KR100346092B1 - Manufacturing method of activated charcoal with micro-pore, loess board and mortar using the same - Google Patents

Manufacturing method of activated charcoal with micro-pore, loess board and mortar using the same Download PDF

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KR100346092B1
KR100346092B1 KR1020000035666A KR20000035666A KR100346092B1 KR 100346092 B1 KR100346092 B1 KR 100346092B1 KR 1020000035666 A KR1020000035666 A KR 1020000035666A KR 20000035666 A KR20000035666 A KR 20000035666A KR 100346092 B1 KR100346092 B1 KR 100346092B1
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activated carbon
high temperature
board
dried
ocher
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KR20020000664A (en
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조상도
문종욱
류택동
정영철
전성식
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/30Active carbon
    • C01B32/354After-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28CPREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C7/00Controlling the operation of apparatus for producing mixtures of clay or cement with other substances; Supplying or proportioning the ingredients for mixing clay or cement with other substances; Discharging the mixture
    • B28C7/0007Pretreatment of the ingredients, e.g. by heating, sorting, grading, drying, disintegrating; Preventing generation of dust
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28CPREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C7/00Controlling the operation of apparatus for producing mixtures of clay or cement with other substances; Supplying or proportioning the ingredients for mixing clay or cement with other substances; Discharging the mixture
    • B28C7/04Supplying or proportioning the ingredients
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/30Active carbon
    • C01B32/306Active carbon with molecular sieve properties
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/30Active carbon
    • C01B32/312Preparation
    • C01B32/318Preparation characterised by the starting materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/022Carbon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/10Clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/026Comminuting, e.g. by grinding or breaking; Defibrillating fibres other than asbestos
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/04Heat treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0032Controlling the process of mixing, e.g. adding ingredients in a quantity depending on a measured or desired value

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Civil Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

본 발명은 각종 활성탄(대나무, 참나무, 소나무)의 미세기공을 보존하는 활성탄 제조방법 및 상기 활성탄과 황토를 이용하여 건축 내장용 마감재인 활성탄 황토보드를 제조하는 방법에 관한 것으로서 본 발명의 제조방법은 다음과 같은 공정으로 진행한다.The present invention relates to a method of manufacturing activated carbon for preserving micropores of various activated carbons (bamboo, oak, pine) and a method for manufacturing activated carbon ocher boards, which are finishing materials for building interior using the activated carbon and ocher. Proceed as follows.

즉, 상기 대나무, 참나무, 소나무의 목재를 1000∼1500℃로 탄화시켜 활성탄을 제조하는 탄화단계, 상기 단화단계에서 탄화된 활성탄을 선별하는 선별단계, 상기 선별된 활성탄을 분쇄하는 분쇄단계, 상기 분쇄된 활성탄을 0.5∼1.0mm의 입자크기로 분류하는 분류단계, 상기 분류된 활성탄을 식품첨가제인 다우코닝 LS303 실리콘(3) : 물(7) 비율로 혼합한 다음 침전하는 침전단계, 침전시킨 활성탄에서 수분을 제거하고 건조시키는 건조단계, 상기 건조된 활성탄과 모래(13 wt%), 면사(3 wt%), 황토(7 wt%), 분쇄한 게르마늄광석(2.5 wt%), 분쇄한 맥반석 광물(1.5 wt%)및 석고플라스터(21 wt%)을 혼합하여 제조된 재료를 물과 혼합하여 일정 수준의 유동성을 가지게 한 후 성형기로 제조하는 성형단계, 성형된 제품의 건조 및 양생단계, 규격품으로 절단하는 가공단계로 구성된다.That is, the carbonization step of carbonizing the wood of the bamboo, oak, pine to 1000 ~ 1500 ℃ to produce activated carbon, the sorting step of sorting the activated carbon carbonized in the shoe step, the grinding step of grinding the selected activated carbon, the pulverization Classifying step of classifying the activated carbon into the particle size of 0.5 ~ 1.0mm, mixing the sorted activated carbon in a food additive Dow Corning LS303 silicone (3): water (7) ratio, and then settling the precipitated activated carbon. Drying step to remove moisture and dry, the dried activated carbon and sand (13 wt%), cotton yarn (3 wt%), ocher (7 wt%), crushed germanium ore (2.5 wt%), pulverized elvanite mineral ( 1.5 wt%) and gypsum plaster (21 wt%) are mixed with water to have a certain level of fluidity, followed by a molding step, a drying and curing step of a molded product, and cutting into a standard product. Consists of machining steps .

