KR100313307B1 - Production of odorless garlic - Google Patents
Production of odorless garlic Download PDFInfo
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- KR100313307B1 KR100313307B1 KR1019940007667A KR19940007667A KR100313307B1 KR 100313307 B1 KR100313307 B1 KR 100313307B1 KR 1019940007667 A KR1019940007667 A KR 1019940007667A KR 19940007667 A KR19940007667 A KR 19940007667A KR 100313307 B1 KR100313307 B1 KR 100313307B1
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L19/00—Products from fruits or vegetables; Preparation or treatment thereof
- A23L19/10—Products from fruits or vegetables; Preparation or treatment thereof of tuberous or like starch containing root crops
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
- A23L5/20—Removal of unwanted matter, e.g. deodorisation or detoxification
- A23L5/27—Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
Abstract
Description
제1도는 본 발명에 의해 제조한 마늘의 조직강도 그래프1 is a graph of the tissue strength of garlic prepared by the present invention
제2도는 무처리한 마늘의 조작강도 그래프2 is a graph of the operating strength of untreated garlic
제3도는 본 발명에 의해 열처리한 마늘의 조직강도 그래프.3 is a graph of tissue strength of garlic heat treated by the present invention.
본 발명은 마늘 특유의 맛과 냄새를 제거하여 생식용 및 조미료로 사용할 수 있는 무취마늘의 제조방법에 관한 것이다.The present invention relates to a method for preparing odorless garlic which can be used as raw food and seasoning by removing the peculiar taste and smell of garlic.
좀더 상세히 설명을 하면, 일반 마늘을 수세, 탈피한 후 유기산이 첨가된 탈취용액에 침지하여 표면에서 나오는 냄새와 대장균을 1차로 제가한후 다시 비타민-C가 첨가된 탈취용액에 넣고 열을 가하여 마늘 조직내 효소를 불활성화 시킨 후, 칼슘용액에 침지하면서 냉각시키는 제조방법에 관한 것이다.In more detail, after washing and stripping the normal garlic, immerse it in the deodorizing solution added with organic acid, firstly remove the odor and Escherichia coli from the surface, and then put it in the deodorizing solution added with vitamin-C and heat it After inactivating the enzyme in the tissue, and relates to a manufacturing method of cooling while immersed in calcium solution.
이 발명은 칼슘이온이 마늘의 내부로 침투하여 조직을 단단하게 한 것을 특징으로 한 무취마늘이다.This invention is odorless garlic, characterized in that the calcium ions penetrate the inside of the garlic to harden the tissue.
마늘은 특유의 맛과 냄새로 인하여 개인에 따라서 기호도 차이는 없으나 생식용 및 조미료로서 널리 이용되고 있으며 마늘 장아찌 및 건조분말 등으로 가공하여 이용하기도 한다.Garlic has no difference in taste because of its unique taste and smell, but it is widely used as raw food and seasoning, and it can also be processed by using garlic pickles and dried powder.
마늘에는 알리닌(allinin)이라는 성분이 들어있다.Garlic contains an ingredient called allinin.
이 알리닌은 유황성분이 많은 아미노산의 일종으로서 다량의 디알릴설파이드(diallyl sulfide, CH2+CH-CH2-S-CH2-CH=CH2), 디알릴디설파이드(diallyl disulfide. CH2=CH-CH2-S-S-CH2-CH=CH2)등의 휘발성 유황화합물을 갖고 있다.This alanine is a sulfur-rich amino acid, a large amount of diallyl sulfide (CH 2 + CH-CH 2 -S-CH 2 -CH = CH 2 ), diallyl disulfide (CH 2 =). Volatile sulfur compounds such as CH-CH 2 -SS-CH 2 -CH = CH 2 ).
알리닌은 알린나아제(allinase)라는 효소의 작용을 받아 알리신(allicin)으로 분해되면서 마늘 특유의 자극적인 냄새를 갖게된다.Allinin is decomposed into allicin by the action of an enzyme called alinase, which has a peculiar smell of garlic.
이러한 문제점을 해결하기 위한 기술적 수단으로 다음과 같이 기술이 공지되었다.As a technical means for solving this problem, the following techniques are known.
