KR100343637B1 - Treatment of leachate - Google Patents

Abstract

The present invention is to more effectively treat the leachate of domestic garbage landfill in consideration of the change in the composition of leachate depending on the landfill period and rainfall of landfill, mixing leachate generated from short-term landfill and leachate generated from long-term landfill Anaerobic digestion process that digests and removes high concentrations of hardly decomposable organic substances in mixed leachate to an appropriate level for denitrification, denitrification / nitrification process to remove nitrogen and hardly decomposable organic substances, and precipitates by coagulating residual hardly decomposable organic substances. In order to provide a leachate purification treatment method for a landfill waste which is subjected to a chemical flocculation process, and to a residual soluble organic material and a fenton oxidation process for removing color, the treatment efficiency of the hardly decomposable organic material according to the present invention is The treatment efficiency of ammonia nitrogen is 98.9% at 93.5%. Increased to.

Description

Treatment of Leachate from Landfills of Household Wastes {Treatment of leachate}

The present invention relates to a method for purifying leachate generated from landfills for household waste.

In more detail, in order to more effectively treat the leachate of domestic garbage landfill in consideration of the change in composition of leachate depending on the landfill period and rainfall of domestic garbage, the leachate generated from short-term landfill waste and long-term landfill waste Process of mixing leachate, anaerobic digestion process to digest and remove high concentrations of hardly decomposable organic substances to a suitable level for denitrification, denitrification / nitrification process to remove nitrogen and hardly decomposable organic substances, and coagulation of residual organic substances The present invention is to provide a leachate purification treatment method for landfills in which household wastes are sequentially subjected to chemical flocculation process and pentone oxidation process to remove residual organic matter and color.

In Korea, most of the household waste that occurs generally is disposed of in landfills, but leachate generated from landfills contains organic substances and ammonia nitrogen in high concentrations. Therefore, it is desirable to purify and discharge the leachate.

Leachate generated from domestic garbage landfill has low concentrations of heavy metals and phosphorus compounds, and high concentrations of organic substances and ammonia nitrogen, and therefore, it is difficult to properly treat them by general purification treatment methods. In particular, when comparing the leachate of domestic garbage generated in domestic landfills with that of foreign landfills, the amount of the leachate from the landfills of foreign lands is different and the composition of the composition is very different. In Japan, where the efficiency is markedly reduced and the living culture of leachate is considered to be the most similar because of the similar life culture with Korea, wastes are treated by incineration, so there is no leachate treatment process due to landfill.

In addition, the leachate has a lot of problems exposed to the conventional treatment method according to the single treatment process because the contaminant contained in the leachate changes as the landfill period elapses.

Therefore, there is an urgent need for a separate leachate treatment method suitable for domestic garbage.

In consideration of such a problem, the proposed prior art is known as a method for treating leachate in a landfill of domestic wastes in Korean Patent Application No. 1996-0032913.

This includes the leachate flow rate adjustment process for adjusting the flow rate of the leachate, the biological treatment process for oxidative decomposition of organic substances in the inflow wastewater by the solid microorganisms, and the activated sludge precipitation process and activity for sedimenting and separating the sludge generated in the biological treatment process. In the landfill leachate treatment method consisting of excess sludge treatment process for treating excess sludge separated from the sludge sedimentation process, the storage process for temporarily storing a large amount of leachate generated in association with the flow adjustment process, and flow into the flow process Organic concentration measurement process for measuring the organic matter concentration in the leachate to determine the characteristics of the leachate, leachate supply control process for supplying the leachate to the digestion process or mixed stirring process according to the characteristics of the leachate introduced into the flow rate adjustment process, and the flow rate Aerobic atmosphere of leachate transported from the adjustment process Aeration process formed by the aerobic microorganisms, but the nitrogen-free zone to remove nitrogen, the aeration process formed in the inlet of the leachate, and the chemical agglomeration process to agglomerate and remove the hardly decomposable organic matter contained in the treated water after the aeration process; And a third precipitation step of solid-liquid separation of the sludge agglomerated in the fenton oxidation step and the pentone oxidation step of oxidatively decomposing residual hardly decomposable organic matter contained in the treated water.

However, such a conventional treatment method is possible to change the treatment process in consideration of the change in leachate properties according to the landfill period of the waste, but there is no mixed treatment process of long- and short-term leachate, so the leachate treatment process is not unified and the process is complicated. As a result, installation costs and maintenance costs were high, which prevented them from being economical.

The present invention is to provide a leachate purification treatment method of landfills further improved to solve the above problems.

