KR100269091B1 - Leaflet containing inorganic adsorbent - Google Patents

Leaflet containing inorganic adsorbent Download PDF

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Publication number
KR100269091B1
KR100269091B1 KR1019980028620A KR19980028620A KR100269091B1 KR 100269091 B1 KR100269091 B1 KR 100269091B1 KR 1019980028620 A KR1019980028620 A KR 1019980028620A KR 19980028620 A KR19980028620 A KR 19980028620A KR 100269091 B1 KR100269091 B1 KR 100269091B1
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South Korea
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inorganic adsorbent
tobacco
leaf
mixed
inorganic
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KR1019980028620A
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Korean (ko)
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KR19980072035A (en
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양광규
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양광규
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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24CMACHINES FOR MAKING CIGARS OR CIGARETTES
    • A24C5/00Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
    • A24C5/14Machines of the continuous-rod type
    • A24C5/20Reels; Supports for bobbins; Other accessories
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/10Chemical features of tobacco products or tobacco substitutes
    • A24B15/12Chemical features of tobacco products or tobacco substitutes of reconstituted tobacco

Abstract

PURPOSE: A tabular leaf including an inorganic adsorbent is provided to improve the taste of a tobacco by adding the inorganic adsorbent for removing the harmful gas or the nasty smell in manufacturing the tabular leaf and to improve the health of a smoker. CONSTITUTION: The tabular leaf including the inorganic adsorbent includes zeolite, sepiolite, silica gel, active white clay and red feldspar granite as the inorganic adsorbent. In the paper type tabular leaf, the inorganic adsorbent is pulverized with the 300 mesh size after drying it in the sun or by the wind and is mixed with 5-30 % of the tabular leaf raw materials. The material as the tobacco extract and the pulverized inorganic adsorbent are mixed and are applied on the tabula and are molded and dried. In the rolled tabular leaf, the pulverized inorganic adsorbent is evenly mixed with pulp, lubricant and adhesive.

Description

무기흡착제를 함유하는 판상엽Leaflet containing inorganic adsorbent

본 발명은 무기흡착제를 함유하는 판상엽에 관한 것이다. 좀더 상세하게는 담배를 피울 때에 유해가스나 이취를 제거할 수 있는 무기흡착제를 판상엽의 제조시에 첨가함으로써 담배 맛을 향상시키고 흡연자의 건강에도 기여할 수 있도록 한 판상엽에 관한 것이다.The present invention relates to a leaflet containing an inorganic adsorbent. More specifically, the present invention relates to a platelet leaf which improves the taste of tobacco and contributes to the health of smokers by adding an inorganic adsorbent that removes harmful gases and odors when smoking the platelet.

