KR100334628B1 - Luminous leather and manufacturing method thereof - Google Patents

Luminous leather and manufacturing method thereof Download PDF

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Publication number
KR100334628B1
KR100334628B1 KR1019990029559A KR19990029559A KR100334628B1 KR 100334628 B1 KR100334628 B1 KR 100334628B1 KR 1019990029559 A KR1019990029559 A KR 1019990029559A KR 19990029559 A KR19990029559 A KR 19990029559A KR 100334628 B1 KR100334628 B1 KR 100334628B1
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leather
light emitting
parts
weight
photoluminescent
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KR1019990029559A
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Korean (ko)
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KR20000053678A (en
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한상태
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한상태
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Priority to KR2019990014473U priority Critical patent/KR200171686Y1/en
Priority to KR1019990029559A priority patent/KR100334628B1/en
Publication of KR20000053678A publication Critical patent/KR20000053678A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02Material containing basic nitrogen
    • D06P3/04Material containing basic nitrogen containing amide groups
    • D06P3/32Material containing basic nitrogen containing amide groups leather skins
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14BMECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
    • C14B1/00Manufacture of leather; Machines or devices therefor
    • C14B1/44Mechanical treatment of leather surfaces
    • C14B1/56Ornamenting, producing designs, embossing
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C13/00Manufacture of special kinds or leather, e.g. vellum
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0004General aspects of dyeing
    • D06P1/0012Effecting dyeing to obtain luminescent or phosphorescent dyeings
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5264Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
    • D06P1/5285Polyurethanes; Polyurea; Polyguanides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Decoration Of Textiles (AREA)

Abstract

본 발명은 피혁의 상부에 발광무늬층과 이 발광무늬층을 보호하는 피복층이 구비된 것을 특징으로 하는 축광피혁과 그 제조방법을 제공하는 것으로, 이 촉광피혁은 피혁의 상부에 발광무늬층이 구비되어 있음으로 인해 밝은 곳에서는 보통의 인쇄무늬역할을 하면서, 그 무늬가 어두운 곳에서 자연발광함에 따라 선명하게 그 무늬를 식별할 수 있어 새로운 미적효과를 갖는 것이다.The present invention provides a photoluminescent leather and a method of manufacturing the same, wherein the light emitting pattern layer and a coating layer for protecting the light emitting pattern layer are provided on the leather. Due to the fact that it acts as a normal printed pattern in bright places, the pattern can be clearly identified as it naturally emits light in dark places, and thus has a new aesthetic effect.

Description

축광피혁과 그 제조방법{Luminous leather and manufacturing method thereof}Luminous leather and manufacturing method

본 발명은 축광피혁과 그 제조방법에 관한 것으로, 특히 야간이나 어두운 곳에서 자연발광함으로써 새로운 미적효과를 가질 수 있게 된 축광피혁과 그 제조방법에 관한 것이다.The present invention relates to a photoluminescent leather and a method for manufacturing the same, and more particularly to a photoluminescent leather and a method for manufacturing the same, which can have a new aesthetic effect by natural light emission at night or in the dark.

피혁은 그 독특한 질감이나 보온효과 및 내구성 등의 특성으로 인해 의복이나 장신용품의 원단으로 주로 사용되고 있으며, 천연피혁과 함께 천연피혁과 유사한 질감을 갖는 인조피혁이 개발되어 사용되고 있다.Leather is mainly used as a fabric of clothing or jewelry because of its unique texture, heat insulation effect and durability, and artificial leather having a texture similar to natural leather has been developed and used together with natural leather.

천연피혁은 동물의 가죽을 취하여 보존처리와 함께 표면가공처리하여 사용하고 있으며, 인조피혁은 부직포 등의 기재에 폴리우레탄 등의 고분자물질을 함침시킨 후 표면가공처리하여 사용하고 있다.Natural leather is used by taking leather of animals and surface processing with preservation treatment. Artificial leather is used by surface processing after impregnating high molecular materials such as polyurethane on the base of nonwoven fabric.

