KR100412148B1 - The Boric Acid Ware Manutacture With iS Poredpottory Omtibacteria And Zinc Oxide - Google Patents

The Boric Acid Ware Manutacture With iS Poredpottory Omtibacteria And Zinc Oxide Download PDF

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KR100412148B1
KR100412148B1 KR10-2001-0051208A KR20010051208A KR100412148B1 KR 100412148 B1 KR100412148 B1 KR 100412148B1 KR 20010051208 A KR20010051208 A KR 20010051208A KR 100412148 B1 KR100412148 B1 KR 100412148B1
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antimicrobial
boric acid
zinc oxide
silver
ceramics
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이광덕
최명부
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5006Boron compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/60Agents for protection against chemical, physical or biological attack
    • C04B2103/67Biocides
    • C04B2103/69Fungicides

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  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

본 발명은 항균 도자기 및 그 제조방법에 관한 것으로, 더욱 구체적으로는 항균성이 우수하고 고온에서도 물성이 변하지 않는 안정성을 가진 붕산 및 산화아연과 은을 이용하여 항균 도자기를 제공할 수 있도록 한 것이다.The present invention relates to an antimicrobial ceramics and a method of manufacturing the same, and more particularly, to provide an antimicrobial ceramics using boric acid, zinc oxide, and silver having excellent antibacterial properties and stability that does not change even at high temperatures.

즉, 붕산 500g을 물 1,000㎖에 용해하는 공정과, 상기 붕산용액을 은고형분이 50% 함유된 은콜로이드용액 100㎖에 합성하는 공정과, 상기 공정의 합성용액을 산화아연 2,000g에 합성하여 반고체장으로 치환하는 공정과, 상기 반고체장을 건조 및 미세분쇄하여 만든 항균제분말제조공정과, 상기 항균제 분말을 도자기유약에 10~25중량% 비율로 합성하여 만든 항균제유약을 도자기에 입히고 소성하여서 된 항균도자기 제조방법이다.That is, a process of dissolving 500 g of boric acid in 1,000 ml of water, a step of synthesizing the boric acid solution into 100 ml of a silver colloidal solution containing 50% of silver solid, and a synthetic solution of the above step into 2,000 g of zinc oxide Antimicrobial agent manufacturing process by substituting the antimicrobial agent powder by the process of substituting the intestine, drying and grinding the semi-solid length, and synthesizing the antimicrobial powder in the ceramic glaze at a ratio of 10 to 25% by weight. It is a pottery manufacturing method.

Description

항균 도자기 및 그 제조방법{The Boric Acid Ware Manutacture With iS Poredpottory Omtibacteria And Zinc Oxide}Antibacterial ceramics and its manufacturing method {The Boric Acid Ware Manutacture With iS Poredpottory Omtibacteria And Zinc Oxide}

본 발명은 항균 도자기 및 그 제조방법에 관한 것으로, 더욱 구체적으로는 항균성이 우수하고 고온에서도 물성이 변하지 않는 안정성을 가진 붕산 및 산화아연과 은을 이용하여 항균 도자기를 제공할 수 있도록 한 것이다.The present invention relates to an antimicrobial ceramics and a method of manufacturing the same, and more particularly, to provide an antimicrobial ceramics using boric acid, zinc oxide, and silver having excellent antibacterial properties and stability that does not change even at high temperatures.

일반적으로 직물, 플라스틱, 종이등의 각종 생활용품에는 항균제를 이용하여 만든 항균기능을 가진 제품들이 널리 사용되고 있으나 음식물을 담는 식기류 및 각종 은자기류(화장실변기, 목욕탕의 타일등)와 같은 제품에는 항균처리를 할 수 없었기 때문에 많은 병원균이 서식하고 있는 실정이다.Generally, products with antimicrobial function made by using antibacterial agent are widely used in various household goods such as textiles, plastics and paper, but antibacterial treatment for products such as tableware and various silverware (toilet toilet, bathroom tiles, etc.) containing food Many pathogens are inhabited because they could not.

즉, 도자기의 경우에는 1300℃이상의 높은 온도에서 소성되기 때문에 상기의 일반 항균제를 이용한 항균처리시에는 도자기를 고온에서 소성하는 과정에서 항균제가 타거나 물성이 변하게되어 항균처리를 할 수 없었다.That is, in the case of porcelain, because it is fired at a high temperature of 1300 ℃ or more, when the antimicrobial treatment using the general antimicrobial agent in the process of baking the porcelain at a high temperature, the antibacterial agent burned or the physical properties were changed to prevent the antibacterial treatment.