상기 제조공정을 통하여 활성탄 황토보드를 제조함으로써 기존의 석고보드보다 압축 및 인장강도, 방습 및 내구성능이 우수하며, 특히 건축물의 실내 습기제거 및 곰팡이·악취제거에 뛰어난 건축자재의 제조가 가능하며, 이는 기존의 석고보드보다 품질과 기능 측면에서 월등한 내장재 역할을 하게 된다.By manufacturing the activated carbon loess board through the manufacturing process, the compressive and tensile strength, moisture resistance and durability are superior to the conventional gypsum board, and in particular, it is possible to manufacture building materials excellent for removing indoor moisture of the building and removing mold and odor. It will serve as a superior interior material in terms of quality and function than conventional gypsum board.

Description

미세기공 보존 활성탄 및 이를 활용한 황토 보드 및 모르타르 제조방법 {Manufacturing method of activated charcoal with micro-pore, loess board and mortar using the same}Microporous preservation activated carbon and manufacturing method of ocher board and mortar using same {Manufacturing method of activated charcoal with micro-pore, loess board and mortar using the same}

본 발명은 활성탄과 황토를 이용하여 건축용 내장마감재인 활성탄 보드의 제조방법에 관한 것으로서, 혼합물로 인한 활성탄 미세기공의 막힘을 최소화하도록 처리하고 미세기공에 혼입되는 물질이 일정시간 지나면 원상태로 전환하여 활성탄의 기능을 충분히 발휘할 수 있는 활성탄 제조방법에 관한 것이다.The present invention relates to a method for manufacturing activated carbon board, which is a built-in finishing material for building using activated carbon and loess, and to minimize the blockage of activated carbon micropores due to the mixture, and converts the activated carbon to the original state after a certain time. It relates to an activated carbon production method that can fully exhibit the function of.

현재 국내에서 사용되고 있는 석고보드는 석고의 미분말과 모래, 균열 저감용 석면을 일정 비율로 첨가하여 제조된 제품이 대부분을 차지하고 있다.Currently, gypsum board used in Korea occupies most of products manufactured by adding gypsum fine powder, sand and crack asbestos at a certain ratio.

상기 기존 석고보드는 급속 경화재인 석고와 모래, 석고보드 양면에 붙이는 펄프류로 만들어졌기 때문에 무겁고 압축강도 및 인장강도가 취약하여 시공시 제품관리가 어려우며, 특히 수분 흡수능력 또한 경화된 석고에 준한 것으로서 경제성 및 내구성 측면에서 문제점을 가지고 있다. 따라서 상기 단점을 보완하고 제품의 내구성, 견고성, 수분 흡수성을 증진시키기 위해 석분, 자갈, 모래 등이 첨가된 보드류를 제조하려는 시도가 계속되어져 왔으나 기경성(anhydraulicity)인 석고 플라스터의 비중과 특성 때문에 여러 가지 문제점을 야기시켜왔다. 즉 압축강도와 인장강도를 높이기 위해 자갈과 모래를 과다 혼입한 경우, 부피에 비해 중량이 높아지므로 운반, 사용시 많은 어려움이 있으며, 인장력을 증대시키기 위하여 섬유의 혼입율을 과다 하게 올렸을 때는 수분흡수율이 저하되기 때문에 흡수성능을 만족시키고 내구성 및 경량성을 동시에 충족시키는 마감재용 보드를 제조하는데는 많은 어려움이 있었다.Since the existing gypsum board is made of gypsum and sand, which are fast curing materials, and pulp attached to both sides of the gypsum board, it is heavy and has poor compressive strength and tensile strength, making it difficult to manage the product during construction. There are problems in terms of economics and durability. Therefore, attempts have been made to manufacture boards to which stone powder, gravel, sand, etc. have been added in order to compensate for the above disadvantages and to improve the durability, robustness, and water absorption of the product, but due to the specific gravity and characteristics of the gypsum plaster which is anhydraulicity, It has caused some problems. In other words, when excessive mixing of gravel and sand to increase the compressive strength and tensile strength, the weight is higher than the volume, there is a lot of difficulties in transportation and use, and the water absorption rate is lowered when excessively increasing the mixing ratio of the fiber to increase the tensile strength As a result, there have been many difficulties in manufacturing a finishing board that satisfies absorbent performance and simultaneously meets durability and light weight.