통상 담배제조회사에서는 담배제조과정에서 생출하는 니분, 설엽, 중골, 대공 등을 파쇄하여 분말로 만들어서 접착제, 보습제 내지는 각종 첨가제를 첨간한 후, 판상엽으로 만들어서 담배 제조시에 배합원료 또는 결속엽으로 사용하고 있다. 통상의 판상엽 제조방법은 그 공정에 따라 2가지로 분류되는데, 하나는 담배잎 줄기나 부스러기, 담배가루 등을 소수성 접착제, 보습제 등과 배합하여 2개의 롤러 사이에서 압연하여 쉬트상으로 제조하는 압연식(특허공고 제 95-5397호)과 다른 하나는 담배잎 줄기나 부스러기, 담배가루 등을 고해, 초지하고 기타 다른 부재료를 배합하여 쉬트상으로 제조하는 제지식(특허공고 제 95-5398호) 판상엽 제조방법이 있다. 그런데 제지식으로 제조한 판상엽에서는 담배를 피울 때에 이 제품의 단점인 섬유취(종이 타는 냄새)와 기타 유해가스를 발생시키고, 압연식 판상엽에서는 판상엽 제조에 사용한 접착제 및 첨가물이 열분해되어 건강에 해로운 공해물질과 기타 유해가스를 발생시킨다. 즉, 제지식 판상엽은 섬유가 많은 주맥과 성형보강제로 펄프를 5∼10% 넣어 고해해서 종이 제조방법과 같은 방법으로 제조하기 때문에 연소할 때에 어쩔 수 없이 섬유취를 동반하게 되는 것이고, 또 압연식 판상엽은 담배 주맥을 3∼8㎝로 절단후 120±10℃에서 1∼3분간 배소처리하여 자극성과 쓴맛을 제거하고 5∼10%의 펄프를 배합한 다음, 분쇄하고 여기에 니분, 보습제, 접착제, 향료를 넣은 수용액을 배합하고 압연 성형하게 되는데, 이때 결합제로 사용하는 접착제는 연소시에 열분해되어 건강 유해물질을 배출하게 된다. 이와같이 섬유취, 접착제의 열분해물질 및 담배연소시 발생하는 유해가스가 주류연(입속으로 들어오는 연기) 속에 섞이게 되므로 이를 제거하기 위하여 담배 산업분야에서는 필터속에 활성탄 및 무기흡착제를 넣어 타르 및 니코친과 이들 유해가스들도 함께 흡착 제거하도록 하고 있다. 이와 같이 주류연 속의 유해가스는 담배 끝에 부착된 흡착필터에 의해 어느정도 제거되지만 부류연(권련이 탈 때 외부로 방출되는 연기) 속에 이행되는 유해가스는 포집할 수 없고, 주위 사람에게 더 많은 간접흡연의 위해를 줄 수가 있다. 또 주류연속에서도 섬유취 등은 그대로 감지되는등 문제점이 있다.In general, a tobacco manufacturing company crushes the nibs, snow leafs, middle bones, and large holes produced during the tobacco manufacturing process to make powder, adds adhesives, moisturizers, or various additives, and then makes them into platelets to form a blended raw material or binding leaf. I'm using it. Conventional platelet manufacturing method is classified into two types according to the process, one is a rolling type that is rolled between two rollers by combining tobacco leaf stem, debris, tobacco powder, etc. with hydrophobic adhesive, moisturizer, etc. (Patent Publication No. 95-5397) and the other one are papermaking formulas (Patent Publication No. 95-5398) produced by crushing tobacco leaf stems, debris, tobacco powder, etc., making paper sheets, and blending other subsidiary materials. There is a method for producing upper leaves. However, in case of smoking tobacco, the leaflets produced with paper produce fiber odors (burning odor) and other harmful gases, which are disadvantages of this product.In the rolled leaflets, the adhesives and additives used for the production of leaflets are thermally decomposed. Generates harmful pollutants and other harmful gases. In other words, the paper-cut plate leaf is made by the same method as the paper manufacturing method by beating 5 to 10% of the pulp with a fiber-inflated liquor and molding reinforcement, so that it is inevitably accompanied with a fiber odor when burning. The platelets were cut to 3-8cm of tobacco stems and roasted for 1 to 3 minutes at 120 ± 10 ℃ to remove irritation and bitter taste, and 5 ~ 10% of pulp was mixed. In addition, the adhesive and flavored aqueous solution is blended and rolled, wherein the adhesive used as a binder is thermally decomposed at the time of combustion to release the harmful substances of health. As such, the odorous gases generated during the combustion of the fiber, adhesive pyrolysis and tobacco are mixed in the mainstream smoke (smoke entering the mouth) .In order to remove this, in the tobacco industry, activated carbon and inorganic adsorbents are put in the filter to remove tar and nicotine and these harmful gases. Are also adsorbed and removed. As such, the harmful gas in the mainstream smoke is somewhat removed by the adsorption filter attached to the end of the cigarette, but the harmful gas carried in the side smoke (smoke emitted to the outside when the cigarette is burned) cannot be collected, and the surrounding people may have more indirect smoking. Can be given. In addition, there is a problem in that even in the mainstream continuous fiber odor is detected as is.

본 발명은 상기와 같은 문제점을 해소하기 위해 안출된 것으로서, 담배를 피울 때에 유해가스나 이취를 제거할 수 있는 무기흡착제를 판상엽의 제조시에 첨가함으로써 담배 맛을 향상시키고 흡연자의 건강에도 기여할 수 있도록 한 판상엽을 제공한다. 판상엽을 제조할 때에 바이오 세라믹 계통의 흡착제를 첨가하여 권련을 제조하게 되면, 권련이 연소되면서 제올라이트 활성화온도인 300℃부근에서 세피오라이트는 700℃부근에서 활성화 되어 주류연과 부류연속의 유해까스를 흡착하게 되고, 이때 무기흡착제가 가지고 있던 수분은 방출되어 담배맛을 순하게 하는 등의 작용을 한다.The present invention has been made to solve the above problems, by adding an inorganic adsorbent that can remove harmful gases or odor when smoking cigarettes in the production of platelets can improve tobacco taste and contribute to the health of smokers Provide one leaflet to help. When manufacturing platelets by adding bio-ceramic adsorbents to manufacture the sheet, when the sheet is burned, the zeolite is activated at around 300 ° C, which is the zeolite activation temperature, and is activated at around 700 ° C to adsorb the harmful cutlets of the mainstream smoke and the sidestream. At this time, the moisture adsorbed by the inorganic adsorbent is released to act as a mild tobacco taste.