본 발명은 이러한 문제점을 해결하기 위하여 항균성이 우수하고 고온에서도 물성이 변하지 않는 안정성을 가진 붕산 및 산화아연, 은을 이용하여 항균처리하되 붕산을 물에 용해하고 상기 붕산용액을 은콜로이드용액과 합성하며 이어서 상기 합성용액을 산화아연에 합성하여 반고체장으로 치환하고 이를 건조 및 미세분쇄공정에서 항균제분말을 만들고 항균제분말을 도자기유약에 합성교반시켜서 된 항균제유약을 도자기에 입히고 소성하는 고정으로 항균도자기에 제조할 수 있게 한 것이다.In order to solve this problem, the present invention is an antibacterial treatment using boric acid, zinc oxide and silver having excellent antibacterial properties and stability that does not change even at high temperature, but dissolves boric acid in water and synthesizes the boric acid solution with a silver colloidal solution. Subsequently, the synthetic solution was synthesized in zinc oxide and replaced with a semi-solid length. The antimicrobial powder was then prepared by drying and pulverizing the antimicrobial powder. It was made possible.

본 발명의 항균도자기는 항균성이 우수하고 고온에서도 물성이 변하지 않는 안정성을 가진 붕산 및 산화아연과 은을 이용하여 제조한다.The antimicrobial ceramics of the present invention are prepared using boric acid, zinc oxide, and silver having excellent antibacterial properties and stable properties that do not change even at high temperatures.

붕산(boricacid)은, 살균효과와 방부효과를 갖고 있으며 무색, 광택 있는 인편의 결정 분말로서 물에 가용되나 160℃이상의 온도에는 피로붕산(H2B2O7)로 되고 고온에서는 무수붕산(B2O3)로되어 도자기가 1300℃이상의 높은 온도에서 소성되는 과정에서도 타거나 그 물성이 변하지 않기 때문에 사용되었다.Boric acid, a bactericidal and antiseptic effect, is a colorless, glossy flake powder that is soluble in water, but becomes pyroboric acid (H 2 B 2 O 7 ) at temperatures above 160 ° C and boric anhydride (B) at high temperatures. 2 O 3 ) was used because it does not burn or change its physical properties even when the ceramics are fired at a high temperature of more than 1300 ℃.

산화아연은; 일명 아연화(zinc oxide)라고도 하며, 은 다음으로 항균성이 우수하고 안정성이 높다. 이러한 산화아연은 백색분말로서 가열하면 황색이 되고 냉각되면 다시 백색으로 복색되는 성질이 있고 비중은 5.47 ~ 5.61, 융점은 1800℃로서 착색력이 우수하고 물에 불용하고 탄산가스를 흡착하는 성질이 있으며, 1800℃의 높은 융점을 가지고 있어 도자기가 1300℃이상의 높은 온도에서 고온에서는 물성이 변하지 않고 안정성을 같기 때문에 사용하였다.Zinc oxide; Also known as zinc oxide (zinc oxide), silver is next to the excellent antibacterial and high stability. The zinc oxide is white powder, yellow when heated, and becomes white again when cooled. Specific gravity is 5.47 ~ 5.61, melting point is 1800 ℃, excellent in coloring power, insoluble in water and adsorbing carbon dioxide gas. It has a high melting point of 1800 ℃, so ceramics are used at high temperature above 1300 ℃ because their physical properties do not change and their stability is the same.

은은; 항균성 및 안정성이 높아 항균제로서 널리 사용되고 있는 것으로, 이러한 은이 함유된 은콜로이드용액을 붕산과 합성하고 이를 산화아연에 치환시켜 산화아연의 항균성을 크게 높이기 위해 사용하였다.Silver; It is widely used as an antimicrobial agent because of its high antimicrobial activity and stability. The silver colloidal solution containing silver was synthesized with boric acid and substituted with zinc oxide, thereby greatly improving the antimicrobial activity of zinc oxide.

상기와 같은 항균제를 이용한 본 발명의 항균 도자기 제조방법은,Antibacterial ceramic production method of the present invention using the antimicrobial agent as described above,

붕산 500g을 물 1,000㎖에 용해하는 붕산용해공정과, 상기 붕산용액을 은고형분이 50%함유된 은콜로이드용액 100㎖에 합성하는 붕산용액 및 은콜로이드용액 합성공정과,A boric acid dissolution step of dissolving 500 g of boric acid in 1,000 ml of water, a process of synthesizing the boric acid solution and silver colloidal solution for synthesizing the boric acid solution into 100 ml of a silver colloidal solution containing 50% silver solids;

상기 고정의 합성용액을 산화아연 2,000g과 합성하여 반고체장으로 만드는 반고체 치환공정과, 상기 반고체장을 건조 및 미세분쇄하여 만든 항균제분말제조공정과, 상기 항균제분말을 도자기유약에 10~25중량%비율로 합성교반하여서 된 항균제유약을 도자기에 입히고 이를 소성하여 항균도자기를 제조한다.Semi-solid substitution process of synthesizing the fixed synthetic solution with 2,000 g of zinc oxide to make a semi-solid length, antimicrobial powder manufacturing process made by drying and grinding the semi-solid length, and the antimicrobial powder 10 to 25% by weight in ceramic glaze Antibacterial glaze obtained by synthetic stirring at a ratio is coated on ceramics and fired to manufacture antimicrobial ceramics.

이와같이 제조하는 본 고안의 항균도자기 제조실시예는 다음과 같다.The antimicrobial ceramic preparation example of the present invention manufactured as described above is as follows.

