KR100382169B1 - Methods for brewing wine by using fruit juice - Google Patents

Methods for brewing wine by using fruit juice Download PDF

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KR100382169B1
KR100382169B1 KR10-2002-0017974A KR20020017974A KR100382169B1 KR 100382169 B1 KR100382169 B1 KR 100382169B1 KR 20020017974 A KR20020017974 A KR 20020017974A KR 100382169 B1 KR100382169 B1 KR 100382169B1
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juice
mixed
fruit juice
liquor
fermented
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KR10-2002-0017974A
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KR20020034119A (en
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권상일
김형식
이창수
정지용
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대한민국
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    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12GWINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G3/00Preparation of other alcoholic beverages
    • C12G3/02Preparation of other alcoholic beverages by fermentation
    • C12G3/021Preparation of other alcoholic beverages by fermentation of botanical family Poaceae, e.g. wheat, millet, sorghum, barley, rye, or corn
    • C12G3/022Preparation of other alcoholic beverages by fermentation of botanical family Poaceae, e.g. wheat, millet, sorghum, barley, rye, or corn of botanical genus Oryza, e.g. rice
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12GWINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G3/00Preparation of other alcoholic beverages
    • C12G3/04Preparation of other alcoholic beverages by mixing, e.g. for preparation of liqueurs
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12GWINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G3/00Preparation of other alcoholic beverages
    • C12G3/04Preparation of other alcoholic beverages by mixing, e.g. for preparation of liqueurs
    • C12G3/06Preparation of other alcoholic beverages by mixing, e.g. for preparation of liqueurs with flavouring ingredients

Abstract

본 발명은 발효주(醱酵酒), 증류주(蒸溜酒) 또는 주정(酒精)에 천연과실과즙(天然果實果汁)을 혼용하여 과즙혼용주류(果汁混用酒類)를 제조하는 방법으로써 쌀을 원료로 발효가 완료된 숙성술덧에 과실과즙을 일정비율 섞는방법, 쌀을 원료로 발효시킨 숙성술덧을 증류한 증류원액에 과실과즙을 일정비율 섞는방법, 원료주정을 정제한 정제주정에 과실과즙을 일정비율 섞는 방법에 관한 것이며, 본 발명의 방법에 의해 제조된 과즙혼용주류는 기존의 곡류를 원료로 발효시켜 제조하는 발효주와 곡류를 원료로 발효시킨 숙성술덧을 증류한 증류주, 원료주정을 정제한 정제주정에 천연과실과즙을 첨가함으로써 곡류를 원료로 한 발효주 또는 증류주, 그리고 정제주정이 가지고 있는 주류에서 유래하는 특유의 맛과 향에 과실과즙의 신선하고 독특한 맛과 향이 조합되어 다양하고 특색있는 주질의 맛과 향을 복합적으로 동시에 느낄 수 있도록 주류와 과실과즙을 혼합한 형태를 특징으로 하는 과즙혼용주류의 제조방법에 관한 것이다.The present invention is a fermented wine (혼 酒), distilled spirits (蒸 溜 酒) or ethanol (酒精) mixed with natural fruit juice (天然 果實 果汁) by using a method for producing a juice mixed liquor (果汁 混用 酒類) fermented rice as a raw material How to mix fruit juice with a certain ratio of ripened sachets, How to mix fruit juice with distilled distilled liquor from fermented rice fermented from rice, How to mix fruit juice with refined alcohol The juice mixed liquor prepared by the method of the present invention is a fermented liquor prepared by fermenting existing grains as a raw material, and distilled liquor distilled from fermented grains fermented with grains as raw materials, and refined liquor purified from raw alcohol. By adding fruit juice, the fresh and unique taste of fruit juice is added to the peculiar taste and aroma derived from fermented or distilled liquor made from cereals and liquor of refined alcohol. The present invention relates to a method for producing a juice mixed liquor characterized by a mixture of liquor and fruit juice so that the flavors can be combined at the same time to feel the flavor and aroma of various and characteristic combinations.

Description

과즙을 이용한 주류의 제조방법{Methods for brewing wine by using fruit juice}Method for producing alcoholic beverages using fruit juice {Methods for brewing wine by using fruit juice}

포도, 머루, 사과, 배 등과 같은 과실과 파인애플, 딸기 등과 같은 과채류는 맛뿐만 아니라 영양도 뛰어나 옛부터 직접 먹거리로 많이 이용되어 왔으며, 또한 저장성 등의 문제로 이러한 과실 및 과채류는 발효성 당인 과당 및 포도당이 다량 함유되어 있어 발효방법에 의해 술을 제조하여 널리 음용되어 왔다.Fruits such as grapes, maroons, apples, pears, and fruits and vegetables such as pineapples and strawberries have been used as foods for a long time since they are not only delicious but also nutritious.In addition, due to storage problems, these fruits and fruits are fructose and Since glucose is contained in a large amount, alcohol has been prepared by the fermentation method and widely used.

이러한 과실을 이용하여 술을 만드는 방법으로는 통상적으로 과실을 수확하여 파쇄·압착 등의 조작을 통해 과즙을 제조한 후 과즙이 변패되지 않도록 아황산등의 처리를 하고 부족한 당을 설탕, 포도당 등으로 보완한 다음 효모 등을 이용하여 알코올발효시켜 이를 그대로 또는 여과 등을 통하여 맑게 제조하는 와인 등이 있으며, 또한 발효된 액을 증류하여 그대로 제성하거나 목통 등에 장기저장하여 브랜디와 같은 유명한 술을 만들기도 하였다.In the process of making liquor using such fruits, the fruits are usually harvested by crushing and pressing, and then processed with sulfurous acid, etc. to prevent the juice from being deformed, and the insufficient sugars are supplemented with sugar or glucose. After fermentation of alcohol using yeast and the like or wine produced by clearing it through filtration, etc. Also, by distilling the fermented liquor and making it as it is or by storing it for a long time in the barrel to make famous liquor such as brandy.

과실과즙을 이용하여 주류를 제조할 경우 과실이 가지고 있는 과당 및 포도당, 다량의 유기산 및 에스테르(ester)에 의한 향긋하고 신선항 향과 맛이 발효 및 증류공정에서 대부분 변화되거나 소실되어 버리기 때문에 과실자체가 가지고 있는 천연의 향과 맛을 즐길 수 없는 단점이 있다.When the liquor is prepared using fruit juice, the fruit itself is fragrant and fresh flavor and taste are mostly changed or lost in the fermentation and distillation process due to fructose and glucose, large amount of organic acid and ester. There is a disadvantage that you can not enjoy the natural aroma and taste that has.

본 발명자들은 과실을 이용하여 과실본래의 향기와 향미성분 등 과실특성을 충분히 살릴 수 있는 2차가공식품의 개발에 대한 연구를 거듭한 결과 쌀을 원료로 발효시킨 숙성술덧과 또는 이를 증류한 증류주(蒸溜酒), 원료주정을 정제한 정제주정(精製酒精)을 기주(基酒)로 하여 원료과실을 착즙즉시 기주에 각각 혼용시킴으로써 천연 그대로의 우수한 과실의 향기와 향미를 느낄 수 있는 주류를 제조할 수 있다는 사실을 발견하고 이에 기존주류에 과실을 혼용한 과즙혼용주류(果汁混用酒類)를 발명하게 된 것이다.The present inventors conducted a study on the development of secondary processed foods that can fully utilize the fruit characteristics such as the aroma and flavor components of the fruit by using the fruit, and as a result, aged wine fermented with rice as raw material or distilled liquor distilled from it ( As a base wine using refined alcohol refined from sake and raw alcohol, the raw materials can be mixed with the juice immediately to produce liquor that can feel the scent and flavor of natural fruits. Discovering the fact that it was possible to invent the juice mixed liquor (果汁 混用 酒類) mixed with fruit in the existing liquor.

도1은 본 발명에 따라 쌀을 입국(粒麴)으로 1차 발효시킨 술덧에 증미(쌀)를 넣고 2차발효시킨 숙성술덧에 과실과즙을 일정량 첨가시킨 과즙혼용주류를 제조하기 위한 공정도이며,1 is a process diagram for preparing a juice mixed liquor in which a certain amount of fruit juice is added to a fermented rice wine added to fermented rice wine first fermented with rice as an entry (발효) fermentation according to the present invention;

도2는 쌀을 입국으로 1차 발효시킨 술덧에 증미(쌀)를 넣고 2차발효시킨 숙성술덧을 증류한 곡류증류원액에 과실과즙을 일정량 첨가시킨 과즙혼용주류를 제조하기 위한 공정도이며,2 is a process diagram for preparing a juice mixed liquor in which a certain amount of fruit juice is added to a distilled grain distilled liquor obtained by adding steamed rice (rice) to the fermented rice fermented with rice as the first fermentation.

도3은 95%원료주정을 활성탄으로 정제한 정제주정에 과실과즙을 일정량 첨가시켜 과즙혼용주류를 제조하기 위한 공정도이다.Figure 3 is a process for producing a fruit juice mixed liquor by adding a certain amount of fruit juice to a refined alcohol purified from 95% raw material alcohol.

