KR100218643B1 - Method and apparatus for production of steel strip - Google Patents
Method and apparatus for production of steel strip Download PDFInfo
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- KR100218643B1 KR100218643B1 KR1019920017125A KR920017125A KR100218643B1 KR 100218643 B1 KR100218643 B1 KR 100218643B1 KR 1019920017125 A KR1019920017125 A KR 1019920017125A KR 920017125 A KR920017125 A KR 920017125A KR 100218643 B1 KR100218643 B1 KR 100218643B1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/46—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/12—Accessories for subsequent treating or working cast stock in situ
- B22D11/1206—Accessories for subsequent treating or working cast stock in situ for plastic shaping of strands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/46—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
- B21B1/466—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting in a non-continuous process, i.e. the cast being cut before rolling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/46—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
- B21B1/463—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting in a continuous process, i.e. the cast not being cut before rolling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/12—Accessories for subsequent treating or working cast stock in situ
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2201/00—Special rolling modes
- B21B2201/14—Soft reduction
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Metal Rolling (AREA)
- Continuous Casting (AREA)
Abstract
강대의 제조방법에 있어서, 고화된 강대표피부(3)와 액상핵심부(4)로 구성되어 있는 연속 주조된 강대(2)가 로울성형으로 두께 축소되고 이어서 압연된다.In the manufacturing method of the steel strip, the continuously cast steel strip 2 composed of the solidified steel strip 3 and the liquid core 4 is reduced in thickness by roll forming and subsequently rolled.
소망하지 않는 두께의 편의를 회피하고, 조직을 개선하고, 로울성형장치를 간단화하기 위해 40 내지 80mm 두께의 강대 빌레트를 주조하고, 두께가 15 내지 40mm 또한 잔류 액상 핵심부가 2 내지 15mm 가 되기까지 최대 3단으로 로울 성형하고 고화 완결되도록 안내한다.Cast a 40 to 80 mm thick steel billet to avoid undesired thicknesses, improve the structure and simplify the roll forming apparatus, and the thickness of 15 to 40 mm and the remaining liquid cores to 2 to 15 mm Roll forming up to three stages and guide to complete solidification.
Description
제1도는 강대 제조설비의 원리도.1 is a principle diagram of steel strip manufacturing equipment.
제2도는 주형으로부터 구동장치까지의 설비중 첫 번째 섹숀의 약시도.2 is a schematic view of the first section of the installation from the mold to the drive.
제3도는 성형로울러쌍이 둘인 제2도의 변형예의 약시도.3 is a schematic view of a variant of FIG. 2 with two forming roller pairs.
제4도는 성형 로울러쌍의 전단에 지지로울러가 배치되어 있는 또다른 변형예에 대한 약시도.4 is a schematic view of another variant in which a support roller is arranged at the front end of the forming roller pair.
제5도는 횡지지부재와 조정 및 위치결정장치가 장설된 성형로울러쌍의 일부도.5 is a partial view of a pair of forming rollers provided with a lateral support member and an adjusting and positioning device.
제6도는 지지프레임과 조정 및 위치결정장치가 장설된 지지로울러쌍의 일부도이다.6 is a partial view of a pair of support rollers equipped with a support frame and an adjustment and positioning device.
* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings
1 : 주형 2, 2' : 강대빌레트, 강대1: Template 2, 2 ': Kangdae Billet, Gangdae
3 : 표피부 4 : 액상핵심부3: epidermis 4: liquid core
5,6 : 성형로울러쌍 7 : 안내로울러5,6: forming roller pair 7: guide roller
8 : 구동로울러 9 : 벤딩로울러8: driving roller 9: bending roller
10 : 구동조정장치 11 : 재단기10: drive adjustment device 11: cutting machine
12 : 노 13 : 추가재단기12: No 13: Additional Cutting Machine
14 : 스케일 제거장치 15 : 로울스탠드14: descaling device 15: roll stand
18 : 층류냉각구역 19 : 권취기18: laminar flow cooling zone 19: winder
21 : 지지로울로 24, 25, 37, 38 : 베어링21: support roller 24, 25, 37, 38: bearing
27, 28 : 횡비임 29, 42 : 스핀들 구동장치27, 28: aspect ratio 29, 42: spindle drive
30, 43 : 모우터 31, 44 : 나사스핀들30, 43: motor 31, 44: screw spindle
32, 45 : 거리너트 33, 46 : 스피링32, 45: Distance nut 33, 46: Spring
34, 47 : 스토퍼판 35 : 내부 냉각로34, 47: stopper plate 35: internal cooling furnace
36, 48 : 조정실린더 36a, 48a : 견인봉36, 48: adjustment cylinder 36a, 48a: tow bar
본 발명은 강대의 제조방법에 관한 것으로, 고화된 강대표피부와 액상 핵심부로 구성되어 있는 연속주조된 강대가 로울성형(로울변형)으로 두께축소되고 이어서 압연된다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a steel strip, wherein a continuously cast steel strip consisting of a solidified steel strip skin and a liquid core part is reduced in thickness to roll forming (roll deformation) and subsequently rolled.
