KR100289062B1 - Method for manufacturing electrode plate of lithium secondary battery - Google Patents

Method for manufacturing electrode plate of lithium secondary battery Download PDF

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KR100289062B1
KR100289062B1 KR1019970070312A KR19970070312A KR100289062B1 KR 100289062 B1 KR100289062 B1 KR 100289062B1 KR 1019970070312 A KR1019970070312 A KR 1019970070312A KR 19970070312 A KR19970070312 A KR 19970070312A KR 100289062 B1 KR100289062 B1 KR 100289062B1
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electrode plate
secondary battery
lithium secondary
slurry
film
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KR19990051073A (en
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장기호
장순호
강성구
류광선
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정선종
한국전자통신연구원
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/043—Processes of manufacture in general involving compressing or compaction
    • H01M4/0435—Rolling or calendering
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/661—Metal or alloys, e.g. alloy coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/72—Grids
    • H01M4/74—Meshes or woven material; Expanded metal
    • H01M4/745—Expanded metal
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

PURPOSE: A method is provided to manufacture a reproducible electrode plate having constant thickness and capacity while reducing interfacial resistance, and to increase yields in manufacturing an electrode plate. CONSTITUTION: The method for manufacturing electrode plate of lithium secondary battery comprises the steps of (i) manufacturing a slurry of anode material or cathode material, applying the slurry onto carrier film with defined thickness, and drying the applied film; (ii) separating the dried electrode films from the carrier film; (iii) laminating an expanding metallic foil between the separated electrode films to form an electrode plate; (iv) and bonding the laminated electrode plate to form a lithium secondary battery.

Description

리튬 2차전지의 전극판 제작방법Manufacturing method of electrode plate of lithium secondary battery

본 발명은 리튬 2차전지의 극판 제작 공정 개선에 관한 것으로, 특히 계면 저항을 줄이면서 극판의 두께와 용량이 일정한 재현성있는 극판을 제작하여 전지 제작 시의 수율을 증가 시키는데 그 목적이 있다.The present invention relates to the improvement of the electrode plate manufacturing process of the lithium secondary battery, and particularly to reduce the interfacial resistance while producing a reproducible electrode plate having a constant thickness and capacity of the electrode plate to increase the yield during battery manufacturing.

일반적인 리튬 이온전지 셀은 양극판/분리막/음극판을 포개서 사용하며 리튬 고분자 셀에서는 양극판/전해질막/음극판의 접합으로 구성된다. 이들 세 층으로 이루어진 단위 셀을 감아서 팩 속에 채워 전지를 형성한다. 그러나 이 경우 양극판, 전해질막, 음극판 각각을 제조해야 하며, 또한 이들 각 층을 재현성 있고 항상 용량이 일정하도록 제작하는 공정과 세 층을 모두 접합시켜야 하는 공정상의 어려움도 있다. 리튬 2차전지의 양극판과 음극판의 집전체로는 금속 포일이나 그리드 형의 확장 금속(Expanded metal) 포일을 사용되며 전지의 무게 및 에너지 밀도를 높이기 위하여 확장금속 포일을 사용할 경우 직접 양극과 음극에 슬러리(slurry)를 도포하면 확장 금속의 구멍으로부터 압력을 받기 때문에 균일한 극판을 제작하기에는 어려움이 있다.In general, a lithium ion battery cell is formed by stacking a positive electrode plate / separation membrane / cathode plate, and a lithium polymer cell is composed of a junction of a positive electrode plate / electrolyte membrane / cathode plate. The unit cell consisting of these three layers is wound and filled into a pack to form a battery. In this case, however, each of the positive electrode plate, the electrolyte membrane, and the negative electrode plate has to be manufactured, and there are also difficulties in the process of manufacturing each of these layers to be reproducible and always have a constant capacity, and a process of bonding all three layers. As the current collector of the cathode and anode plates of lithium secondary batteries, metal foils or grid-type expanded metal foils are used, and when expanded metal foils are used to increase the weight and energy density of the battery, slurry is directly added to the positive and negative electrodes. When (slurry) is applied, it is difficult to produce a uniform electrode plate because pressure is applied from the holes of the expanded metal.

