KR100295749B1 - Method for producing high strength composite fibric for protective clothing - Google Patents
Method for producing high strength composite fibric for protective clothing Download PDFInfo
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- KR100295749B1 KR100295749B1 KR1019980022074A KR19980022074A KR100295749B1 KR 100295749 B1 KR100295749 B1 KR 100295749B1 KR 1019980022074 A KR1019980022074 A KR 1019980022074A KR 19980022074 A KR19980022074 A KR 19980022074A KR 100295749 B1 KR100295749 B1 KR 100295749B1
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
- D03D1/0035—Protective fabrics
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
- D02G1/02—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist
- D02G1/0206—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
- D02G1/16—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics using jets or streams of turbulent gases, e.g. air, steam
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/26—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre with characteristics dependent on the amount or direction of twist
- D02G3/28—Doubled, plied, or cabled threads
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
- D02J1/08—Interlacing constituent filaments without breakage thereof, e.g. by use of turbulent air streams
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
- D03D13/004—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft with weave pattern being non-standard or providing special effects
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/30—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the fibres or filaments
- D03D15/37—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the fibres or filaments with specific cross-section or surface shape
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/04—Outerwear; Protective garments
Abstract
Description
본 발명은 고강력 복합 방호복 직물의 제조방법에 관한 것으로서, 보다 상세하게는 특수한 사가공 기술을 채용하고 조직을 변화시켜 직물의 색상을 다양하게 발현시키고 촉감을 개선한 고강력 복합 방호복 직물의 제조방법에 관한 것이다.The present invention relates to a method for manufacturing a high strength composite protective clothing fabric, and more particularly, employing a special processing technology and changing the texture to express a variety of colors of the fabric and to improve the feel of a high strength composite protective clothing fabric It is about.
고강력 방호복 직물에 채용되는 고강력 방향족 섬유로는 미합중국 듀폰(Du Pont)사에서 개발, 판매하고 있는 "케블라(Kevlar)"(상표명)가 있는데 이 방향족 아라미드계 섬유는 분해 및 탄화온도가 427℃∼482℃이고, 20∼30g/d의 고강력을 지닌 섬유이다.High-strength aromatic fibers used in high-strength protective clothing fabrics include "Kevlar" (trade name) developed and sold by Du Pont, USA, which has a decomposition and carbonization temperature of 427 ° C. It is -482 degreeC and is a fiber with high strength of 20-30g / d.
종래기술은 상기의 "케블라" 원사와 같은 고강력 방향족 아라미드계 섬유를 단순히 느슨하게 제직하여 헬멧, 방한복 등의 보강 재료로 사용하는 것이었다. 그러나, 이 방향족 아라미드계 섬유는 우수한 물성에도 불구하고 염색성, 제직성이 좋지 않아서 통상의 의류용 소재로 자유롭게 사용되지 못하고 일부 안감으로 사용되는 정도였다.The prior art has simply been loosely weaving high-strength aromatic aramid fibers, such as the "Kevlar" yarns, to use them as reinforcing materials for helmets, winter clothes, and the like. However, the aromatic aramid fibers, despite their excellent physical properties, have poor dyeing and weaving properties, so that they cannot be used freely as a general garment material, but used as part of lining.
종래의 이러한 기술은 의류용 소재로서의 다양한 요구를 충족시키기에는 너무 부족하고 심미한 외관과 다양한 색상을 발현시키기 어려운 단점이 있었다.This conventional technique has a disadvantage that it is too insufficient to meet the various demands as the material for clothing, and difficult to express aesthetic appearance and various colors.
