KR100291065B1 - Waster water and foul water for froth secession disposal process - Google Patents

Abstract

PURPOSE: An advanced treatment method of sewage and wastewater using foam separation process is provided, which remove polymer such as nonbiodegradable organics by more than 90 % by forming foam forcibly at the initial stage and effectively nitrify organic matter of low molecular weight as feed of microorganism. The residual nitrate and inorganic ammonia are recovered by forming foam, denitrified at anoxic state and gasified by ionic anaerobic decomposition. The residually dissolving nitrogen, nitrate and ammonia nitrogen are further recovered as foam by changing molecular structure caused by magnetic electron ion and foam separated by reacting with ozone of strong oxidizing force. CONSTITUTION: The method comprises the following steps: (i) remove coarse and fine impurities by screen and sand settled at the settling basin by pickup handler; (ii) recover the adipose organic matter, fatty nitrogen, alkyl benzene sulfonate(ABS) contained in supernatant of settling basin by reacting with air, oxygen or ozone as foam and remove polymer by conducting low concentration hydrophilicity and by nitrifying of low molecular weight nitrogen; (iii) aerobically nitrify by foam separation type by nitrifying microorganism that eats nitrogen as food and by foaming residue nitrate, ammonium, soluble organic nitrogen reacted with oxygen or ozone; (iv) denitrification by dissociating oxygen taking nitric acid as receptor of nitrifying microorganism after forming anoxic state; (v) stripping gas by removing aerobic filamentous fungi and by decomposing energy of organic matter; (vi) remove nutrient sale and recycle; (vii) pass digestion basin and dewater by concentrating excess sludge at centrifugal concentrator; (viii) remove suspended sludge, inorganic phosphorus; (ix) magnetically ionize by changing molecular structure of nutrient salts; (x) oxidize and gasify by oxidizing coloring matter and colitis germ; and (xi) settling filter the ozonized water.

Description

Wastewater and sewage treatment by foam separation method {WASTER WATER AND FOUL WATER FOR FROTH SECESSION DISPOSAL PROCESS}

The present invention relates to ozone of the applicant's patent 133627 (high concentration organic inorganic wastewater treatment apparatus and method) Processing means. The present invention relates to a method for treating wastewater and sewage by means of a foam separation method which has technically improved the means for microbial invasion of Patent No. 141576 (High-altitude solid-liquid separation and digestion treatment method), and an apparatus thereof.

Environmental foundation facilities such as sewage, industrial wastewater, dyeing wastewater, livestock wastewater, and landfill leachate, which are currently in operation or under construction in Korea, are treated based on normal digestion and standard activated sludge, but microorganisms are single cells and are not biodegradable. There is a limitation that the material cannot be removed. The waste and sewage contains 10% or more of the concentration of fatty organic matter, oil-soluble nitrogen, synthetic detergent (ABS) which cannot be removed by digestion, enzymes, microorganisms and catalysts. As it is interfaced with toxic loads on microorganisms and ionic organic substances, it makes the microbial treatment process difficult and also maintains the proliferation and activation process for ending microorganisms of 10-20 days of age in treating large amounts of sewage. It becomes a problem. Currently, domestic facilities do not consider any treatment measures, technologies, and facilities for them. Therefore, considerable reinvestment is required to make resources for advanced treatment and dewatering in the future.

As described above, high-molecular compounds such as fatty organic matter and oil-soluble nitrogen-decomposable synthetic detergent that cannot be removed by conventional treatment methods are recovered at least 90% by forced foaming in the initial stage, Nitrifying nutrients efficiently as food for microorganisms, denitrifying in anoxic state, gasifying by ionizing anaerobic decomposition, recovering nitrates and inorganic ammonia, etc., which cannot be nitrified by foaming, and remaining soluble nitrogen, nitrate, Ammonia nitrogen, magnetic magnetic ions ( ) To recover the foam by modifying the molecular structure. The strong oxidizing power of) is reacted with dissolved organics and residual soluble nitrogen (SON), and recovered by foam separation. The polymer compound recovered by the foaming may be separated by ozone ( The present invention provides a device and a method capable of resource-processing water by vaporizing and treating the same with an oxidizing agent.