1)대한민국 특허 공고번호 92-3549(발명자:박봉래)에서는 알긴산 나트륨등의 해조류즙과 천연제오라이트를 가한 용액에 침지하여 마늘의 냄새를 제거하는 것을 요지로 한다.1) In Korean Patent Publication No. 92-3549 (Inventor: Bong Rae Park), it is essential to remove the smell of garlic by immersing in a solution of seaweed juice such as sodium alginate and natural zeolite.
위 제조법은 상온에서 장시간의 침지(2일-4일)로 인한 조직의 연화현상이 발생되며, 박피를 하지 않은 상태에서 탈취함으로서 건조시 갈변현상과 마늘조직의 수축현상이 발생되어 경제적인 효용성이 부족한 결점이 있다.In the above method, the softening of the tissue occurs due to prolonged immersion (2 days-4 days) at room temperature, and by deodorization without peeling, browning phenomenon and shrinkage of garlic tissue occur during drying. There is a shortcoming.
2) 대한민국 특허 공개번호 93-5552(발명자:사까이 이사오)에서는 탄산수소 나트륨을 포함한 처리액에 완충액으로서 시트르산, 타르타르산, 말산 등의 카르복시산 기타의 유기산을 함유시켜 두고 그 욕조에 마늘을 침지하는 것을 특징으로 하는 마늘의 악취제거법을 요지로 한다.2) In Korean Patent Publication No. 93-5552 (Inventor: Sakai Isao), a solution containing sodium hydrogen carbonate contains carboxylic acid such as citric acid, tartaric acid, malic acid, and other organic acids as a buffer solution, and dipping garlic in the bath. Garlic odor removal method characterized by the summary.
위 제조법은 조직의 상태는 양호하나 냄새를 완전히 제거하지 못하였다. 발명자의 위 내용에 언급했듯이 식용으로 마늘을 섭취하였을 때 식후에 발생하는 구취일부는 제거하였으나 먹을때 발생되는 냄새는 전해 제거하지 못하였다. 따라서 산업용으로 사용하는데 한계가 있다.The above recipe was in good condition but did not completely remove the odor. As mentioned in the above inventors, when ingesting garlic for food, some bad breath generated after eating was removed, but the smell generated when eating was not removed electrolytically. Therefore, there is a limit to use for industrial use.
따라서, 본 발명은 마늘 자체의 냄새를 제거한후 마늘조직이 생마늘과 유사한 식감을 갖는 것을 특징으로 하는 무취마늘을 제호하는데 그 목적이 있다.Accordingly, an object of the present invention is to provide a odorless garlic, which has a texture similar to raw garlic after removing the smell of garlic itself.
마늘과(genus Allium)에 속하는 식물조직은 일반적으로 티오셜피네이트(thiosulfinate), 디오설포네이트(thiosulfonnate)등의 매우 특징있는 휘발성 유황화합물이 들어있다.Plant tissues belonging to the genus Allium generally contain very characteristic volatile sulfur compounds such as thiosulfinate and thiosulfonnate.
따라서, 마늘의 경우 S-알킬시스테인 설폭사이드(S-alkylcysteine sulfoxide)는 효소작용을 받아 1-알킬설페니산(S-slkylsulfenic acid)으로 된다.Therefore, in the case of garlic, S-alkylcysteine sulfoxide is subjected to enzymatic reaction to 1-alkylsulfenic acid.
여기서, 형성된 1-알킬설페니산(S-alkylsulfenic acid)은 불안정하여 마늘 특유의 냄새의 주성분인 휘발성 유황화합물로 변한다.Here, the formed 1-alkylsulfenic acid is unstable and turns into a volatile sulfur compound which is the main component of garlic's characteristic odor.
본 발명자는 휘발성황화합물을 유기산으로 흡착한후 외부로 방출하고 또 냄새작용에 중요한 역할을 하는 효소를 불활성화시켜 동시에 칼슘이온을 마늘 내부에 침투시킴으로서 발명의 목적을 달성할 수 있었다.The present inventors were able to achieve the object of the invention by adsorbing volatile sulfur compounds with organic acids and then releasing them to the outside and inactivating enzymes that play an important role in odor.
즉, 아세트산(유기산)이 함유된 탈취용액에 마늘을 상온에서 30분간 방치한다.That is, garlic is left to stand at room temperature for 30 minutes in a deodorizing solution containing acetic acid (organic acid).
이렇게 얻어진 마늘을 다시 비타민 C가 첨가된 탈취용액에 넣고 온도를 상승시켜 80℃에서 5분간 브랜칭을 한다.The garlic thus obtained is added to the deodorizing solution to which vitamin C is added, and the temperature is raised and branched at 80 ° C. for 5 minutes.
