KR100387422B1 - Soluble liquid electric mosquito-repellent solution - Google Patents
Soluble liquid electric mosquito-repellent solution Download PDFInfo
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- KR100387422B1 KR100387422B1 KR10-1999-0044505A KR19990044505A KR100387422B1 KR 100387422 B1 KR100387422 B1 KR 100387422B1 KR 19990044505 A KR19990044505 A KR 19990044505A KR 100387422 B1 KR100387422 B1 KR 100387422B1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/20—Poisoning, narcotising, or burning insects
- A01M1/2022—Poisoning or narcotising insects by vaporising an insecticide
- A01M1/2061—Poisoning or narcotising insects by vaporising an insecticide using a heat source
- A01M1/2066—Poisoning or narcotising insects by vaporising an insecticide using a heat source burning insecticide, e.g. impregnated candles, burning coils
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M13/00—Fumigators; Apparatus for distributing gases
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/20—Combustible or heat-generating compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M2200/00—Kind of animal
- A01M2200/01—Insects
- A01M2200/012—Flying insects
Abstract
본 발명은 용기에 충진 되어 있는 살충약제를 다공성 흡액심지를 통하여 상승시킨 다음 가열 증발시켜 위생해충을 살충하는 전기 훈증 살충용 모기향액에 있어서, 비이온성 계면활성제를 사용하여 제조한 수용성 액체전자 모기향액을 제공한다. 본 발명에 따른 모기향액은 휘발성 유기용제를 사용하지 않는 수용성이어서 사용시 화재의 위험이 없고 넓은 공간에서도 안전하게 사용할 수 있다.The present invention is a water-soluble liquid electronic mosquito repellent prepared by using a nonionic surfactant in the mosquito repellent for electric fumigation insecticide which raises the insecticide filled in the container through the porous absorbent wick and then heats and evaporates to kill hygienic pests. To provide. The mosquito repellent liquid according to the present invention is water-soluble without using a volatile organic solvent, so there is no risk of fire in use and can be safely used in a wide space.
Description
본 발명은 비이온성 계면활성제를 사용하여 제조한 수용성 액체 전자 모기향액에 관한 것이다. 보다 상세히 하면, 본 발명은 용기에 충진 되어 있는 살충약제를 다공성 흡액심지를 통하여 상승시킨 다음 가열 증발시켜 위생해충을 살충하는 전기 훈증 살충제 모기향액에 관한 것으로 수용성 모기향액을 제공함으로써 기존의 휘발성 유기용제를 사용하는 제품보다 넓은 공간에서 안전하게 사용할 수 있도록 된 액체 전자 모기향액에 관한 것이다.The present invention relates to a water-soluble liquid electronic mosquito repellent liquid prepared using a nonionic surfactant. More specifically, the present invention relates to an electrically fumigated insecticide mosquito repellent solution that kills hygienic pests by raising the pesticides filled in the container through a porous absorbent wick and then heating and evaporating them to provide a water-soluble mosquito repellent solution. The present invention relates to a liquid electronic mosquito repellent liquid that can be used safely in a larger space than a product using
또한 종래에는 30일 내지는 45일간 사용하도록 고안이 되어 있었던 것을 본 발명의 모기향액을 사용함으로써 60일, 90일 또는 120일 까지도 사용이 가능하게 하였다.In addition, it was possible to use up to 60 days, 90 days or 120 days by using the mosquito repellent liquid of the present invention, which was designed to be used for 30 days to 45 days.
기존의 전기 훈증 살충 장치는 10∼15㎡ 정도의 작은 공간에서 사용 하는 가정용으로 고안되었기 때문에 레스토랑, 사무실, 학교, 병원, 공장이나 대형 상가 같은 넓은 공간에서는 기존의 전기 훈증 살충 장치로는 약효를 발휘하지 못하므로 레스토랑, 사무실, 학교, 병원, 공장이나 대형 상가 같은 넓은 공간에서 사용할 수있는 전기 훈증 살충 장치가 필요하게 되었다.Since the existing electric fumigation insecticide is designed for home use in a small space of about 10 to 15㎡, it is effective as a conventional electric fumigation insecticide device in a large space such as a restaurant, office, school, hospital, factory or large shopping mall. The need for electric fumigation insecticides for large spaces such as restaurants, offices, schools, hospitals, factories or large malls has been needed.