EP-A1 0 286 862에 의해 공지된 이 방법에 있어서는 두께 40 내지 50mm 이고 통과형 주형에서 주조된 강대가 주형에서 배출된 뒤, 주형에서 형성된 강대 표피부의 내벽이 서로 융착할 정도로 로울쌍에 의해 압착된다.In this method known by EP-A1 0 286 862, the rolled steel sheet is 40 to 50 mm thick and cast from the casting mold after the steel sheet is discharged from the mold, so that the inner walls of the steel sheet formed in the mold are welded together. Squeezed.
주어진 길이의 통과형 주형에서의 연속주조시에는 형성된 강대표피의 두께는 사실상 주조속도에 좌우된다.In continuous casting in a pass-through mold of a given length, the thickness of the steel strip formed is in fact dependent on the casting speed.
로울러간의 간극이 일정히 유지되는 것을 보장하기 위해서는 압연력이 순간 순간의 강대표피두께에 적응되어야 한다. 주조속도가 너무 낮을 경우에는 이용할 수 있는 압연력은 더 이상 충분하지 않으며, 따라서 생산된 강대의 두께는 설정 두께를 초과하게 된다. 한편 주조속도가 너무 높을때에는 양 강대 표피부의 융착은 생산 강대의 설정 두께의 미달하에서만 달성될 수 있다.To ensure that the clearance between the rollers is kept constant, the rolling force must be adapted to the instantaneous outer skin thickness. If the casting speed is too low, the available rolling force is no longer sufficient, so the thickness of the produced steel strip will exceed the set thickness. On the other hand, when the casting speed is too high, fusion of both strip skins can be achieved only under the set thickness of the production strip.
본 발명의 목적은 생산된 강대의 원하지 않는 두께 편의(벗어남)를 회피하고 양호한 조직을 얻을 수 있는 방법 및 그 방법의 실시를 위한 설비를 제공하는 것이다. 그위에, 성형장치의 간략화 및 그 에너수요의 절감도 달성될 수 있게 하려는 것이다.It is an object of the present invention to provide a method and a facility for carrying out the method which can avoid undesired thickness biases of the produced steel strip and obtain good structure. On top of that, it is intended to simplify the molding apparatus and to reduce the energy demand.
상기 설정목적은 40 내지 80mm 두께의 강대 빌레트를 주조하고, 그 강대빌레트를 최대 3단으로 15 내지 40mm의 두께 및 2 내지 15mm의 잔류액 핵심부가 되기까지 로울성형하고, 그런다음 그 강대를 고화완결(경화완결)되도록 까지 변형(성형)없이 이송함으로써 본 발명에 의해 달성된다.The purpose of the setting is to cast a steel billet with a thickness of 40 to 80 mm, roll forming the coil to a maximum of three stages up to a thickness of 15 to 40 mm and a residual liquid of 2 to 15 mm, and then solidify the steel sheet. It is achieved by the present invention by conveying without deformation (molding) to (cure hardening).
이렇게하여 주조속도와 강대 두께는 상호간에 보다 자유롭게 선정됨으로써 높은 생산성을 달성할 수가 있다.In this way, casting speed and strip thickness can be freely selected between each other to achieve high productivity.
또한 품질면에서도 핵이 조밀하고 편석이 없는 조직이 얻어질 수 있다.Also, in terms of quality, a dense nucleus and no segregation can be obtained.
성형장치의 압연력(조정력)의 감소에 의해 구조적 간략화 및 에너지 절감이 달성될수 있다.Structural simplification and energy savings can be achieved by reducing the rolling force (adjustment force) of the molding apparatus.
강대 표피부의 두께는 로울성형전 6 내지 19mm인 것이 바람직하다.It is preferable that the thickness of the stripped skin portion is 6 to 19 mm before roll forming.