Figure 1 is an embodiment of the organic, inorganic, nitrogen, phosphorus advanced treatment of the present invention

Figure 2 is an embodiment of the dye advanced treatment of the present invention

Figure 3 is a schematic cross-sectional view of the foam separation type polymer compound removal tank and recovery device in Figure 1

Figure 4 is a foam separation ozone in Figure 1 Schematic cross section of a contact bath

5 is a schematic cross-sectional view of the polymer compound oxidizing tank in FIG.

6 is a schematic cross-sectional view of the precipitation filtration tank in FIG.

Explanation of symbols on the main parts of the drawing

1,1a; Debris removal screen 2; Tide

3; Primary precipitation tank 4; Foam Separation Polymer Compound Removal Tank

5; Denitrification tank 6; Degassing tank

7,7a; Foam separation type aerobic oxidizing tank 8; Secondary Precipitator

9; Filtration tank 10; Mixing tank

11; Centrifugal concentrator 12; Polymer Compound Vaporizer

13; Ionization tank 14; Foam separation ozone Oxidation tank

15; Coral contact membrane 16; ozone( )generator

17; Pazone ( Destroyer 18; Diffuser

19; Microbial membrane 20; Foam recovery tank

21; Bubble breaker 22; Motor impeller

23; Magnet pump 24; agitator

25; Dehydrator 26; Sedimentation filtration tank

27; Sedimentation tank 28; Coral filtration membrane

29; Discharge tank 30; Brower

31; Foam recovery line 32; Liquefaction Transfer Line

33; Acupuncture lifting stage 34; Flow adjustment tank

The advanced treatment of wastewater and wastewater by foam separation method to achieve the object of the present invention is a pre-treatment step, the fatty organic, oil-containing nitrogen, synthetic detergent, etc. contained in the influent source ozone ( ) And pre-treatment step of recovering foaming by foaming with oxygen and destroying by liquefaction and treating it in a separate process. Capillary fillings, in which microorganisms can proliferate and nitrify microorganisms, are embedded, and ammonia is nitrified sufficiently by nitrification microorganisms, and nitrates and ammonium salts, which cannot be nitrified, react with oxygen supplied to recover, destroy, In the liquefied state, the hydrophilic nitrogen is oxygen or ozone during the pretreatment step. The first treatment step of dissociating and denitrifying oxygen as an acceptor of the respiratory means of nitrifying microorganisms in an anoxic state and nitrifying by nitrifying microorganisms in the anoxic state and gasifying carbon and nitrogen by dissociation energy of organic matter in anaerobic ionization. And sedimenting and separating the treated water in the sedimentation basin and concentrating the precipitated surplus sludge and phosphorus contained in the centrifugal condenser and removing the dehydration with a dehydrator. The supernatant of the sedimentation tank is introduced into an ionization tank, and the nitric acid contained in the filtered water. And residual soluble organic nitrogen, nitrate, and ammonia nitrogen. Filtration ionization step of changing the molecular structure of the ion into ions and recovering it by foaming, and flowing the treated water into the foam separation ozone contact tank to ozone undecomposed residual soluble organic nitrogen (SON), nitrate, and inorganic ammonia. ( ) And a high-treatment step of removing the dye by foaming and highly oxidizing and removing the pigment, and vaporizing a high molecular compound to recover the foam in the liquid phase and oxidize and vaporize each step.