기존의 전기 훈증 살충 장치로 넓은 공간에서 사용하기 위하여는 너무 많은 전기 훈증 살충 장치가 요구되고 그에 따르는 구입비용의 부담과 전력 소비량도 늘어나는 이중의 부담과 많은 전기 훈증 살충 장치의 설치로 미관상 좋지 않은 점 등으로 말미암아 사용이 적합하지 않았다.Existing electric fumigation insecticides require a lot of electric fumigation insecticides to be used in a large space, resulting in a double burden of increasing the cost of purchasing and power consumption, and the unfavorable appearance of many electric fumigation insecticides. It is not suitable for use due to the back.
본 발명은 상기와 같은 문제점을 해결하기 위한 것으로 50∼300㎡정도의 넓은 공간에서 하나의 전기 훈증 살충 장치만으로도 모기 등 해충 구제의 효과를 제공할 수 있도록 개선함으로써 경제적 부담과 사용상의 불편을 최소화하고자 발명된 것으로서, 종래의 전기 훈증 살충 장치들은 휘발성 유기 용제들을 사용함으로써 부주의로 인한 화제의 위험성을 갖고 있었는 데 대하여, 본 발명에 따라서 비이온성 계면활성제를 사용하여 제조한 살충제 조성물은 화제의 위험이 없는 안전한 모기향액 조성물이 제공된다.The present invention is to solve the problems described above to minimize the economic burden and inconvenience in use by improving to provide the effect of pest control such as mosquitoes with only one electric fumigation insecticide device in a large space of about 50 ~ 300㎡ As invented, conventional electric fumigation insecticide devices have the risk of inadvertent topicality by using volatile organic solvents, whereas the pesticide compositions prepared using nonionic surfactants according to the present invention have no risk of topicality. Safe mosquito repellent compositions are provided.
본 발명의 수성 모기향액은 하기의 계면활성제를 함유하며, 피레스로이드계 화합물, 살균제, 기피제, 효력증강제, 색소, 향료 등을 유기용제에 첨가하여 제조된다.The aqueous mosquito repellent liquid of the present invention contains the following surfactant, and is prepared by adding a pyrethroid-based compound, a bactericide, a repellent, a potentiator, a dye, a perfume, and the like to an organic solvent.
본 발명에 사용된 계면활성제들로써는 다음 구조식 (1)의 비이온성 계면활성제인 폴리옥시 알킬렌알킬 에테르계 화합물과 구조식 (2)의 폴리옥시 알킬렌알킬 페닐 에테르계 화합물(2)와 아래의 일반식 (3)을 갖는 폴리옥시 에틸렌 지방산 에스테르계 화합물이 사용될 수 있으며, 아래의 일반식 (4) 또는 (5)를 갖는 다가 알코올 지방산 에스테르 화합물, 아래의 일반식 (6) 또는 (7)을 갖는 다가 알코올 지방산 에테르 화합물로 표시되는 다가알콜 지방산 부분 에테르와, 일반식(8)로 표시되는 폴리옥시 에틸렌 폴리옥시 프로필렌 글리콜 또는 폴리옥시 에틸렌 다가 알코올 지방산 부분 에스테르 화합물들이 사용되며 필요하다면 양이온성 계면활성제, 음이온성 계면활성제, 양쪽성 계면활성제를 약간량씩 사용할 수 있다.The surfactants used in the present invention include polyoxyalkylenealkyl ether compounds, which are nonionic surfactants of formula (1), polyoxyalkylenealkyl phenyl ether compounds of formula (2), and the following general Polyoxyethylene fatty acid ester compounds having the formula (3) can be used, and a polyhydric alcohol fatty acid ester compound having the general formula (4) or (5) below, having the general formula (6) or (7) below Polyhydric alcohol fatty acid partial ethers represented by polyhydric alcohol fatty acid ether compounds, polyoxy ethylene polyoxy propylene glycol or polyoxy ethylene polyhydric alcohol fatty acid partial ester compounds represented by the general formula (8) are used, and if necessary cationic surfactants, Some amount of anionic surfactant and amphoteric surfactant can be used.