본 발명의 목적은 흡연시 섬유취와 각종 유해가스를 흡착 제거할 수 있는 판상엽을 제공하는데 그 목적이 있다.An object of the present invention is to provide a platelet that can adsorb and remove fiber odor and various harmful gases during smoking.

본 발명의 또 하나의 목적은 담배맛을 순화시킬 수 있는 판상엽을 제공하는데 그 목적이 있다.Another object of the present invention is to provide a platelet that can purify the taste of tobacco.

본 발명은 담배잎줄기, 담배잎 부스러기, 담배 가루 등의 담배니분과 펄프를 원료(이하 "판상엽 원료"라 함)로 하여 통상의 방법으로 판상엽을 제조할 때에 무기흡착제를 단독 또는 1개 이상 혼합하여 제조하는 것으로 구성된다. 본 발명에 사용하는 무기흡착제로는 제올라이트(Zeolite), 세피오라이트(Sepiolite), 실리카겔(Silicagel), 활성백토, 맥반석 등의 무기흡착제가 사용되는데, 바람직하기로는 제올라이트와 세피오라이트가 좋다. 이들 무기흡착제는 1종 또는 2종 이상을 혼합하여 사용할 수 있으며, 2종 이상을 혼합하여 사용할 경우는 엽배합 성질에 따라 적당한 중량비로 배합하여 양건 또는 풍건한 후, 300메쉬 이하(300메쉬체 통과)로 분쇄하여 사용한다. 무기흡착제의 크기가 300메쉬 이상이면, 제지식의 경우 노즐이 막힐 염려가 있고 균일 도포가 안되는 결점이 있다. 무기흡착제의 배합비율은 상기 판상엽 원료의 5∼30%를 사용한다. 제지식 판상엽에서는 담배추출물 등 다른 원료와 분쇄된 무기흡착제를 함께 잘 혼합하여 판상으로 초지후에 도포 성형하여 건조하거나 펄프 투입시 무기흡착제를 함께 넣어 성형토록한다. 압연식 판상엽에서는 분쇄된 무기흡착제를 펄프 투입시 또는 니분, 보습제, 접착제 배합시 함께 넣어 균일하게 배합하고 압착성형한다.In the present invention, an inorganic adsorbent alone or one inorganic sorbent is used to prepare a leaflet using a conventional method using tobacco leaf powder and pulp such as tobacco leaf stem, tobacco leaf debris, and tobacco powder as raw materials (hereinafter referred to as "leaflet raw material"). It consists of mixing and manufacturing above. As the inorganic adsorbent used in the present invention, inorganic adsorbents such as zeolite, sepiolite, silica gel, activated clay and elvan are used. Preferably, zeolite and sepiolite are used. These inorganic adsorbents may be used alone or in combination of two or more thereof, and in the case of mixing two or more thereof, they may be formulated in an appropriate weight ratio depending on the foliar composition properties, and then dried or air dried, and then 300 mesh or less (300 mesh sieve passes). Grind to use. If the size of the inorganic adsorbent is 300 mesh or more, there is a concern that the nozzle may be clogged in the case of the papermaking type, and there is a drawback that uniform coating is not possible. The mixing ratio of the inorganic adsorbent is 5 to 30% of the above-mentioned leaflet raw material. In papermaking platelets, other raw materials such as tobacco extracts and ground inorganic adsorbents are mixed well together, and then coated and molded after papermaking into a sheet, or when the pulp is added, the inorganic adsorbents are put together for molding. In the rolled leaflets, the pulverized inorganic adsorbent is put together at the time of pulp input or when the powder, moisturizer and adhesive are mixed, and then uniformly mixed and pressed.

이하 본 발명을 실시예 및 실험예에 따라 상세히 설명한다. 본 실시예 등에서 사용하는 %는 특별한 지시가 없는한 중량%를 나타낸다.Hereinafter, the present invention will be described in detail according to Examples and Experimental Examples. % Used in the present Example etc. shows weight% unless there is particular notice.