이와같이 기존의 전지 전극 제작 공정에서는 금속 포일이나 기공이 50% 이상이 되는 그리드형 확장금속 집전체 위에 양극 또는 음극 슬러리를 직접 도포하고 건조하여 양극 또는 음전극 판을 제작한다.As described above, in the conventional battery electrode manufacturing process, a positive electrode or a negative electrode slurry is directly applied and dried on a grid-type expanded metal current collector having a metal foil or pores of 50% or more to manufacture a positive or negative electrode plate.

그러나 그리드형 확장 금속에 슬러리를 직접 도포할 경우 슬러리가 확장금속 위를 밀려가면서 확장금속의 기공으로부터 압력이 형성되어 기공 속으로 슬러리가 충분히 함침되지 못하고 건조시킬 경우 요철이 형성된다. 이는 충분히 함침된 경우와 함침되지 않은 부분에 슬러리 양이 일정하지 않고 따라서 극판의 두께를 일정하게 제작할 수 없는 원인이 된다.However, when the slurry is directly applied to the grid-type expanded metal, as the slurry is pushed on the expanded metal, pressure is formed from the pores of the expanded metal, and when the slurry is not sufficiently impregnated into the pores, irregularities are formed. This causes a case where the amount of slurry is not constant in the case where it is sufficiently impregnated and the part which is not impregnated, and thus the thickness of the electrode plate cannot be made constant.

본 발명은 상기한 문제점을 해결하기 위한 것으로, 리튬 고분자 2차전지의 극판 제작 공정에 있어서, 특히 계면 저항을 줄이면서 극판의 두께와 용량이 일정한 재현성있는 극판을 제작시켜 극판 제작 시의 수율을 증가 시키기 위한 것이다.The present invention is to solve the above problems, in the manufacturing process of the electrode plate of the lithium polymer secondary battery, in particular, while reducing the interfacial resistance to produce a reproducible electrode plate with a constant thickness and capacity of the electrode plate to increase the yield during production of the electrode plate It is to let.

본 발명에서 제안한 제작 공정은 기존의 극판 제작 공정 중 집전체 위에 극막을 직접 제작하여 극판 수율을 일정하게 조절할 수 없는 공정을 피하고 극막/집전체/극막을 접합함으로써 항상 두께 및 용량이 일정하고 재현성있는 극판을 제작할 수 있어 전지 제작 시 수율 향상을 도모할 수 있고 또한 전지의 용량 감소와 수명 단축의 단점을 개선시킬 수 있다.The fabrication process proposed by the present invention avoids the process of uniformly controlling the yield of the electrode plate by directly manufacturing the electrode film on the current collector of the existing electrode plate manufacturing process, and the thickness and capacity of the electrode plate are always constant and reproducible by joining the electrode film. It is possible to manufacture the electrode plate to improve the yield in battery production, and also to improve the shortcomings of battery capacity reduction and shortening of life.

도 1은 본 발명에 의한 리튬 폴리머 2차전지 극판에 대한 모식도.1 is a schematic diagram of a lithium polymer secondary battery electrode plate according to the present invention.

도 2는 리튬 2차전지의 극판 제작 공정을 위한 대한 모식도.Figure 2 is a schematic diagram for the electrode plate manufacturing process of the lithium secondary battery.

＜도면의 주요부분에 대한 부호의 설명＞<Description of the code | symbol about the principal part of drawing>

1 : 집전체 (그리드형 금속 포일) 2 : 양극 또는 음극 자유지지 막1: current collector (grid type metal foil) 2: positive or negative electrode free supporting membrane

3 : 이형막(운송 막) 4 : 풀기 롤3: Release film (transport film) 4: Release roll

5 : 감기 롤 6 : 접합 롤(laminator)5: Winding Roll 6: Laminator

이하, 본 발명의 실시예를 상세히 설명하면 다음과 같다.Hereinafter, an embodiment of the present invention will be described in detail.

도 1은 본 발명에 의한 양전극판과 음전극판을 접합하는 공정을 설명하기 위한 도면으로서, 이에 도시된 바와같이, 우선 슬러리를 제조하고 도포기를 이용하여 이형막 위에 슬러리를 일정한 두께로 도포하고 건조 시킨다. 여기서 이형막은 상기 슬러리에 의해 제조되는 자유지지막을 지지하기 위한 운송막으로서 전극막 접합시에 이형막에서 자유지지막을 분리시켜 전극막을 접합시킨다.1 is a view for explaining the process of bonding the positive electrode plate and the negative electrode plate according to the present invention, as shown in the first, to prepare a slurry, using a coater to apply the slurry to a release film to a certain thickness and dried. . Here, the release film is a transport film for supporting the free support film produced by the slurry, and when the electrode film is bonded, the free support film is separated from the release film to bond the electrode film.

