KR100248118B1 - Method of producing tone cloth - Google Patents

Method of producing tone cloth Download PDF

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Publication number
KR100248118B1
KR100248118B1 KR1019930031513A KR930031513A KR100248118B1 KR 100248118 B1 KR100248118 B1 KR 100248118B1 KR 1019930031513 A KR1019930031513 A KR 1019930031513A KR 930031513 A KR930031513 A KR 930031513A KR 100248118 B1 KR100248118 B1 KR 100248118B1
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South Korea
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fabric
alkali
reducing agent
present
processing machine
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KR1019930031513A
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Korean (ko)
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KR950018806A (en
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김익수
최태수
전광수
공종배
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조민호
에스케이케미칼주식회사
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B9/00Solvent-treatment of textile materials
    • D06B9/02Solvent-treatment of textile materials solvent-dyeing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0096Multicolour dyeing

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

본 발명은 점도가 30 센티포아즈 이하인 환원제 또는 알칼리를 다색성 직물가공기를 이용하여 직물에 균일하게 분포시키는 것을 특징으로 하는 톤을 가지는 직물의 제조방법으로서,The present invention provides a method for producing a fabric having a tone, characterized in that the viscosity or 30 centipoise or less reducing agent or alkali uniformly distributed in the fabric using a multi-color fabric processing machine,

본 발명에 의하면 후처리에 의한 폐수 발생이 적고, 독특한 질감의 직물을 제조할 수 있다.According to the present invention, it is possible to produce a fabric having a unique texture with less generation of wastewater by post-treatment.

Description

톤을 가지는 직물의 제조방법Manufacturing method of fabric having a tone

첨부된 도면은 본 발명에서 사용한 다색성 직물가공기The attached drawings are multi-color fabric processing machine used in the present invention

* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

1 : 브러쉬 2 : 슬릿1: brush 2: slit

3 : 모터 4 : 액량제어기3: motor 4: liquid level controller

5 : 조액자동펌핑장치 6,6' : 조액5: Automatic liquid pumping device 6,6 ': Liquid solution

7,7' : 슬릿폭조절장치 F : 직물7,7 ': slit width adjusting device F: fabric

본 발명은 톤을 가지는 직물의 제조방법에 관한 것이다.The present invention relates to a method for producing a fabric having a tone.

더욱 상세하게는 다색성 직물가공기를 이용하여 환원제 또는 알칼리를 직물에 부여해 톤을 가지는 직물을 제조하는 방법에 관한 것이다.More particularly, the present invention relates to a method for producing a fabric having a tone by applying a reducing agent or an alkali to the fabric using a multicolor fabric processing machine.

종래에 환원제 또는 알칼리에 의한 직물에의 톤의 부여는 날염법에 의해 이루어졌다.Conventionally, the provision of tones to fabrics by reducing agents or alkalis has been achieved by the printing method.

날염법에서는 날염호에 환원제 또는 알칼리를 착색염료 및 발염 염료와 동시에 배합하여 인날 후 증열공정 중에서 발염염료를 환원시켜 다색상의 직물을 얻는다.In the printing method, a reducing agent or an alkali is mixed with a printing dye at the same time with a coloring dye and a printing dye, and after printing, the printing dye is reduced in a steaming process to obtain a multicolor fabric.

이러한 날염법에서는 처리액의 조성물의 점도가 3,000~10,000 센티포아즈 정도로 매우 높아야 직물에 무늬 부여가 가능하기 때문에 제조경비가 많이 들고 후처리시 발생하는 날염호의 제거로 인한 폐수처리 등의 문제가 야기된다.In this printing method, the viscosity of the treatment liquid must be very high, such as 3,000 to 10,000 centipoise, so that the fabric can be patterned, which causes problems such as wastewater treatment due to the high manufacturing cost and removal of the printing foil generated during post-treatment. do.

본 발명은 기존의 날염법과는 달리 다색성 직물가공기를 이용하여 점도가 낮은 환원제 또는 알칼리를 직물에 부여함으로써 톤을 가지는 직물을 제조하는 방법을 제공하는데에 그 목적이 있다.The object of the present invention is to provide a method for producing a fabric having a tone by applying a reducing agent or alkali having a low viscosity to the fabric using a multi-color fabric processing machine, unlike the conventional printing method.