(상기식들에서 R은 탄소수 1∼8의 알킬기를 표시하고, R1은 소수원자 또는 탄소수 1∼3의 알킬기를 표시하고, R2, R3및 R4는 탄소수 1∼8의 알킬기 또는 하나의 수소 원자가 탄소수 1∼3의 알킬기가 치환된 페닐기를 표시하며, x, y, z는 0∼6의 정수이며 또한 x+y는 1∼6의 정수를 갖는다.)(Wherein R represents an alkyl group having 1 to 8 carbon atoms, R 1 represents a minor atom or an alkyl group having 1 to 3 carbon atoms, and R 2 , R 3 and R 4 represent an alkyl group having 1 to 8 carbon atoms or one Represents a phenyl group in which an alkyl group having 1 to 3 carbon atoms is substituted, x, y, z are integers of 0 to 6, and x + y has an integer of 1 to 6.
본 조성물에 사용될 수 있는 살충약제로는 피레스로이드계 화합물인 에스바이오 알레트린, 디-시스/트란스 알레트린, 프랄레트린, 후라메트린 등이며, 기피제로는 퍼메트린, 디에칠톨루아미드 등이며, 효력증강제로는 피페로닐 부톡시드, 시넬기스트 에스 421 등을 사용하였으며 화학적 안정성과 증산성능을 개선하기 위하여 디부틸 히드록시 톨루엔(BHT), 3-t-부틸-4-히드록시 아니솔 등의 산화방지제를 첨가하여 사용할 수 있으며 수성약액의 경시적 착색 변화를 방지하기 위하여 에틸렌 디아민의 4차 초산염을 사용할 수 있으며, 기타 살충제 조성물의 제조에 사용되는 통상의 부형제 및 보조제를 더 함유할 수 있다.Insecticides that can be used in the composition are pyrethroid-based compounds such as esbio allelin, di-cis / trans allelin, pralethrin, flamethrin, and the like repellents are permethrin, dietyl toluamide, As a potentiator, piperonyl butoxide and Sinelgist S 421 were used. Dibutyl hydroxy toluene (BHT), 3-t-butyl-4-hydroxy anisole, etc. were used to improve chemical stability and transpiration performance. Can be used in addition to the antioxidant of the quaternary acetate of ethylene diamine can be used to prevent the color change of the aqueous solution over time, and may further contain conventional excipients and auxiliaries used in the preparation of other pesticide compositions. .
아래의 실시예에서 본 발명을 상세히 설명하고자 한다. 아래에서 사용된 %는 모두 중량%이다.In the following examples will be described the present invention in detail. All percentages used below are by weight.
실시예 1Example 1
에스바이오 알레트린 0.5 - 15 %Esbio Alletrin 0.5-15%
향료 0.2 %Fragrance 0.2%
디부틸 히드록시 톨루엔 0.1 - 7 %Dibutyl hydroxy toluene 0.1-7%
에틸렌 디아민의 4차 초산염 0.01 - 5 %Quaternary acetate of ethylene diamine 0.01-5%
폴리옥시 에틸렌 폴리옥시 프로필렌 글리콜 72.8 - 99.19 %Polyoxyethylene Polyoxypropylene Glycol 72.8-99.19%
상기 조성물을 액체전자 모기향용 약액 용기에 담아 사용한다.The composition is used in a liquid container for liquid electronic mosquito flavor.