In the foam separation method of each step to achieve the object of the present invention, the foam separation type polymer compound removal tank of the pretreatment step is abandoned ozone ( Or oxygen and fatty and oily organic energy to react efficiently in coral or filter demister, promote nitrification of low molecular nitrogen and recover bubbles in foam recovery tank without foaming. Foam separation type polymer compound removal means for removing in a liquefied state and oxygen or ozone in the process of removing the polymer compound by foaming ), Low molecular nitrogen is nitrified, ammonia is nitrified by aerobic microbial infiltration means, nitrifying and foamed nitrification means to recover nitrates, inorganic ammonia, etc. And denitrification by nitrifying microbial respiratory means in anoxic state and degassing by dissociation energy of organic matter in anaerobic ionization, and microsludge by filtering supernatant of sedimentation tank to remove dissolved organic, inorganic, nitrogen , Phosphorus electrons ( Ionization means for changing the molecular structure of the ion into ions and removing them by oxidation or foaming, and ozone by using ozone-spraying of undecomposed residual soluble organic nitrogen, nitrate, ammonia nitrogen, etc. ) To form foam and recover ozone ( Foam separation type ozone which oxidizes pigment highly by strong oxidation power of The organic energy in the polymer compound vaporization tank is converted to oxygen or ozone ( ) And the gasification of the high molecular compound which vaporizes the bubbles that are oxidized and foamed by the oxidization and dissociation energy of organic matter by the continuous circulation of conveying, and concentrates the precipitated sludge settled in the sedimentation tank with a centrifugal concentrator for dehydration or alumina. It is composed of means for adjusting pH with zeolite, coagulating with polymer coagulant, and removing sludge and phosphorus with dehydrator.

Hereinafter will be described with reference to the embodiment and the effect of the present invention.

1 is an exemplary embodiment of the present invention, as shown therein, sand and solids contained in a sediment removal screen (1) (1a) for removing a contaminant contained in the influent water and the separation liquid passed through the contaminant remover. A conventional sedimentation tank (2) for sedimentation is provided with a sedimentation lifter (33) and a flow control tank (34) for raising the sediment, and the primary settling tank (3) and the settling tank (3) A foam separation type polymer compound removal tank (4) for recovering fatty and oil-containing high molecular compounds and synthetic detergents contained in a foam, and a foam separation type aerobic nitrification tank (7) for nitrifying nutrients such as ammonia as food for microorganisms In connection, an anoxic denitrification tank 5, an ionization anaerobic degassing tank 6 is installed, and a secondary sedimentation tank 8 for conventional sedimentation separation is installed.

A filtration tank 9 for filtering the microparticles contained in the sedimentation tank supernatant is provided, and an ionization tank 13 for changing the molecular structure of the residual nutrients is provided.

A mixing tank 10 for adjusting the pH of the secondary sludge battery 8 with alumina, and a centrifugal concentrator 11 for removing excess sludge and phosphorus by reacting a polymer coagulant with the excess sludge that has passed through the mixing tank. And a polymer compound vaporization tank 12 for collecting, oxidizing, and vaporizing the bubbles recovered in each step in a liquefied state.

In FIG. 2, as an exemplary embodiment for removing the dye, residual dissolved organic nitrogen nitrate, inorganic ammonia, and foam separation ozone for removing the pigment contained in the monthly liquid passed through the above-described ionization tank 13 ( The contact tank 14 and the settling filtration tank 15 for adsorption and filtration of the fine particles are installed, and air or pure oxygen Ozone is used as a raw material ( Generator (16) and Ozone ( ) Is composed of a destroyer 17.

Hereinafter, the configuration of the present invention in more detail as follows.

Taxonomy screen (1) (1a) and the sedimentation tank (2) is installed, the acupuncture lifting device (33) to lift the sediment deposited on the floor is installed and the flow adjustment tank 34 is installed in conjunction. A primary sedimentation tank 3 for separating the sludge contained in the raw water of the flow rate adjustment tank 34 is provided, and ozone ( ) Or a diffuser 18 to abandon oxygen or air is installed, and in the middle of the tank, an air bubble that is abandoned at the diffuser is blocked and oxygen or ozone in the bubble state is blocked. Coral or self-degrading coral 15) is installed about 30cm, the upper part of the tank is covered with a plurality of tanks, and a plurality of foam recovery tanks 20 are installed at the top of each tank, the bubble of the foam recovered in the center A bubble breaker 21 is installed to destroy the foam and the foam separation type polymer compound removal tank 4 in which the logistic conveyance flows up and down under each tank in zigzag is installed.