본 발명의 목적은 방향족 아라미드계 섬유를 나이론, 폴리프로필렌 또는 폴리에스터와 특수 복합 사가공 기술로 혼섬하거나, 특수한 조직을 통하여 고강력 방향족 아라미드계 섬유를 직물 표면 또는 이면에 치우치게 위치시켜 방향족 아라미드계 섬유의 고강력 기능을 유지시키면서 나이론 또는 폴리프로필렌 또는 폴리에스터와의 적절한 혼섬효과에 의한 촉감 개선과 자유로운 색상발현 및 심미한 외관 효과를 얻을 수 있는 고강력 복합 방호복 직물을 제공하는데 있다.An object of the present invention is to blend an aromatic aramid fiber with nylon, polypropylene or polyester with a special composite microfabrication technique, or to place a highly strong aromatic aramid fiber on the surface or back side of the fabric through a special structure to form an aromatic aramid fiber. It is to provide a high strength composite protective clothing fabric that can improve the feel and free color expression and aesthetic appearance effect by appropriate blending effect with nylon or polypropylene or polyester while maintaining the high strength function of the.
도1은 본 발명의 일실시예에 따른 고강력 복합 방호복 직물을 직조하기 위한 조직도이다.1 is a tissue diagram for weaving a high strength composite protective clothing fabric according to an embodiment of the present invention.
도2는 도1의 조직도에 의한 통경순서도의 예이다.FIG. 2 is an example of a diameter flow chart according to the organization chart of FIG. 1.
도3은 본 발명의 다른 실시예에 따른 고강력 복합 방호복 직물을 직조하기 위한 조직도이다.Figure 3 is a tissue diagram for weaving a high strength composite protective clothing fabric according to another embodiment of the present invention.
도4는 본 발명에 채용되는 2중 카바링사의 카바링상태를 보여주기 위한 도면이다.Figure 4 is a view for showing the cabaling state of the double cabaring yarn employed in the present invention.
※ 도면의 주요부분에 대한 부호의 설명※ Explanation of code for main part of drawing
101 : 고강력사 102 : 1차 카바링사101: high strength yarn 102: the first cabaring yarn
103 : 2차 카바링사103: the second cabaring company
본 발명에 따른 고강력 복합 방호복 직물의 제조 방법은 면번수 10 내지 50수의 고강력 방향족 아라미드계 방적사를 공기교락가공(Air Interlacing)을 거친 70d 내지 3000d의 나이론, 40d 내지 3000d의 폴리프로필렌 또는 75d 내지 4000d의 폴리에스터 원사와 (100∼1,000 Twist/Meter)×
상기 나이론, 폴리프로필렌 및 폴리에스터 섬유의 공기교락 가공은 2∼7㎏/㎠의 압력으로 고압 공기를 분사시키는 노즐(Nozzle)에 통과시켜 이루어지는 것이 바람직한데 이것은 방향족 아라미드계 섬유가 나이론, 폴리프로필렌 또는 폴리에스터 섬유와 합연될 때 방향족 아라미드계 섬유가 불규칙적으로 섬유사(Filament)속으로 파고 들어서 생겨나는 직물 표면의 흠을 없애주기 위한 것이다.The air entanglement processing of the nylon, polypropylene, and polyester fibers is preferably performed by passing through a nozzle for injecting high pressure air at a pressure of 2 to 7 kg / cm 2, wherein the aromatic aramid fibers are nylon, polypropylene or When combined with the polyester fibers, the aromatic aramid fibers are to remove the flaw of the fabric surface caused by irregularly dug into the fiber yarn (Filament).