이와같은 처리를 함으로써 마늘에 함유된 효소는 불활성화기 되어 S-알킬시스테인 설폭사이드(S-alkylcysteine sulfoxide)화합물이 S-알킬설페니산(S-alkylsulfenic acid)으로 전환되는 것을 막을 수 있다.By doing this, the enzyme contained in garlic can be inactivated to prevent the conversion of S-alkylcysteine sulfoxide compounds to S-alkylsulfenic acid.
또, 아세트산(유기산)은 마늘의 설파이드(sulfide)를 흡착하여 브랜칭과정중 외부로 방출된다.Acetic acid (organic acid) also adsorbs garlic's sulfide and is released to the outside during the branching process.
그리고 블랜칭한 마늘을 0.1~2.0%의 칼슘용액에 침지, 냉각하면서 삼투압 현상으로 칼슘이온은 마늘의 내부로 들어가며 마늘 내부의 수분과 치환되어 조직을 단단하게 하여준다.And immersed and cooled in 0.1 ~ 2.0% calcium solution of the blanched garlic, the calcium ion enters the inside of the garlic by osmotic pressure and is replaced with the moisture inside the garlic to harden the tissue.
본 발명에 사용하는 유기산은 산도가 10%인 아세트산이며 다른 유기산(구연산, 피트산, 말산등)을 사용하여도 무방하지만 본 발명에서는 마늘외부에 오염된 미생물, 대장균등이 살균될 수 있도록 하기위하여 산도 10%인 아세트산을 사용하였다.The organic acid used in the present invention is acetic acid having an acidity of 10%, and other organic acids (citric acid, phytic acid, malic acid, etc.) may be used, but in the present invention, in order to sterilize microorganisms and E. coli contaminated outside garlic Acetic acid with 10% acidity was used.
또, 칼슘으로 사용하는 화합물은 냄새가 없는 백색분말로 염화칼슘, 초산칼슘, 탄산칼슘, 수산화칼슘, 황산칼슘, 구연산칼슘, 글루콘산 칼슘등 어는 것을 사용하여도 무방하다.In addition, the compound used for calcium may be a white powder with no odor, and may be used, such as calcium chloride, calcium acetate, calcium carbonate, calcium hydroxide, calcium sulfate, calcium citrate and calcium gluconate.
본 발명의 조직감 향상을 위하여 칼슘을 처리한 결과는 표 1과, 제1, 2 및 3도와 같다.The results of treatment with calcium for improving the texture of the present invention are shown in Table 1, 1, 2 and 3 degrees.
제1도는 본 발명으로 제조한 마늘의 조직강도를 나타낸 그래프이고, 제2도는 생마늘의 조직강도 그래프이며, 제3도는 본 발명에서 열처리(브랜징)만하고 칼슘용액처리를 하지 않은 마늘의 조직강도 그래프이다.1 is a graph showing the tissue strength of garlic prepared by the present invention, Figure 2 is a graph of tissue strength of raw garlic, Figure 3 is a graph of the tissue strength of garlic without heat treatment (branding) in the present invention only calcium treatment to be.
마늘의 조직강도는 레오메타(SUN RHED METER CR-200D, SUN ScIENTIFIC CO. LTD)를 이용하여 침입강도를 측정한 값으로 정의하였다.Tissue strength of garlic was defined as the measured value of invasive strength using a rheometer (SUN RHED METER CR-200D, SUN ScIENTIFIC CO. LTD).
침입강도는 레오메타의 시료대 위에 마늘을 올려놓고 시료대의 상승속도와 침입속도와의 차이(시연도)를 측정하여 일정의 길이까지의 용력(하중)을 측정하는 것으로 이응력의 값에 의해서 강도(Strength)와 경도(Hardness)가 계산된다.Penetration strength is to measure the difference between the ascent rate and the penetration rate of the sample stand by placing garlic on the sample table of the rheometer and measuring the capacity (load) up to a certain length. Strength and Hardness are calculated.
[표 1]TABLE 1
주) *는 침입강도 측정거리를 나타냄.Note) * indicates the breaking strength measurement distance.
표와 도면의 결과로 보아 본 발명으로 제조한 마늘은 마늘의 냄새를 제거하였을뿐 아니라 조직면에서도 생마늘과 유사한 결과를 얻었다.As a result of the table and drawing, garlic prepared by the present invention not only removed the smell of garlic, but also obtained similar results to raw garlic in terms of tissue.