이하, 본 발명을 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail.

본 발명은 점도가 30 센티포아즈 이하인 환원제 또는 알칼리를 다색성 직물가공기를 이용하여 직물에 균일하게 분포시키는 것을 특징으로 하는 톤을 가지는 직물의 제조방법이다.The present invention is a method for producing a fabric having a tone, characterized in that the viscosity or 30 centipoise or less reducing agent or alkali uniformly distributed in the fabric using a multi-color fabric processing machine.

이하, 본 발명을 더욱 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail.

본 발명에 사용되는 환원제로는 소디움하이드로설파이트(Na2, S2, O4), 롱가리트(C(Sodium Sulfoxylate formaldehyde, NaHSO2· CH2O · 2H2O), 롱가리트 Z(Zinc formaldehyde Sulfoxylate), 염화 제일주석(Stannous Chloride SnCl2·2H2O) 등이고 알칼리로는 탄산나트륨, 수산화나트륨, 탄산칼륨 등이다.Reducing agents used in the present invention include sodium hydrosulfite (Na 2 , S 2 , O 4 ), long garrit (C (Sodium Sulfoxylate formaldehyde, NaHSO 2 · CH 2 O · 2H 2 O), long garrit Z (Zinc formaldehyde) Sulfoxylate) and stannous chloride (Stannous Chloride SnCl 2 · 2H 2 O), and alkali alkalis include sodium carbonate, sodium hydroxide and potassium carbonate.

환원제의 사용량은 롱가리트 C인 경우 15~25% ows일 때 효과가 양호한 바, 사용량이 15% ows 미만이면 톤 효과가 미흡하며, 25% ows를 초과하면 액의 안정성이 불량하다.If the amount of reducing agent is used, the effect is good at 15-25% ows in the case of longgarit C. If the amount is less than 15% ows, the effect of the reducing agent is insufficient, and the stability of the liquid is poor when it exceeds 25% ows.

또한 알칼리의 사용량은 탄산나트륨의 경우 7~15% ows, 수산화나트륨의 경우 2~5% ows 가 효과가 양호하다. 사용량이 적으면 효과가 미흡하고, 사용량이 많으면 효과가 크게 증대되지 않는다.In addition, the amount of alkali used is 7-15% ows for sodium carbonate, 2-5% ows for sodium hydroxide is good effect. If the amount is small, the effect is insufficient. If the amount is large, the effect is not greatly increased.

환원제를 사용할 때 산 흡수제로 요소를 3~6% ows, 알칼리를 사용할 때 흡수제로 폴리에틸렌글리콜(분자량 400)을 6~10% ows를 사용하면 효과가 증대된다.The effect is increased by using 3-6% ows of urea as acid absorbent when using reducing agent and 6 ~ 10% ows of polyethylene glycol (molecular weight 400) as absorbent when using alkali.

본 발명에 사용되는 염료로는 환원제 가발염료(환원제에 의해서 가발되는 염료), 알칼리 가발염료(알칼리에 의해서 가발되는 염료) 그리고 착색염료(가발되지 않는 염료)가 사용된다.As the dyes used in the present invention, reducing wig dyes (dyes wigged by reducing agents), alkaline wig dyes (dyes wigged with alkalis) and colored dyes (dyes not wigged) are used.

환원제 가발염료는 염화 제일주석의 경우는 이민계, 아조계 염료이며, 롱가리트 C의 경우 아조, 안트라퀴논계 등이며 알칼리 가발염료로는 -OCOR, -NHCOR, -COOR, -CN 등의 기를 가지는 염료이다.Reducing agent wig dyes are imine-based and azo-based dyes in the case of cationic tin chloride, azo and anthraquinone-based dyes in the case of long garrit C, and alkali wig dyes having groups such as -OCOR, -NHCOR, -COOR, and -CN. Dye.