본 발명의 바람직한 추가 양태에 따라 로울성형도(변형율)는 10 내지 60%이며 주조중에 변동될 수 있다.According to a further preferred embodiment of the invention the roll forming degree (strain) is 10 to 60% and can vary during casting.
주조속도가 2 내지 10m/분의 경우, 로울성형된 강대는 1 내지 5m 의 길이에 걸쳐 평행 안내된다.When the casting speed is 2 to 10 m / min, the roll-formed steel strip is guided in parallel over the length of 1 to 5 m.
강대는 고화완결후 압연온도로 조정되고 압연된다.The steel strip is adjusted to the rolling temperature after the solidification and rolled.
본 발명에 의한 장치 구체예에 있어서는, 강대주조 주형의 방법 실시를 위한 설비에 있어, 지지로울러(안내로울러)로 구성된 고화완결구역 및 구동장치가 최대 3쌍의 성형로울러의 후단에 배치되어 있다.In the embodiment of the apparatus according to the present invention, in the facility for carrying out the method of the steel casting mold, the solidification zone and the driving device composed of the support rollers (guide rollers) are arranged at the rear end of up to three pairs of the molding rollers.
그리고 성형로울러 및/또는 지지로울러에는 기계식 위치결정장치 및 유압식 가압 장치가 장설되어 있다.In addition, the forming roller and / or the support roller are equipped with a mechanical positioning device and a hydraulic pressure device.
본 발명의 추가 양태는 특허청구의 범위 종속항(제9항 내지 16항)에 나타나있다.Further aspects of the invention are indicated in the claims subclaims (claims 9 to 16) of the claims.
도면에는 본 발명의 특징 및 이점을 갖춘 실시예들이 도시되어 있다.The drawings illustrate embodiments with features and advantages of the invention.
제1도의 설비는 40 내지 80mm 두께의 강대 빌레트를 주조하기 위한 주형(1), 성형 로울러쌍(5), 안내로울러(7) 및 구동로울러(8)로 구성되어 있다. 강대의 방향 전환을 위해 벤딩로울러(9)가 배치되어 있다. 이어서 강대(2')는 구동조정장치(10)에 도달하여 재단기(11)에 의해 절단될 수 있다. 그런다음 온도조정을 위해 강대토막은 노(12)를 통과하는데, 이 노의 다음에는 추가의 재단기(13) 및 스케일 제거장치(14)가 설치되어 있다.The equipment of FIG. 1 consists of a mold 1, a forming roller pair 5, a guide roller 7 and a drive roller 8 for casting a steel billet 40 to 80 mm thick. A bending roller 9 is arranged to change the direction of the steel strip. The strip 2 'may then be reached by the drive adjuster 10 and cut by the cutter 11. The steel strip then passes through the furnace 12 for temperature control, after which an additional cutter 13 and a descaling device 14 are installed.
물질전진방향으로 배치된 스텍켈 압연기는 전후에 권취로(16,17)가 장설된 로울 스탠드(15)로 구성되어 있다.The stackel rolling machine arranged in the material advancing direction is constituted by a roll stand 15 in which winding paths 16 and 17 are installed before and after.
스텍켈 압연기를 떠나는 압연스트립(2'')은 층류냉각구역(18)을 지나고 이어서 권취기(19)에 권취된다.The rolling strip 2 ″ leaving the stacker rolling mill passes through the laminar flow cooling zone 18 and is then wound up in the winder 19.
제2도 내지 4도는 연속주조장치에서 강대(2,2')를 제조하는 단계를 보여준다.2 to 4 show the steps of manufacturing steel strips 2, 2 'in a continuous casting apparatus.
주형(1)에 주입된 용강으로부터 강대 표피부(3)의 냉각 및 고화에 의해 액상핵심부(4)를 가진 주조강대(2)가 생긴다.The molten steel injected into the mold 1 produces a cast steel strip 2 having a liquid core 4 by cooling and solidifying the strip skin 3.
주형(1) 하부에서 강대의 폭측에 있는 강대 표피부(3)는 내부 냉각로(35)를 가진 성형 로울러(5,6)에 의해 그 대향 간격이 축소된다.The steel strip skin 3 on the width side of the steel strip under the mold 1 is shortened by its forming rollers 5 and 6 with an internal cooling path 35.