본 발명에 의해 목적을 달성할 수 있는 처리공정은 다음과 같다.The treatment process which can achieve the objective by this invention is as follows.
제1공정 : 침지공정Step 1: Immersion Process
일정량의 마늘을 유기산이 첨가된 탈취용액에(산도 5-15%인 아세트산)30분간 침지한다.A certain amount of garlic is immersed in a deodorizing solution to which organic acid is added (acetic acid with an acidity of 5-15%) for 30 minutes.
이때 탈취용액으로 사용하는 아세트산의 산도가 5%미만이면 충분한 탈취가 이루어지지 않으며 15%이상이 되면 최종 제품에 대하여 신맛이 나므로 부적합하다.At this time, if the acidity of acetic acid used as the deodorizing solution is less than 5%, sufficient deodorization is not achieved, and if it is more than 15%, the final product has a sour taste, which is not suitable.
제2공정 : 효소실활 공정Second Process: Enzyme Inactivation Process
제1공정에서 얻어진 마늘을 비타민-C가 첨가된 탈취용액에 넣고 70~85℃로 1~5분간 열처리(브랜칭)를 한다.Garlic obtained in the first step is put in a deodorizing solution to which vitamin-C is added and heat-treated (branching) for 1 to 5 minutes at 70 ~ 85 ℃.
이때 70℃미만이면 열처리 시간이 상대적으로 길어져 조직이 약해지며, 85℃이상이 되면 열처리시간은 짧고 효소는 빨리 실활되나 고온으로 인하여 조직은 약해진다. 또 비타민-C는 열처리 과정에서 갈변현상을 막기 위하여 0.01%를 사용한다.At this time, if the temperature is less than 70 ° C, the heat treatment time is relatively long, and the tissue is weakened. If the temperature is higher than 85 ° C, the heat treatment time is short and the enzyme is inactivated quickly, but the tissue is weakened due to the high temperature. Vitamin-C also uses 0.01% to prevent browning during heat treatment.
제3공정:조직감 향상공정3rd step: texture improvement process
제2공정에서 얻어진 마늘을 0.1~2.0% 수산화칼슘(Ca(OH)2)용액에 침지하여 칼슘(Ca)이온이 마늘내부에 침투하도록 3시간 이상 방치한다.Garlic obtained in the second step is immersed in 0.1 ~ 2.0% calcium hydroxide (Ca (OH) 2 ) solution and allowed to stand for at least 3 hours to allow calcium (Ca) ions to penetrate into the garlic.
이때 수산화칼슘을 0.1%미만 사용하면 조직이 충분히 단단하게 되지 않으며 2.0%이상이 되면 조직이 너무 단단하여 식감이 불량하다.If the calcium hydroxide is less than 0.1%, the tissue is not sufficiently hard. If it is more than 2.0%, the tissue is too hard and the texture is poor.
제4공정 : 건조공정4th process: drying process
제3공정에서 얻어진 마늘에 90℃에서 30분간 열풍건조한다.Hot-air-dried at 90 degreeC for 30 minutes to the garlic obtained by the 3rd process.
제5공정 : 포장공정5th process: packaging process
제4공정에서 얻어진 마늘을 76cmHg 압력하에서 진공포장(PET/Nylon/CPP)한다.Garlic obtained in the fourth step is vacuum packed (PET / Nylon / CPP) under 76 cmHg pressure.
본 발명은 실시예에 따라 아래에 구체적으로 설명한다.The present invention is described in detail below according to the embodiment.
[실시예 1]Example 1
탈피한 마늘 1kg을 10% 아세트산(탈취용액)에 30분간 침지한 다음 다시 0.01% 비타민-C가 첨가된 탈취용액에 넣고 80℃에서 5분간 브랜칭하였다.1 kg of peeled garlic was immersed in 10% acetic acid (deodorant solution) for 30 minutes and then placed in 0.01% vitamin-C added deodorant solution and branched at 80 ° C. for 5 minutes.
브랜칭후 0.1% 수산화칼슘 용액에 침지하면서 냉각하였다.After branching it was cooled while immersed in 0.1% calcium hydroxide solution.