실시예 2Example 2
디-시스/트란스 알레트린 2.0 - 10 %Di-cis / Trans Alletrin 2.0-10%
향료 0.2 %Fragrance 0.2%
디부틸 히드록시 톨루엔 0.1 - 7 %Dibutyl hydroxy toluene 0.1-7%
에틸렌 디아민의 4차 초산염 0.01 - 5 %Quaternary acetate of ethylene diamine 0.01-5%
폴리옥시 알킬렌 알킬 에테르 77.8 - 97.69 %Polyoxyalkylene alkyl ether 77.8-97.69%
상기 조성물을 액체전자 모기향용 약액 용기에 담아 사용한다.The composition is used in a liquid container for liquid electronic mosquito flavor.
실시예 3Example 3
프랄레트린 0.5 - 8 %Praletrin 0.5-8%
향료 0.2 %Fragrance 0.2%
디부틸 히드록시 톨루엔 0.1 - 7 %Dibutyl hydroxy toluene 0.1-7%
에틸렌 디아민의 4차 초산염 0.01 - 5 %Quaternary acetate of ethylene diamine 0.01-5%
폴리옥시 에틸렌 폴리옥시 프로필렌 글리콜 79.8 - 99.19 %Polyoxyethylene Polyoxypropylene Glycol 79.8-99.19%
상기 조성물을 액체전자 모기향용 약액 용기에 담아 사용한다.The composition is used in a liquid container for liquid electronic mosquito flavor.
실시예 4Example 4
후라메트린 0.45 - 12 %Framethrin 0.45-12%
향료 0.2 %Fragrance 0.2%
디부틸 히드록시 톨루엔 0.1 - 7 %Dibutyl hydroxy toluene 0.1-7%
에틸렌 디아민의 4차 초산염 0.01 - 5 %Quaternary acetate of ethylene diamine 0.01-5%
폴리옥시 에틸렌 폴리옥시 프로필렌 글리콜 75.8 - 99.24 %Polyoxyethylene Polyoxypropylene Glycol 75.8-99.24%
상기 조성물을 액체전자 모기향용 약액 용기에 담아 사용한다.The composition is used in a liquid container for liquid electronic mosquito flavor.
본 발명은 넓은 공간에서 하나의 전기 훈증 살충 장치만으로도 모기 등 해충 구제의 효과를 제공할 수 있도록 개선함으로써 경제적 부담과 사용상의 불편을 최소화하고자 발명된 것으로서, 종래의 전기 훈증 살충 장치들은 휘발성 유기 용제들을 사용함으로써 부주의로 인한 화제의 위험성을 갖고 있었는 데 대하여, 본 발명에 따라서 비이온성 계면활성제를 사용하여 제조한 살충제 조성물은 화제의 위험이 없는 안전한 모기향액 조성물이다.The present invention has been invented to minimize the economic burden and inconvenience in use by improving to provide a pest control effect such as mosquitoes in a large space with only one electric fumigation insecticide device, conventional electric fumigation insecticide devices are volatile organic solvents The use of a pesticide composition prepared using a nonionic surfactant according to the present invention, while having a risk of inadvertent topical use by use, is a safe mosquito repellent composition with no risk of topicality.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-1999-0044505A KR100387422B1 (en) | 1999-10-14 | 1999-10-14 | Soluble liquid electric mosquito-repellent solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-1999-0044505A KR100387422B1 (en) | 1999-10-14 | 1999-10-14 | Soluble liquid electric mosquito-repellent solution |
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| Publication Number | Publication Date |
|---|---|
| KR20010037156A KR20010037156A (en) | 2001-05-07 |
| KR100387422B1 true KR100387422B1 (en) | 2003-06-18 |
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| Application Number | Title | Priority Date | Filing Date |
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| KR10-1999-0044505A KR100387422B1 (en) | 1999-10-14 | 1999-10-14 | Soluble liquid electric mosquito-repellent solution |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| KR20040101790A (en) * | 2003-05-27 | 2004-12-03 | 국보제약주식회사 | An insecticide composition for industrial hygienl and a wick for used thereal |
| GB2481881B (en) * | 2010-05-27 | 2015-02-11 | Exosect Ltd | Liquid formulations |
| GB201106741D0 (en) | 2011-04-20 | 2011-06-01 | Exosect Ltd | Coating compositions for pathogen control in monocotyledonous plants |
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