그러나, 상기 피혁에 미적인 효과를 부여하기 위해 무늬를 인쇄하거나 입체무늬를 부여하는 등의 단순한 방법만 사용되고 있어 현대인의 다양한 욕구를 충족시키기에는 한계를 가지는 문제점이 있었다.However, in order to give the leather an aesthetic effect, only a simple method such as printing a pattern or giving a three-dimensional pattern is used, which has a problem in that it has a limit to satisfy various needs of modern people.

본 발명은 상기한 문제점을 해소하기 위한 것으로, 피혁에 전혀 새로운 미적효과를 부여하여 다양한 수요자의 욕구를 충족시킬 수 있게 된 축광피혁과 그 제조방법을 제공함에 그 목적이 있다.The present invention has been made to solve the above problems, and has an object of providing a photoluminescent leather and a method of manufacturing the same to give a completely new aesthetic effect to the leather to satisfy the needs of various consumers.

상기 목적을 달성하기 위한 본 발명은, 발광물질 25~35중량부, 우레탄계 및 아크릴계 바인더 25~35중량부, 왁스 10~20중량부를 적량의 물에 넣은 혼합물을 피혁원단(10)의 상부에 도포한 발광무늬층(12)과, 이 발광무늬층(12)의 상부에 도포하여 그 무늬층을 보호하는 피복층(14)이 형성된 축광피혁을 제공한다.The present invention for achieving the above object, 25 to 35 parts by weight of the light emitting material, 25 to 35 parts by weight of urethane-based and acrylic binder, 10 to 20 parts by weight of the wax is applied to the upper portion of the leather fabric (10) Provided is a light-emitting leather having a light-emitting pattern layer 12 and a coating layer 14 coated on the light-emitting pattern layer 12 to protect the patterned layer.

상기 발광물질은 (SrO)n-Al2O3, (MO)n-Al2O3및 아연황화물 등으로 이루어진 군에서 선택된 하나 이상의 물질이 발광 유효성분으로 한다.The light emitting material is one or more materials selected from the group consisting of (SrO) n -Al 2 O 3 , (MO) n -Al 2 O 3 and zinc sulfide as the light emitting active ingredient.

상기 구조의 축광피혁은 피혁의 상부에 발광무늬층이 구비되어 있음으로 인해 밝은 곳에서는 보통의 인쇄무늬역할을 하면서, 그 무늬가 어두운 곳에서 자연발광함에 따라 선명하게 그 무늬를 식별할 수 있어 새로운 미적효과를 갖게 한다.The photoluminescent leather of the above structure is provided with a light emitting pattern layer on the upper part of the leather, and thus serves as a normal printed pattern in bright places, and the pattern can be clearly identified as the light is naturally emitted in a dark place. It has an aesthetic effect.

상기 축광피혁의 제조공정은 그 발광물질의 특성으로 인해 일반 피혁제조공정과는 다른 공정을 선택하여야 하는데, 본 발명자는 다음을 구성으로 하는 축광피혁의 제조방법을 발명하였다.The manufacturing process of the photoluminescent leather has to select a process different from the general leather manufacturing process due to the characteristics of the light emitting material, the inventors invented a manufacturing method of the photoluminescent leather having the following configuration.

본 발명의 축광피혁 제조방법은, 피혁 원단의 상부층에 발광물질 25~35중량부, 우레탄계 내지 아크릴계 바인더 25~35중량부, 왁스 10~20중량부를 적량의 물에 넣은 혼합물로써 발광무늬층을 형성한 다음, 투명 내지 반투명의 피복층을 형성하는 것을 특징으로 하는 것이다.In the method of manufacturing the photoluminescent leather of the present invention, a light emitting pattern layer is formed by a mixture of 25 to 35 parts by weight of a light emitting material, 25 to 35 parts by weight of a urethane-acrylic binder, and 10 to 20 parts by weight of a wax in an appropriate amount of water on the upper layer of the leather fabric. Next, the transparent to translucent coating layer is formed.

상기 발광물질은 (SrO)n-Al2O3, (MO)n-Al2O3, 아연황화물 등으로 이루어진 군에서 선택된 하나 이상의 물질을 사용한다.The light emitting material uses one or more materials selected from the group consisting of (SrO) n -Al 2 O 3 , (MO) n -Al 2 O 3 , zinc sulfide and the like.