이와 같이 제조되는 본 발명의 고강력 복합 방호복 직물은 고강력 방향족 아라미드계 섬유의 고강력 기능뿐만 아니라 외력에 의한 내마모성 또는 항 필링성(Anti-Pilling)을 갖는다. 상기 제직공정에서는 평직, 능직, 주자직의 직물을 제직할 수 있고 특히 도1의 특수 조직을 채용하여 일반원사를 바닥사로 하여 제직하면 직물의 표면 내마모 성능이 뛰어나고 마찰에 잘 견디는 직물 제조가 가능하다. 도2는 도1의 조직으로 제직할 때의 통경순서도의 일예를 보여준 것이다.The high strength composite protective clothing fabric of the present invention prepared as described above has not only the high strength function of the high strength aromatic aramid fibers, but also wear resistance or anti-pilling by external force. In the weaving process, it is possible to weave the fabric of plain weave, twill weave, and runner weave. In particular, weaving with a special yarn of Fig. 1 as a bottom yarn, weaving the surface of the fabric is excellent in the wear resistance of the fabric and can withstand the friction well. Do. Figure 2 shows an example of the diameter flow chart when weaving into the tissue of Figure 1;
상기 직물제조시 다른 원사와의 혼직시 합연사의 데니어가 굵어 자연스럽게 립(Rip) 조직을 형성하게 되는데 립 부위 합연사 데니어와 바닥사 데니어는 (1.5∼3.5 =
상기 방법으로 제조한 직물을 염색가공후 아크릴(Acryl) 또는 폴리우레탄 등으로 수지 코팅하면 고강력 기능과 내마모성 및 항필링성을 갖춘 고강력 복합 방호복 직물이 얻어진다.When the fabric produced by the above method is dyed and resin coated with acrylic or polyurethane, a high strength composite protective clothing fabric having high strength function, abrasion resistance, and anti-pilling property is obtained.
상기 직물 제조시 고강력 방향족 아라미드계 섬유 대신 일반 나이론 또는 폴리프로필렌 또는 폴리에스터 원사를 사용해도 사가공 또는 조직상의 특수성으로 인하여 상기 직물의 약 85% 정도의 강력 및 내마모 기능이 발현된다.The use of ordinary nylon or polypropylene or polyester yarns in place of high strength aromatic aramid fibers in the fabric production results in about 85% strength and wear resistance of the fabrics due to the processing or tissue specificity.
또한 합연시 심사(core)에 총합연 데니어의 5∼20% 정도의 폴리우레탄 스판텍스를 넣어서 신축 효과를 발현시킬 수도 있다.In addition, a polyurethane spantex of about 5 to 20% of the total joint denier may be added to the core at the time of jointing to express an elastic effect.
본 발명의 다른 형태에 따르면 본 발명은 면번수 10 내지 50수의 고강력 방향족 폴리아라미드계 방적사, 70d 내지 3000d의 나이론, 40d 내지 3000d의 폴리프로필렌 또는 75d 내지 4000d의 폴리에스터 원사를 사용, 혼직하되 도3의 조직도에 따라서 제직하고 염색 및 수지 코팅을 행함으로써 이루어진다.According to another aspect of the present invention, the present invention is mixed with 10 to 50 high strength aromatic polyaramid-based yarn, 70d to 3000d nylon, 40d to 3000d polypropylene or 75d to 4000d polyester yarn This is done by weaving, dyeing, and resin coating in accordance with the organization chart of FIG.
이때 상기 고강력 방향족 아라미드계 방적사는 단독으로 사용하거나 상기 데니어 범위의 나이론, 폴리프로필렌 또는 폴리에스터와 합연하여 사용할 수 있다. 상기와 같은 방법으로 제직하면 조직특성상 고강력 방향족 아라미드계 방적사는 조직의 뒷면으로 미끄러져 들어가므로 표면에서는 보이지 않게 된다. 따라서 조직 뒷면에 위치한 방향족 아라미드계 섬유가 고강력 내마모성의 기능을 갖게 하고 표면은 다양한 색상 발현이 가능케 된다.At this time, the high-strength aromatic aramid-based yarn can be used alone or in combination with nylon, polypropylene or polyester in the denier range. When weaving in the same manner as described above, the highly strong aromatic aramid yarn is slid to the back side of the tissue due to the nature of the tissue, so that it is invisible from the surface. Therefore, the aromatic aramid fibers located on the back of the tissue has a high strength wear resistance function and the surface can be expressed in various colors.
