The volatile odor generating material is immobilized to the inert corrosion precursor material and the odor generation is reduced. In the case of composting, the odor generation period is improved as well as the degree of erosion (Humification Grade) is improved. Compared to the general composting process, it is shortened to about 1/2 to 1/3.

In addition, when the fulvic acid electrolytic oxidized mineral complex salt is applied to the soil, it has a bacteriostatic effect, which can grow useful microorganisms in the soil, and improves the grain structure of the soil.

[Example 1]

When the Anthrax peppers were sprayed with 0.01% aqueous solution of fulvic acid electrolytic oxidized mineral complex salts on the side and in the soil, the spread of anthrax was suppressed, and the pepper was not sprayed once every two weeks. .

[Example 2]

No other pesticides were applied to apples, but the leaves and fruits were sprayed once every two weeks with 0.01% aqueous solution of Fulvic acid hydrochloric acid mineral complex.

[Example 3]

As the oxidation number of mineral complex salt to prenatal Full - the composting process and the piggery for swine as once or less as a result piggery is ammonia (NH ₃₎ concentration spray 2ppm an aqueous solution of 0.04% in 5 days was reduced odor, composted case odor As the incidence was reduced, the maturation period was shortened to around 95% of the degree of corrosion at around 25 days.

As is apparent from the above description, when spraying Fulvic hydrochloric acid mineral complexes on crops, the prevention and healing effect of the disease is excellent, and when the odor occurrence is severe, such as barn or compost, the odor is reduced. The environment is improved, and in the case of composting, the period of staying is shortened and the size of facilities is reduced, which can bring inexpensive facility costs.

In addition, when applied to the soil, it is expected to be widely used in these fields because it has bacteriostatic action and soil improvement effect.

Claims (4)

After treating alkali (alkali) to peat (hydrochloric acid), hydrochloric acid (HCl) is injected and treated to pH 2.5 or less, and the acidic fulvic acid solution extracted is injected into the electrolytic oxidation tank (3), and the direct current in the rectifier (6) Is applied to make pulvic acid electrolyzed water with peroxyfulvic acid with an ORP value of +1,110 mV or more, and it is used as an active corrosive pellet (9) and luteum rock A mineral reaction tower (8a) filled with a pumice stone of Dacite quality is installed inside the mineral reaction tank (7), and air is injected into the lower portion of the mineral reaction tower (8a). 9) Pulvic acid electrolytic oxidation cycle through the layer and pumice (10) layer or the mineral reaction tower (8b) filled with the active corrosion material pellet (9) and pumice (10) outside the mineral reaction tank (7) Passing through the active corrosive material pellets (9) layer and the pumice layer (10) filled in the mineral reaction tower (8b) by the pump (13) The method for producing oxidation mineral complexes Full - to receive prenatal supply of minerals (Minerals). A method of controlling pests by spraying fulvic acid electrolytically oxidized mineral complexes prepared by the method of claim 1 to leaves and fruits of crops. A method of spraying fulvic acid electrolytic water mineral complex prepared by the method of claim 1 to a barn or compost to reduce odor and improve the degree of corrosion. delete