이렇게하여 두께 15 내지 40mm이고 잔류 액상핵심부(4)가 2 내지 15mm되는 강대가 얻어진다. 로울 성형된 주조강대(2)는 안내로울러(7)에 의해 형성된 로울러통로 사이를 변형받지 않고 통과하면서 완전히 고화된다. 강대이송은 구동로울러(8)에 의해 행해진다.In this way, a steel strip having a thickness of 15 to 40 mm and a residual liquid core 4 of 2 to 15 mm is obtained. The roll-formed cast steel 2 is completely solidified while passing through the roller passages formed by the guide rollers 7 without being deformed. The steel strip feed is performed by the drive roller 8.
제2도의 실시예에서는 주조강대(2)가 성형로울러쌍(5) 사이에서 1단으로 로울성형(로울변형)된다. 그 대신에 제3도의 실시예에서는 성형 로울러쌍(5와 6)사이에서 2단 로울성형이 일어난다.In the embodiment of FIG. 2, the cast steel strip 2 is roll-formed (roll deformation) in one stage between the pairs of forming rollers 5. Instead, two-stage roll forming takes place between the forming roller pairs 5 and 6 in the embodiment of FIG.
높은 성형속도 또는 높은 성형단계를 허용하지 않는 강의 경우에는 2단 또는 3단의 로울성형이 유리할 것이다.Two or three stage roll forming would be advantageous for steels that do not allow high forming speeds or high forming steps.
주조강대(2)의 냉각을 위해 안내로울러들(7) 사이에는 분수노즐(20)이 배치되어 있다.A fountain nozzle 20 is disposed between the guide rollers 7 for cooling the cast steel 2.
제4도의 변형예에서는 주조강대가 주형 하부에서 먼저 품질에 따른 온도 조정을 하기 위해 지지로울러들(21)사이에서 먼저 변형없이 이동안내된다. 지지로울러(21) 및 안내로울러(7)는 내부안내로(22 또는 23)을 갖고 있다.In the variant of FIG. 4, the cast steel is first guided without deformation between the support rollers 21 in order to adjust the temperature according to the quality at the bottom of the mold. The support roller 21 and the guide roller 7 have internal guideways 22 or 23.
제5도에 표시된 구조형상의 경우에는 성형로울러(5)가 다중 수장되어 있는데, 베어링(24,25)은 횡비임(27,28)에 고정되어 있고 그 횡비임들은 양측에서 대향 위치 한채로 스탠드(26)에서 이동될 수 있다.In the case of the structure shown in FIG. 5, the forming rollers 5 are multiplely stored, and the bearings 24 and 25 are fixed to the side beams 27 and 28, and the side beams stand at opposite sides on both sides. May be moved at 26.
횡부재(27,28) 및 성형로울러(5)의 위치결정장치로서 스핀들 구동장치(29)가 스탠드(26)에 고정되어 있다. 모우터(30)와 연결된 스핀들 구동장치(29)는 횡부재(27,28)의 방향으로 각각 한개의 나사스핀들(31)을 갖고 있다.The spindle drive 29 is fixed to the stand 26 as a positioning device for the transverse members 27 and 28 and the forming roller 5. The spindle drive 29 connected to the motor 30 has one screw spindle 31 in the direction of the transverse members 27 and 28, respectively.
나사스핀들(31)에 나사연결된 각 거리너트(32)는 삽입스프링(33)에 의해 회전이 확실히 방지된다. 횡비임(27,28)에는 스토퍼판(34)이 각 거리너트(32)에 할당되어 있다. 각 견인봉(36a)을 가진 조정실린더(36)에 의해 횡비임들(27,28)은 상호간에 견인되며, 두 비임간의 간격 및 그에따른 성형로울들(5)의 간격은 스핀들 구동장치(29)에 의해 조정되는 거리너트(32)에 의해 정해진다.Each distance nut 32 screwed to the screw spindle 31 is reliably prevented from rotation by the insertion spring 33. In the side beams 27 and 28, stopper plates 34 are assigned to the respective distance nuts 32. The transverse beams 27 and 28 are mutually towed by the adjustment cylinder 36 with the respective towbars 36a, and the spacing between the two beams and thus the spacing of the forming rollers 5 is the spindle drive 29 Is determined by the distance nut 32 adjusted by
이렇게하여 거리조정시에도 성형로울쌍(5)은 주형(1)의 주조 캐비티와 중심이 일치한채 유지될 수 있다. 추가의 성형로울쌍(6)(제3도)에 대해서도 유사한 베어링 및 조정장치가 설치된다.In this way, the pair of forming rolls 5 can be kept in center with the casting cavity of the mold 1 even when the distance is adjusted. Similar bearings and adjusters are provided for the additional forming roller pair 6 (FIG. 3).