원료로 사용하는 쌀의 25%를 수세, 침지, 증자과정을 거쳐 38℃정도로 냉각시키고여기에 종국(種麴)을 파종하여 입국을 제조한 후 제조된 입국에 물, 배양효모 등을 가하여 1단담금하고 25℃에서 2∼3일간 발효시킨다. 발효된 1단담금 술덧에 원료처리한 나머지 원료미 75%와 물을 가하여 2단담금하고 25℃에서 약 4∼5일정도 발효시켜 18%곡류발효원액을 얻은 다음 이것에 포도과즙, 머루과즙, 사과과즙, 배과즙, 딸기과즙, 복분자과즙을 각각 별도로 혼용하여 알코올도수 6%(6%과즙혼용주 총용량의 67%에 해당하는 과실과즙을 혼용)와 16%(16%과즙혼용주 총용량의 11%에 해당하는 과실과즙을 혼용)의 과즙혼용주(果汁混用酒)를 각각 완성한다.25% of the rice used as a raw material is cooled to about 38 ℃ through washing, dipping, and increasing the steaming process, and seeding is made here to make an entry, followed by adding water and culture yeast to the prepared entry. Immerse and ferment for 2 to 3 days at 25 ℃. To the fermented one-dump tassels, the raw material was treated with 75% of the remaining raw rice and water, followed by two-stage quenching, followed by fermentation at 25 ° C. for about 4-5 days to obtain an 18% cereal fermentation stock solution. Apple juice, pear juice, strawberry juice, and bokbunja juice are mixed separately, and the alcohol content is 6% (6% mixed with fruit juice equivalent to 67% of the total capacity of the juice blend) and 16% (16% Complete 11% fruit juice mixed with 11% fruit juice.

상기 18%곡류발효원액을 감압증류하여 40%곡류증류원액을 얻은 다음 이것에 포도과즙, 머루과즙, 사과과즙, 배과즙, 딸기과즙, 복분자과즙을 각각 별도로 혼용하여 알코올도수 12%(12%과즙혼용주 총용량의 70%에 해당하는 과실과즙을 혼용)와 30%(30%과즙혼용주 총용량의 25%에 해당하는 과실과즙을 혼용)의 과즙혼용주를 각각 완성한다.The 18% cereal fermentation stock solution was distilled under reduced pressure to obtain 40% cereal distillation stock solution, followed by grape juice, burberry, apple juice, pear juice, strawberry juice, and bokbunja fruit juice. Complete the fruit blends of 70% of the total fruit juice blend and fruit juice of 30% (mix the fruit juice of 25% of the 30% fruit juice blend).

95% 원료주정을 활성탄처리를 하여 40%정제주정을 얻은 다음 포도과즙, 머루과즙, 사과과즙, 배과즙, 딸기과즙, 복분자과즙을 각각 혼용하여 알코올도수 12%(12%과즙혼용주 총용량의 70%에 해당하는 과실과즙을 혼용)와 30%(30%과즙혼용주 총용량의 25%에 해당하는 과실과즙을 혼용)의 과즙혼용주를 각각 완성한다.95% raw alcohol is treated with activated carbon to obtain 40% refined alcohol, followed by grape juice, green fruit juice, apple juice, pear juice, strawberry juice, and bokbunja juice, respectively. Complete 70% fruit juice mix) and 30% (30% fruit juice mix 25% fruit juice).

(실시예)(Example)

비교예1 : 원료미 2,500g을 통상적인 방법에 따라 침지 2시간, 물빼기 1시간, 50분간 증자처리하고 건조효모(Saccharomyces Koreanus) 30g, 물 4,000㎖를 가해 25℃에서 3일간 발효시킨 1단담금 술덧에 남은 원료미 7,500g을 위와 같은 방법으로 원료처리한 증미와 물 12,000㎖를 가해 2단담금하고 25℃에서 5일간 발효시켜 알코올분 18%곡류발효원액 24,780㎖를 얻었다. Comparative Example 1 One step of fermenting 2,500 g of raw rice by steaming for 2 hours, dipping 1 hour, 50 minutes, and fermenting 30 g of dry yeast (Saccharomyces Koreanus) and 4,000 ml of water according to a conventional method for 3 days at 25 ° C 7,500 g of the remaining raw rice in the soaked rice was added with 12,000 ml of the steamed water and the raw material treated in the same manner as above, and immersed in two stages and fermented at 25 ° C. for 5 days to obtain 24,780 ml of alcohol content 18% cereal fermentation stock.

실시예 1-1 :비교예1과 동일한 방법으로 제조한 2개의 18%발효원액에 포도과즙을 각각 혼용하여 알코올도수 6%(6%포도과즙혼용주 총용량의 67%에 해당하는 포도과즙을 혼용)와 16%(16%포도과즙혼용주 총용량의 11%에 해당하는 포도과즙을 혼용)의 포도과즙혼용주를 각각 얻었다. Example 1-1: Grape juice was mixed with two 18% fermentation stock solutions prepared in the same manner as in Comparative Example 1 to obtain grape juice of 6% alcohol content (67% of the total blend of 6% grape juice juice). Mixed) and 16% (mixed grape juice corresponding to 11% of the total capacity of 16% grape juice blend) grape juice blends were obtained, respectively.

실시예 1-2 :비교예1과 동일한 방법으로 제조한 2개의 18%발효원액에 머루과즙을 각각 혼용하여 알코올도수 6%(6%머루과즙혼용주 총용량의 67%에 해당하는 머루과즙을 혼용)와 16%(16%머루과즙혼용주 총용량의 11%에 해당하는 머루과즙을 혼용)의 머루과즙혼용주를 각각 얻었다. Example 1-2: Two grapefruit juices prepared in the same manner as in Comparative Example 1 were mixed with the fruit juice juice each 6% alcohol content (67% of 6% fruit juice blends total amount of juice) Mixed) and 16% (Mellow fruit juice corresponding to 11% of the total capacity of 16% fruit juice blend) was obtained.

실시예 1-3 :비교예1과 동일한 방법으로 제조한 2개의 18%발효원액에 사과과즙을 각각 혼용하여 알코올도수 6%(6%사과과즙혼용주 총용량의 67%에 해당하는 사과과즙을 혼용)와 16%(16%사과과즙혼용주 총용량의 11%에 해당하는 사과과즙을 혼용)의 사과과즙혼용주를 각각 얻었다. Example 1-3: Apple juice is mixed with two 18% fermented stock solutions prepared in the same manner as in Comparative Example 1 to 6% (6% apple juice juice equivalent to 67% of the total capacity of the apple juice blend) Mixed) and 16% (mixed apple juice corresponding to 11% of the total capacity of the 16% apple juice blend).

실시예 1-4 :비교예1과 동일한 방법으로 제조한 2개의 18%발효원액에 배과즙을 각각 혼용하여 알코올도수 6%(6%배과즙혼용주 총용량의 67%에 해당하는 배과즙을 혼용)와 16%(16%배과즙혼용주 총용량의 11%에 해당하는 배과즙을 혼용)의 배과즙혼용주를 각각 얻었다. Example 1-4: Two pear juices were mixed in two 18% fermentation stock solutions prepared in the same manner as in Comparative Example 1 to prepare pear juices corresponding to 67% of the total alcohol content of 6% (6% pear juice mixture). Mixed with) and 16% (mixed with pear juice corresponding to 11% of the total capacity of 16% pear juice blend) was obtained.

실시예 1-5 :비교예1과 동일한 방법으로 제조한 2개의 18%발효원액에 딸기과즙을각각 혼용하여 알코올도수 6%(6%딸기과즙혼용주 총용량의 67%에 해당하는 딸기과즙을 혼용)와 16%(16%딸기과즙혼용주 총용량의 11%에 해당하는 딸기과즙을 혼용)의 딸기과즙혼용주를 각각 얻었다. Example 1-5: Strawberry fruit juice was mixed with two 18% fermented stock solutions prepared in the same manner as in Comparative Example 1 to prepare strawberry juice of 6% (67% of 6% strawberry juice blend) Mixed) and 16% (16% strawberry juice mixed with 11% of the strawberry juice juice corresponding to 11% of the total capacity of the strawberry juice blend) was obtained.

실시예 1-6 :비교예1과 동일한 방법으로 제조한 2개의 18%발효원액에 복분자과즙을 각각 혼용하여 알코올도수 6%(6%복분자과즙혼용주 총용량의 67%에 해당하는 복분자과즙을 혼용)와 16%(16%복분자과즙혼용주 총용량의 11%에 해당하는 복분자과즙을 혼용)의 복분자과즙혼용주를 각각 얻었다. Example 1-6: Bokbunja juice was mixed with two 18% fermentation stock solutions prepared in the same manner as in Comparative Example 1 to prepare 6% (6% Bokbunja juice mixed with Bokbunja juice corresponding to 67% of the total capacity Mixed with bokbunja juice mixed with 16% (mixed with bokbunja juice corresponding to 11% of the total dose of 16% bokbunja juice blend).