따라서 1/10000mm 정도의 미세기공이 무수히 분포되어 있으며, 1g당 총면적 250∼300㎡(75∼90평) 정도의 표면적을 가짐으로써 물과 공기 중에 존재하는 유해 물질과 악취 성분을 제거하는 기능이 있는 활성탄과 황토를 이용하여 가벼우면서도 강하고 수분흡수력과 흡음 및 차음성능이 뛰어난 활성탄 황토보드를 제조하는 연구가 수행되어지고 있다. 그러나 상기 활성탄의 경우, 상기 장점에도 불구하고 다른 이물질의 혼합을 거부하는 특징과 혼합된 이물질이 활성탄의 미세기공을 고체화시키는 문제점으로 인하여 실제적인 현장에 적용하지 못하고 있는 실정이다.Therefore, the micropores of about 1 / 10000mm are distributed innumerably, and have a surface area of about 250 ~ 300㎡ (75 ~ 90 pyeong) per 1g, which removes harmful substances and odors in water and air. Research on the manufacture of activated carbon ocher board using light activated carbon and loess, excellent in water absorption, sound absorption and sound insulation, has been conducted. However, in the case of the activated carbon, despite the above advantages, the foreign matter mixed with the feature of rejecting the mixing of other foreign matters is not applied to the actual site due to the problem of solidifying the micropores of the activated carbon.

본 발명의 목적은 상기 석고보드의 문제점 및 활성탄의 문제점을 해결하기 위한 상기 활성탄의 미세기공이 유지되도록 하는 각종 보드 또는 모르타르에 혼합하는 활성탄 제조방법을 제공하는데 있다.An object of the present invention is to provide a method for producing activated carbon mixed with various boards or mortar to maintain the micropores of the activated carbon for solving the problems of the gypsum board and the problem of activated carbon.

본 발명의 다른 목적은 상기 활성탄의 이용을 통하여 석고보드 특성상 무겁고 파손율이 높으며, 낮은 흡수율을 보완하고 제거함과 동시에 황토, 게르마늄광석 및 맥반석을 혼합하여 악취제거 및 실내의 곰팡이 방지의 기능을 가지고 면사, 황토 및 석고를 이용하여 가볍고 강한 건축 내장용 보드 제조방법을 제공하는데 있다.Another object of the present invention is heavy and high failure rate in the characteristics of gypsum board through the use of the activated carbon, supplementing and removing the low absorption rate and at the same time by mixing ocher, germanium ore and elvan to remove odor and prevent mold in the room To provide a light and strong building interior board manufacturing method using, ocher and gypsum.

이외에 상기 장점을 가지는 미세기공이 유지된 활성탄, 황토, 게르마늄광석 및 맥반석의 혼합물로 이루어진 상기 보드와 유사한 특성을 가지는 정벌용 모르타르 제조방법을 제공하는데 있다.In addition, to provide a method for producing mortar for juveniles having similar characteristics to the board made of a mixture of activated carbon, loess, germanium ore and elvan, which have the micropores having the above advantages.

본 발명은 활성탄의 주재료인 목재(특히 소나무, 참나무, 대나무)를 분류하여 1000℃∼1500℃ 온도로 가마에서 가열, 탄화시킨 후 탄화된 활성탄만 선별하여 이것을 0.5∼1.0mm의 입자로 분쇄하고 여기에 식품첨가제인 다우코닝 LS303 실리콘과 물을 3:7로 섞은 용액에 침전시킨 것을 1차 건조한 다음, 게르마늄광석, 맥반석, 황토, 모래, 면사 및 석고 플라스터를 혼합하여 성형, 양생과정을 거쳐 활성탄 황토보드를 제조하는 것이다.The present invention classifies the main materials of activated carbon (particularly pine, oak, and bamboo), heats and carbonizes them in a kiln at a temperature of 1000 ° C to 1500 ° C, and then sorts only the carbonized activated carbon and grinds it into particles of 0.5 to 1.0 mm. Was precipitated in a solution of Dow Corning LS303 silicone, which is a food additive, in a 3: 7 mixture of water, and dried first.Then, it was formed and cured by mixing germanium ore, elvan, loess, sand, cotton yarn and gypsum plaster. To manufacture the board.

