KR100349875B1 - The method of preparing fertilizer of pottasium substance with organic material component - Google Patents
The method of preparing fertilizer of pottasium substance with organic material component Download PDFInfo
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- KR100349875B1 KR100349875B1 KR1019990022629A KR19990022629A KR100349875B1 KR 100349875 B1 KR100349875 B1 KR 100349875B1 KR 1019990022629 A KR1019990022629 A KR 1019990022629A KR 19990022629 A KR19990022629 A KR 19990022629A KR 100349875 B1 KR100349875 B1 KR 100349875B1
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- fertilizer
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- pottasium
- organic material
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Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
Abstract
가리질함유광물, 염화가리광물, 황산가리광물 또는 염화칼리움에 동물성단백질, 강피류, 유박류를 황산에 용해시켜 교질화한 교질액을 첨가하여 반응시켜 얻어진 가리질 비료와 유기질 비료가 일정함량으로 균질화시킨 일체형의 유기물이 함유된 가리질 비료의 제조방법에 관한것임.Homogenous fertilizers and organic fertilizers obtained by dissolving animal proteins, barks and oils in sulfuric acid and adding colloidal colloids to the screening minerals, chlorinated chloride minerals, or chlorinated chlorides are homogenized to a uniform content. To a method of preparing fertilized fertilizer containing an integrated organic substance.
Description
본 발명은 유기물이 함유된 가리질 비료의 제조방법에 관한 것으로 더욱 구체적으로는 칼륨함유광석중 산화칼리움(K2O)함량이 높은 갈리하석의 가리원에 동물성단백질을 무기산에 용해시킨 교질물을 첨가하여 반응시킨 유기물이 함유된 가리질 비료의 제조방법에 관한 것이다.The present invention relates to a method for producing an organic matter-containing fertilizer, and more specifically to a colloid obtained by dissolving an animal protein in an inorganic acid in a galley basin with a high content of potassium oxide (K 2 O) in potassium-containing ore. It relates to a method for producing fertilized fertilizer containing added and reacted organic matter.
종래 가리질 비료에 있어서 염화칼륨은 그 자체는 중성이지만 토양에 사용하면 칼륨이 흡수되고 염소가 잔류하므로 생리적 산성비료이다.Potassium chloride is a neutral nutrient in conventional fertilizers, but it is a physiological acid fertilizer because potassium is absorbed and chlorine remains when used in soil.
토양에 습기를 증가시켜 작물의 한해(가뭄에 의한 피해)를 방지할 수 있으나 토양중의 칼슘과 작용하여 가용성 염화물로 되어 칼슘을 유실시키고 토양을 산성화시키는 문제점을 갖고 있다.Increasing the moisture in the soil can prevent the crop year (damage caused by drought), but has a problem in that it is soluble chloride to lose calcium and acidify the soil by working with calcium in the soil.
또 가리질 비료인 황산칼슘은 각종 비료중에서 가장 흡습성이 작고 중성이며, 각종 비료 배합이 가능하나 생리적 산성비료이고, 이것을 연용하면 토양유기물이 극도로 소모하고 함부로 사용하면 토양의 물리 화학적 성질을 나쁘게 할뿐 아니라 작물의 품질에도 해를 끼친다.In addition, calcium sulfate, which is a fertilizer, is the most hygroscopic and neutral among various fertilizers, but it is possible to mix various fertilizers, but it is a physiological acid fertilizer. It also harms crop quality.
본 발명은 종래 가리질 비료를 토양에 시비하는 과정에서 발생하는 문제점 즉, 토양중의 칼슘과 작용하여 가용성 염화물로 되어 칼슘을 유실되게하는 것을 방지하고, 가리질 비료의 연용에 따른 토양을 산성화시키는 문제점을 해결하고 농작물이 요구하는 적정량의 비료성분을 흡수할 수 있게하며 비료의 흡수성을 좋게하여 유실을 방지하기 위한 목적으로 가리질 비료와 유기물을 일체화시킨 유기물이 함유된 가리질 비료를 제조함에 목적이 있다 하겠다.The present invention is a problem that occurs in the process of fertilizing the conventional fertilizer to the soil, that is, to work with calcium in the soil to prevent the loss of calcium by soluble chloride, the problem of acidifying the soil according to the application of the fertilizer In order to solve the problem and to absorb the appropriate amount of fertilizer components required by the crop, and to improve the absorbency of the fertilizer to prevent the loss, the purpose of the manufacturing of the fertilizer containing the organic matter integrating the screening fertilizer and organic matter.
