KR100415943B1 - Process for synthetic leather having double-faced coating layers mixed with perfume and ceramic - Google Patents
Process for synthetic leather having double-faced coating layers mixed with perfume and ceramic Download PDFInfo
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- KR100415943B1 KR100415943B1 KR10-2001-0009496A KR20010009496A KR100415943B1 KR 100415943 B1 KR100415943 B1 KR 100415943B1 KR 20010009496 A KR20010009496 A KR 20010009496A KR 100415943 B1 KR100415943 B1 KR 100415943B1
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- leather
- roller
- polyurethane resin
- artificial
- fragrance
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0005—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
- D06N7/0039—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by the physical or chemical aspects of the layers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/904—Artificial leather
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
본 발명은 향료와 세라믹 혼합앙면코팅층으로된 인조피혁과 그 제조방법에 관한 것으로,The present invention relates to a synthetic leather and a manufacturing method of the fragrance and ceramic mixed face coating layer,
더욱, 상세하게는 인조피혁이면서 천연가죽과 같은 부드러움과 통기성을 유지하면서도 내구성이 월등하여 생산량을 많이 할 수 있으며 폴리우레탄수지에 원적외선을 방사하는 바이오 세라믹분말과 향료를 혼합하여준 도포층과 섬유포의 표면층사이에 형성된 미세 인조모공을 통하여 향기와 세라믹에 의하여 신진대사가 원활하게 이루어지게할 목적으로한 것이다.More specifically, it is an artificial leather, while maintaining the softness and breathability like natural leather, while being durable, it can produce a lot. Also, the coating layer and fiber cloth mixed with bio ceramic powder and fragrance that emit far infrared rays to polyurethane resin Through the artificial artificial pores formed between the surface layer is intended to facilitate the metabolism by fragrance and ceramics.
침적 후 탈수된 섬유포(1)의 앙면에 수용성 발포제와 향료 및 바이오 세라믹분말이 혼합된 폴리우레탄수지를 리버스로울러(7)(8)로 구성된 양면코팅장치에서 코팅한 코팅층을 형성하고 응고실에서 숙성 응고 후 세척, 탈수, 에어 건조, 열건조하는 제1공정과, 상기 인조피혁에 수용성 폴리우레탄 수지층(33)의 한쪽 표면에 텐숀조정로울러(23)와 리버스 두께조정 로울러(26)로 조절되는 리버스 로울러코팅(24)(25)에 수지공급통(27)의 수지를 한꺼번에 코팅하여 철망컨베이어(28)로된 열건조실(29)과 가죽무늬조각로울러(30)와 고무로울러(31)에서 표면층(35)에 가죽무늬모양을 압입 방법으로 각종 가죽무늬를 표현하는 가죽무늬모양을 제2공정의 결합으로 이루어짐을 특징으로한 향료와 세라믹 혼합 양면코팅층으로된 인조피혁과 그 제조방법과 같이 제조된 인조피혁은 수용성 폴리우레탄 수지의 노화현상으로 섬유포와 수지가 분리되는 현상이 발생되지 않으며 반영구적으로 사용할 수 있고 폴리우레탄 수지 내에 발포, 향료, 원적외선 바이오 세라믹 등의 첨가에 의하여 가죽냄새와는 다른 독특한 향기를 발생하고 원적외선 바이오 세라믹의 원적외선 방사로 인체의 혈행을 촉진하고 노화를 방지할 수 있는 효과와 함께 고가의 이형지 종이를 사용하지 않게 되므로 생산 원가를 절감할 수 있는 효과가 있고 피혁의 바닥부가 되는 섬유포를 폴리우레탄 수지가 감싸고 있어 부드러우면서 내구성이 뒤어난 인조피혁이다.After the deposition, the coating layer coated with a double-side coating device composed of reverse rollers (7) and (8) was formed on the face of the dehydrated fiber cloth (1) with a water-soluble foaming agent, a flavoring agent, and a bio ceramic powder. The first step of washing after coagulation, dehydration, air drying and heat drying, and the tension adjusting roller 23 and the reverse thickness adjusting roller 26 are adjusted to one surface of the water-soluble polyurethane resin layer 33 in the artificial leather. The surface layer in the heat drying chamber 29 and the leather pattern engraving roller 30 and the rubber roller engraving roller 31 made of a wire mesh conveyor 28 by coating the resin of the resin supply container 27 on the reverse roller coating 24 and 25 at once. (35) Artificial leather made of a double-sided coating layer and a mixture of perfume and ceramics, characterized in that the leather pattern is represented by the combination of the second process to express the various leather patterns by the method of indenting the leather pattern shape and the manufacturing method synthetic Leather does not separate fiber cloth and resin due to aging of water-soluble polyurethane resin, and it can be used semi-permanently, and by adding foam, fragrance, far-infrared bio ceramic, etc. Generated by the far-infrared radiation of the far-infrared bio-ceramic, which promotes blood circulation of the human body and prevents aging, and it does not use expensive release paper. It is a synthetic leather that is soft and durable because it is wrapped in polyurethane resin.