비교예 2: 비교예1과 동일한 방법으로 제조한 18%곡류발효원액 24,780㎖를 감압증류하여 40%곡류증류원액 10,480㎖를 얻었다. Comparative Example 2 : 24,780 ml of the 18% cereal fermentation stock solution prepared in the same manner as in Comparative Example 1 was distilled under reduced pressure to obtain 10,480 ml of the 40% grain distillation stock solution.

실시예 2-1 :비교예2와 동일하게 제조한 2개의 40%곡류증류원액에 포도과즙을 각각 혼용하여 알코올도수 12%(12%포도과즙혼용주 총용량의 70%에 해당하는 포도과즙을 혼용)와 30%(30%포도과즙혼용주 총용량의 25%에 해당하는 포도과즙을 혼용)의 포도과즙혼용주를 각각 얻었다. Example 2-1: Grape juice was mixed with two 40% cereal distillates prepared in the same manner as in Comparative Example 2 to obtain 12% grape juice corresponding to 70% of the total capacity of 12% grape juice mixed liquor. Mixed) and 30% (mixed grape juice corresponding to 25% of the total capacity of the 30% grape juice mixed wine) were obtained.

실시예 2-2 :비교예2와 동일하게 제조한 2개의 40%곡류증류원액에 머루과즙을 각각 혼용하여 알코올도수 12%(12%머루과즙혼용주 총용량의 70%에 해당하는 머루과즙을 혼용)와 30%(30%머루과즙혼용주 총용량의 25%에 해당하는 머루과즙을 혼용)의 머루과즙혼용주를 각각 얻었다. Example 2-2: Two grapefruit juices prepared in the same manner as in Comparative Example 2 were mixed with fruit juice, respectively, alcohol content 12% (12% fruit juice juice equivalent to 70% of the total capacity of 12% fruit juice blend) Mixed) and 30% (30% of the mixed fruit juice equivalent to 25% of the total capacity of the fruit juice juice) were obtained the fruit juice blend of the fruit juice.

실시예 2-3 :비교예2와 동일하게 제조한 2개의 40%곡류증류원액에 사과과즙을 각각 혼용하여 알코올도수 12%(12%사과과즙혼용주 총용량의 70%에 해당하는 사과과즙을 혼용)와 30%(30%사과과즙혼용주 총용량의 25%에 해당하는 사과과즙을 혼용)의 사과과즙혼용주를 각각 얻었다. Example 2-3: Apple juice is mixed with two 40% cereal distillates prepared in the same manner as in Comparative Example 2 to obtain 12% apple juice (70% of the total capacity of 12% apple juice mixed liquor) Mixed) and 30% (30% apple juice mixed apple juice corresponding to 25% of the total capacity of the apple juice blend) was obtained respectively.

실시예 2-4 :비교예2와 동일하게 제조한 2개의 40%곡류증류원액에 배과즙을 각각 혼용하여 알코올도수 12%(12%배과즙혼용주 총용량의 70%에 해당하는 배과즙을 혼용)와 30%(30%배과즙혼용주 총용량의 25%에 해당하는 배과즙을 혼용)의 배과즙혼용주를 각각 얻었다. Example 2-4: Two pear juices were mixed in two 40% cereal distillates prepared in the same manner as in Comparative Example 2 to prepare pear juices corresponding to 70% of the total capacity of 12% pear juice mixed liquor. Mixed) and 30% (mixed pear juice equivalent to 25% of the total capacity of the 30% pear juice blend) were obtained.

실시예 2-5 :비교예2와 동일하게 제조한 2개의 40%곡류증류원액에 딸기과즙을 각각 혼용하여 알코올도수 12%(12%딸기과즙혼용주 총용량의 70%에 해당하는 딸기과즙을 혼용)와 30%(30%딸기과즙혼용주 총용량의 25%에 해당하는 딸기과즙을 혼용)의 딸기과즙혼용주를 각각 얻었다. Example 2-5: Strawberry juice was mixed with two 40% cereal distillates prepared in the same manner as in Comparative Example 2 to obtain 12% strawberry juice (70% of the total capacity of the 12% strawberry juice blend) Mixed) and 30% (30% strawberry juice mixed with strawberry juice corresponding to 25% of the total capacity of the strawberry juice blend) was obtained respectively.

실시예 2-6 :비교예2와 동일하게 제조한 2개의 40%곡류증류원액에 복분자과즙을 각각 혼용하여 알코올도수 12%(12%복분자과즙혼용주 총용량의 70%에 해당하는 복분자과즙을 혼용)와 30%(30%복분자과즙혼용주 총용량의 25%에 해당하는 복분자과즙을 혼용)의 복분자과즙혼용주를 각각 얻었다. Example 2-6: Bokbunja juice was mixed with two 40% cereal distillates prepared in the same manner as in Comparative Example 2 to prepare a bokbunja juice corresponding to 70% of the total capacity of 12% (12% Bokbunja juice mixed alcohol). Mixed) and 30% (mixed bokbunja juice equivalent to 25% of the total capacity of the 30% bokbunja juice blended liquor).

비교예 3 :95%원료주정 5,000㎖를 활성탄처리하여 40%정제주정 11,815㎖를 얻었다. Comparative Example 3: Activated charcoal was treated with 5,000 ml of 95% raw alcohol to obtain 11,815 ml of 40% crude alcohol.

실시예 3-1 :비교예3과 동일하게 제조한 2개의 40%정제주정에 포도과즙을 각각 혼용하여 알코올도수 12%(12%포도과즙혼용주 총용량의 70%에 해당하는 포도과즙을 혼용)와 30%(30%포도과즙혼용주 총용량의 25%에 해당하는 포도과즙을 혼용)의 포도과즙혼용주를 각각 얻었다. Example 3-1: Grape juice was mixed with two 40% tablets prepared in the same manner as Comparative Example 3, and grape juice was mixed with 12% alcohol content (70% of the total blend of 12% grape juice). ) And 30% (30% grape juice mixed with grape juice corresponding to 25% of the total capacity of the grape juice blend) were obtained respectively.

실시예 3-2 :비교예3과 동일하게 제조한 2개의 40%정제주정에 머루과즙을 각각 혼용하여 알코올도수 12%(12%머루과즙혼용주 총용량의 70%에 해당하는 머루과즙을 혼용)와 30%(30%머루과즙혼용주 총용량의 25%에 해당하는 머루과즙을 혼용)의 머루과즙혼용주를 각각 얻었다. Example 3-2: Mix two grapefruit juice with two 40% tablets prepared in the same manner as in Comparative Example 3, and mix the grapefruit juice corresponding to 70% of the total capacity of 12% ) And 30% (30% of the mixed fruit juice juice corresponding to 25% of the total capacity of the fruit juice juice) were obtained the fruit juice blend of the fruit juice.

실시예 3-3 :비교예3과 동일하게 제조한 2개의 40%정제주정에 사과과즙을 각각 혼용하여 알코올도수 12%(12%사과과즙혼용주 총용량의 70%에 해당하는 사과과즙을 혼용)와 30%(30%사과과즙혼용주 총용량의 25%에 해당하는 사과과즙을 혼용)의 사과과즙혼용주를 각각 얻었다. Example 3-3: Mix apple juice with two 40% tablets prepared in the same manner as Comparative Example 3, and mix apple juice corresponding to 70% of the total capacity of 12% apple juice mixed liquor with alcohol. ) And 30% apple juice blends of 30% (30% apple juice blends).

실시예 3-4 :비교예3과 동일하게 제조한 2개의 40%정제주정에 배과즙을 각각 혼용하여 알코올도수 12%(12%배과즙혼용주 총용량의 70%에 해당하는 배과즙을 혼용)와 30%(30%배과즙혼용주 총용량의 25%에 해당하는 배과즙을 혼용)의 배과즙혼용주를 각각 얻었다. Example 3-4: Two pear juices were mixed in two 40% tablets prepared in the same manner as in Comparative Example 3, and pear juice was mixed with 12% alcohol content (70% of the total capacity of the 12% pear juice mixture). ) And 30% (30% pear juice mixed with pear juice corresponding to 25% of the total capacity) were obtained pear juice mixed wine, respectively.

실시예 3-5 :비교예2와 동일하게 제조한 2개의 40%정제주정에 딸기과즙을 각각 혼용하여 알코올도수 12%(12%딸기과즙혼용주 총용량의 70%에 해당하는 딸기과즙을 혼용)와 30%(30%딸기과즙혼용주 총용량의 25%에 해당하는 딸기과즙을 혼용)의 딸기과즙혼용주를 각각 얻었다. Example 3-5 Mixing strawberry juice to two 40% tablets prepared in the same manner as in Comparative Example 2 mixed 12% (12% strawberry juice blend strawberry juice corresponding to 70% of the total capacity of 12% strawberry juice blend ) And 30% (30% strawberry juice blend of strawberry juice corresponding to 25% of the total capacity of the strawberry juice blend) was obtained respectively.