즉, 본 발명의 주재료인 활성탄이 다른 이물질의 혼합을 거부하는 특징과 혼합된 이물질이 활성탄의 미세기공을 고체화시켜 버리는 문제를 해결하기 위하여 분쇄된 활성탄의 미세기공의 이물질로 인한 충전을 피하기 위해 식품첨가제인 다우코닝 LS303 실리콘(3) : 물(7)의 비율로 혼합하여 희석시킨 후, 이것에 분쇄·선별된 활성탄을 마대에 담아 상기 혼합액에 10∼30분간 침전시켜 건진 것을 100∼120℃의고열로 건조시킨다. 활성탄을 다우코닝 LS303 실리콘과 물의 혼합액에 침전시키는 이유는 활성탄의 미세기공이 다른 이물질로 충전되는 것을 막기 위함이며, 침전시킨 활성탄을 혼합·건조시키는 과정을 통해 활성탄의 미세기공을 메우고 있는 다른 혼합물은 서서히 용해되어 활성탄 고유의 특징인 미세기공을 그대로 복원시켜 상기 문제점을 해결하였고, 추가적으로 혼입되는 재료의 안전한 경화를 위해 보드용 석고 플라스터를 사용하였다. 또한 일단 경화에 성공하였다 하더라도 경화속도와 경화 반응에 소요되는 시간 및 경화가 완료된 후 강도가 제품의 품질에 악영향을 미치는 부작용을 발생시킨다. 즉, 경화 속도가 너무 빨리 진행되면 제품 제조과정에 시간적 문제와 제품에 완성도를 인정할 수 없고, 너무 느리게 경화되면 보드가 얇은 아크릴과 같이 휘청거려 보드의 기능을 상실하게 되는 문제점을 가진다. 따라서 상기 문제점을 해결하기 위하여 활성탄에 황토를 섞어 신축성을 조절하고, 석고와 광물가루를 분쇄하여 배합함으로써 강도를 증대시키고 중량은 감소하는 이중효과를 얻을 수 있었다. 또한 응집력을 높일 수 있는 석면을 대체하기 위하여 미세한 면사를 넣어 응집력을 높였으며, 보드의 견고성을 향상시키기 위해 양면에 균열 방지망과 펄프류를 부착시켜, 기존 석고보드의 단점을 개선토록 하였다.That is, in order to solve the problem that the activated carbon, which is the main material of the present invention, refuses the mixing of other foreign substances and the mixed foreign substances solidify the micropores of the activated carbon, foods to avoid filling by the foreign substances of the micropores of the pulverized activated carbon Dow Corning LS303 silicone (3) as an additive was mixed and diluted at a ratio of water (7), and then pulverized and screened activated carbon was placed in a sack and precipitated in the mixed solution for 10 to 30 minutes to dry. Dry at high heat. The reason why the activated carbon is precipitated in the mixture of Dow Corning LS303 silicon and water is to prevent the micropores of the activated carbon from filling with other foreign substances, and the other mixture filling the micropores of the activated carbon through mixing and drying the precipitated activated carbon is The above problems were solved by slowly dissolving the micropores, which are inherent in activated carbon, and additionally used a board plaster plaster for safe curing of the mixed materials. In addition, even after successful curing, the curing rate, the time required for the curing reaction, and the strength after the completion of the curing has a side effect that adversely affects the quality of the product. In other words, if the curing speed is too fast, the product manufacturing process cannot recognize the time and completeness of the product, and if the curing is too slow, the board may be shaken like thin acrylic and lose the function of the board. Therefore, in order to solve the above problems, it was possible to obtain the dual effect of increasing the strength and reducing the weight by adjusting the elasticity by mixing the clay with activated carbon and crushing and mixing the gypsum and mineral powder. In addition, fine coarse yarn was added to replace asbestos to increase cohesiveness, and cohesion was improved by attaching crack prevention nets and pulp on both sides in order to improve the firmness of the board.

즉, 상기 침전 및 건조과정을 거친 활성탄의 특징은 활성탄의 미세기공이 잠시 충전되었다가도 이물질의 배합과정에서 용해, 분해되어 원재료 활성탄의 본래 상태대로 미세기공이 존재하게 되므로 신축성, 단열성, 흡음 및 방음성능이 타 재료보다 월등해진다. 또한 상기 활성탄의 특징에 황토와 석고 플라스터의 장점을 접목시켰으며, 여기에 이물질과 반응할 때 게르마늄광석 속에 내포된 이온전자를 순수 산소로 전환, 생성시켜 주어 분해, 중화 및 제거작용을 일으키는 광물성 원소인 게르마늄광석을 혼합시켰으며, 또한 맥반석 광물을 추가로 혼입하여 시멘트 모르타르의 마감벽면이나 실내건축물의 공간장식을 위해 사용한 각종 도료의 화학성 악취를 보다 효과적으로 제거하도록 하였다.In other words, the characteristic of activated carbon that has been precipitated and dried is that the micropores of activated carbon are temporarily charged and then dissolved and decomposed in the mixing process of foreign substances, so that the micropores exist as the raw materials of the activated carbon. Performance is superior to other materials. In addition, the characteristics of the activated carbon are combined with the merits of ocher and gypsum plaster, and when reacting with foreign substances, the mineral elements that convert and generate ion electrons contained in germanium ores into pure oxygen, causing decomposition, neutralization and removal. Phosphorus germanium ores were mixed, and in addition, elvan minerals were added to remove the chemical odors of various paints used for the space decoration of cement mortar finishing walls and interior buildings.