Description
본 발명은 향료와 세라믹 혼합앙면코팅층으로된 인조피혁과 그 제조방법에 관한 것으로,The present invention relates to a synthetic leather and a manufacturing method of the fragrance and ceramic mixed face coating layer,
더욱, 상세하게는 인조피혁이면서 천연가죽과 같은 부드러움과 통기성을 유지하면서도 내구성이 월등하여 생산량을 많이 할 수 있으며 폴리우레탄수지에 원적외선을 방사하는 바이오 세라믹분말과 향료를 혼합하여준 도포층과 섬유포의 표면층사이에 형성된 미세 인조모공을 통하여 향기와 세라믹에 의하여 신진대사가 원활하게 이루어지게할 목적으로한 것이다.More specifically, it is an artificial leather, while maintaining the softness and breathability like natural leather, while being durable, it can produce a lot. Also, the coating layer and fiber cloth mixed with bio ceramic powder and fragrance that emit far infrared rays to polyurethane resin Through the artificial artificial pores formed between the surface layer is intended to facilitate the metabolism by fragrance and ceramics.
일반적으로 종래에는 인조피혁의 바닥부가 되는 부직포 또는 섬유포의 한 쪽 표면에 수용성 폴리우레탄 수지를 나이프코팅하여 1차 인조피혁층을 형성한 다음 피혁 무늬가 형성되어 있는 이형지종이 위에 폴리우레탄 수지를 코팅하여 전사용 시트를 만들어 1차 섬유포위에 코팅한 것과 전사방식으로 접합한 다음 이를 응고실에서 침수하여 폴리우레탄 수지를 응고시켜 세척한 다음 이형지 종이를 제거하고 건조하여 표면에는 피혁무늬 피막이 표현되고 그 하위에는 섬유포와 폴리우레탄 수지가 결합되어 섬유층이 일체로 형성된 인조피혁을 만들었다.In general, a conventional artificial leather layer is formed by knife coating a water-soluble polyurethane resin on one surface of a nonwoven fabric or a textile fabric that is a bottom part of artificial leather, and then a polyurethane resin is coated on a release paper on which a leather pattern is formed. After making the transfer sheet and coating it on the primary fiber cloth and bonding it by transfer method, it is immersed in the coagulation room to coagulate and wash the polyurethane resin, then remove the release paper paper and dry to express the leather pattern film on the surface. The fiber cloth and the polyurethane resin are combined to create an artificial leather in which the fiber layer is integrally formed.
이상과 같이 이형지종이를 사용하여 생산되는 인조피혁의 문제점으로는,As a problem of the artificial leather produced using the release paper as described above,
첫째, 이형지 종이, 폴리우레탄 수지, 섬유포 3종류를 접합한 것을 응고실에서 침수 세척하므로 이 과정에서 이형지 종이쪽으로는 발포시 가스와 용제가 빠져나가지 못하고 섬유포 쪽으로만 빠져나가기 때문에 통기성이 없고 세척시 용제가 세척이 잘되지 않아 완제품 후 상품이 변질될 우려가 있고 폴리우레탄 수지가 빨리 노화현상이 생기는 문제점이 있다.First, it is immersed and washed in the coagulation room by bonding three types of release paper, polyurethane resin and fiber cloth. In this process, gas and solvent do not escape to the release paper side, but only the fiber cloth. There is a possibility that the product is deteriorated after the finished product is not washed well and the polyurethane resin is quickly aging phenomenon.