실시예 3-6 :비교예2와 동일하게 제조한 2개의 40%정제주정에 복분자과즙을 각각 혼용하여 알코올도수 12%(12%복분자과즙혼용주 총용량의 70%에 해당하는 복분자과즙을 혼용)와 30%(30%복분자과즙혼용주 총용량의 25%에 해당하는 복분자과즙을 혼용)의 복분자과즙혼용주를 각각 얻었다. Example 3-6: Bokbunja fruit juice was mixed with two 40% tablets of alcohol prepared in the same manner as in Comparative Example 2, and mixed with Bokbunja fruit juice corresponding to 70% of the total capacity of 12% (12% Bokbunja juice mixed liquor). ) And 30% (mixtures of bokbunja juice corresponding to 25% of the total dose of 30% bokbunja juice blends) were obtained.

[표1]Table 1

[표2][Table 2]

주1) 이론알코올생성량 : 원료중 발효가능한 유효성분(전분)으로부터 생산가능한 순수알코올의 이론적수량으로 원료미사용량×원료미전분가×0.715Note 1) Theoretical alcohol production: The theoretical amount of pure alcohol that can be produced from the fermentable active ingredient (starch) in the raw material.

(0.715 : 전분의 알코올환산계수. 0.6435 : 포도당의 알코올환산계수)(0.715: Alcohol conversion factor of starch. 0.6435: Alcohol conversion factor of glucose)

주2) 숙성술덧 총알코올량 : 숙성술덧중의 순수알코올량으로 숙성술덧량×숙성술덧알코올분Note 2) Total alcohol content of aged liquor: The amount of pure alcohol in the aged liquor, aged liquor x aged liquor

주3) 발효비율 : 숙성술덧의 총알코올 생성량과 이론알코올 생성량과의 비율Note 3) Fermentation ratio: Ratio between total alcohol production and theoretical alcohol production

주4) 증류원액 총알코올량 : 감압증류한 증류원액중의 순수알코올량으로 증류원액량×증류원액 알코올분Note 4) Total alcohol content of distilled liquor: Distilled liquor amount × distilled liquor alcohol content

주5) 증류비율 : 증류원액의 총알코올 생성량과 숙성술덧 총알코올량과의 비율Note 5) Distillation Ratio: Ratio of total alcohol production in distilled liquor and total alcohol content

주6) 정제비율 : 정제주정의 총알코올 생성량과 원료주정 총알코올량과의 비율Note 6) Refining ratio: Ratio of total alcohol production of refined alcohol with total alcohol content of raw alcohol

쌀을 원료로 발효시킨 18%곡류발효원액의 발효비율(생산수율)은 82.08%로서 곡류를 이용한 일반적인 탁·약주 제조시의 발효비율과 큰 차이가 없어 기주(곡류발효원액)제조시 발효과정에서의 제조비율(생산수율)은 문제가 없는 것으로 확인 되었다.The fermentation rate (production yield) of the 18% cereal fermented stock fermented with rice as raw material is 82.08%, which is not significantly different from the fermentation ratio of general turbid and herbal wines made with grains. The manufacturing ratio of (production yield) was confirmed to be no problem.

18%곡류발효원액을 증류한 곡류증류원액은 알코올도수를 40.0%에서 증류를 중지하였으며, 이때의 증류비율은 95.52%로 나타나, 통상적인 숙성술덧의 증류에 있어서의 증류비율과 차이가 없었다. 증류방법은 약 65℃의 온도에서 증류가 가능하도록 감압증류(減壓蒸溜)를 선택하여 푸르푸랄(Furfural)취(탄내)를 제거하고 주질을 담백(淡白)하게 하여 과즙과 혼화시 상대적으로 과실의 맛과 향을 부각시킬 수 있는 주질로 완성하였다.The distillation of the 18% cereal fermentation stock distilled distilled at 40.0% alcohol content, the distillation ratio was 95.52%, which was not different from the distillation ratio in the distillation of conventional ripening. Distillation method is to select the distillation at a temperature of about 65 ℃ to remove the furfural odor (coal) by distillation under reduced pressure and to make the main color pale (상대적 白) relatively fruit when mixed with fruit juice Finished with a quality that can highlight the taste and aroma of.

원료주정은 활성탄(活性炭)처리에 의한 정제공정을 거쳐 증류기주로서의 주질을 한층 순화시켜, 역시 과즙과 혼화시 상대적으로 과실의 맛과 향을 부각시킬 수 있는 주질로 완성하였다.Raw alcoholic beverages were refined through activated carbon treatment to further refine the quality of the distillation column, and finished to a quality that can highlight the taste and aroma of fruit when mixed with fruit juice.

[표3]Table 3

주1) 과즙혼용비율 = (각 과실과즙사용량/제성주 량)×100Note 1) Mixing ratio of fruit juice = (the amount of fruit juice used / the amount of sake) x 100

비교예1은 18%곡류발효원액으로 하였으며, 실시예1-1의 포도과즙 67%혼용시험구는 18%곡류발효원액 1,000㎖에 포도과즙 2,000㎖를 혼용(총 제성주량의 67%에 해당)하여 6%과즙혼용주 3,000㎖를 완성하였고, 실시예1-1의 포도과즙 11%혼용시험구는 18%곡류발효원액 1,000㎖에 포도과즙 125㎖를 혼용(총 제성주량의 11%에 해당)하여 16%과즙혼용주 1,125㎖를 제조하였다. 나머지 실시예1-2, 실시예1-3, 실시예1-4, 실시예1-5, 실시예1-6의 시험구도 실시예1-1의 67%혼용시험구와 11%혼용시험구의 혼용방법과 같으며, 다만 과실과즙의 종류만 머루과즙, 사과과즙, 배과즙, 딸기과즙, 복분자과즙으로 각각 달리하여 제조하였다.Comparative Example 1 was 18% cereal fermentation stock solution, grape juice of 67% mixed test of Example 1-1 was mixed with 2,000 ml of grape juice and 1,000 ml of 18% cereal fermentation stock solution (corresponding to 67% of total sake) 3,000 ml of 6% mixed fruit juice was completed, and 11% mixed fruit juice of Example 1-1 was mixed with 1,000 ml of 18% cereal fermentation stock solution and 125 ml of grape juice (corresponding to 11% of the total alcohol content). 1125 ml of juice blends were prepared. The remaining test specimens of Example 1-2, Example 1-3, Example 1-4, Example 1-5, and Example 1-6 were mixed with 67% mixed test sphere and 11% mixed test sphere of Example 1-1. It is the same as the method, but only the fruit juice was prepared by different types of fruit juice, apple juice, pear juice, strawberry juice, bokbunja juice.

[표4]Table 4

비교예2는 40%곡류증류원액으로 하였으며, 실시예2-1의 포도과즙 70%혼용시험구는 40%곡류증류원액 1,000㎖에 포도과즙 2,333㎖를 혼용(총 제성주량의 70%에 해당)하여 12%과즙혼용주 3,333㎖를 완성하였고, 실시예2-1의 포도과즙 25%혼용시험구는 40%곡류증류원액 1,000㎖에 포도과즙 333㎖를 혼용(총 제성주량의 25%에 해당)하여 30%과즙혼용주 1,333㎖를 제조하였다. 나머지 실시예2-2, 실시예2-3, 실시예2-4, 실시예2-5, 실시예2-6의 시험구도 실시예2-1의 70%혼용시험구와 25%혼용시험구의 혼용방법과 같으며, 다만 과실과즙의 종류만 머루과즙, 사과과즙, 배과즙, 딸기과즙, 복분자과즙으로 각각 달리하여 제조하였다.Comparative Example 2 was a 40% cereal distillate stock solution, and the 70% mixed fruit juice of Example 2-1 was mixed with 1,000 ml of 40% cereal distillate solution and 2,333 ml of grape juice (corresponding to 70% of the total alcohol content). 3,333 ml of 12% mixed fruit juice was completed, and 25% mixed fruit juice of Example 2-1 was mixed with 1,000 ml of 40% cereal distillate solution and 333 ml of grape juice (corresponding to 25% of the total alcohol content). 1333 ml of% juice blend was prepared. The test strips of Examples 2-2, 2-3, Example 2-4, Example 2-5, and Example 2-6 are also mixed with 70% mixed test sphere and 25% mixed test sphere of Example 2-1. It is the same as the method, but only the fruit juice was prepared by different types of fruit juice, apple juice, pear juice, strawberry juice, bokbunja juice.