In the tank, the low molecular weight organic nitrogen contained in the treated water from which the high molecular compound is removed, the organic energy and the oxygen or ozone ) Is linked to a low molecular hydrophilic and microbial aerobic nitrification tank (7) to nutrient ammonia. Foam separation type aerobic nitrification tank (7) is composed of a plurality of tanks and a plurality of foam recovery tank (20) and the bubble breaker (21) is installed in the center of the top of the covered, microorganisms can be formed and the nutrients live together for a long time The microorganism infiltrating membrane 19 is installed as a filler having a capillary hole formed therein, and an acid pipe 18 to abandon oxygen or air is installed at the bottom.

The denitrification tank 5 to denitrate the nitrified in the above step, the degassing tank 6 in which the nitrogen gas and the magnet pump 23 to be organic gasified are installed, respectively, with the agitator 24 installed therein, and the nutrients of the treated water. Depending on the concentration and the purpose of treatment, the foam separation type aerobic oxidizing tank (7a) is installed in duplicate as in the previous step.

The secondary sedimentation tank (8) for the sedimentation and separation of the treated water introduced therein is installed, and the filtration tank incorporating the coral filtration membrane (28) for filtering the residual nutrients and microparticles contained in the secondary sedimentation tank (8). 9) and an ionization tank 13 in which the magnet pump 23 is connected.

In order to remove excess sludge drawn from the sedimentation tank (8) and phosphorus contained therein, a mixing tank (10) to mix alumina, and a centrifugal concentrator (11) is installed.

Foam separation polymer compound removal tank (4), foam separation aerobic nitrification tank (7) (7a), foam separation ozone ( ) The foams of the oxidation tank 14 and the foam separation ionization tank 13 are collected by the liquefaction recovery line 31, and the ozone ( ), Or an acid pipe 18 for dispersing oxygen or air is installed, and a polymer compound vaporization tank 12 having a foam recovery tank 20 and a bubble breaker 21 is installed.

The above process is a simple advanced treatment process for low concentration wastewater without domestic sewage or dye, and the following process is a process for highly removing the dye, and as shown in FIG. The tanks are segregated each month by partitions and ozone ( Ozone supplied from generator Coral direct contact is blocked and bubble destruction is induced to generate strong oxidative power of self-decomposition, and the coral contact film 15 is installed to react efficiently with the pigment, and the ceramic diffuser 18 is installed at the bottom. Is foamed type ozone which is covered with a plurality of foam recovery tanks 20 and a bubble breaker 21 is installed at the center thereof. ) An oxidation tank 14 is provided.

Foam separation ozone ( In the oxidizing tank (14) ), The inlet pipe is installed at the center to introduce the treated water, which is highly removed from organic, inorganic, nitrogen, chromatic, and coliform bacteria, and a coral filtration membrane (28) is installed at the center of the gravity sedimentation tank (27). The sedimentation filtration tank 26 is installed and connected to the discharge tank 29 is installed.

ozone( The generator 16 is installed at a position higher than the surface of the treated water, and the foam separation type ozone ( Pyrolysis to supply the ozone exhausted from the contact tank 14 to the foam separation type polymer compound removal tank 14 or the polymer compound vaporization tank 12 of the previous stage for reuse and to destroy waste ozone discharged therefrom. ozone( Destroyer 17 is installed.

Referring to the operation of the embodiment of the present invention configured in this way in detail as follows.

Raw wood, which has undergone the pretreatment of the crude wood debris removal screen (1) (1a) and the settling tank (2), is introduced into the first settling tank (3) by the flow adjusting tank 34, and the sludge is sedimented and sedimented first. Is drawn by the digestion and dehydration process and the supernatant is introduced into the foam separation type polymer compound removal tank (4). As the straight line is blocked and destroyed by the pressure in the tank, it is self-decomposed and strong oxidizing power is brought into efficient contact with raw water in the capillary pores of the coral, and reacts mainly with fatty organic substances, oil-soluble nitrogen, and surfactants (ABS), Bubbles are formed and low molecular hydrophilic nitrogen is nitrated through the nitrite step.