[실시예 1]Example 1

황색종 입줄기 5㎏과 버어리종 입줄기 5㎏을 혼합하여 3㎝ 길이로 세절한후, 0.8㎏의 펄프와 혼합한다. 이 혼합물에 담배잎 부스러기 1.2㎏, 담배가루 1.3㎏을 첨가 혼합하고 항온항습조에서 수분이 균일하도록 조화시킨 후에 150메쉬 크기로 분쇄한다. 다음 양건하여 300메쉬 이하로 분쇄한 제올라이트 1.0㎏과 세피오라이트 3.0㎏ 및 글리세린 0.2㎏, 구아닌껌 0.15㎏, 소디움 카복시메틸셀루로즈 0.15㎏을 배합하고 로울러로 압연하여 쉬이트로 제조한다.5 kg of yellow species and 5 kg of Burley species are mixed, cut into 3 cm lengths, and mixed with 0.8 kg of pulp. 1.2 kg of tobacco leaf crumbs and 1.3 kg of tobacco powder are added to the mixture and mixed, and the mixture is pulverized to 150 mesh in a constant temperature and humidity chamber. Next, 1.0 kg of zeolite pulverized to 300 mesh or less, 3.0 kg of sepiolite, 0.2 kg of glycerin, 0.15 kg of guanine gum, and 0.15 kg of sodium carboxymethylcellulose were combined and rolled with a roller to prepare a sheet.

[실시예 2]Example 2

황색종 입줄기 4㎏과 버어리종 입줄기 3㎏을 혼합하여 3㎝ 길이로 세절한후, 0.8㎏의 펄프와 혼합한다. 이 혼합물에 담배잎 부스러기 1.2㎏, 담배가루 1.3㎏을 혼합하여 디플레이크 기계에 넣어 담배섬유관속을 분리하고 추출기에서 추출하여 수불용성 성분을 분리한 다음, 수불용성 물질을 바우어식 이중 리파이너에 넣어 작은 섬유관속을 피브릴화하고 증해하여 초지를 만든 후, 상기 담배추출물에는 300메쉬 이하로 분쇄한 세피오라이트 3㎏과 글리세린 0.2㎏, 과당 0.2㎏을 넣어 잘 혼합하고 상기 초지에 도포하여 판상엽을 제조하였다.4 kg of yellow species and 3 kg of Burley species are mixed, cut into 3 cm lengths, and mixed with 0.8 kg of pulp. To this mixture, 1.2 kg of tobacco leaf crumbs and 1.3 kg of tobacco powder are mixed and placed in a de-flake machine to separate the tobacco fiber tube, and extracted from the extractor to separate the water-insoluble component, and then the water-insoluble substance is added to a small double refiner. After fibrillating the fiber tube and cooking to make paper, the tobacco extract was mixed with 3 kg of sepiolite, 0.2 kg of glycerin and 0.2 kg of fructose, which was ground to 300 mesh or less, mixed well and coated on the paper to prepare a leaflet. .

[시험예 1][Test Example 1]

미국형 권련 배합의 한 예에 따라, 황색종 35%, 버어리종 22%, 메릴랜드엽 2%, 오리엔트엽 11%, 주맥 7%, 실시예 1의 판상엽 23%를 배합하고, 0.9㎜로 절각한 후, 통상의 담배향료를 가향하고 숙성하여 권련담배를 제조하였다. 담배 제조기는 하우니 소형권상기(Hauni pilot maker)를 사용하여 킹사이즈로 제조하였다. 제조된 권련은 원주가 24.5㎜, 길이가 84㎜, 전충량목은 752㎎/cig. 이었다.According to one example of the American type of citrus blend, 35% of yellow species, 22% of Burley species, 2% of Maryland leaves, 11% of Orient leaves, 7% of jug and 23% of the leaflets of Example 1, and 0.9 mm After cutting, the cigarette was flavored and aged to prepare a tobacco cigarette. Tobacco makers were made king size using a Hauni pilot maker. The produced citrus was 24.5 mm in circumference, 84 mm in length, and 752 mg / cig in total weight. It was.

[시험예 2][Test Example 2]

실시예 1의 판상엽 대신에 실시예 2의 판상엽을 사용하는 외에는 시험예 1과 동일한 방법으로 담배를 제조하였다. 제조된 권련은 원주가 24.3㎜, 길이가 84㎜, 전충량목은 750㎎/cig. 이었다.Cigarettes were prepared in the same manner as in Test Example 1, except that the platelets of Example 2 were used instead of the platelets of Example 1. The produced citrus was 24.3 mm in circumference, 84 mm in length, and 750 mg / cig in total weight. It was.