본 발명은 종래 가리질 비료를 시비하는 과정에서 발생하는 문제점 즉, 칼슘과 작용하여 칼슘을 가용성으로 쉽게 유실되게 하고 연용(연속적으로 사용함)함에 따라 토양을 산성화시키므로서 퇴비, 록비와 같은 유기질 비료를 병용하거나 별도로 시비해야하고 칼슘성분도 토양에 보충해야하는 문제점을 갖고 있으므로 이를 해결하는 방법으로 가리질 비료와 유기질 비료가 균질화된 일체성을 갖는 비료를 제조하는 방법으로 이를 구체적으로 설명하면 가리질함유광물중 산화칼리움(K2O)함량이 높은 갈리하석의 가리원을 분쇄한 분말에 동물성단백질을 무기산에 첨가하여 충분히 용해시켜 교질화한 교질액을 첨가하여 온도 38℃-40℃가 될 때까지 충분히 교반하여 반응시킨다음 반응물을 얻고 과잉의 산을 제거하기 위하여 암모니아수를 첨가하여 과잉의 산을 없앤다음 반건조시켜 60℃로 유지시킨 회전형 드럼에서 입상화한 제품을 얻었다.The present invention is a problem that occurs in the conventional fertilizer fertilizer process, that is, by working with calcium, so that the calcium is easily lost and soluble (use continuously) by acidifying the soil by using a combination of organic fertilizers such as compost, rockbi Or fertilizer separately, and calcium components must be supplemented to the soil. Therefore, the fertilizers and organic fertilizers to be homogenized are prepared as a method of solving this. (K 2 O) Animal powder is added to the inorganic acid and dissolved sufficiently to add the colloidal colloidal solution to the powder obtained by grinding Gariwon, a high content of galli stone, and stirred until the temperature is 38 ° C-40 ° C. Excess by adding ammonia water to obtain reactant and remove excess acid Removal of the acid, and then to obtain a granulated product in which a rotatable drum maintained at 60 ℃ by semi-dry.
본 방법에서 가리원의 원료로서 칼륨함유광석의 성분은 표 1과 같다.In this method, the components of potassium-containing ore as a raw material of Garywon are shown in Table 1.
또 유기물원으로서는 동물성단백질을 상온에서 황산에 용해시켜 교질물을 얻을 수 있지만 유기물원을 증자한다음 황산에 첨가하면 농작물의 흡수성을 증가시킬 수 있고, 또 제품의 고급화를 얻기 위해서는 유기물원에 황산을 첨가하여 얻어진 교질물을 원심분리기로서 찌꺼기(잔산)를 제거한 다음 정재된 교질물을 가리원 원료에 첨가할 수 있다.In addition, as an organic source, a colloidal product can be obtained by dissolving animal protein in sulfuric acid at room temperature, but by increasing the organic source and adding it to sulfuric acid, the absorption of crops can be increased, and sulfuric acid can be added to the organic source to obtain a high quality product. The colloid obtained by the addition may be removed by a centrifugal separator (residual acid), and then the refined colloid may be added to the Girwon raw material.
그리고 본 방법에서 가리원 물질과 교질물의 반응은 밀폐된 용기에 가리원분말과 교질물을 각각 동량으로 함께 충진시킨다음 전체 수분함량을 30%로 조절하고 상온(20℃)에서 교반하면서 반응시킨 결과 시간경과에 따른 온도변화는 표(2)와 같다.In this method, the reaction of Garywon material and colloid is filled with Garywon powder and colloid in an airtight container, respectively, in the same amount, and then the total water content is adjusted to 30% and the reaction is carried out while stirring at room temperature (20 ℃). The temperature change over time is shown in Table (2).
이상의 표(2)에서 반응시점에서 시간경과에 따라 반응온도는 점점 상승하여 39℃ 부근에서 더 반응이 진행되지 않음을 알 수 있고, 반응시간은 약 1시간 정도에서 완결됨을 알 수 있다.In the above Table (2), it can be seen that the reaction temperature gradually increases with time at the time of the reaction, so that the reaction does not proceed further around 39 ° C, and the reaction time is completed in about 1 hour.
이상의 반응을 거쳐 중성화 처리를 거쳐 건조입상화시킨 제품의 성분은 가리비료(K2O)10-35%, 유기물이 18-24%, 질소질비료 1-2%, 인산질비료 0.1-0.3% 기타 성분으로 구성된 유기물이 함유된 가리질 비료라할 수 있다.The components of dried granulated product through neutralization through the above reaction are 10-35% of scallop (K 2 O), 18-24% of organic matter, 1-2% of nitrogenous fertilizer, 0.1-0.3% of phosphate fertilizer It can be said to be a vegetative fertilizer containing an organic substance consisting of.