또한 기존 석고보드의 제조공정에서는 사용되지 않는 합성수지 또는 천연섬유로 직조된 그물망인 균열 방지망을 보드 양면에 접합함으로써 운반 및 사용과정에서 파손율을 줄여 내구성을 갖도록 하였으며, 상기 방법을 통하여 제조된 황토보드는 단위중량 또한 기존 석고보드에 비해 1/4정도로 가벼워지므로 시공의 편의성을 확보할 수 있다.In addition, by bonding the crack prevention net, which is a mesh made of synthetic resin or natural fiber, which is not used in the manufacturing process of the existing gypsum board to both sides of the board, the durability is reduced by reducing the breakage rate during the transport and use process. The unit weight is also about 1/4 lighter than the existing gypsum board, thereby ensuring the convenience of construction.

또한, 현장에서 일반적으로 많이 사용되고 있는 시멘트, 세라믹 또는 황토가 첨가된 제품은 현장에서 혼합을 실시하여 건조 또는 양생에 필요한 원가 및 시간이 많이 소요되는 반면, 본 발명의 황토보드는 물을 혼합하지 아니하고 건조된 상태로 포장하여 현장에서 바닥이나 벽면의 적정부위에 정벌용 재료로 사용할 수 있도록 건식공법을 채택함으로써 제조단가 및 생산공정을 단축시킬 수 있다.In addition, cement, ceramic or loess added products commonly used in the field is a lot of cost and time required for drying or curing by mixing in the field, while the loess board of the present invention does not mix water The dry packing method can be used as a material for consolidation on the floor or wall at the site by drying the packaging, which can shorten the manufacturing cost and production process.

본 활성탄 황토보드의 제조방법에 대한 실시예는, 먼저 대나무, 참나무, 소나무를 각각 길이 500∼1000mm로 절단·가공하는 단계, 상기 재료를 각각 1000∼1500℃ 고온으로 탄화시키는 탄화단계, 상기 탄화단계에서 탄화된 활성탄을 각각 선별, 분리하는 단계, 상기 분리한 활성탄을 각각 분쇄하여 0.5∼1.0mm의 입자크기로 선별하는 단계, 상기 선별되어진 활성탄의 미세기공을 보호하기 위해 상기 활성탄을 마대에 각각 담아 다우코닝 LS303 실리콘과 물을 3 : 7의 비율로 희석시킨 희석액에 10∼30분간 침전시키는 단계, 상기 침전시킨 활성탄을 100∼120℃의 고온에서 건조시킨후 1.0mm망으로 치는 단계, 0.15∼0.20mm의 입자크기로 분쇄한 게르마늄광석과 맥반석, 잡티 등 이물질을 제거하고 가로, 세로 1.0mm망으로 쳐서 100∼150℃의 고온에서 건조시킨 양질의 황토, 가로, 세로 1.0mm망으로 쳐서 100∼150℃의 고온에서 건조시킨 양질의 모래, 인장용 혼합 미세 면사 및 석고 플라스터를 상기 활성탄에 게르마늄광석(2.5wt%), 맥반석(1.5wt%), 황토(7wt%), 모래(13wt%), 면사(3wt%) 및 석고 플라스터(21wt%)의 비율로 혼합하는 단계, 상기 혼합한 재료에 물을 첨가하여 적정수준의 유동성 평가를 거친 후, 성형기를 통과하는 과정에서 균열 방지망을 접착하고 표면처리 후 펄프류(종이 각지)를 접착하는 단계, 상기 석고 플라스터는 기경성이므로 공기에 노출되게 하여 성형과 동시에 자체 경화시키거나, 여기에 60∼70℃의 열을 더 추가하여 짧은 시간에 경화시키는 양생단계, 제품의 크기는 임의로 확장 및 축소가 가능하며, 성형화되어 건조된 제품을 규격별로 절단·가공하면 목표의 활성탄 황토보드가 완성되는 단계로 구성된다.Embodiments of the method for manufacturing the activated carbon ocher board, the first step of cutting and processing bamboo, oak, pine to each 500 to 1000mm in length, the carbonization step of carbonizing the material at 1000 to 1500 ℃ high temperature, respectively, the carbonization step Selecting and separating the carbonized activated carbon at each step, and crushing the separated activated carbon, respectively, and sorting to a particle size of 0.5 ~ 1.0mm, each of the activated carbon in the sack to protect the micropores of the selected activated carbon Precipitating the Dow Corning LS303 silicone and water in a diluent diluted 3: 7 for 10 to 30 minutes, drying the precipitated activated carbon at a high temperature of 100 to 120 ° C. and striking with 1.0 mm mesh, 0.15 to 0.20 Debris of germanium ore, elvan, blemishes, etc., crushed to a particle size of mm and removed with good quality ocher, horizontal, High quality sand, tensile mixed fine cotton yarn and gypsum plaster, dried at a high temperature of 100 to 150 ° C. with a 1.0 mm mesh, were added to the activated carbon with germanium ore (2.5 wt%), elvan (1.5 wt%), and loess (7 wt%). ), Sand (13wt%), cotton yarn (3wt%) and gypsum plaster (21wt%) in the ratio of mixing, adding water to the mixed material after the appropriate level of fluidity evaluation and passing through the molding machine Bonding the crack prevention net and surface pulp (paper) after the surface treatment, the gypsum plaster is airtight, so that it is exposed to the air to cure itself at the same time of molding, or further heat of 60 ~ 70 ℃ In addition, the curing step of curing in a short time, the size of the product can be arbitrarily expanded and reduced, and consists of the step of completing the activated carbon ocher board of the target when the molded and dried product is cut and processed according to the specifications.