둘째, 이형지 종이가 소모품이므로 생산 원가가 상승됨.Second, since release paper is a consumable, production costs will rise.
셋째, 응고와 세척 탈수시 용제가 완전히 빠져나가지 못하여 인조피혁이 부드럽지 못할 뿐만 아니라 오래 사용하면 섬유포와 폴리우레탄 수지가 분리되는 문제가 발생하며 빨리 마모되는 등의 결점이 있었다.Third, when the solidification and washing and dehydration, the solvent is not completely escaped, the artificial leather is not soft, and if used for a long time, there is a problem that the fiber cloth and the polyurethane resin is separated and wears quickly.
본 발명에서는 상기한 종래의 문제점을 해결하기 위하여 섬유포를 코팅할 경우 좌, 우 폭이 줄거나 상, 하 길이가 길어지는 문제를 해결하지 못하여 이형지 종이를 사용하여 종이 위에 폴리우레탄 수지를 도포한 다음 코팅된 섬유포와 접합하여 전사하는 방법을 사용하고 있으며,In the present invention, in order to solve the above-mentioned problems, when the fiber cloth is coated, the left and right widths are reduced or the upper and lower lengths are not solved. Thus, the polyurethane resin is applied onto the paper using a release paper. It uses a method of bonding and transferring the coated fiber cloth,
또는 로울러를 통하여 나이프 코팅을 하는 방법도 있는데 이 또한 섬유포의 좌, 우와 상, 하 가 줄거나 길어지는 문제가 발생하므로 나이프 코팅 시 두께가 일정치 못하여 본 발명에서는 섬유포 코팅시 텐숀 조정장치를 잘 조정하여 좌,우 폭과 상, 하 길이가 변동이 없도록 한 다음 1차 리버스 코팅 장치로 양면을 정량 코팅을 하여 폴리우레탄 수지의 중간에 섬유포를 감싸는 역할을 하여 응고, 세척, 탈수, 열건조 후, 2차에서 한쪽 면을 리버스 로울러 코팅을 한 다음 열건조한 후 가죽무늬조각 로울러를 압입하는 방법으로 본 발명 목적에 대응하는 각종 가죽무늬가 표현된 인조피혁을 얻게한 것이다.Or there is also a method of coating the knife through the roller, which also causes a problem that the left, right, top, bottom of the fabric cloth is reduced or longer, so the thickness is not constant when coating the knife in the present invention, the tension adjustment device is well adjusted in the coating fabric After the left, right width and the upper and lower lengths to be unchanged, and then quantitatively coated on both sides with the first reverse coating device to wrap the fiber cloth in the middle of the polyurethane resin to solidify, wash, dehydrate, heat dry, By applying a reverse roller coating on one side in the secondary and then heat-drying, the artificial leather is obtained by expressing various leather patterns corresponding to the object of the present invention by press-fitting the leather pattern engraving roller.
도1은 본발명의 제1공정도1 is a first process diagram of the present invention.
도2는 본발명의 제2공정도2 is a second process diagram of the present invention.