(실시예)(Example)

- 항균제 분말제조 --Antibacterial Powder Manufacturing-

제 1 단계First step

붕산 500g을 물 1000㎖에 용해시켜 붕산용액을 만든다.500 g of boric acid is dissolved in 1000 ml of water to form a boric acid solution.

제 2 단계2nd step

상기 붕산용액을 은 고형분일 50%함유된 은콜로이드용액 100㎖를 준비한다.100 ml of a silver colloidal solution containing 50% of the solid content of the boric acid solution is prepared.

제 3 단계3rd step

상기 제1단계의 붕산용액과 제2단계의 은 콜로이드용액을 합성하여 골고루 교반한다.The boric acid solution of the first step and the silver colloidal solution of the second step are synthesized and stirred evenly.

제 4 단계4th step

상기 3단계의 합성용앨을 산화아연 2,000g과 합성하여 반고체장을 만든다.Synthesizing the three phases of the synthesis solution with 2,000 g of zinc oxide to create a semi-solid length.

제 5 단계5th step

상기 4단계를 거친 반고체장을 간이 건조기를 이용하여 100의 온도에서 가열 건조시킨다.The semi-solid length that passed through the four steps is heated and dried at a temperature of 100 using a simple dryer.

제 6 단계6th step

상기 5단계의 가열건조 및 반고체장을 분쇄기를 용해 미세분쇄하여 항균제분말을 제조한다.- 도자기 제조 -제 1 단계상기의 항균제분말 500g을 도자기 유약 1,000㎖에 넣고 이를 골고루 교반하여 용해시킨 항균제유약을 만든다.제 2 단계도자기 또는 각종 도자기류를 제1단계의 항균제 유약에 침지시킨 다음 이를 건조시킨다.제 3 단계제2단계에 의하여 항균제 유약이 발라져 있는 도자기를 가마에 넣고 소성가공하여 항균 도자기를 제조한다.이러한 본 발명의 항균도자기는 도자기 표면에 있는 붕산, 산화아연, 은의 항균기능에 의해서 갖게되어 녹초균, 대장균, 농농균등이 항균되었다.Disintegrating and grinding the five stages of heat drying and semi-solid length to prepare an antimicrobial powder.-Manufacture of porcelain-Step 1 Put 500 g of the antimicrobial powder in porcelain glaze into 1000 ml of porcelain glaze and stir it to dissolve it. The second step ceramics or various ceramics are immersed in the antimicrobial glaze of the first stage and then dried.The third step, pottery coated with the antimicrobial glaze in the second stage is put into a kiln and plasticized to produce antimicrobial ceramics. The antimicrobial ceramics of the present invention have the antimicrobial functions of boric acid, zinc oxide, and silver on the surface of porcelain, which prevents mycelial bacteria, Escherichia coli, and agrobacteria.

이와같이 본 발명은 항균성이 우수하고 고온에서도 물성이 변하지 않으며 안정성을 가진 붕산 및 산화아연과 은을 이용하여 항균도자기를 제조할 수 있게 되므로 이러한 항균도자기는 일반적인 음식을 담는 각종 식기뿐만 아니라 각종 병균들이 서식하고 위생상태가 좋지 않은 화장실 변기 및 목욕탕의 타일과 같은 각종 도자기류에 적용하여 매우 위생적으로 사용할 수 있는 이점이 있다.As described above, the present invention is excellent in antimicrobial properties and does not change even at high temperatures, and thus it is possible to manufacture antimicrobial ceramics using boric acid, zinc oxide and silver having stability. Such antimicrobial ceramics are inhabited by various germs as well as various tableware containing general food. And it is very hygienic can be used to apply to various ceramics, such as bathroom toilet bowl and bathroom tiles are not good hygiene.

Claims (2)

붕산 500g을 물 1,000㎖에 용해하는 공정과, 상기 붕산용액을 은고형분이 50% 함유된 은콜로이드용액 100㎖에 합성하는 공정과, 상기 공정의 합성용액을 산화아연 2,000g에 합성하여 반고체장으로 치환하는 공정과, 상기 반고체장을 건조 및 미세분쇄하여 만든 항균제분말제조공정과, 상기 항균제분말을 도자기유약에 10~25중량% 비율로 합성하여 만든 항균제유약을 도자기에 입히고 소성하여서 된 항균도자기 제조방법.Dissolving 500 g of boric acid in 1,000 ml of water; synthesizing the boric acid solution in 100 ml of silver colloidal solution containing 50% of silver solid; Substituting process, antimicrobial powder manufacturing process made by drying and grinding the semi-solid length, antimicrobial glaze produced by synthesizing the antimicrobial powder in the ceramic glaze at a ratio of 10 to 25% by weight in ceramics and firing Way. 제 1항의 제조방법에 의해 도자기 표면에 항균성을 갖도록한 항균도자기.An antimicrobial ceramic having antimicrobial properties on the surface of porcelain by the manufacturing method of claim 1.
KR10-2001-0051208A 2001-08-21 2001-08-21 The Boric Acid Ware Manutacture With iS Poredpottory Omtibacteria And Zinc Oxide KR100412148B1 (en)

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