이 과정은 오디오나 비디오 테이프의 자성체 도포와 같은 방식이다. 이렇게 이형 막 위에 슬러리를 도포시켜 2개의 롤로 제작한 후, 가운데에 집전체(1)를 두고 그 집전체(1)의 양면에 이형 막에서 분리된 자유지지 극막(2)을 열에 의하여 접합 시키면 일정한 두께의 극판을 형성한다.This process is the same as the magnetic application of audio or video tape. In this way, the slurry is applied onto the release film to make two rolls, and then the current collector 1 is placed in the center, and the free supporting electrode membrane 2 separated from the release film is bonded to both surfaces of the current collector 1 by heat. Form a plate of thickness.

도 2는 본 발명에 의한 전극판 제조 공정을 설명하기 위한 계통도로서, 전극용 슬러리를 이형막(3) 위에 일정하게 도포시켜 자유지지막(2)을 형성하고, 이를 롤(4)로 구성하며, 아울러 집전체(1)도 롤(4)로 구성한다. 그리고, 상기 이형막(3)위에 자유지지막(2)이 형성된 롤에서 이형막(3)과 자유지지막(2)을 분리시켜 이형막(3)은 뒷쪽의 감기롤(5)로 감고, 두개의 자유지지막(2)과 집전체(1)는, 집전체(1)를 사이에 두고 상하면에 자유지지막(2)이 접합되도록 접합롤(6)에 공급된다. 접합롤(6)에서는 열에의해 집전체(1)의 상하면에 자유지지막(2)을 열압착시켜 부착하고, 그 부착된 전극판을 감기롤(5)에서 감아서 전극판을 제조하게 된다.FIG. 2 is a schematic diagram illustrating an electrode plate manufacturing process according to the present invention, in which a slurry for electrodes is uniformly coated on a release film 3 to form a free support film 2, which is constituted by a roll 4. In addition, the current collector 1 is also constituted by a roll 4. Then, the release membrane 3 and the free support membrane 2 are separated from the roll on which the free support membrane 2 is formed on the release membrane 3, and the release membrane 3 is wound by a winding roll 5 on the rear side. The two free supporting films 2 and the current collector 1 are supplied to the bonding roll 6 so that the free supporting films 2 are joined to the upper and lower surfaces with the current collector 1 interposed therebetween. In the bonding roll 6, the free supporting film 2 is thermally compressed on the upper and lower surfaces of the current collector 1 by heat, and the attached electrode plate is wound on the winding roll 5 to produce an electrode plate.

이때, 자유지지막을 구성하는 슬러리에는 고분자가 함유되어 있어 열에 의한 접합 시 고분자가 유연하게 되고 양쪽에 있는 극막 간의 계면이 없는 완전 단일막으로 접합된다. 도 1에는 접합전과 후의 전극 구조를 도식적으로 보여주고 있다.At this time, the slurry constituting the free support membrane contains a polymer, so that the polymer becomes flexible during thermal bonding and is bonded as a complete single membrane without an interface between the polar membranes on both sides. 1 schematically shows the electrode structure before and after bonding.

상기의 제작 공정은 기존의 극판 제작 공정 중 집전체 위에 극막을 직접 제작하여 극판 수율을 일정하게 조절할 수 없는 공정을 피하고 극막/집전체/극막을 접합함으로써 항상 두께 및 용량이 일정하고 재현성있는 극판을 제작할 수 있어 전지 제작 시 수율 향상을 도모할 수 있고 또한 전지 용량의 감소와 수명의 단축의 단점을 개선시킬 수 있다.In the above manufacturing process, the electrode plate is manufactured directly on the current collector during the existing electrode plate manufacturing process, and the electrode plate / current collector / electrode film is bonded to avoid the process of uniformly controlling the yield of the plate. It is possible to improve the yield in battery production, and also to improve the disadvantages of reduced battery capacity and shortened life.