Bubbles are high molecular compounds that are difficult to break with vesicles due to their viscous interface. In order to destroy and circulate these molecules to make them low molecular weight and hydrophilic, they have to undergo long-term digestion and aeration, and these processes do not remove biodegradable synthetic detergents (ABS), nitrates, residual soluble organic nitrogen (SON), and inorganic ammonia. It is discharged to the outside, causing contamination of the appeal as nutrients.

Therefore, in the present process, without using the defoaming means, the air or oxygen or ozone is supersaturated to induce bubble generation and they rise to the outlet of the foam recovery tank (20).

At this time, the bubble is instantaneously destroyed and liquefied by the rotation of the motor impeller 22 of the bubble breaker 21 installed at a gap of about 1 mm with the bottom of the foam recovery tank, thereby liquefying the foam recovery line 31 by the fluid force of the impeller. Through the polymer compound vaporization tank 12 is collected.

After the foam separation process of 10 mg / L for ozone reaction, 1 hour for pure oxygen, and 2 hours for oxygen, air, fatty organics, oil-based nitrogen, and surfactants are almost recovered as bubbles. In the process, the low molecular weight hydrophilic organics are solvated, and the soluble nitrogen reacted with ozone or oxygen undergoes nitrous acid production.

Nitrified,

Some of the ammonia is produced by nitrite

Nitrified.

In the above process, in order to remove the hydrophilized organic matter and nutrients, it is overflowed to the foam-separable aerobic oxidation tank (7). In treating large volumes of waste and sewage with a conventional activated sludge method, it is practically difficult to maintain the microbial age cycle by appropriately operating conditions such as microorganism holding temperature, BNP proportional value, and excess sludge conveyance, and also organic fatty acids and high protein. Oil-containing nitrogen contained in the ABS, synthetic detergent ABS and the like as a non-chargeable interfacial material rather acts as a toxin load on the microorganism has a problem that can be almost eliminated by the microorganism.

As a countermeasure against this, if the treated water having sufficiently removed the polymer compound in the previous stage flows into the foam-separable aerobic oxidation tank (7), organic nutrients can be infiltrated into the capillary of the microbial infiltrating membrane (19) for a long time, thereby proliferating heterogeneous microorganisms. Nitrogen microorganisms can live together to maintain microbial production and the age of the active cycle.

This microbial cycle must be completed before the next step is nitrification. In addition, the non-decomposable ABS, nitrified nitrate, and ammonium, which remain due to the abandonment of the process, react with oxygen to form bubbles, and they are recovered as much as possible by liquefaction by the bubble breaker 21 of the foam recovery tank 20. Since only the hydrophilic nutrients are filled in the microbial immersion membrane 19 to feed the microorganisms, the maintenance operation such as BNP value, MLSS value, etc. is solved.

Nitrogen microorganism is activated in the foam separation type nitrification tank (7) to sufficiently nitrify ammonia nitrogen, flow into the denitrification tank (5), and the contained nitrate is mixed by the stirring of the organic energy and the stirrer (24). , , When oxygen is dissolved in the water by forming dissolved oxygen-free state, when the nitrifier takes nitric acid as a receptor for respiratory means, oxygen is dissociated and denitrified.

When denitrification is established, the dissociation energy of organic matter is decomposed by gasification by the stirring of the stirrer 24 in the anaerobic degassing tank 6, and the aerobic filamentous microorganism is removed.

In this process, the magnet pump 23 circulates the treated water from the bottom of the tank and strips it. When the treated water passes through the magnet capillaries (+,-), salt, phosphorus, etc. Inorganic materials are magnetized in the same direction as the magnetic field of the magnet. Organic materials such as C, H, and N are magnetized in the opposite direction of the magnetic field. By the ion minerals,

As the molecular structure changes, it softens and dissociates slowly.

As the molecular structure is changed to nitrification or ammonia, they are removed by gasification by stripping.

Since the above efficient denitrification and degassing process requires sufficient microbial activity cycle in the aerobic nitrification tank 7 so that ammonia should be nitrided as a food for microorganisms,

If degassing (9) is not sufficiently removed from the treated nutrients, a means of returning to the previous step of removing the polymer compound (4) or to the foam separation type aerobic nitrification tank (7) can be taken. When treating waste and sewage, the aerobic nitrification tank (7a) is installed in duplicate so that nitrification and dedusting efficiency can be established at the same time by intermittent aeration and mutually returned according to the microbial state of the aerobic nitrification tank (7) (7a) before and after. Allow the salt to be sufficiently removed and overflow into the secondary settling tank (8).