The present invention is a process for mixing the leachate from the short-term landfill and the leachate from the long-term landfill, and the anaerobic digestion process for extinguishing and removing the high concentration of organic substances in the mixed leachate to an appropriate level for denitrification, and the digestion process Denitrification / nitrification process to remove nitrogen and hardly decomposable organic substances from the treated water, chemical agglomeration process to agglomerate and precipitate residual organic material from the denitrification / nitrification process, and residual water from the treated water The purpose of the present invention is to provide a method for purifying leachate of domestic garbage landfill, which consists of a fenton oxidation process for removing organic substances and colors.

Another object of the present invention is to mix the leachate from the short-term landfill and the leachate from the long-term landfill waste to a predetermined ratio, and then to process the whole process to unify the subsequent processes landfill landfill To provide leachate treatment.

Another object of the present invention is to mix the leachate of the long-term and short-term landfill waste to make the concentration of organic substances and nitrogen to properly exclude the addition of external carbon, such as methanol, and chemical agglomeration process The present invention aims to provide a method for treating leachate in domestic garbage landfills, which is able to reuse some of the sludge in the fenton oxidation process as a flocculant.

The above object of the present invention,

In the leachate treatment method of landfill, which consists of anaerobic digestion process, denitrification process, chemical flocculation process and fenton oxidation process,

A leachate collection and mixing process for mixing leachate from short-term landfill and leachate from long-term landfill to a certain ratio;

A conventional anaerobic digestion process of adding high anaerobic bacteria to the mixed leachate to remove high concentration organic materials for easy denitrification;

A normal denitrification / nitrification process for removing nitrogen and organic substances from the treated water after the extinguishing process,

A chemical flocculation process of coagulating and precipitating residual organic materials by adding a flocculant and a coagulant aid to the treated water after denitrification and nitrification;

Achievement by the leachate treatment method of landfills containing domestic waste, characterized in that a fenton oxidation process is performed to add residual Fenton reagent and coagulant aid to remove residual organic matter and color. do.

In particular, when performing the chemical flocculation step, the flocculant is achieved by the leachate purification treatment of domestic landfills, characterized in that by recycling the fentonized sludge.

1 is a total ball of the leachate purification treatment process of landfills according to the present invention.

Figure 2 is a process chart showing the denitrification / nitrification process according to the present invention.

Figure 3 is a process chart showing the chemical flocculation process and fenton oxidation process according to the present invention.

4 is a graph of leachate water quality analysis by landfill period.

* Explanation of Signs of Major Parts of Drawings *

1. Leachate collection process 2. Short-term landfill

3. Long-term landfill waste 4. Short-term leachate extraction pipe

5. Long-term leachate extraction pipe 8. Mixing sump

10. Leachate Treatment Process 11. Stirring Mixing Tank

12. Anaerobic Digester 13. Denitrification / Nitrification Process

14. Chemical flocculation process 15. Fenton oxidation process

The above objects and features of the present invention will be more clearly understood by the following detailed description based on the accompanying drawings.

1 to 4 show a specific embodiment of the leachate purification treatment method of the landfill according to the present invention, Figure 1 shows the entire treatment process of the present invention, Figure 2 shows a denitrification / nitrification process 3 shows a chemical flocculation process and a fenton oxidation process, and FIG. 4 shows a graph of water quality analysis of leachate by landfill period.

Leachate purification method of landfill according to the present invention is a process for mixing the leachate generated from short-term landfill waste and the leachate generated from long-term landfill waste, the landfill years of leachate generated from short-term landfill waste is 1-3 The landfill years of leachate from long-term landfill waste are mixed with leachate of 3 years or more,

In the use of a flocculant in a chemical flocculation process, it is a well-known feature to recycle the sedimentation tank sludge of a fenton oxidation process as a flocculant.

As shown in FIG. 1, before performing the leachate treatment process 10, a leachate mixing process 1 for mixing leachate generated from short-term landfill waste 2 and leachate generated from long-term landfill waste 3 is performed. Will be implemented.

As shown in FIG. 1, the leachate generated from the short-term landfill waste 2 having a landfill period of 1 to 3 years located at the top of the landfill layer has a short-term leachate extraction pipe having a short-term leachate collection tank 6 in the middle ( 4) and the mixed transfer pipe (7) to be collected into the mixing tank (8), and the leachate generated from the long-term landfill waste (3), which is more than three years in the landfill period located at the bottom of the landfill layer is a long-term leachate collection tank Through the long-term leachate extraction pipe (5) and the mixed feed pipe (7) equipped with (6-1) was to be collected into the mixing tank (8).