본 발명의 또다른 형태에 따르면 본 발명은 면번수 10 내지 50수의 고강력 방향족 아라미드계 방적사를 70d 내지 3000d의 나이론, 40d 내지 3000d의 폴리프로필렌 또는 75d 내지 4000d의 폴리에스터 원사를 사용하여 도4와 같이 이중 카바링(covering)하여 염색이 어려운 방향족 아라미드계 섬유를 완전히 감싸도록 한 카바링사를 제조하고 일반사를 바닥사로 하여 제직, 염색, 후가공공정을 거침으로써 이루어진다.According to still another aspect of the present invention, the present invention uses a high strength aromatic aramid spun yarn of 10 to 50 cotton number using 70d to 3000d nylon, 40d to 3000d polypropylene or 75d to 4000d polyester yarn. It is made by producing a cabaring yarn to completely cover the aromatic aramid fibers that are difficult to dye by double covering (covering), and through the weaving, dyeing, post-processing process using a general yarn as a bottom yarn.
첨부된 도4를 참조하면 상기 이중 카바링시 1차 카바링사(102)의 T/M은 좌연(Z 연,방적사추연 방향)으로 (1000∼3500 ×
이하에서 본 발명의 바람직한 실시예를 기술할 것이다. 그러나, 이하의 실시예들은 본 발명을 예증하기 위한 것이므로 본 발명의 범위를 국한시키는 것으로 이해되어져서는 안 될 것이다.Hereinafter, a preferred embodiment of the present invention will be described. However, the following examples are intended to illustrate the invention and should not be understood as limiting the scope of the invention.
실시예 1Example 1
면번수 30 수의 고강력 방향족 아라미드계 방적사와 4 Kg/㎠의 공기압으로 공기교락시킨 600 데니어의 폴리에스터 섬유를 450 T/M으로 연사하여 복합가공사(합연사)를 제조하였다. 또한, 바닥사는 폴리에스터 150 데니어를 650 T/M으로 연사하였다.A composite fiber (ply-twisted yarn) was prepared by twisting a high-strength aromatic aramid spun yarn of 30 cotton number and 600 denier polyester fibers air-interlaced at an air pressure of 4 Kg / cm 2 at 450 T / M. In addition, the bottom yarn was twisted polyester 150 denier at 650 T / M.
상기 복합 가공사와 바닥사를 경사 2:13, 위사 2:5의 비율로 배열하여 래피어직기에서 도1의 특수 조직을 채용하여 생지밀도 122 X 52 본/inch로 제직하였다. 이와 같이 제직된 생지를 통상의 폴리에스터 직물 염색가공 방법에 따라 염색 및 코팅을 완료하여 본 발명의 고강력 복합 방호복 직물을 완성하였다.The composite machined yarn and the bottom yarn were arranged in a ratio of inclined 2:13 and weft 2: 5, and the weaving machine adopted a special structure of FIG. Dyeing and coating was completed according to the conventional polyester fabric dyeing processing method of the woven fabric as described above to complete the high strength composite protective clothing fabric of the present invention.
실시예 2Example 2
면번수 20 수의 고강력 방향족 아라미드계 방적사와 230 데니어의 나이론 6 섬유를 450 T/M으로 합연하여 복합가공사를 제조하였다. 또한, 바닥사는 나이론 6 섬유 840 데니어를 250 T/M으로 연사하였다.A composite fiber was fabricated by combining a high-strength aromatic aramid spun yarn with a cotton number of 20 and 230 denier nylon 6 fibers at 450 T / M. In addition, the floor yarns twisted nylon 6 fiber 840 denier at 250 T / M.
상기 복합 가공사와 바닥사를 래피어직기에서 도3의 특수 조직을 채용하여 생지밀도 74 X 46 본/inch로 제직하였다. 도3에서 경사에 4 에는 바닥사로서 나이론 6섬유 840 데니어를 위치시키고, 5 에는 복합 가공사를 위치시켰으며, 위사에는 나이론 6 섬유 840 데니어만을 사용하였다. 이와 같이 제직된 생지를 통상의 나이론 직물 염색가공 방법에 따라 염색 및 코팅을 완료한 결과 직물표면에 나이론 섬유가 위치하여 다양한 색상의 심미한 외관 효과가 발현되었으며, 이면에는 복합가공사가 위치하여 고강력 및 내마모성을 갖는 직물이 수득되었다.The composite yarn and the bottom yarn were woven with 74 × 46 bone / inch of raw paper density by adopting the special structure of FIG. 3 in a rapier loom. In Fig. 3, the nylon 6 fiber 840 denier was positioned as the bottom yarn at 4, the composite fabric yarn was placed at 5, and only the nylon 6 fiber 840 denier was used as the weft yarn. As a result of dyeing and coating the woven dough according to the conventional nylon fabric dyeing and processing method, nylon fibers were placed on the surface of the fabric, resulting in aesthetical appearance of various colors. And a fabric having wear resistance.