The secondary sedimentation tank (8) is transferred to the filtration tank (9) to filter fine sludge by the coral sand filtration membrane (28), and the filtrate is pumped to the upper part of the ionization tank (13) by a magnet pump (23) for stripping ( Stripping) causes the remaining organic, inorganic, nitrogen, phosphorus, etc. to pass through the magnet's magnetism (+,-). ) Constituent molecules are changed and oxidized or foamed,

The foam is recovered in the foam recovery tank 20 and introduced into the polymer compound vaporization tank 12, and the treated water is discharged from the discharge tank 29.

In the above process, organic matter, nitrogen, and the like have been sufficiently removed, but phosphorus is contained in a large amount in the excess sludge sedimented and separated in the secondary settling tank (8). Surplus sludge is destabilized and difficult to dehydrate, so it enters the centrifugal concentrator (11) and concentrates to 90% or more of water content to undergo a digestion or dehydration process, or adjust the pH to 7 or less with alumina, etc. in the mixing tank (10). The flocculant is line-mixed and solid-liquid separated by the concentrator or dehydrator 25 to remove fine sludge and phosphorus highly, and to prevent the operation load by conveying excess sludge.

In each of the above treatment steps, the foam is recovered to the liquefaction recovery line 31 is introduced into the polymer compound vaporization tank 12 and reacted with air or oxygen or ozone released from the bottom to form bubbles, foam recovery, bubble breakage, liquefaction As the transport proceeds continuously, the polymer gradually becomes low molecular weight, water solubilization, and hydrophilization, and many of them are vaporized by dissociation energy of organic matter. It can be removed by returning it to the next processing step.

The above is only a simple advanced treatment for low concentrations of nutrients in domestic sewage or wastewater. Manure, livestock wastewater, landfill leachate, industrial wastewater, dyeing wastewater, and sewage that combine them with sewage require a separate pigment removal process.

The ozone supplied from the ionization tank 13 into the foam separation ozone oxidation tank 14, transferred to the next tank under each tank, and supplied from the ozone generator 16 is diffused in the ceramic acid pipe 18 '. Ozone bubbles are blocked by the coral sand contact membrane 19 and are destroyed by elevated pressure in the tank to have a strong oxidative power of self-decomposition. SON), nitrogen nitrate , , It is reduced to form bubbles, and these are destroyed by the bubble breaker 21 of the foam recovery tank 20, and are dissolved in the liquid phase into the polymer compound vaporization tank 12 to be removed, and at the same time, the pigment is highly oxidized.

When large amount of ozone is used to remove pigments, pure oxygen is used. Compressed air is introduced under the adsorption tower to adsorb dust, moisture and nitrogen to the adsorbent, and only oxygen is passed to the upper side and stored in the oxygen storage tank. The ozone generator 16 is introduced into the ozone generator 16 to generate ozone having a high concentration.

At this time, do not directly lift the atmospheric ozone to the waste ozone destroyer (17), but pyrolyze the waste ozone in the ozone destroyer (17) after reuse in the polymer compound removal tank (4) or the polymer compound vaporization tank (12) in the pretreatment stage. To destroy.

The dye-oxidized treated water is introduced into the sedimentation filtration tank (15), and the finely divided microsludge is first settled by gravity in the sedimentation tank (27) at the bottom, and the separated water passes through the coral sand filtration membrane (28). While the minerals and fine particles such as iron manganese are adsorbed to the capillary pores of the coral, and the blue water only flows into the discharge tank 29 to discharge.