[표5]Table 5

비교예3은 40%정제주정으로 하였으며, 실시예3-1의 포도과즙 70%혼용시험구는40%정제주정 1,000㎖에 포도과즙 2,333㎖를 혼용(총 제성주량의 70%에 해당)하여 12%과즙혼용주 3,333㎖를 완성하였고, 실시예3-1의 포도과즙 25%혼용시험구는 40%정제주정 1,000㎖에 포도과즙 333㎖를 혼용(총 제성주량의 25%에 해당)하여 30%과즙혼용주 1,333㎖를 제조하였다. 나머지 실시예3-2, 실시예3-3, 실시예3-4, 실시예3-5, 실시예3-6의 시험구도 실시예3-1의 70%혼용시험구와 25%혼용시험구의 혼용방법과 같으며, 다만 과실과즙의 종류만 머루과즙, 사과과즙, 배과즙, 딸기과즙, 복분자과즙으로 각각 달리하여 제조하였다.Comparative Example 3 was 40% tablet alcohol, and the grape juice 70% mixed test group of Example 3-1 was mixed with 1,000 ml of 40% tablet alcohol and 2,333 ml of grape juice (corresponding to 70% of the total alcohol content). 3,333 ml of juice blends were completed, and the grape juice 25% mixed test group of Example 3-1 mixed 40% tablets with 1,000 ml of grape juice (corresponding to 25% of the total alcohol content) to mix with 30% juice. 1333 ml of the week was prepared. The test strips of Examples 3-2, 3-3, 3-4, 3-5, and 3-6 were also mixed with 70% mixed test sphere and 25% mixed test sphere of Example 3-1. It is the same as the method, but only the fruit juice was prepared by different types of fruit juice, apple juice, pear juice, strawberry juice, bokbunja juice.

상기와 같이 제조한 과즙혼용주류의 향기성분동향을 파악하기 위해 주류의 향기에 많은 영향을 끼치는 아세트알데히드와 에틸아세테이트, 퓨젤유성분에 대하여 가스크로마토그래피를 이용하여 직접주입법으로 분석하였으며, 각 성분함량은 아래(표6), (표7), (표8)의 실시예별 과즙혼용주의 향기성분 함량과 같다.In order to grasp the fragrance component trends of the juice mixed liquor prepared as described above, the acetaldehyde, ethyl acetate, and fusel oil components were analyzed by direct injection method using gas chromatography. It is the same as the scent component content of the juice mixture according to Examples of Table 6, Table 7, Table 8.

[표6]Table 6

주1) 노르말프로필알코올, 이소부틸알코올, 이소아밀알코올 등을 총칭하며,Note 1) Normally propyl alcohol, isobutyl alcohol, isoamyl alcohol, etc.,

아미노산발효에 의해 생성되는 주류 향기성분의 일종으로 자극취가 강함.It is a kind of alcoholic odor component produced by amino acid fermentation.

* 가스크로마토그라피 분석조건* Gas chromatography analysis conditions

· Detector : FIDDetector: FID

· Column : PEGHTColumn: PEGHT

· Injector Temperature : 170℃Injector Temperature: 170 ℃

· Detector Temperature : 220℃Detector Temperature: 220 ℃

· Column Temperature : 90℃Column Temperature: 90 ℃

· Carrier gas : N2(60㎖/min)Carrier gas: N 2 (60ml / min)

주류의 주요 향기성분인 아세트알데히드, 에틸아세테이트, 퓨젤유성분은 술덧의 발효공정에서 주로 생성되는 물질로서 그 합계치가 상기 (표6)에서 보는 바와 같이 비교예1의 18%곡류발효원액에서는 929ppm이 검출되었으며 실시예1-1의 18%곡류발효원액 1,000㎖에 포도과즙 2,000㎖를 혼용한 67%과즙혼용시험구의 향기성분은 299ppm을, 18%곡류발효원액 1,000㎖에 포도과즙 125㎖를 혼용한 11%과즙혼용시험구의 향기성분은 771ppm을,Acetaldehyde, ethyl acetate, and fusel oil components, which are the main fragrance components of alcoholic beverages, are mainly produced in fermentation process of rice bran, and their total value is 929ppm detected in the 18% cereal fermentation stock solution of Comparative Example 1 as shown in (Table 6). The aroma component of 67% fruit juice mixed test was mixed with 1,000 ml of 18% grain fermented stock solution of Example 1-1, and 299 ppm of the fruit mixture was mixed with 1,000 ml of 18% grain fermented stock solution. The fragrance ingredient of the test mixture for% fruit juice was 771 ppm,

실시예1-2의 18%곡류발효원액 1,000㎖에 머루과즙 2,000㎖를 혼용한 67%과즙혼용시험구의 향기성분은 290ppm을, 18%곡류발효원액 1,000㎖에 머루과즙 125㎖를 혼용한 11%과즙혼용시험구의 향기성분은 695ppm을,The scent component of the 67% fruit juice mixing test was mixed with 1,000 ml of 18% cereal fermentation stock solution of Example 1-2, and 290 ppm of 11% mixed with 125 ml of beetroot juice in 1,000 ml of 18% grain fermentation stock solution. The fragrance component of the fruit juice mixing test was 695 ppm,

실시예1-3의 18%곡류발효원액 1,000㎖에 사과과즙 2,000㎖를 혼용한 67%과즙혼용시험구의 향기성분은 309ppm을, 18%곡류발효원액 1,000㎖에 사과과즙 125㎖를 혼용한 11%과즙혼용시험구의 향기성분은 774ppm을,The flavor component of the 67% fruit juice mixing test was mixed with 1,000 ml of the 18% cereal fermentation stock solution of Example 1-3, and 309 ppm was mixed with 1,000 ml of the 18% cereal fermentation stock solution. The odor component of the fruit juice mixing test was 774ppm,

실시예1-4의 18%곡류발효원액 1,000㎖에 배과즙 2,000㎖를 혼용한 67%과즙혼용시험구의 향기성분은 285ppm을, 18%곡류발효원액 1,000㎖에 배과즙 125㎖를 혼용한 11%과즙혼용시험구의 향기성분은 773ppm을,67% fruit juice mixed test was mixed with 1,000 ml of the 18% cereal fermented stock solution of Example 1-4, and the fragrance component of the test mixture was 285 ppm, and 11% with 125 ml of the pear juice mixed with 1,000 ml of the 18% cereal fermented stock solution. The fragrance component of the fruit juice mixing test was 773ppm,

실시예1-5의 18%곡류발효원액 1,000㎖에 딸기과즙 2,000㎖를 혼용한 67%과즙혼용시험구의 향기성분은 306ppm을, 18%곡류발효원액 1,000㎖에 딸기과즙 125㎖를 혼용한 11%과즙혼용시험구의 향기성분은 776ppm을,The flavor component of the 67% fruit juice mixing test was mixed with 1,000 ml of the 18% grain fermented stock solution of Example 1-5, and the fragrance component of the test mixture was 306 ppm, and 11% with 125 ml of the strawberry juice mixed with 1,000 ml of the 18% grain fermented stock solution. The odor component of the fruit juice mixing test was 776ppm,

실시예1-6의 18%곡류발효원액 1,000㎖에 복분자과즙 2,000㎖를 혼용한 67%과즙혼용시험구의 향기성분은 320ppm을, 18%곡류발효원액 1,000㎖에 복분자과즙 125㎖를 혼용한 11%과즙혼용시험구의 향기성분은 791ppm을 나타내 실시예1-1에서 실시예1-6까지 공히 각 과실과즙의 혼용비율이 높을수록(18% 곡류발효원액의 혼용비율이 낮을수록) 아세트알데히드, 에틸아세테이트, 퓨젤유의 합계치인 향기성분함량이 비교예1의 향기성분의 합계치에 비해 낮게 나타나 상대적으로 과실과즙의 순수한 향과 맛을 최종 제성주(과즙혼용주류)에 더욱 부각시킬 수 있음을 확인하였다.The flavor component of the 67% fruit juice mixed test mixture containing 2,000 ml of Bokbunja fruit juice in 1,000 ml of the 18% cereal fermentation stock solution of Example 1-6 was 320 ppm and 11% of 125 ml of Bokbunja fruit juice mixed with 1,000 ml of 18% grain fermentation stock solution. The aroma component of the fruit juice mixing test group was 791ppm, and the higher the mixing ratio of each fruit juice (the lower the mixing ratio of the 18% cereal fermentation stock solution) from Example 1-1 to Example 1-6, the acetaldehyde and ethyl acetate It was confirmed that the content of the fragrance component, which is the total value of the fusel oil, was lower than the total value of the fragrance component of Comparative Example 1, and thus the pure aroma and taste of the fruit juice could be more emphasized in the final sake (juice mixture).