냉각된 마늘을 90℃에서 30분간 열풍건조하여 76cmHg 압력하에 진공포장(PET/Nylon/CPP)하였다.The cooled garlic was dried by hot air at 90 ° C. for 30 minutes, and vacuum-packed (PET / Nylon / CPP) under 76 cmHg pressure.
[실시예 2]Example 2
산도 5%인 아세트산 60분간 침지한 것을 제외하고는 실시예1에서와 동일하게 처리하였다.The same process as in Example 1 was conducted except that the acid was immersed for 60 minutes with 5% acidity.
[실시예 3]Example 3
산도 15%인 아세트산에 20분간 침지한 것을 제외하고는 실시예1에서와 동일하게 처리하였다.The same process as in Example 1 was carried out except that it was immersed in acetic acid having an acidity of 15% for 20 minutes.
[실시예 4]Example 4
수산화칼슘 0.5%를 혼합한 것을 제외하고는 실시예1에서 동일하게 처리하였다.The same treatment was performed in Example 1 except that 0.5% of calcium hydroxide was mixed.
[실시예 5]Example 5
수산화칼슘 1.0%를 혼합한 것을 제외하고는 실시예1에서 동일하게 처리하였다.The same treatment was performed in Example 1 except that 1.0% of calcium hydroxide was mixed.
[실시예 6]Example 6
수산화칼슘 1.5%를 혼합한 것을 제외하고는 실시예1에서 동일하게 처리하였다.The same treatment was carried out in Example 1 except that 1.5% calcium hydroxide was mixed.
[실시예 7]Example 7
수산화칼슘 대신 구연산칼슘 0.1%를 혼합한 것을 제외하고는 실시예 1에서 동일하게 처리하였다.The same process as in Example 1 was conducted except that 0.1% of calcium citrate was mixed instead of calcium hydroxide.
[실시예 8]Example 8
수산화칼슘 대신 황산칼슘 0.1%를 혼합한 것을 제외하고는 실시예 1에서 동일하게 처리하였다.The same treatment was carried out in the same manner as in Example 1 except that 0.1% calcium sulfate was mixed instead of calcium hydroxide.
[실시예 9]Example 9
수산화칼슘 대신 초산칼슘 0.1%를 혼합한 것을 제외하고는 실시예 1에서와 동일하게 처리하였다.The same process as in Example 1 was conducted except that 0.1% of calcium acetate was mixed instead of calcium hydroxide.
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KR1019940007667A KR100313307B1 (en) | 1994-04-12 | 1994-04-12 | Production of odorless garlic |
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KR1019940007667A KR100313307B1 (en) | 1994-04-12 | 1994-04-12 | Production of odorless garlic |
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KR100313307B1 true KR100313307B1 (en) | 2001-12-28 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20010088486A (en) * | 2001-07-25 | 2001-09-28 | 이용화 | manufacturing method of garlic |
KR100840991B1 (en) | 2007-02-27 | 2008-06-24 | 류병호 | Method for producing the black garlic |
KR101250009B1 (en) * | 2011-01-31 | 2013-04-03 | 한국식품연구원 | Ginger slices and method of manufacturing the same |
KR101296417B1 (en) | 2011-06-10 | 2013-08-13 | 영농조합법인 늘새봄 | A grind garlic prevented green stools and the method of making it |
KR101369762B1 (en) * | 2011-08-30 | 2014-03-07 | 한국식품연구원 | Confected garlic using honey or confected garlic using honey and soy sauce and producing method thereof |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100754112B1 (en) * | 2006-08-18 | 2007-08-31 | 서상문 | Dry garlics manufacture method of jelly type |
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1994
- 1994-04-12 KR KR1019940007667A patent/KR100313307B1/en not_active IP Right Cessation
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20010088486A (en) * | 2001-07-25 | 2001-09-28 | 이용화 | manufacturing method of garlic |
KR100840991B1 (en) | 2007-02-27 | 2008-06-24 | 류병호 | Method for producing the black garlic |
KR101250009B1 (en) * | 2011-01-31 | 2013-04-03 | 한국식품연구원 | Ginger slices and method of manufacturing the same |
KR101296417B1 (en) | 2011-06-10 | 2013-08-13 | 영농조합법인 늘새봄 | A grind garlic prevented green stools and the method of making it |
KR101369762B1 (en) * | 2011-08-30 | 2014-03-07 | 한국식품연구원 | Confected garlic using honey or confected garlic using honey and soy sauce and producing method thereof |
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KR950028648A (en) | 1995-11-22 |
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