실시예 3Example 3
면번수 30 수의 고강력 방향족 아라미드계 방적사를 심사로 하여 나이론 6 섬유 155 데니어로 2300 T/M의 Z 연을 주어 1차 카바링하고, 다시 나이론 6 섬유 155 데니어로 2300 T/M의 S 연을 주어 이중 카바링사를 제조하였다. 상기 이중 카바링사와 나이론 500 데니어 공기가공사(Air jet)를 경,위사 공히 1:3으로 배열하여 래피어직기에서 평직으로 생지밀도 43 X 40 본/inch로 제직하였다. 이와 같이 제직된 생지를 통상의 나이론 직물 염색가공 방법에 따라 염색 및 코팅을 완료한 결과 고강력 방향족 아라미드 방적사가 완벽하게 카바링되어 다양한 색상의 심미한 외관 효과가 발현될 수 있었으며, 고강력 및 내마모성을 갖는 직물이 수득되었다.A high strength aromatic aramid spun yarn with 30 number of cottons was screened and subjected to primary carbaring with nylon 6 fiber 155 deniers and 2300 T / M Z lead, followed by S 6 of 2300 T / M with nylon 6 fiber 155 deniers. To give a double cabaring yarn. The double cabaring yarn and nylon 500 denier air jet (air jet) was arranged in a light and weft yarn 1: 3 weaving in a plain weave density 43 X 40 bone / inch in a rapier loom. As a result of the dyeing and coating of the woven dough according to the conventional nylon fabric dyeing processing method, high strength aromatic aramid yarn was perfectly carburized to express aesthetic appearance of various colors, and high strength and wear resistance. A fabric with was obtained.
상술한 바와 같이 본 발명의 방법에 따르면 고강력 내마모 기능과 다양한 색상에 의한 심미적인 외관을 동시에 갖춘 고강력 복합 방호복 직물을 수 있는 효과가 있다.As described above, according to the method of the present invention, there is an effect that a high-strength composite protective clothing fabric having a high-strength wear-resistant function and aesthetic appearance by various colors at the same time.
이상에서 본 발명은 기재된 구체예에 대해서만 상세히 설명되었지만 본 발명의 기술사상 범위 내에서 다양한 변형 및 수정이 가능함은 당업자에게 있어서 명백한 것이며, 이러한 변형 및 수정이 첨부된 특허청구범위에 속함은 당연한 것이다.Although the present invention has been described in detail only with respect to the described embodiments, it will be apparent to those skilled in the art that various modifications and variations are possible within the technical scope of the present invention, and such modifications and modifications are within the scope of the appended claims.
Claims (5)
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JPH0426346A (en) * | 1990-05-18 | 1992-01-29 | Mitsuba Electric Mfg Co Ltd | Rectifying device in ac generator for car |
US5177948A (en) * | 1989-06-13 | 1993-01-12 | Kolmes Nathaniel H | Yarn and glove |
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US5177948A (en) * | 1989-06-13 | 1993-01-12 | Kolmes Nathaniel H | Yarn and glove |
US5177948B1 (en) * | 1989-06-13 | 1995-04-18 | Nathaniel H Kolmes | Yarn and glove |
JPH0426346A (en) * | 1990-05-18 | 1992-01-29 | Mitsuba Electric Mfg Co Ltd | Rectifying device in ac generator for car |
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