제6도에 도시된 구성의 경우에는 안내로울러들(7)이 역시 중복 배치되어 있고 베어링(37,38)은 프레임(39,40)에 지지되어 있다.In the case of the configuration shown in FIG. 6, the guide rollers 7 are also overlapped and the bearings 37 and 38 are supported on the frames 39 and 40.
프레임(39,40)은 양쪽으로 스탠드(41)에서 안내된다.Frames 39 and 40 are guided from stand 41 to both sides.
프레임(39,40) 및 안내로울(7)의 위치결정장치로서 스탠드(41)에는 스핀들 구동장치(42)가 고정되어 있다. 모우터(43)와 연결된 스핀들 구동장치(42)는 프레임(39,40)의 방향으로 각각 한개의 나사스핀들(44)을 갖고 있다.The spindle drive 42 is fixed to the stand 41 as a positioning device for the frames 39 and 40 and the guide roll 7. The spindle drive 42 connected to the motor 43 has one screw spindle 44 in the direction of the frames 39 and 40, respectively.
나사스핀들(44)위에 나사 죄어져 있는 각 거리 너트(45)는 삽입 스프링(46)에 의해 회전이 방지된다. 프레임(39,40)에는 스토퍼판(47)이 각 거리너트(45)에 할당배치되어 있다. 견인봉(48a)을 가진 조정실린더(48)에 의해 프레임들(39,40)은 상호간에 견인되는데, 그 두 프레임간의 간격 및 거기따른 안내로울러들(7)의 간격은 스핀들 구동장치(42)에 의해 조정되는 거리너트(45)에 의해 결정된다.Each distance nut 45 screwed onto the screw spindle 44 is prevented from rotating by the insertion spring 46. In the frames 39 and 40, a stopper plate 47 is assigned to each of the distance nuts 45. Frames 39 and 40 are mutually towed by an adjustment cylinder 48 with a traction rod 48a, wherein the spacing between the two frames and the distance between the guide rollers 7 follows. It is determined by the distance nut 45 adjusted by.
이렇게하여 안내로울러들(7)은 간격조정시에도 대응하는 성형로울러(5)에 일치 배향된채 머무를 수 있다.In this way, the guide rollers 7 can remain in alignment with the corresponding forming roller 5 even when the gap is adjusted.
Claims (16)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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DEP4131116.7 | 1991-09-19 | ||
DE4131116 | 1991-09-19 | ||
DEP4135214.9 | 1991-10-25 | ||
DE4135214A DE4135214C2 (en) | 1991-09-19 | 1991-10-25 | Process and plant for the production of steel strip |
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KR930005685A KR930005685A (en) | 1993-04-20 |
KR100218643B1 true KR100218643B1 (en) | 1999-09-01 |
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Application Number | Title | Priority Date | Filing Date |
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KR1019920017125A KR100218643B1 (en) | 1991-09-19 | 1992-09-19 | Method and apparatus for production of steel strip |
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KR (1) | KR100218643B1 (en) |
DE (2) | DE4135214C2 (en) |
ZA (1) | ZA926474B (en) |
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Publication number | Priority date | Publication date | Assignee | Title |
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AT401744B (en) * | 1993-10-14 | 1996-11-25 | Voest Alpine Ind Anlagen | METHOD AND SYSTEM FOR CONTINUOUS CASTING |
AT410522B (en) * | 2001-05-07 | 2003-05-26 | Hulek Anton | METHOD AND CONTINUOUS CASTING SYSTEM FOR VERTICAL CONTINUOUS CASTING OF A STEEL STRIP |
DE102013214939A1 (en) | 2013-07-30 | 2015-02-05 | Sms Siemag Ag | Casting mill for producing metal strips |
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DE3627991A1 (en) * | 1986-08-18 | 1988-02-25 | Mannesmann Ag | METHOD FOR CONTINUOUSLY MOLDING SLABS AND DEVICE FOR CARRYING OUT THE METHOD |
-
1991
- 1991-10-25 DE DE4135214A patent/DE4135214C2/en not_active Expired - Fee Related
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1992
- 1992-08-27 ZA ZA926474A patent/ZA926474B/en unknown
- 1992-08-27 DE DE59206481T patent/DE59206481D1/en not_active Expired - Lifetime
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ZA926474B (en) | 1993-04-28 |
DE4135214C2 (en) | 2000-12-14 |
KR930005685A (en) | 1993-04-20 |
DE4135214A1 (en) | 1993-03-25 |
DE59206481D1 (en) | 1996-07-11 |
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