또한 상기 활성탄 황토보드의 가공 절단면의 부러짐과 부스러짐을 방지하기 위하여 활성탄을 포함하는 액체형 실리콘 또는 일반 실리콘으로 처리하며 마감할 수 있다. 상기 활성탄 황토보드는 건축용 내부 마감재뿐만 아니라 상기 우기시나 장마철의 습기 및 곰팡이를 차단할 수 있는 특징을 이용하여 가구(부엌 싱크대, 옷장, 신발장)의 내장재로서도 다양하게 적용할 수 있다.In addition, in order to prevent breakage and chipping of the processed cut surface of the activated carbon ocher board, it may be finished by treating with liquid silicon or ordinary silicon containing activated carbon. The activated carbon ocher board can be applied to various interior materials of furniture (kitchen sinks, wardrobes, shoe cabinets) using not only the interior finishing materials for construction but also the ability to block moisture and mold during the rainy season or during the rainy season.

한편, 상기 활성탄에 게르마늄광석(2.5wt%), 맥반석(1.5wt%), 황토(7wt%), 모래(13wt%), 면사(3wt%) 및 석고 플라스터(21wt%)를 혼합하는 혼합단계에서 석고플라스터(21wt%)대신에 석고분말(30wt%)를 혼합하고 석고 플라스터의 급속한 경화를 지연시키기 위하여 백색 시멘트(3 wt%)를 더 첨가하여 정벌용 모르타르를 제조할 수 있다. 상기 정벌용 모르타르는 물을 혼합하지 않은 건조된 상태로 포장·제품화하여 현장에서 바로 물과 혼합하여 사용할 수 있으며, 상기 백색 시멘트에 따른 경화시간 지연에 따라 미장공의 현장작업이 용이하도록 하였다.On the other hand, in the mixing step of mixing the germanium ore (2.5wt%), elvan (1.5wt%), ocher (7wt%), sand (13wt%), cotton yarn (3wt%) and gypsum plaster (21wt%) to the activated carbon Instead of gypsum plaster (21 wt%), gypsum powder (30 wt%) may be mixed and white cement (3 wt%) may be further added to delay the rapid curing of the gypsum plaster. The mortar for punishment can be packaged and commercialized in a dry state without mixing the water can be used immediately mixed with the water in the field, the site work of the plasterer according to the delay of the curing time according to the white cement.

상술한 바와 같이 본 발명에 의한 활성탄 황토보드는 활성탄과 석고 플라스터의 결합을 극대화시켰을 뿐만 아니라 게르마늄광석과 황토, 맥반석을 첨가함으로써 종래의 내장마감재인 석고보드에 비해 가볍고 파손율이 적고 강도 증가에 따라 내구성이 증대된 건축자재 또는 가구용 등의 다양한 응용성을 가지는 자재이다. 또한 상기 보드는 제조시에 사용되는 균열 보호망 적용에 의해서 강도 개선효과를 더 높일 수 있다.As described above, the activated carbon loess board according to the present invention not only maximizes the binding of activated carbon and gypsum plaster, but also adds germanium ore, loess, and elvan to lighter, less breakage rate, and increases the strength as compared to the conventional gypsum board. It is a material having various applications such as building materials or furniture with increased durability. In addition, the board can further enhance the strength improvement effect by applying a crack protection net used at the time of manufacture.

상기 개선점 이외에도 상기 보드는, 실내의 습기는 물론이며 휘발성 악취제거에 탁월한 기능을 발휘하며, 시멘트에서 발생하는 각종 유해 화학물질 및 각종 도료의 화학성 악취를 효과적으로 흡수함은 물론 방음·차음효과에서도 기존의 석고보드에 비하여 뛰어난 성능을 나타낸다.In addition to the above improvements, the board exhibits excellent functions for removing volatile odors as well as moisture in the room, and effectively absorbs chemical odors of various harmful chemicals and paints generated from cement, as well as existing sound insulation and sound insulation effects. Excellent performance compared to gypsum board.