도3은 본발명의 인조피혁 예시도Figure 3 is an illustration of artificial leather of the present invention
도4는 본발명의 인조피혁 확대예시 단면도Figure 4 is an enlarged cross-sectional view of artificial leather of the present invention
*도면의 주요 부분에 대한 부호 설명** Description of symbols on the main parts of the drawings *
1 : 섬유포 2 : 수조통1: fiber cloth 2: water tank
3 : 탈수로울러 4 : 바나나로울러3: dehydration roller 4: banana roller
5 : 1차텐숀조정로울러 6 : 가이드로울러5: 1st tension adjustment roller 6: Guide roller
7 : 리버스로울러 8 : 리버스로울러7: Reverse Roller 8: Reverse Roller
9 : 수지공급통 11 : 응고실9: resin supply container 11: solidification chamber
12 : 2차텐숀조정로울러 15 : 세척실12: 2nd tension adjustment roller 15: washing room
18 : 탈수로울러 19 : 에어건조장치18: dehydration roller 19: air drying device
20 : 열건조실 23 : 3차텐숀조정로울러20: heat drying chamber 23: 3rd tension adjustment roller
24, 25 : 2차리버스로울러 26 : 리버스두께조정로울러24, 25: 2nd reverse roller 26: Reverse thickness adjustment roller
27 : 2차수지공급통27: secondary resin supply container
28 : 철망컨베이어 29 : 열건조실28: wire mesh conveyor 29: heat drying room
30 : 가죽무늬조각로울러 31 : 고무로울러30: leather pattern engraving roller 31: rubber roller
32 : 인조피혁 33 : 폴리우레탄수지층32: artificial leather 33: polyurethane resin layer
34 : 인조피혁수지층 35 : 표면층34: artificial leather resin layer 35: surface layer
36 : 미세 인조모공 38 : 세라믹36: fine artificial pores 38: ceramic
37 : 각종향료37: Various Spices
본발명을 첨부도면에 의하여 공정별로 상세히 설명하면 다음과 같다.Referring to the present invention in detail by process according to the accompanying drawings as follows.
제1공정, 1st process
도1의 예시와 같이 부직포나 섬유포(1)를 수조통(2)에 침수되게 통과시킨 후 탈수로울러(3)에서 탈수하여 각종향료(37)와 원적외선 바이오 세라믹(38)이 혼합된 폴리우레탄수지의 침투를 조절할 수 있게하여 가이드로울러(6)와 1차 텐숀조정로울러(5)를 잘 조정하여 좌, 우 폭과 상, 하 길이의 변동이 없도록 바나나로울러(4)로지지하여준 다음 양쪽의 수지공급통(9)과 리버스로울러(7)(8)로 구성된 코팅장치로 양면을 정량 코팅을 하여 폴리우레탄 수지층(33)의 중간에 섬유포(1)를 감싸는 역할을 한 다음 피혁의 몸체가 되는 인조피혁 수지층을 형성하고 이를 2차 텐숀조정로울러(12)와 저온수가 담겨있는 응고실(11)을 서서히 통과하는 동안 응고되면서 친수성이 강한 수용성의 폴리우레탄층의 용제가 녹아 나온 후 세척실(15)에서 세척한 다음 탈수로울러(18)에서 탈수후 에어건조장치(19)와 열건조실(20)을 통과하면서 발포약으로부터 가스가 발생하여 미세 구멍이 생기며 폴리우레탄 수지가 섬유포(1)속을 통과하여 응고되도록 한다.As shown in FIG. 1, the nonwoven fabric or fiber cloth 1 is immersed in the water tank 2, and then dehydrated in the dehydration roller 3 to mix various perfumes 37 and far-infrared bio ceramics 38. The guide roller (6) and the primary tension adjustment roller (5) can be adjusted well so that the penetration of the roller can be controlled by the banana roller (4) so that there are no fluctuations in the left, right width, up and down length. A coating device consisting of a supply container (9) and a reverse roller (7) (8) performs quantitative coating on both sides to wrap the fiber cloth (1) in the middle of the polyurethane resin layer (33), and then becomes a body of leather. After forming the artificial leather resin layer and solidifying it slowly through the secondary tension adjusting roller 12 and the coagulation chamber 11 containing the low temperature water, the solvent of the hydrophilic water-soluble polyurethane layer melted, and then the washing chamber ( 15) and then from the dehydration roller (18) Suhu while passing through the air drying device 19 and the heat drying chamber 20 Ie, the fine holes by a gas generated from the foaming around so that the polyurethane resin is solidified to pass through the inside of seomyupo (1).