일반적인 리튬 2차전지 셀의 구조는 양극/전해질/음극으로 구성되며 특히 고분자 2차전지의 경우는 양극/전해질/음극의 접합으로 구성된다. 본 발명에서 제작한 극판 제작 공정은 도포 공정과 접합 공정으로 구성되기 때문에 기존의 접합 공정을 그대로 이용할 수 있으며 기존의 극판 제작 공정 중 집전체 위에 극막을 직접 제작함으로써 극판 수율을 일정하게 조절할 수 없는 공정상의 문제점을 피하고 극막/집전체/극막을 접합함으로써 항상 두께 및 용량이 일정하고 재현성있는 극판을 제작할 수 있어 전지 제작 시 수율 향상을 도모할 수 있고 또한 전지 용량의 감소와 수명의 단축의 단점을 개선시킬 수 있다.The structure of a general lithium secondary battery cell is composed of a positive electrode / electrolyte / negative electrode, in particular, a polymer secondary battery is composed of a junction of a positive electrode / electrolyte / negative electrode. Since the electrode plate manufacturing process manufactured in the present invention is composed of a coating process and a bonding process, the existing bonding process can be used as it is, and the process of producing the electrode film directly on the current collector during the existing electrode plate manufacturing process cannot control the yield of the electrode plate constantly. By avoiding the problem on top and joining the membrane, current collector, and membrane, it is possible to manufacture the electrode plate with constant thickness and capacity and reproducibility, so that the yield can be improved when manufacturing the battery, and the disadvantage of reduction of battery capacity and shortening of the life can be improved. You can.

Claims (2)

양극물질 내지 음극물질의 슬러리를 제작한 후 운송막위에 일정한 두께로 슬러리를 도포하여 건조하는 전극막 형성단계;An electrode film forming step of preparing a slurry of a cathode material to a cathode material and then applying a slurry to a predetermined thickness on a transport film to dry the slurry; 상기 운송막으로부터 건조된 상기 전극막을 분리하는 분리단계;A separation step of separating the dried electrode film from the transport film; 상기 분리된 전극막들사이에 확장금속호일이 배치되도록 적층하여 전극판을 형성하는 전극판 형성단계; 및An electrode plate forming step of forming an electrode plate by stacking the expanded metal foils between the separated electrode films; And 상기 적층된 전극판을 접합하여 리틈 2차 전지전극판을 제작하는 전극판 제작단계를 포함함을 특징으로 하는 리튬 2차 전지의 전극판 제작 방법.The electrode plate manufacturing method of the lithium secondary battery comprising the electrode plate manufacturing step of bonding the laminated electrode plate to produce a gap secondary battery electrode plate. 상기 운송막으로는 화학적인처리에 의해 접착력이 조절된 이형필름을 사용함을 특징으로 하는 리튬 2차 전지의 전극판 제작 방법.Method for producing an electrode plate of a lithium secondary battery, characterized in that for use as a transport film, a release film whose adhesion is controlled by chemical treatment. 제 1 항에 있어서, 상기 리튬 2차전지의 전극판 제작 방법은,According to claim 1, The electrode plate manufacturing method of the lithium secondary battery, 상기 이형막 위에 슬러리를 도포하여 건조시킨 후 이를 2개의 롤로 제작하고, 집전체 금속을 롤로 제작하며, 상기 2개의 롤 사이에 상기 집전체 금속 롤을 배치하며 상기 2개의 롤에서 이형막과 자유지지막을 분리시켜 2개의 자유지지막 사이에 집전체 금속이 배치되게 하여 접합롤에 공급하여 그 접합롤레서 열과 압력을 이용하여 열압착시키는 것을 특징으로 하는 리튬 2차전지의 전극판 제작 방법.Applying the slurry on the release film and drying it, it is made into two rolls, the current collector metal is made into rolls, the current collector metal roll is disposed between the two rolls, and the release film and free support on the two rolls. A method of manufacturing an electrode plate for a lithium secondary battery, characterized in that the membrane is separated and a current collector metal is disposed between two free supporting membranes, and supplied to a bonding roll and thermocompression bonding using the bonding roller heat and pressure.
KR1019970070312A 1997-12-19 1997-12-19 Method for manufacturing electrode plate of lithium secondary battery KR100289062B1 (en)

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