상기 피복층은 유브이코팅층이거나 경화제가 혼합된 유성페인트로써 형성할 수 있다.The coating layer may be formed of a UV coating layer or oil paint mixed with a curing agent.

상기 제조공정을 통하여 천연피혁에 축광효과를 갖는 피혁을 간단하게 제조할 수 있게 된다.Through the manufacturing process it is possible to simply manufacture a leather having a photoluminescent effect on the natural leather.

도 1은 본 발명에 따른 축광피혁 일부분의 절개 사시도이다.1 is a cutaway perspective view of a portion of the photoluminescent leather according to the present invention.

*도면의 주요부분에 대한 부호의 설명** Description of the symbols for the main parts of the drawings *

10 : 피혁원단 12 : 발광무늬층10: leather fabric 12: light emitting pattern layer

14 : 피복층14: coating layer

이하, 본 발명의 축광피혁 및 이를 제조하는 공정을 도면과 실시예를 통하여 상세하게 설명한다.Hereinafter, the photoluminescent leather of the present invention and a process for manufacturing the same will be described in detail with reference to the accompanying drawings and examples.

도 1은 본 발명의 축광피혁의 단면도로서, 피혁원단(10)의 상부층에 발광무늬층(12)이 형성되어 있고, 상기 발광무늬층(12)의 상부에 이를 보호하는 피복층(14)이 형성된 것을 나타내고 있다.1 is a cross-sectional view of the photoluminescent leather of the present invention, the light emitting pattern layer 12 is formed on the upper layer of the leather fabric 10, the coating layer 14 is formed on the light emitting pattern layer 12 to protect it It is shown.

상기 피혁원단(10)은 보존처리된 천연피혁 원단이거나 인조피혁 원단을 사용할 수 있으며, 이 피혁원단(10)의 상부층에 본 발명의 발광무늬층(12)과 피복층(14)을 형성하기 전에 원하는 색상으로 바탕색을 염색한 것을 사용할 수도있다.The leather fabric 10 may be a preservation-treated natural leather fabric or artificial leather fabric, and before forming the light emitting pattern layer 12 and the coating layer 14 of the present invention on the upper layer of the leather fabric 10 You can also use the background color dyed as a color.

본 이와 같은 피혁원단(10)에 발광물질 25~35중량부, 우레탄계 및 아크릴계 바인더 25~35중량부, 왁스 10~20중량부를 적량의 물에 넣은 혼합물로써 발광무늬층(12)을 형성한 다음, 투명 내지 반투명의 피복층(14)을 형성하는데, 상기 혼합물에 혼합되는 발광물질은 무기물질로서 분말상의 것이 대부분으로 이를 다른 물질과 함께 물에 혼합시키면 에멀젼용액이 되고, 이 혼합물은 시간경과에 따라 그 균일성이 떨어지므로 단시간에 발광무늬층을 형성하는 것이 중요하다.The light emitting pattern layer 12 is formed of a mixture of 25 to 35 parts by weight of a light emitting material, 25 to 35 parts by weight of a urethane-based and acrylic binder, and 10 to 20 parts by weight of a wax in an appropriate amount of water. , To form a transparent to semi-transparent coating layer 14, the luminescent material mixed in the mixture is an inorganic material, most of which is in the form of a powder, and when mixed with other materials in water to form an emulsion solution, the mixture over time Since the uniformity is inferior, it is important to form a light emitting pattern layer in a short time.

발광무늬층(12)의 발광물질은 (SrO)n-Al2O3, (MO)n-Al2O3및 아연황화물로 이루어진 군에서 선택된 하나 이상의 물질을 사용하고, 이 발광물질이 혼합된 혼합물로써 인쇄롤을 이용하여 인쇄한다.As the light emitting material of the light emitting pattern layer 12, one or more materials selected from the group consisting of (SrO) n -Al 2 O 3 , (MO) n -Al 2 O 3 and zinc sulfide are used. Print using a printing roll as a mixture.