롱가리트 C의 처리에 의한 직물은 동색계의 농담의 톤을 가지며 알칼리, 염화제일주석의 처리에 의한 직물은 이색 또는 동색계의 톤을 가진다.Fabrics treated with Longgarit C have a tone of the same color shade and fabrics treated with alkali, tin chloride have a dichroic or the same color tone.

본 발명에서 다색성 직물가공기는 국내 특허출원 제 93-27222호의 것을 사용하였으며, 도면으로 나타내었다.In the present invention, the multi-color fabric processing machine used was that of Korean Patent Application No. 93-27222, and is shown in the drawings.

이와같은 본 발명에 의하면 후처리시 폐수의 발생이 적고, 기존 섬유와는 다른 독특한 질감의 직물을 얻을 수 있다.According to the present invention, less waste water is generated during the post-treatment, and a fabric having a unique texture different from the existing fibers can be obtained.

이하, 본 발명을 실시예에 의하여 보다 구체적으로 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail with reference to Examples.

단, 본 발명이 실시예로 국한되는 것은 아니다.However, the present invention is not limited to the examples.

실시예 및 비교예에서 조성물의 점도는 30cps 이하이고, 다색성 직물가공기의 조건은 다음과 같다.In Examples and Comparative Examples, the viscosity of the composition is 30 cps or less, and the conditions of the multicolor fabric processing machine are as follows.

* 다색성 직물가공기의 조건* Condition of multicolor fabric processing machine

[실시예 1~4]EXAMPLES 1-4

폴리에스테르 직물을 [표 1]의 염료로 염색한 후 [표 2]의 조성물을 다색성 직물 가공기로 직물에 균일한 분포로 부여하고 180℃에서 1분간 열처리하여 수세한 후 직물을 건조하였다.After dyeing the polyester fabric with the dye of [Table 1], the composition of [Table 2] was applied to the fabric with a multi-color fabric processing machine in a uniform distribution, washed with heat treatment for 1 minute at 180 ℃ and dried the fabric.

[표 1] 염료 및 사용량[Table 1] Dyes and Usage

[표 2] 환원제 및 알칼리의 조성물TABLE 2 Composition of Reducing Agent and Alkali

[비교예 1~4][Comparative Examples 1-4]

환원제 및 알칼리의 조성물을 [표 3]과 같이 하고 실시예와 동일하게 처리하였다.The composition of the reducing agent and alkali was carried out as in Table 3, and was treated in the same manner as in Example.

[표 3] 환원제 및 알칼리의 조성물TABLE 3 Composition of reducing agent and alkali

상기 실시예 및 비교예에서 제조된 직물의 물성은 다음 표4와 같다.Physical properties of the fabrics prepared in Examples and Comparative Examples are shown in Table 4 below.

[표 4]TABLE 4

Claims (3)

점도가 30 센티포아즈 이하인 환원제 또는 알카리를 다색성 직물가공기를 이용하여 직물에 균일하게 분포시키는 것을 특징으로 하는 톤을 가지는 직물의 제조방법.A method of producing a fabric having a tone, characterized in that the viscosity or 30 centipoise or less reducing agent or alkali uniformly distributed in the fabric using a multi-color fabric processing machine. 제 1 항에 있어서, 상기 환원제는 소디움하이드로설파이트, 롱가리트C(소디움 설폭시레이트 포름알데히드), 롱가리트Z(징크 포름알데히드 설폭시레이트), 또는 염화제일주석임을 특징으로 하는 톤을 가지는 직물의 제조방법.The fabric of claim 1, wherein the reducing agent is sodium hydrosulfite, longgarite C (sodium sulfoxylate formaldehyde), longgarite Z (zinc formaldehyde sulfoxylate), or tin tin chloride. Manufacturing method. 제 1 항에 있어서, 상기 알칼리는 탄산나트륨, 수산화나트륨, 또는 탄산칼슘임을 특징으로 하는 톤을 가지는 직물의 제조방법.The method of claim 1, wherein the alkali is sodium carbonate, sodium hydroxide, or calcium carbonate.
KR1019930031513A 1993-12-30 1993-12-30 Method of producing tone cloth KR100248118B1 (en)

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KR100248118B1 true KR100248118B1 (en) 2000-05-01

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