여기에서 가리질 비료는 가리원의 성분함량에 따라 최종제품인 가리비료 함량에 차이가 있을 수 있고, 소량으로 존재하는 질소비료는 염화암모늄 또는 황산암모늄이 될 수 있으며, 인산질비료는 유기물의 첨가에 따른 반응에 의하여 소량으로 얻어진 것이라 하겠다.Here, the fertilizer to be screened may have a difference in the content of the final product according to the ingredients of the garriwon, the nitrogen fertilizer present in a small amount may be ammonium chloride or ammonium sulfate, and the phosphate fertilizer is reacted according to the addition of organic matter. It is said that it is obtained in a small amount by.
본 발명에 의한 비료는 폐기되는 각종 유기물을 재활용할 수 있어 자원재활용이나 공해 방지측면에서 극히 유리하고 가리질 비료와 유기질비료가 일정비율로 균질한 상태로 일체화되어있어 종래와 같이 가리질 비료시비후 퇴비, 록비, 동물성유기질 비료를 별도로 시비하는 번잡성을 해소할 수 있으며, 토양중의 칼슘유실과 가리질 비료의 연용에 따른 토양의 산성화를 효율적으로 방지할 수 있다.The fertilizer according to the present invention can recycle various organic materials to be discarded and is extremely advantageous in terms of resource recycling or pollution prevention, and the fertilizer to be screened and organic fertilizer are integrated in a homogeneous state at a constant rate, so that the manure after fertilizing as conventionally, It can solve the trouble of fertilizing rock fertilizer and animal organic fertilizer separately, and can effectively prevent acidification of soil due to the application of calcium loss and screening fertilizer.
그 밖에도 가리질 비료와 유기질 비료를 일체화시키므로서 종래 별도로 시비되는 퇴비의 유실을 방지할 수 있고 시비의 작업성은 개선할 수 있으며 농작물에 흡수되는 흡수율을 증가시킬 수 있는 유기물이 함유된 가리질 비료라 할 수 있다.In addition, by integrating screening fertilizer and organic fertilizer, it is possible to prevent the loss of compost which is conventionally fertilized separately, improve the workability of fertilization, and can be said to be a screening fertilizer containing organic matter that can increase the absorption rate of crops. have.
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CN111213459A (en) * | 2020-02-04 | 2020-06-02 | 北京市农林科学院 | Comprehensive soil nematode preventing and controlling method |
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KR100382832B1 (en) * | 2000-09-14 | 2003-05-09 | (주)에코바이오 | Rock powder-based fertilizer composition and preparation thereof |
KR20040026466A (en) * | 2002-09-24 | 2004-03-31 | 박태헌 | The manufacturing processes and techniques of the organic compound fertilizer made from the natural organic minerals and the oil cakes of several kinds of seeds |
Citations (5)
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KR880006146A (en) * | 1986-11-07 | 1988-07-21 | 안상훈 | Manufacturing method of long-acting fertilizer |
JPH01197379A (en) * | 1988-02-02 | 1989-08-09 | Tosoh Corp | Mixed fertilizer |
JPH05330965A (en) * | 1992-02-03 | 1993-12-14 | Nakagawa Sakae | Production of organic fertilizer capable of increasing sugar content of crops by amino acid and its product |
JPH0733574A (en) * | 1993-07-26 | 1995-02-03 | Unie Kafue:Kk | Fertilizer, its production, use of the fertilizer, soil improver containing the fertilizer and soil containing the soil-improver |
KR980001865A (en) * | 1997-12-29 | 1998-03-30 | 김용환 | Alkaline water quality and soil modifier aqueous solution composition based on potassium and preparation method thereof |
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1999
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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KR880006146A (en) * | 1986-11-07 | 1988-07-21 | 안상훈 | Manufacturing method of long-acting fertilizer |
JPH01197379A (en) * | 1988-02-02 | 1989-08-09 | Tosoh Corp | Mixed fertilizer |
JPH05330965A (en) * | 1992-02-03 | 1993-12-14 | Nakagawa Sakae | Production of organic fertilizer capable of increasing sugar content of crops by amino acid and its product |
JPH0733574A (en) * | 1993-07-26 | 1995-02-03 | Unie Kafue:Kk | Fertilizer, its production, use of the fertilizer, soil improver containing the fertilizer and soil containing the soil-improver |
KR980001865A (en) * | 1997-12-29 | 1998-03-30 | 김용환 | Alkaline water quality and soil modifier aqueous solution composition based on potassium and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111213459A (en) * | 2020-02-04 | 2020-06-02 | 北京市农林科学院 | Comprehensive soil nematode preventing and controlling method |
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