As described in detail above, in the simple process of the foam separation type polymer compound removal tank, the foam separation type aerobic oxidizing tank, and the foam separation type ozone contact tank in the pretreatment step, a fatty, oil-containing polymer compound, a synthetic detergent ( ABS) can be highly processed at the beginning, and the hydrophilic low molecular nutrients and microorganisms can live together in the capillary of the filler for a long time, so microorganisms can be easily proliferated and nitrided microorganisms can be fixed, making microorganisms easy to maintain and Denitrification, return for degassing, surplus sludge return, long-term digestion and active sludge function can be completed, and advanced processing can be completed, so the initial construction cost is low and the load for surplus sludge transport, BNP proportion, etc. by microbial infiltration means Since there is no change, non-skilled personnel can always produce stable effluent. Effective efficiency can be obtained even with a small amount of air, oxygen or ozone, which is abandoned by the foam recovery means of each group, the demister means of each group and the filling means of microbial invasion, and thus the energy can be reduced by 50% of the power. There is.

Claims (6)

Removing the sediment contaminants contained in the influent from the sediment removal screen and removing the sand deposited in the sedimentation tank with a sedimentation lifter; The step of removing the macromolecular organic matter, oil-containing nitrogen, ABS, etc. contained in the sludge separated sedimentation tank in the first settling tank is recovered by foaming by reacting it with air or oxygen or ozone to make hydrophilic at low concentration and nitrify low molecular nitrogen. , In the first step, the organic material and the heterogeneous microorganisms contained in the liquid phase overflowed in the liquid phase are infiltrated in the capillary pores, so that the microorganisms can be easily multiplied and a microbial age cycle in which nitrification can be activated is established. Nitrifying as a food, and a foam-aerobic aerobic nitrification step in which nitrate, ammonium, residual soluble organic nitrogen, etc., which are not nitrified, are reacted with oxygen or ozone and recovered by foaming; Nitrate contained in the treated water of the step is mixed with organic energy , , To take nitric acid to form an anoxic state while reducing to nitrogen, and to take nitric acid as a respiratory means receptor for nitrifying microorganisms to dissociate and denitrate oxygen; Magnet electron ion ) And degassing the aerobic phase microorganism in the anaerobic state and degassing the decomposition energy of organic matter, Overlapping or returning nitrification, denitrification, and degassing means for the purpose of sufficiently removing nutrients and maintaining a microbial cycle; Sedimenting and separating the treated water from the settling tank and concentrating the excess sludge drawn from the settling tank with a centrifugal concentrator to undergo a digestion tank and a dehydration process; Raising the PH with natural zeolite powder and coal ash, adjusting the pH with alumina sulfate, etc. and reacting the polymer coagulant to solid-liquid separation in the dehydrator to remove suspended sludge, inorganic and phosphorus; Magnet ionization step of foaming and degassing by changing the molecular structure of nutrients contained in the filtered water, An ozone oxidation step in which ionized water flows into the ozone contacting tank, and the remaining soluble organic nitrogen (SON), nitrate, and ammonium react with ozone to recover from foaming, and oxidize and remove the contained pigments and E. coli with ozone; In each step, the foam recovered by foaming is destroyed and recovered in a polymer compound vaporization tank by liquefaction, reacted with oxygen or ozone, oxidized and vaporized by organic energy, and the ozone treated water is passed through a precipitation filtration tank. Advanced waste and sewage treatment by separation method. The method of claim 1; It has a strong oxidative power of self-decomposition by over-aeration of air or oxygen or ozone generated in the step of removing high molecular compound, blocking the straight line of bubbles from filling membranes such as coral sand or filter sari, and destroying bubbles by the internal pressure by blocking. It efficiently reacts with treated water and capillary pores to collect and liquefy fatty organic substances, nitrogenous nitrogen, and synthetic detergent (ABS), which are not biodegradable, to collect and evaporate high molecular compound vaporization tanks, Method of removing foamed polymer compound nitrifying. The method of claim 1; Hydrophilized organics, ammonia nitrogen, and nutrients can be prolonged in the capillary of pores by reacting with air or oxygen or ozone abandoned in the foam separation process, so that heterogeneous microorganisms can easily proliferate and nitrify