이후 피복층(14)은 발광무늬층(12)을 보호하기 위한 층으로 내부의 무늬를 외부에서 식별하기 용이하면서 그 내구성도 뛰어나야 하므로 경화제가 적량혼합된 투명 또는 반투명의 에나멜페인트를 이용하여 피복층(14)을 형성하거나, 유브이코팅이 바람직하다.Since the coating layer 14 is a layer for protecting the light emitting pattern layer 12, the inside pattern should be easy to be distinguished from the outside and excellent in durability. Therefore, the coating layer 14 may be formed using transparent or translucent enamel paint mixed with a suitable amount of a curing agent. ) Or UV coating is preferred.

실시예 1. 발광무늬층의 원료 혼합물 제조Example 1. Preparation of a raw material mixture of the light emitting pattern layer

다음의 배합비로 350g의 혼합물을 제조하였다.350 g of a mixture was prepared at the following blending ratio.

(SrO)n-Al2O3계의 분말 100g100 g of (SrO) n- Al 2 O 3 powder

우레탄바인더 50gUrethane Binder 50g

아크릴바인더 50gAcrylic Binder 50g

왁스 50g50 g of wax

러스터 50g50 g of luster

물 50g50 g of water

실시예 2. 발광무늬층의 원료 혼합물 제조Example 2 Preparation of a Raw Material Mixture of a Light-emitting Pattern Layer

다음의 배합비로 350g의 혼합물을 제조하였다.350 g of a mixture was prepared at the following blending ratio.

(MO)n-Al2O3계의 분말 100g100 g of (MO) n- Al 2 O 3 powder

우레탄바인더 50gUrethane Binder 50g

아크릴바인더 50gAcrylic Binder 50g

왁스 50g50 g of wax

러스터 50g50 g of luster

물 50g50 g of water

실시예 3-4. 축광피혁의 제조Example 3-4. Manufacture of Photoluminescent Leather

적색으로 염색처리된 천연피혁의 표면에 상기 실시예 1과 실시예 2의 혼합물을 각각 이용하여 발광무늬층을 형성시켜 건조시킨 다음, 그 위에 유브이코팅처리하여 피복층을 형성하였다.On the surface of the natural leather dyed red, a light emitting pattern layer was formed by using the mixtures of Example 1 and Example 2, respectively, dried, and then coated on it to form a coating layer.

실시예 5-6. 축광피혁의 제조Example 5-6. Manufacture of Photoluminescent Leather

상기 실시예 3-4에서 피복층을 투명에나멜 100g과 경화제 50g을 신나 50g에 용해시켜 이를 이용하여 피복층을 형성한 것 이외에는 상기 실시예 3-4와 동일하게 축광피혁을 제조하였다.In Example 3-4, photoluminescent leather was manufactured in the same manner as in Example 3-4, except that 100 g of transparent enamel and 50 g of a curing agent were dissolved in 50 g of thinner, thereby forming a coating layer.

실시예 7-8. 축광피혁의 제조Example 7-8. Manufacture of Photoluminescent Leather

폴리우레탄계 인조피혁의 표면을 적색으로 염색한 다음 그 표면에 상기 실시예 1과 실시예 2의 혼합물을 각각 이용하여 발광무늬층을 형성시켜 건조시킨 다음, 그 위에 유브이코팅처리하여 피복층을 형성하였다.The surface of the polyurethane-based artificial leather was dyed red, and a light emitting pattern layer was formed using the mixture of Example 1 and Example 2 on the surface, followed by drying, followed by UV coating to form a coating layer thereon.

이상의 실시예 3-8에서 제조된 축광피혁의 질감은 통상적인 천연피혁이나 합성피혁과 질감면에서 뒤떨어지지 않음을 확인할 수 있었고, 밝은 곳에서도 그 무늬를 뚜렷하게 식별할 수 있음은 물론 어두운 곳에서 그 무늬를 뚜렷하게 식별할 수 있으며 발광물질 특유의 은은한 빛이 전혀 새로운 미감을 부여하고 있음을 확인할 수 있었다.It can be seen that the texture of the photoluminescent leather prepared in Example 3-8 is inferior to that of conventional natural leather or synthetic leather, and the pattern can be clearly distinguished even in bright places, as well as in the dark. The pattern can be clearly identified, and the soft light unique to the luminescent material gives a completely new aesthetic.