[비교예 1]Comparative Example 1

상기 실시예 1의 판상엽 대신에 무기흡착제가 첨가되지 아니한 종래의 판상엽을 배합하는 외에는 시험예 1의 방법과 동일한 방법으로 담배를 제조하였다.Cigarettes were manufactured in the same manner as in Test Example 1, except that the conventional platelets having no inorganic adsorbent were added instead of the platelets of Example 1.

위와 같이 제조한 담배에 대해 패널원 10명을 대상으로 그 맛과 이취미 유무를 테스트하고 결과를 표 1에 기재하였다.The tobacco manufactured as described above was tested for the taste and taste of 10 panel members 10 and the results are shown in Table 1.

구 분division 시험예 1Test Example 1 시험예 2Test Example 2 비교예 1Comparative Example 1 비 고Remarks 양호인원수Number of healthy people 44 55 1One 담배맛 비교Tobacco flavor comparison 이취미Hobby radish radish U 섬유취 등Textile odor

상기 표 1의 기재로 알 수 있는 바와 같이, 본 발명 판상엽을 배합한 담배는 섬유취나 기타 이취미를 전혀 느낄 수 없었는데 비해 종래 판상엽을 배합한 비교예 1 제품은 이취미가 있었고, 담배맛에 있어서도 본 발명 판상엽을 배합한 담배가 훨씬 우수하게 평가 되었음을 알 수 있다. 판상엽을 제조할 때에 바이오 세라믹 계통의 흡착제를 첨가하여 권련을 제조하면 담배맛을 순화시킴은 물론, 더 나아가서 이들 무기흡착제가 담배 피울 때에 연소 과정에서 활성화 되어 섬유취, 접착제 열분해물질 및 유해가스 등을 흡착 제거하게 되고, 자신이 갖고 있던 수분을 방출하면서 담배맛도 순하게 하는 등 일석이조의 효과가 있다.As can be seen from the description of Table 1, the tobacco containing the leaflet of the present invention was not able to feel fiber odor or other odors at all, whereas the comparative example 1 product containing the conventional leaflet had odor and tobacco taste In addition, it can be seen that the tobacco compounded with the leaflets of the present invention was evaluated much better. When manufacturing leaflets by adding bio-ceramic adsorbents to produce platelets, the tobacco taste is not only purified, but furthermore, these inorganic adsorbents are activated in the combustion process when smoked, resulting in fiber odors, adhesive pyrolysis substances and harmful gases. It absorbs and removes water, and releases its own water while making the tobacco taste milder.

Claims (2)

담배잎줄기 분말, 담배잎 부스러기, 담배 가루 등의 담배니분과 펄프를 원료로 하여 판상엽을 제조함에 있어서, 제올라이트, 세피오라이트, 실리카겔, 활성백토, 맥반석중에서 선택된 1종 또는 2종 이상의 무기흡착제 분말을 판상엽 원료 총중량의 5∼30%를 배합하여 제조하여서 됨을 특징으로 하는 판상엽.To prepare leaflets using tobacco powder and tobacco pulp such as tobacco leaf stem powder, tobacco leaf debris and tobacco powder, one or two or more inorganic adsorbent powders selected from zeolite, sepiolite, silica gel, activated clay and elvan A platelet leaf, characterized in that it is prepared by mixing 5 to 30% of the total weight of the platelet leaf material. 제 1 항에 있어서, 상기 무기흡착제는 제올라이트 또는 세피오라이트중에서 선택된 1종 또는 2종 이상의 무기흡착제로서, 그 크기가 300메쉬 이하임을 특징으로 하는 판상엽.The platelet of claim 1, wherein the inorganic adsorbent is one or two or more inorganic adsorbents selected from zeolites and sepiolites and has a size of 300 mesh or less.
KR1019980028620A 1998-07-15 1998-07-15 Leaflet containing inorganic adsorbent KR100269091B1 (en)

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KR20030095913A (en) * 2002-06-15 2003-12-24 (주)하이엔텍 A catalyst for removing injuriousness matterial in cigarette smoke and the catalyst

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KR20010074561A (en) * 2001-05-04 2001-08-04 전창호 Tobacco composition and preparation method thereof
KR102386078B1 (en) * 2020-03-13 2022-04-12 주식회사 케이티앤지 Reconstituted tobacco sheet comprising clove by-products and a smoking article including the same
KR20230103038A (en) * 2021-12-31 2023-07-07 주식회사 케이티앤지 A smoking article comprising reconstituted tobacco sheet comprising calcium carbonate

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030095913A (en) * 2002-06-15 2003-12-24 (주)하이엔텍 A catalyst for removing injuriousness matterial in cigarette smoke and the catalyst

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