In particular, as shown in FIG. 5, the short-term leachate generated from the short-term landfill waste 2 has a high content of hardly decomposable organic substances and a low nitrogen content, while the long-term leachate generated from the long-term landfill waste 3 is relatively Since the content of the hardly decomposable organic substance is low but the nitrogen content is high, the concentration of the hardly decomposable organic substance and nitrogen (BOD / NH ⁴⁺ -N) is mixed by mixing the short-term leachate and the long-term leachate at a ratio of 7-5: 3-5. 4: 1 ratio, so that the denitrification / nitrification process can be carried out without any external carbon source (usually using methanol), which had to be added separately when performing the denitrification / nitrification process. do.

The treated water subjected to the process of mixing the leachate generated from the short-term landfill waste (2) and the leachate generated from the long-term landfill waste (3) as described above is anaerobic digestion process (13), denitrification / in the leachate treatment process (10) The nitrification step (15) is performed sequentially.

The mixed leachate collected in the mixing collection tank 8 is supplied to the stirring mixing tank 11 while continuously stirring by the conventional stirring apparatus 9.

The stirring mixing tank 11 is also provided with a conventional stirring device (not specifically shown) to continuously carry out stirring, and the mixed leachate is mixed in the mixing collection tank 8 when performing the above process. It is also possible to supply directly to the anaerobic digestion tank 12 to be described later without going through).

The anaerobic digestion process 12 is a process for removing a high concentration of hardly decomposable organic substances, and is carried out by conventional anaerobic microorganisms under anaerobic conditions.

The denitrification / nitridation process 13 is carried out by a denitrification tank 13-1 consisting of two tanks and a nitrification tank 13-2 consisting of five tanks, as shown in detail in FIG. The outer conveyance (13-5) for 50 to 100%, the inner conveyance (13-4) for reducing and degassing the nitrate nitrogen is carried out at 400 to 600%.

The anaerobic digestion process 12 and the denitrification / nitridation process 13 as described above are a conventional process, and thus, a detailed description thereof will be omitted.

The treated water which completed the denitrification / nitridation process 13 was subjected to a chemical agglomeration process 14 as shown in FIG. 4.

The chemical flocculation and precipitation process 14 is a process for precipitating and removing the hardly decomposable organic substance remaining in the treated water after the denitrification / nitridation process 13, and optimally treating the treated water after the denitrification / nitridation process 13. In order to maintain pH 5.5, which is a coagulation condition of sodium hydroxide (NaOH), the pH was adjusted to 5.5, and then ferric chloride (FeCl ₃ ) 600 to 1000 mg / L, which acts as a coagulant, and fentonyl oxide, which will be described in detail later. Recycle the iron salt sludge produced in the process (15) and rapidly stirred for 15 to 25 minutes, and 5 to 15 mg / L of anionic polymer (anion) as a coagulant aid to the treated water mixed with ferric chloride for 6 to 14 minutes After stirring, the treated water mixed with ferric chloride and the polymer anion was precipitated for 2 hours, and then sludge was dewatered and the supernatant (treated water located at the upper side) was introduced into the Fenton oxidation process (15). Let's do it.

As described above, by recycling 25 to 35% of the iron salt sludge sedimented after fenton oxidation as the coagulant of the chemical coagulation process (14), the treatment efficiency of the hardly decomposable organic substance is increased compared to the case where only the coagulant is administered as before. -12% can be improved, and the effect of reducing sludge generation by 25-35% can be obtained.

In the present invention, the iron salt sludge precipitated in the Fenton oxidation process 15 used as a flocculant in the chemical coagulation process 14 as described above can be reused by the following reaction formula.

As shown in the above formula, when the chemical agglomeration process (14) is carried out, the component that actually participates in the flocculation reaction in the FeCl ₃ aqueous solution is a metal salt (Fe ³⁺ ), so that the flocculant sludge (Fe (OH) ₃ ) can be used as the flocculant. Will be.

As described above, 25 to 35% of the iron salt sludge sedimented and separated in the Fenton oxidation process (15) is used as a flocculant in the chemical flocculation process (14), and in the case of using less than 25% of iron salt sludge as the flocculant, the sludge is recycled. If the efficiency is less than 35% iron salt sludge is used, the reaction time of the flocculation treatment facility is reduced according to the flow load, the treatment efficiency is reduced.

The treated water after the chemical coagulation process 14 was subjected to the Fenton oxidation process 15 as shown in FIG.

Fenton oxidation process (15) is to remove the hardly decomposable organic substances and the color remaining in the treated water in the treated water after the chemical coagulation process (14), Fenton reagent in the treated water after the chemical coagulation process (14) Add ferrous sulfate and hydrogen peroxide and pH adjuster (sulfuric acid or caustic soda) at the same time to maintain pH 3-4 and stir for 3.5-4.5 hours. At this time, ferrous sulfate and hydrogen peroxide were added with 350-450 mgFe ²⁺ / L and 250-321 mgH ₂ O ₂ / L, respectively. After performing the above process, using sodium hydroxide (NaOH) to neutralize the pH is preferably maintained at 6 ~ 7 so as to maintain a pH of 6.5 and about 5 ~ 15mg / of anion polymer as a coagulant aid during slow stirring L was injected.