상술한 바와 같이 본 발명의 축광피혁은 통상적인 피혁의 용도 그대로 사용할 수 있으면서 밝은 곳에서는 보통의 인쇄무늬 역할을 하면서도 어두운 곳에서는 발광무늬층에서 발하는 빛으로 인해 전혀 새로운 미감을 표현할 수 있는 효과가 있는 것이다.As described above, the photoluminescent leather of the present invention can be used as it is in a conventional leather, and serves as a normal printed pattern in bright places, but has an effect of expressing a completely new aesthetic due to light emitted from a light emitting pattern layer in a dark place. will be.

또한, 본 발명의 축광피혁 제조방법을 통하여 천연피혁의 표면에 발광무늬층을 용이하게 형성할 수 있으며, 그 제조공정에 많은 시간이 소요되지 않아 대량생산공정에 적합한 효과가 있다.In addition, the light-emitting pattern layer can be easily formed on the surface of the natural leather through the method of manufacturing the photoluminescent leather of the present invention, the manufacturing process does not take much time, there is an effect suitable for mass production process.

Claims (4)

(정정) 발광물질 25~35중량부, 우레탄계 및 아크릴계 바인더 25~35중량부 및, 왁스 10~20중량부를 적량의 물에 넣은 혼합물을 피혁원단(10)의 상부에 도포한 발광무늬층(12)과, 이 발광무늬층(12)의 상부에 도포하여 그 무늬층을 보호하는 피복층(14)이 형성된 축광피혁.(Correction) A light emitting pattern layer 12 having 25 to 35 parts by weight of a light emitting material, 25 to 35 parts by weight of a urethane-based and acrylic binder, and a mixture of 10 to 20 parts by weight of wax in an appropriate amount of water coated on the top of the leather fabric 10. And a coating layer 14 applied to the upper portion of the light emitting pattern layer 12 to protect the pattern layer. (정정) 제 1 항에 있어서, 상기 발광물질은 (SrO)n-Al2O3, (MO)n-Al2O3및 아연황화물로 이루어진 군에서 선택된 하나 이상의 물질을 유효성분으로 포함하는 것을 특징으로 하는 축광피혁.(Correction) The method of claim 1, wherein the light emitting material comprises (SrO) n -Al 2 O 3 , (MO) n -Al 2 O 3 and zinc sulfide containing one or more materials selected from the group consisting of an active ingredient Luminous leather characterized by the above. (정정) 피혁 원단의 상부층에 발광물질 25~35중량부, 우레탄계 및 아크릴계 바인더 25~35중량부 및, 왁스 10~20중량부를 적량의 물에 넣은 혼합물로써 발광무늬층을 형성한 다음, 투명 내지 반투명의 피복층을 형성하는 것을 특징으로 하는 축광피혁의 제조방법.(Correction) A light emitting pattern layer was formed by a mixture of 25 to 35 parts by weight of a light emitting material, 25 to 35 parts by weight of a urethane and acrylic binder, and 10 to 20 parts by weight of a wax in an appropriate amount of water on the upper layer of the leather fabric, and then A method of manufacturing photoluminescent leather, characterized by forming a translucent coating layer. (정정) 제 3 항에 있어서, 상기 발광물질은 (SrO)n-Al2O3, (MO)n-Al2O3및 아연황화물로 이루어진 군에서 선택된 하나 이상의 물질을 유효성분으로 포함하는 것을 특징으로 하는 축광피혁의 제조방법.(Correction) The method according to claim 3, wherein the light emitting material comprises at least one material selected from the group consisting of (SrO) n -Al 2 O 3 , (MO) n -Al 2 O 3 and zinc sulfide as an active ingredient. A method of manufacturing a photoluminescent leather, characterized in that.
KR1019990029559A 1999-07-21 1999-07-21 Luminous leather and manufacturing method thereof KR100334628B1 (en)

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