제2공정, Second process ,
도2의 제2공정도와 같이 섬유포(1)의 양면에 상기 제1공정을 거쳐 양면에 수용성 폴리우레탄수지용액으로된 폴리우레탄수지층이 도포된 인조피혁의 폴리우레탄 수지층(33)의 한쪽 표면에 3차텐숀조정로울러(23)에 의하여 연동되는 리버스로울러(24)(25)로 구성된 코팅기계의 리버스두께조정로울러(26)를 조정하여 두께를 맞춘 후 각종향료(37)와 원적외선바이오 세라믹(38)분말과 수용성용제에 발포약이 혼합된 폴리우레탄수지를 2차 수지공급통(27)에서 한꺼번에 코팅한 다음 철망컨베이어(28)위에 코팅된 섬유포가 올려진 상태로 열건조실(29)을 통과하면서 나온 인조피혁수지층(34)에는 발포약이 열을 받으면서 가스를 발생하여 미세 인조모공(36)을 형성하고 가죽무늬조각로울러(30), 고무로울러(31)를 압입 방법으로 통과하여 표면층(35)위에 각종 가죽무늬를 표현한다.One surface of the polyurethane resin layer 33 of artificial leather having a polyurethane resin layer made of a water-soluble polyurethane resin solution coated on both sides of the fiber cloth 1 as shown in the second process diagram of FIG. After adjusting the thickness of the reverse thickness adjusting roller (26) of the coating machine consisting of reverse rollers (24) and (25) interlocked by the third tension adjusting roller (23), various flavors (37) and far-infrared bio ceramics ( 38) Coating the polyurethane resin mixed with the powder and the water-soluble solvent in the secondary resin supply container (27) at once, and then pass through the heat-drying chamber (29) with the coated fiber cloth on the wire mesh conveyor (28). The artificial leather resin layer 34, which is released while generating a gas while the foaming agent receives heat, forms fine artificial pores 36 and passes through the leather pattern engraving roller 30 and the rubber roller 31 by a press-in method. 35) Various leather patterns on The prefecture.
이와같이 만들어진 인조피혁은 그 용도에 따라 왁스, 보강제 스프레이 등과 같은 끝손질을 선택적으로 실시한다.The artificial leather thus produced is selectively subjected to finishing such as wax, reinforcing agent spray, etc. according to the use thereof.
상기 공정에 의하여 제조된 본 발명 인조피혁은 도3과 도4의 예시와 같이 섬유층(1), 인조피혁양면코팅수용성 폴리우레탄 수지층(33), 인조피혁수지층(34), 표면층(35), 미세 인조모공(36), 각종향료(37), 세라믹(38)으로 구성되어 있다.The artificial leather of the present invention manufactured by the above process is a fiber layer (1), artificial leather double-coated water-soluble polyurethane resin layer (33), artificial leather resin layer (34), surface layer (35) as shown in Figures 3 and 4 , Fine artificial pores 36, various perfumes 37, and ceramics 38.
이상과 같이 제조된 인조피혁은 수용성 폴리우레탄 수지의 노화현상으로 섬유포와 수지가 분리되는 현상이 발생되지 않으며 반영구적으로 사용할 수 있고 폴리우레탄 수지 내에 발포, 향료, 원적외선 바이오 세라믹 등의 첨가에 의하여 가죽냄새와는 다른 독특한 향기를 발생하고 원적외선 바이오 세라믹의 원적외선 방사로 인체의 혈행을 촉진하고 노화를 방지할 수 있는 효과와 함께 고가의 이형지 종이를 사용하지 않게 되므로 생산 원가를 절감할 수 있는 효과가 있고 피혁의 바닥부가 되는 섬유포를 폴리우레탄 수지가 감싸고 있어 부드러우면서 내구성이 뒤어난 인조피혁이다.The artificial leather manufactured as described above can be used semi-permanently due to the aging phenomenon of water-soluble polyurethane resin, which does not cause separation of fiber cloth and resin, and can be used in the polyurethane resin by adding foam, perfume, far-infrared bio ceramic, etc. It produces a unique scent that is different from that of far-infrared bio-ceramic, which promotes blood circulation and prevents aging of the human body, and does not use expensive release paper. It is a soft, durable artificial leather with a polyurethane resin wrapped around the fabric of the fabric.
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KR100402910B1 (en) * | 2001-05-08 | 2003-10-22 | 서상우 | Fragnance Slow-Releasing Artificial Leather and Preparing Method Thereof |
KR101519737B1 (en) | 2013-11-21 | 2015-05-12 | 현대자동차주식회사 | Method for removing smell of an artificial leather and the artificial leather using thereof |
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