[표7]Table 7

상기 (표7)에서 보는 바와 같이 술덧의 발효과정에서 주로 유래되는 향기성분인 아세트알데히드, 에틸아세테이트, 퓨젤유의 합계치가 비교예2의 40%곡류증류원액에서는 1,802ppm이 검출되었으며 실시예2-1의 40%곡류증류원액 1,000㎖에 포도과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향기성분은 545ppm을, 40%곡류증류원액 1,000㎖에 포도과즙 333㎖를 혼용한 25%과즙혼용시험구의 향기성분은 1,343ppm을,As shown in Table 7 above, the total value of acetaldehyde, ethyl acetate, and fusel oil, which are mainly derived from the fermentation process, was 1,802 ppm in the 40% cereal distillate of Comparative Example 2, and Example 2-1. Aroma of 25% Fruit Juice Mix Test Mixture with 545ppm of 70% Fruit Juice Mixing Test Mix with 1,000ml of 40% Grain Distillate Stock Solution and 333ml of Grape Juice Mixture with 1,000ml of 40% Grain Distillate Ingredients is 1,343ppm,

실시예2-2의 40%곡류증류원액 1,000㎖에 머루과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향기성분은 481ppm을, 40%곡류증류원액 1,000㎖에 머루과즙 333㎖를 혼용한 25%과즙혼용시험구의 향기성분은 1,241ppm을,70% fruit juice test mixture containing 2,333 ml of wild fruit juice in 1,000 ml of 40% cereal distillate stock solution of Example 2-2 was 481 ppm and 25% of 333 ml of wild fruit juice mixed in 1,000 ml of 40% cereal distillate solution. The fragrance component of the fruit juice mixing test was 1,241ppm,

실시예2-3의 40%곡류증류원액 1,000㎖에 사과과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향기성분은 454ppm을, 40%곡류증류원액 1,000㎖에 사과과즙 333㎖를 혼용한 25%과즙혼용시험구의 향기성분은 1,165ppm을,70% fruit juice test mixture containing 333 ppm of apple juice 2,333 ml mixed with 1,000 ml of 40% cereal distillate stock solution of Example 2-3 was 25% mixed with 333 ml of apple juice mixed with 1,000 ml of 40% cereal distillate stock solution. The fragrance component of the fruit juice mixing test was 1,165ppm,

실시예2-4의 40%곡류증류원액 1,000㎖에 배과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향기성분은 582ppm을, 40%곡류증류원액 1,000㎖에 배과즙 333㎖를 혼용한 25%과즙혼용시험구의 향기성분은 1,435ppm을,Aroma component of 70% fruit juice mixing test which mixed 2,333 ml of pear juice with 1,000 ml of 40% cereal distillate of Example 2-4 was 582 ppm and 25% of 333 ml of pear juice mixed with 1,000 ml of 40% cereal distillate. The fragrance component of the fruit juice mixing test was 1,435ppm,

실시예2-5의 40%곡류증류원액 1,000㎖에 딸기과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향기성분은 533ppm을, 40%곡류증류원액 1,000㎖에 딸기과즙 333㎖를 혼용한 25%과즙혼용시험구의 향기성분은 1,261ppm을,70% fruit juice test mixture containing 533ppm of strawberry fruit juice 2,333ml mixed with 1,000ml of 40% cereal distillate stock solution of Example 2-5 25% mixed with 333ml of strawberry juice mixed with 1,000ml of 40% cereal distillate solution The fragrance component of the fruit juice mixing test was 1,261ppm,

실시예2-6의 40%곡류증류원액 1,000㎖에 복분자과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향기성분은 452ppm을, 40%곡류증류원액 1,000㎖에 복분자과즙 333㎖를 혼용한 40%과즙혼용시험구의 향기성분은 1,210ppm을 나타내 실시예2-1에서 실시예2-6까지 공히 각 과실과즙의 혼용비율이 높을수록(40% 곡류증류원액의 혼용비율이 낮을수록) 아세트알데히드, 에틸아세테이트, 퓨젤유의 합계치인 향기성분함량이 비교예2의 향기성분의 합계치에 비해 낮게 나타나 상대적으로 과실과즙의 순수한 향과 맛을 최종 제성주(과즙혼용주류)에 더욱 부각시킬 수 있음을 확인하였다.Aroma component of 70% fruit juice test mixture which mixed 2,333 ml of bokbunja fruit juice with 1,000 ml of 40% cereal distillate stock solution of Example 2-6 was 452 ppm and 40% of 333 ml of bokbunja fruit juice mixed with 1,000 ml of 40% cereal distillate solution The fragrance component of the fruit juice mixing test group showed 1,210ppm, and the higher the mixing ratio of each fruit juice (the lower the mixing ratio of 40% cereal distillate) from Example 2-1 to Example 2-6, acetaldehyde and ethyl It was confirmed that the content of the fragrance component, which is the total value of the acetate and fusel oils, was lower than the total value of the fragrance component of Comparative Example 2, so that the pure aroma and taste of the fruit juice could be more highlighted in the final sake (juice mixture).

[표8]Table 8

상기 (표8)에서 보는 바와 같이 술덧의 발효과정에서 주로 유래되는 향기성분인 아세트알데히드, 에틸아세테이트, 퓨젤유의 합계치가 비교예3의 40%정제주정에서는 원료주정의 특성상 검출되지 않았고, 실시예3-1, 실시예3-2, 실시예3-3, 실시예3-4, 실시예3-5, 실시예3-6의 40%정제주정에 1,000㎖에 포도, 머루, 사과, 배, 딸기, 복분자과즙을 각각 2,333㎖을 혼용한 70%과즙혼용시험구에서도 검출되지 않았으며, 실시예3-1, 실시예3-2, 실시예3-3, 실시예3-4, 실시예3-5, 실시예3-6의 40%정제주정에 1,000㎖에 포도, 머루, 사과, 배, 딸기, 복분자과즙을 각각 333㎖을 혼용한 25%과즙혼용시험구에서도 검출되지 않아 상대적으로 과실과즙의 순수한 향과 맛을 최종 제성주(과즙혼용주류)에 전량 부각시킬 수 있음을 확인하였다.As shown in Table 8, the total value of acetaldehyde, ethyl acetate, and fusel oil, which are mainly derived from the fermentation process, was not detected in the characteristics of raw alcohol in 40% refined alcohol of Comparative Example 3. -1, Example 3-2, Example 3-3, Example 3-4, Example 3-5, Example 3-6 in 40 ml tablets of grapes, grapefruit, apple, pear, strawberry , Bokbunja fruit juice was not detected in the 70% fruit juice mixed test mixture containing 2,333 ml each, and Example 3-1, Example 3-2, Example 3-3, Example 3-4, and Example 3- 5, Example 3-6 of 40% tablets alcohol, grapes, maroon, apple, pear, strawberry, bokbunja juice was not detected in the 25% fruit juice mixing test mixed with 333 ml each of relatively fruit juice It was confirmed that the pure flavor and taste can be highlighted in the final sake (juice mixture).

상기와 같이 제조한 과즙혼용주류의 유기산 성분동향을 파악하기 위해 주석산, 사과산, 구연산, 호박산등 주요 향미성분에 대하여 액체크로마토그래피를 이용하여 직접주입법으로 분석하였으며, 각 성분함량은 아래 (표9), (표10), (표11)의 실시예별 숙성술덧의 향미성분 함량과 같다.In order to grasp the organic acid component trends of the juice mixed liquor prepared as described above, major flavor components such as tartaric acid, malic acid, citric acid and succinic acid were analyzed by direct injection using liquid chromatography, and the contents of each component are shown in Table 9 below. , (Table 10), (Table 11) is the same as the flavor component content of the aged aging in each.

[표9]Table 9

* 액체크로마토그래피 분석조건* Liquid chromatography analysis conditions

· Detector : UV(210nm)Detector: UV (210nm)

· Column : SUPELCOGEL C-610H, 30cm×7.8mm IDColumn: SUPELCOGEL C-610H, 30cm × 7.8mm ID

· Mobile Phase : 0.1% Phosphoric acidMobile Phase: 0.1% Phosphoric acid

· Flow Rate : 0.5㎖/minFlow Rate: 0.5ml / min

· Injection Volume : 5㎕Injection Volume: 5µl

· Runing time : 30minRuning time: 30min

상기 (표9)에서 보는 바와 같이 주류의 향미성분인 주석산, 사과산, 구연산, 호박산의 합계치가 비교예1의 18%곡류발효원액에서는 4,040ppm이 검출되었으며, 실시예1-1의 18%곡류발효원액 1,000㎖에 포도과즙 2,000㎖를 혼용한 67%과즙혼용시험구의 향미성분은 8,518ppm을, 18%곡류발효원액 1,000㎖에 포도과즙 125㎖를 혼용한 11%과즙혼용시험구의 향미성분은 4,947ppm을,As shown in Table 9, 4,040 ppm of 18% cereal fermentation stock solution of Comparative Example 1 was found in the total value of the main components of tartaric acid, malic acid, citric acid and succinic acid, and 18% grain fermentation of Example 1-1. The flavor component of the 67% fruit juice mixed test mixture containing 1,000 ml of juice and 2,000 ml of grape juice was 8,518 ppm, and the flavor component of the mixed 11% fruit juice mixed test sample containing 125 ml of grape juice was 1,000 ml of 18% cereal fermentation stock solution. of,

실시예1-2의 18%곡류발효원액 1,000㎖에 머루과즙 2,000㎖를 혼용한 67%과즙혼용시험구의 향미성분은 7,832ppm을, 18%곡류발효원액 1,000㎖에 머루과즙 125㎖를 혼용한 11%과즙혼용시험구의 향미성분은 5,705ppm을,The flavor component of the 67% fruit juice mixing test which mixed 2,000 ml of fruit juice with 1,000 ml of the 18% grain fermentation stock solution of Example 1-2 was 7,832ppm, and 125 ml of fruit juice was mixed with 1,000 ml of the 18% grain fermentation stock solution 11 The flavor component of the test mixture for% fruit juice was 5,705 ppm,