또한 활성탄 황토 정벌용 모르타르는 주택의 바닥이나 실내 벽체에 시공하여 우기시나 장마철의 습기를 흡수하여 곰팡이의 발생을 차단할 수 있다.In addition, activated charcoal loess mortar can be installed on the floor or interior wall of the house to absorb the moisture during the rainy season or during the rainy season to block the occurrence of mold.

Claims (5)

활성탄을 분쇄하여 다우코닝 LS303 실리콘과 물을 3 : 7의 비율로 희석시킨 희석액에 10∼30분간 침전시키는 단계; 및,Pulverizing the activated carbon and precipitating the Dow Corning LS303 silicone and water in a diluent diluted 3: 7 for 10 to 30 minutes; And, 상기 침전시킨 활성탄을 100∼120℃의 고온에서 건조시키는 단계로 이루어지는 것을 특징으로 하는 미세기공 보존 활성탄의 제조방법Method for producing microporous preservation activated carbon, characterized in that the step of drying the precipitated activated carbon at a high temperature of 100 ~ 120 ℃ 제1항에서, 상기 활성탄에 게르마늄광석, 맥반석, 황토, 석고, 모래 및 황토를 첨가하여 건축내장용 또는 가구용 보드 제작 방법The method of claim 1, wherein the addition of germanium ore, elvan, loess, gypsum, sand and loess to the activated carbon, the building interior or furniture board manufacturing method 제1항에서, 상기 활성탄이 대나무, 소나무 또는 참나무를 1000∼1500℃에서 탄화시켜 제조된 활성탄 또는 그 혼합물인 것을 특징으로 하는 미세기공 보존 활성탄 제조방법The method of claim 1, wherein the activated carbon is activated carbon prepared by carbonizing bamboo, pine or oak at 1000 to 1500 ° C or a mixture thereof. 목재를 길이 500∼1000mm로 절단·가공하는 단계;Cutting and processing the wood to a length of 500 to 1000 mm; 상기 재료를 각각 1000∼1500℃ 고온으로 탄화시키는 탄화 단계;A carbonization step of carbonizing the materials at 1000 to 1500 ° C. high temperature, respectively; 상기 탄화단계에서 탄화된 활성탄을 각각 선별, 분리하는 단계;Sorting and separating the activated carbon carbonized in the carbonization step; 상기 분리한 활성탄을 각각 분쇄하여 0.5∼1.0mm의 입자크기로 선별하는 단계;Pulverizing the separated activated carbons and sorting the particles to a particle size of 0.5 to 1.0 mm; 상기 선별되어진 활성탄을 마대에 각각 담아 다우코닝 LS303 실리콘과 물을 3 : 7의 비율로 희석시킨 희석액에 10∼30분간 침전시키는 단계;Immersing the selected activated carbon in a sack for 10-30 minutes in a dilution of Dow Corning LS303 silicon and water diluted at a ratio of 3: 7; 상기 침전시킨 활성탄을 100∼120℃의 고온에서 건조시킨후 1.0mm망으로 치는 단계;Drying the precipitated activated carbon at a high temperature of 100 to 120 ° C. and then striking with 1.0 mm mesh; 0.15∼0.20mm의 입자크기로 분쇄한 게르마늄광석과 맥반석, 가로, 세로 1.0mm망으로 쳐서 100∼150℃의 고온에서 건조시킨 황토, 가로, 세로 1.0mm망으로 쳐서 100∼150℃의 고온에서 건조시킨 모래, 면사 및 석고 플라스터를 상기 활성탄에 게르마늄광석(2.5wt%), 맥반석(1.5wt%), 황토(7wt%), 모래(13wt%), 면사(3wt%) 및 석고 플라스터(21wt%)의 비율로 혼합하는 단계;Germanium ore pulverized to a particle size of 0.15 to 0.20 mm and dried at a high temperature of 100 to 150 ° C., dried at high temperature of 100 to 150 ° C., and dried at a high temperature of 100 to 150 ° C. The activated sand, cotton yarn and gypsum plaster were added to the activated carbon by germanium ore (2.5 wt%), elvan (1.5 wt%), ocher (7 wt%), sand (13 wt%), cotton yarn (3 wt%) and gypsum plaster (21 wt%). Mixing at a ratio of; 상기 혼합한 재료에 물을 첨가하여 적정수준의 유동성을 갖게 하여, 성형기를 통과시켜 보드를 성형하는 단계;Adding water to the mixed material to provide an appropriate level of fluidity, and passing the molding machine to form a board; 상기 보드에 균열 방지망을 접착하고 표면처리 후 펄프류(종이 각지)를 접착하는 단계;Adhering a crack preventing net to the board and adhering pulp (paper all over) after surface treatment; 상기 펄프류가 접착된 보드를 공기에 노출되게 하여 자체 경화시키거나 60∼70℃의 열을 더 추가하여 짧은 시간에 경화시키는 양생단계; 및,Curing