In the Fenton oxidation process 15 as described above, in the prior art, the pH was adjusted before the reaction process of the Fenton oxidation process, but in the present invention, the pH and the pH control agent were added at the same time as the Fenton reagent to simultaneously perform oxidation and pH adjustment. Therefore, compared to the conventional pH adjuster is used in a small amount, it is easy to maintain the proper pH during the reaction.

In addition, by providing a sufficient reaction time during the Fenton oxidation process (15), the hydrogen peroxide generated during the Fenton reaction was reduced, thereby reducing the adverse effects due to the hydrogen peroxide (flotation of precipitated sludge, increase of organic matter in the treated water).

The treatment efficiency of the non-degradable organic material is 50 to 70% and the treatment efficiency of nitrogen is 30 to 50% by the treatment process that has been conventionally used, whereas the hardly degradable organic material is confirmed by the present invention as shown in the following table. The treatment efficiency of was increased to 93.5% and the treatment efficiency of nitrogen was increased to 98.9%.

Category BOD CODcr T-N NH ₃ -N inflow 1334 3596 1990 1450 process 17 234 572 16 Processing efficiency (%) 98.7 93.5 71.3 98.9

In the present invention, in treating the leachate of landfills, the leachate generated from different short-term landfills and leachate generated from long-term landfills are mixed so that the properties of the treated water are uniform before the leachate treatment process. Rather than supplying the carbon source required for the denitrification process, the leachate generated from the mixed short-term landfill waste can not only supply enough carbon source but also simplify the overall structure of the process, thereby increasing economic efficiency.

In the chemical flocculation process according to the present invention, since the fenton oxide sludge generated during the fenton oxidation process in the leachate treatment process is reused as a flocculant without being buried as in the prior art, the treatment cost of the fenton oxide sludge can be reduced. As a result, the amount of coagulant added for coagulation can be reduced, thereby reducing the drug cost.

In addition, in the fenton oxidation process of the present invention, the pH adjusting agent is simultaneously added to the fenton reagent and the pH adjusting agent is used to simultaneously perform oxidation and pH adjustment, so that a small amount of the pH adjusting agent can be used, and the pH can be easily maintained at a proper pH during the reaction.

In addition, the treatment process used in the prior art was 50 to 70% of the treatment efficiency of the non-degradable organic material, the treatment efficiency of nitrogen was 30 to 50%, whereas by treating the leachate according to the present invention, COD _CR ) treatment efficiency is 93.5%, and nitrogen (NH ₃ -N) treatment efficiency DL 98.9% is greatly increased, so that the leachate generated in domestic garbage landfill can be purified and discharged more cleanly, thus reducing water pollution. Can be significantly reduced.

Claims (5)

In the leachate treatment method of landfill, which consists of anaerobic digestion process, denitrification process, chemical flocculation process and fenton oxidation process, Leachate mixing process (1) for collecting and mixing leachate from short-term landfill and leachate from long-term landfill, Anaerobic digestion process (12) of digesting and removing high concentration hardly decomposable organic substances in mixed leachate, A denitrification / nitrification process (13) to remove nitrogen and hardly decomposable organic substances from the treated water after the extinguishing process, A chemical agglomeration process (14) for agglomeration and precipitation of residual organic materials in the treated water after denitrification / nitrification, A method for purifying leachate from household waste landfills, characterized in that the Fenton oxidation process (15) is carried out sequentially to remove residual organic matter and chromaticity of the treated water after chemical coagulation. The method of claim 1, The leachate mixing process (1) generated from the leachate generated from the short-term landfill waste and the long-term landfill waste (3), Leachate purification of municipal waste landfills, characterized in that the landfill years of the leachate generated from the short-term landfill waste (2) is 1 to 3 years and that of the leachate generated from the long-term landfill waste (3) is 3 years Way. The method of claim 1, Leachate purification method of landfills, characterized in that the sludge generated in the Fenton oxidation process (15) is reused as a flocculant in the chemical coagulation process (14). The method of claim 3, wherein When the sludge of the fenton oxidation process is reused as a flocculant in the chemical coagulation process (14), the amount thereof is 25 to 35% of the fenton oxide sludge. The method of claim 1, Leachate treatment method of landfills, characterized in that the pH adjusting agent and the Fenton reagent are simultaneously added in the Fenton oxidation process (15).