실시예1-3의 18%곡류발효원액 1,000㎖에 사과과즙 2,000㎖를 혼용한 67%과즙혼용시험구의 향미성분은 4,936ppm을, 18%곡류발효원액 1,000㎖에 사과과즙 125㎖를 혼용한 11%과즙혼용시험구의 향미성분은 4,445ppm을,The flavor component of the 67% fruit juice mixed test mixture containing 1,000 ml of the 18% grain fermented stock solution of Example 1-3 was 4,936 ppm, and the mixed fruit juice 125 ml of 1,000 ml of the 18% grain fermented stock solution was mixed with 11 ml. The flavor component of the test mixture for% juice was 4,445 ppm,

실시예1-6의 18%곡류발효원액 1,000㎖에 복분자과즙 2,000㎖를 혼용한 67%과즙혼용시험구의 향미성분은 7,168ppm을, 18%곡류발효원액 1,000㎖에 복분자과즙 125㎖를 혼용한 11%과즙혼용시험구의 향미성분은 5,185ppm을 나타내 실시예1-1, 실시예1-2, 실시예1-3, 실시예1-6 공히 각 과실과즙의 혼용비율이 높을수록(18% 곡류발효원액의 혼용비율이 낮을수록) 주석산, 사과산, 호박산 등 유기산의 합계치인 향미성분함량이 비교예1의 향미성분의 합계치에 비해 높게 나타나 과실과즙의 순수한 향과 맛이 최종 제성주(과즙혼용주류)에 그대로 전가되었음을 확인하였다.The flavor component of the 67% fruit juice mixed test mixture containing 2,000 ml of Bokbunja fruit juice in 1,000 ml of the 18% cereal fermentation stock solution of Example 1-6 was 7,168 ppm, and the mixture of 125 ml of Bokbunja fruit juice containing 1,000 ml of the 18% grain fermentation stock solution 11 The flavor component of the mixed fruit juice test group showed 5,185 ppm, and the higher the mixing ratio of each fruit juice (Example 1-1, Example 1-2, Example 1-3, Example 1-6) (18% cereal fermentation) The lower the mixing ratio of the stock solution, the higher the flavor content, which is the sum of organic acids such as tartaric acid, malic acid, and succinic acid, is higher than the total value of the flavor components of Comparative Example 1, resulting in the pure flavor and taste of the fruit juice. It was confirmed that the transfer as it is.

반면, 실시예1-4의 18%곡류발효원액 1,000㎖에 배과즙 2,000㎖를 혼용한 67%과즙혼용시험구의 향미성분은 1,721ppm을, 18%곡류발효원액 1,000㎖에 배과즙 125㎖를 혼용한 11%과즙혼용시험구의 향미성분은 2,812ppm을 나타내었으며, 실시예1-5의 18%곡류발효원액 1,000㎖에 딸기과즙 2,000㎖를 혼용한 67%과즙혼용시험구의 향미성분은 3,342ppm을, 18%곡류발효원액 1,000㎖에 딸기과즙 125㎖를 혼용한 11%과즙혼용시험구의 향미성분은 2,400ppm을 나타내 비교예1의 향미성분의 합계치보다 낮게 나타났으나 이는 배와 딸기에 함유되어 있는 유기산의 총함량이 다른 과실에 비해 낮은데 기인하는 것이며, 오히려 배와 딸기과즙의 혼용비율이 높을수록 18%곡류발효원액에서 검출된 구연산함량의 수치를 낮게 희석하여 구연산 자체의 신맛을 줄이는 대신 배 또는 딸기과즙자체의 유기산 및 당분인 포도당(葡萄糖)에 의한 감미롭고 시원한 과즙의 맛을 더 한층 느낄수 있음을 확인하였다.On the other hand, the flavor component of the 67% fruit juice mixed test mixture containing 1,000 ml of the 18% cereal fermented stock solution of Example 1-4 was mixed with 2,000 ml of pear juice, and 125 ml of pear juice was mixed with 1,000 ml of the 18% cereal fermented stock solution. The flavor component of the 11% mixed fruit juice test group was 2,812ppm, and the flavor component of the mixed 67% fruit juice test group was 2,000 ml of strawberry juice in 1,000 ml of the 18% cereal fermentation stock solution of Example 1-5. The flavor component of the mixed 11% fruit juice test mixture containing 1,000 ml of 18% cereal fermentation stock and 125 ml of strawberry juice appeared to be 2,400 ppm, which was lower than the sum of the flavor components of Comparative Example 1, but it was an organic acid contained in pear and strawberry. This is because the total content of is lower than other fruits, but the higher the ratio of pear and strawberry juice is, the lower the dilution of citric acid content detected in the 18% cereal fermentation stock solution to reduce the sour taste of citric acid itself. Organic acids of the juice itself It was confirmed that the sugar glucose feel by (葡萄糖) more sweet taste of cold milk.

[표10]Table 10

상기 (표10)에서 보는 바와 같이 주류의 향미성분인 주석산, 사과산, 구연산, 호박산의 합계치가 비교예2의 40%곡류증류원액에서는 증류원액의 특성상 검출되지 않았으며, 실시예2-1의 40%곡류증류원액 1,000㎖에 포도과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향미성분은 6,830ppm을, 40%곡류증류원액 1,000㎖에 포도과즙 333㎖를 혼용한 25%과즙혼용시험구의 향미성분은 1,510ppm을,As shown in Table 10, the total value of the main components of tartaric acid, malic acid, citric acid, and succinic acid was not detected in the 40% cereal distillate of Comparative Example 2 due to the characteristics of the distilled liquor. Flavor Components of the 25% Fruit Juice Mix Test Mixture of 70% Juice Mixture Mixture Mixture with 1,000ml of Cereal Distillate Juice and 2,333ml of Grape Juice Mixture Mixture 6,830ppm, and 333ml of Grape Juice Mixture with 1,000ml of 40% Grain Distillate Solution Is 1510ppm,

실시예2-2의 40%곡류증류원액 1,000㎖에 머루과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향미성분은 6,560ppm을, 40%곡류증류원액 1,000㎖에 머루과즙 333㎖를 혼용한 25%과즙혼용시험구의 향미성분은 2,700ppm을,The flavor component of the 70% fruit juice test mixture containing 2,333 ml of fruit juice was mixed with 1,000 ml of 40% cereal juice distillate of Example 2-2, and 25% of 333 ml of fruit juice was mixed with 1,000 ml of 40% cereal distillate. The flavor component of the test mixture containing% juice was 2,700 ppm,

실시예2-3의 40%곡류증류원액 1,000㎖에 사과과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향미성분은 3,950ppm을, 40%곡류증류원액 1,000㎖에 사과과즙 333㎖를 혼용한 25%과즙혼용시험구의 향미성분은 1,570ppm을,The flavor component of the 70% fruit juice mixed test mixture containing 2,333 ml of apple juice in 1,000 ml of 40% cereal distillate stock solution of Example 2-3 was 3,950 ppm, and 333 ml of apple juice mixed in 1,000 ml of 40% cereal distillate stock solution. The flavor component of the test mixture containing% fruit juice was 1,570 ppm,

실시예2-4의 40%곡류증류원액 1,000㎖에 배과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향미성분은 900ppm을, 40%곡류증류원액 1,000㎖에 배과즙 333㎖를 혼용한 25%과즙혼용시험구의 향미성분은 382ppm을,The flavor component of the 70% fruit juice test mixture containing 2,333 ml of pear juice in 1,000 ml of 40% cereal distillate of Example 2-4 was 900 ppm and 25% of 333 ml of pear juice mixed in 1,000 ml of 40% cereal distillate. The flavor component of the mixed fruit juice test group was 382ppm,

실시예2-5의 40%곡류증류원액 1,000㎖에 딸기과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향미성분은 2,680ppm을, 40%곡류증류원액 1,000㎖에 딸기과즙 333㎖를 혼용한 25%과즙혼용시험구의 향미성분은 1,010ppm을,The flavor component of the 70% fruit juice test mixture containing 2,333 ml of strawberry juice in 1,000 ml of 40% cereal distillate stock solution of Example 2-5 was 2,680 ppm, and 333 ml of strawberry juice was mixed in 1,000 ml of 40% cereal distillate stock solution. The flavor component of the blend of% fruit juice was 1,010 ppm,

실시예2-6의 40%곡류증류원액 1,000㎖에 복분자과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향미성분은 5,890ppm을, 40%곡류증류원액 1,000㎖에 복분자과즙 333㎖를 혼용한 25%과즙혼용시험구의 향미성분은 2,076ppm을 나타내 실시예2-1, 실시예2-2, 실시예2-3, 실시예2-4, 실시예2-5, 실시예2-6 공히 각 과실과즙의 혼용비율이 높을수록(40%곡류증류원액의 혼용비율이 낮을수록) 주석산, 사과산, 호박산 등 유기산의 합계치인 향미성분함량이 비교예2의 향미성분의 합계치에 비해 높게 나타나 과실과즙의 순수한 향과 맛이 최종 제성주(과즙혼용주류)에 그대로 전가되었음을 확인하였다.The flavor component of the 70% fruit juice test mixture containing 2,333 ml of bokbunja fruit juice in 1,000 ml of 40% cereal distillate stock solution of Example 2-6 was 5,890 ppm, and 333 ml of bokbunja fruit juice mixed in 1,000 ml of 40% cereal distillate solution. The flavor component of the blend of% fruit juice showed 2,076 ppm. Examples 2-1, 2-2, 2-3, 2-4, 2-5, and 2-6 were each fruit. The higher the blending ratio of the fruit juice (the lower the mixing ratio of 40% cereal distillate), the higher the flavor component, which is the sum of organic acids such as tartaric acid, malic acid, and succinic acid, was found to be higher than the sum of the flavor components of Comparative Example 2. It was confirmed that the aroma and taste were passed directly to the final sake (juice mixture).