step by allowing the pulp is bonded to the board exposed to the air to cure itself or to add a heat of 60 ~ 70 ℃ to cure in a short time; And, 상기 양생된 건조된 제품을 규격별로 절단·가공하는 단계;Cutting and processing the cured dried product according to specifications; 로 구성되는 것을 특징으로 하는 활성탄 황토보드 제작방법Activated carbon ocher board manufacturing method characterized in that 목재를 길이 500∼1000mm로 절단, 가공하는 단계;Cutting and processing the wood to 500-1000 mm in length; 상기 재료를 각각 1000∼1500℃ 고온으로 탄화시키는 탄화 단계;A carbonization step of carbonizing the materials at 1000 to 1500 ° C. high temperature, respectively; 상기 탄화단계에서 탄화된 활성탄을 각각 선별, 분리하는 단계;Sorting and separating the activated carbon carbonized in the carbonization step; 상기 분리한 활성탄을 각각 분쇄하여 0.5∼1.0mm의 입자크기로 선별하는 단계;Pulverizing the separated activated carbons and sorting the particles to a particle size of 0.5 to 1.0 mm; 상기 선별되어진 활성탄을 마대에 각각 담아 다우코닝 LS303 실리콘과 물을 3 : 7의 비율로 희석시킨 희석액에 10∼30분간 침전시키는 단계;Immersing the selected activated carbon in a sack for 10-30 minutes in a dilution of Dow Corning LS303 silicon and water diluted at a ratio of 3: 7; 상기 침전시킨 활성탄을 100∼120℃의 고온에서 건조시킨후 1.0mm망으로 치는 단계; 및,Drying the precipitated activated carbon at a high temperature of 100 to 120 ° C. and then striking with 1.0 mm mesh; And, 0.15∼0.20mm의 입자크기로 분쇄한 게르마늄광석과 맥반석, 가로, 세로 1.0mm망으로 쳐서 100∼150℃의 고온에서 건조시킨 황토, 가로, 세로 1.0mm망으로 쳐서 100∼150℃의 고온에서 건조시킨 모래, 면사, 석고 및 백색 시멘트를 상기 활성탄에 게르마늄광석(2.5wt%), 맥반석(1.5wt%), 황토(7wt%), 모래(13wt%), 면사(3wt%), 석고분말(30wt%) 및 백색시멘트(3wt%)의 비율로 혼합하는 단계;Germanium ore pulverized to a particle size of 0.15 to 0.20 mm and dried at a high temperature of 100 to 150 ° C., dried at high temperature of 100 to 150 ° C., and dried at a high temperature of 100 to 150 ° C. Sand, cotton yarn, gypsum and white cement were added to the activated carbon to germanium ore (2.5 wt%), elvan (1.5 wt%), ocher (7 wt%), sand (13 wt%), cotton yarn (3 wt%), gypsum powder (30 wt%). %) And white cement (3wt%) at the ratio of mixing; 로 구성되는 것을 특징으로 하는 활성탄 황토 정벌용 모르타르 제조방법Activated carbon loess mortar production method characterized in that consisting of
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100803740B1 (en) * 2006-02-13 2008-02-15 오희범 An activated carbon block of filter assembly and the method for manufacturing the same
KR102245412B1 (en) * 2020-02-28 2021-04-28 자현당 주식회사 Finishing material for far-infrared radiation

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KR100723647B1 (en) * 2004-11-02 2007-05-31 김신호 Camera Rotating Device
WO2007097600A1 (en) * 2006-02-27 2007-08-30 Duk-Ja Park Active bamboo charcoal producing method and apparatus
KR100877324B1 (en) * 2008-03-31 2009-01-07 김영근 Interior materials for construction and method of manufacturing thereof
KR101672754B1 (en) 2015-05-20 2016-11-04 (주)엔와이우드 A eco-friendly mortar composition using wasting wood powder, a eco-friendly mortar comprising the same and eco-friendly mortar flooring or wall manufactured by using the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100803740B1 (en) * 2006-02-13 2008-02-15 오희범 An activated carbon block of filter assembly and the method for manufacturing the same
KR102245412B1 (en) * 2020-02-28 2021-04-28 자현당 주식회사 Finishing material for far-infrared radiation

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