microorganisms. It maintains the age cycle of microorganisms, nitrifies ammonia as food for microorganisms, and residual soluble organic nitrogen, nitrates, and ammonium, which are not nitrified, react with oxygen, recover with foam, separate from treated water, and block oxygen molecules by nitrates. Form an anoxic state, which causes nitric acid to be taken as a receptor for the respiratory means of nitrifying microorganisms, dissociates and denitrates oxygen. ) And organic, inorganic and nitrogen removal by aerobic microorganisms dissociated by gasification by the decomposition energy of organic matters. The method of claim 1; Under the logistics, it is transferred to the upper part of the next tank. As ozone of the ozone generator is diffused from the ceramic acid pipe, the ozone bubble is blocked by the coral filling film and the bubble is destroyed by the pressure in the tank, so that it has strong oxidative power of self-decomposition. A method for removing E. coli pigment, which is an organic-inorganic nitrogen, which is efficiently recovered from foaming and highly oxidized the pigment by allowing it to react efficiently with residual soluble organic nitrogen (SON), nitrate, and inorganic ammonia, which are difficult to biodegrade using a catalyst of coral threads. The method of claim 1; Polymer compound in the vaporization stage of the polymer compound is contacted with air or oxygen or ozone to react with organic energy to oxidize to increase the bubble formation and dissociate the organic material by continuously circulating the recovery, bubble destruction, and liquefaction transport process in the foam recovery tank. A method of oxidizing a high molecular compound to oxidize and vaporize a high molecular compound by energy. A pretreatment means of a sediment remover for removing the sediment crops contained in raw water and a sediment remover for removing and removing sand deposited in the sedimentation tank; Blocks, destroys and self-decomposes the oxygen or ozone bubbles abandoned by the diffuser to make the oxygen or ozone have strong oxidizing power, and the filling capillary is used as a catalyst to improve the reaction with fatty organics, organic nitrogen, and surfactants. Capillary contact membrane means, The contact membrane removes the foamed polymer compound by allowing ozone (O₃) or oxygen to react efficiently with the compound to activate the foaming, recover in the foam recovery tank, and destroy in the bubble destroyer to separate the treated water by liquefaction. and, Sludge membrane means for allowing organics and nutrients to immerse in the capillary for a long time to facilitate the proliferation of heterogeneous microorganisms and to allow nitrification of microorganisms to live together; Foam separation type aerobic nitrification means for nitrifying ammonia as a food by microorganisms and recovering residual nitrogen, nitrate, etc. with foam and separating the treated water from the treated water; Mixing means of a stirrer which mixes nitrate and organic energy contained in the treated water and takes dissolved oxygen in the process of reducing nitrate to form an anoxic state, Denitrification means for dissociating oxygen as a receptor for the respiration means of nitrifying microorganisms in anoxic state, Mixing means of stirrer for changing the molecular structure by magnetic of magnetic and degassing with anaerobic decomposition energy of organic matter, Concentration means of the suspended activated sludge contained in the excess sludge drawn from the sedimentation tank and the centrifugal concentrator to remove phosphorus, dehydration means of the dehydrator, and ozone of the ozone generator are diffused from the ceramic diffuser, and the bubbles of ozone are filled in the coral Destroyed by the strong ozone Organic acid consisting of a coral contact membrane means that the oxidizing power of) reacts with nitrate, inorganic ammonia, residual soluble organic nitrogen (SON), etc., as a catalyst, and means for recovering by foaming and separating from treated water, Foam separation type ozone oxidation treatment means for highly oxidizing and removing inorganic, nitrogen, E. coli, pigments, etc., Foam separation type polymer compound removal tank, foam separation aerobic nitrification tank, foam separation ozone oxidation tank Bubbles formed in the foam separation ionization tank by means of the foam breaker of each foam recovery tank to recover the liquid by liquefaction to separate the treated water, and Means for oxidizing and vaporizing a high molecular compound, which is oxidized and vaporized by organic dissociation energy of a high molecular compound by continuously circulating bubbles, destruction, liquefaction, and conveyance by oxygen or ozone, and fine particles contained in ozone-treated water. An advanced waste and sewage treatment apparatus, consisting of sediment filtration means that precipitates in a sedimentation tank with primary gravity and passes sewage through a coral filter membrane.