[표11]Table 11

상기 (표11)에서 보는 바와 같이 주류의 향미성분인 주석산, 사과산, 구연산, 호박산의 합계치가 비교예2의 40%정제주정에서는 원료주정의 특성상 검출되지 않았으며, 실시예3-1의 40%정제주정 1,000㎖에 포도과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향미성분은 7,615ppm을, 40%정제주정 1,000㎖에 포도과즙 333㎖를 혼용한 25%과즙혼용시험구의 향미성분은 1,720ppm을,As shown in Table 11, the total value of tartaric acid, malic acid, citric acid, and succinic acid as the flavor components of the liquor was not detected in the 40% tablet alcohol of Comparative Example 2 due to the characteristics of the raw alcohol, and 40% of Example 3-1. The flavor component of the 70% fruit juice test mixture containing 2,333 ml of grape juice and 1,000 ml of refined alcohol was 7,615 ppm, and the flavor component of the 25% fruit juice test mixture containing 333 ml of grape juice with 1,000 ml of 40% tablets was 1,720 ppm. of,

실시예3-2의 40%정제주정 1,000㎖에 머루과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향미성분은 6,690ppm을, 40%정제주정 1,000㎖에 머루과즙 333㎖를 혼용한 25%과즙혼용시험구의 향미성분은 3,170ppm을,The flavor component of the 70% fruit juice test mixture containing 2,333 ml of fruit juice was mixed with 1,000 ml of 40% tablet of alcohol of Example 3-2. 25% fruit juice of 333 ml of fruit juice was mixed with 1,000 ml of 40% tablet of alcohol. Flavor component of the mixed test strip was 3,170ppm,

실시예3-3의 40%정제주정 1,000㎖에 사과과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향미성분은 4,440ppm을, 40%정제주정 1,000㎖에 사과과즙 333㎖를 혼용한 25%과즙혼용시험구의 향미성분은 1,735ppm을,The flavor component of the 70% fruit juice mixing test blended with 1,000 ml of 40% tableted alcohol of Example 3-3 was 4,440 ppm, and the 25% fruit juice mixed with 333 ml of apple juice with 1,000 ml of 40% tableted alcohol. Flavor component of the mixed test was 1,735ppm,

실시예3-4의 40%정제주정 1,000㎖에 배과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향미성분은 934ppm을, 40%정제주정 1,000㎖에 배과즙 333㎖를 혼용한 25%과즙혼용시험구의 향미성분은 390ppm을,The flavor component of the 70% fruit juice mixing test which mixed 2,333 ml of pear juice with 1,000 ml of 40% tablet alcohol of Example 3-4 was mixed with 25% fruit juice having 934 ppm of pear and 40 ml of pear juice with 1,000 ml of 40% tablet alcohol. The flavor component of the test strip was 390ppm,

실시예3-5의 40%정제주정 1,000㎖에 딸기과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향미성분은 2,540ppm을, 40%정제주정 1,000㎖에 딸기과즙 333㎖를 혼용한 25%과즙혼용시험구의 향미성분은 990ppm을,The flavor component of the 70% fruit juice test mixture containing 2,333 ml of strawberry juice in 1,000 ml of 40% tableted alcohol of Example 3-5 was 25% fruit juice containing 2,540 ppm of strawberry fruit juice and 333 ml of strawberry juice in 1,000 ml of 40% tableted alcohol. The flavor component of the mixed test zone was 990ppm,

실시예3-6의 40%정제주정 1,000㎖에 복분자과즙 2,333㎖를 혼용한 70%과즙혼용시험구의 향미성분은 5,030ppm을, 40%정제주정 1,000㎖에 복분자과즙 333㎖를 혼용한 25%과즙혼용시험구의 향미성분은 2,220ppm을 나타내 실시예3-1, 실시예3-2, 실시예3-3, 실시예3-4, 실시예3-5, 실시예3-6 공히 각 과실과즙의 혼용비율이 높을수록(40%정제주정의 혼용비율이 낮을수록) 주석산, 사과산, 호박산 등 유기산의 합계치인 향미성분함량이 비교예3의 향미성분의 합계치에 비해 높게 나타나 과실과즙의 순수한 향과 맛이 최종 제성주(과즙혼용주류)에 그대로 부가되었음을 확인하였다.The flavor component of the 70% fruit juice test mixture containing 2,333 ml of bokbunja fruit juice in 1,000 ml of 40% tableted alcohol of Example 3-6 was 5,030 ppm, and 25% fruit juice containing 333 ml of bokbunja fruit juice in 1,000 ml of 40% tableted alcohol. Flavor component of the mixed test zone was 2,220ppm. Example 3-1, Example 3-2, Example 3-3, Example 3-4, Example 3-5, Example 3-6 The higher the blending ratio (the lower the blending ratio of 40% refined alcohol), the higher the flavor component, which is the sum of organic acids such as tartaric acid, malic acid, and succinic acid, was higher than the sum of the flavor components of Comparative Example 3. It was confirmed that it was added as it is to this final sake (juice mixture).

본 발명의 방법에 의해 제조된 과즙혼용주류는 기주(18%곡류발효원액, 40%곡류증류원액, 40%정제주정)에 각 제성주(각 과즙혼용주)량의 11%에서 70%까지에 해당하는 포도과즙, 머루과즙, 사과과즙, 배과즙, 딸기과즙, 복분자과즙을 각각 혼용함으로써 기존의 곡류를 원료로 한 발효주나 증류주가 가지고 있는 미묘한 향과 맛성분에 과실과즙이 가지고 있는 천연의 각종 향기와 향미성분이 조화롭게 혼합되어 독특한 주질을 느낄 수 있는 혼합주류에 대한 제조방법의 발명으로 남아도는 쌀 소비촉진과 동시에 전국적으로 산재되어 있는 과실의 가공방법 개선으로 농가소득증대에도 크게 기여할 수 있는 효과가 있다.Juice blended liquor prepared by the method of the present invention is in the host (18% cereal fermentation stock, 40% cereal distilled stock, 40% tablet alcohol) from 11% to 70% of the amount of each sake (each juice blend) By mixing the corresponding grape juice, grapefruit juice, apple juice, pear juice, strawberry juice, and bokbunja juice, respectively, various kinds of natural fruit juices have subtle flavors and flavors of fermented or distilled liquor made from existing grains. The invention of the manufacturing method for mixed liquor, which has a unique blend of scents and flavors in harmony, promotes the consumption of rice and improves the processing method of fruits scattered throughout the country. It works.

Claims (3)

원료로 사용하는 쌀의 25%를 수세, 침지, 증자과정을 거쳐 38℃정도로 냉각시키고, 여기에 종국(種麴)을 파종하여 입국을 제조한 후 제조된 입국에 물, 배양효모 등을 가하여 1단담금하고 25℃에서 2∼3일간 발효시킨 후, 발효된 1단담금 술덧에 수세, 침지, 증자과정을 거친 나머지 원료미 75%와 물을 가하여 2단담금하고 25℃에서 약 4∼5일정도 발효시켜 18%곡류발효원액을 제조한 후, 18% 곡류발효원액 1000㎖당 포도과즙을 125㎖에서 500㎖까지를 혼용하는 것을 특징으로 하는 과즙혼용주 제조방법.25% of the rice used as a raw material is cooled to about 38 ° C through washing, dipping, and increasing the steaming process, and seeding (종) is made here to prepare an entry and then add water and culture yeast to the prepared entry. After quenching and fermenting at 25 ° C for 2 to 3 days, the fermented single lump of rice was washed with water, immersed and steamed, and then double-diluted with 75% of raw rice and water. After fermentation to prepare a 18% cereal fermentation stock, grape juice per 1000ml of the 18% grain fermentation stock is mixed juice from 125ml to 500ml. 제1항에 있어서 첨가하는 과즙이 포도과즙외에 머루과즙, 사과과즙, 배과즙, 딸기과즙, 복분자과즙을 혼용하는 것을 특징으로 하는 과즙혼용주 제조방법.The juice preparation method according to claim 1, wherein the juice added is a mixture of grape juice, apple juice, apple juice, pear juice, strawberry juice, and bokbunja juice. 삭제delete
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