KR100210202B1 - Fabric for oil fence - Google Patents

Fabric for oil fence Download PDF

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Publication number
KR100210202B1
KR100210202B1 KR1019960024558A KR19960024558A KR100210202B1 KR 100210202 B1 KR100210202 B1 KR 100210202B1 KR 1019960024558 A KR1019960024558 A KR 1019960024558A KR 19960024558 A KR19960024558 A KR 19960024558A KR 100210202 B1 KR100210202 B1 KR 100210202B1
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South Korea
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oil
water
environmental pollution
forge
permeability
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KR1019960024558A
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Korean (ko)
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KR980001849A (en
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노귀영
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노귀영
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B21/00Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Removal Of Floating Material (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Filtering Materials (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

본 발명은 유·수 선택분리투과성이 우수한 환경오염방지용 포지에 관한 것으로서, 종래의 환경오염방지용 포지에 있어 유·수 선택분리투과성이 없고, 강, 신도가 낮아서 기름오염에 의한 방제작업과 폐유의 여과처리를 제대로 할 수 없었던 문제점을 해소한 것으로, 폴리프로필렌사를 사용하여 더블랏셀편으로 편성된 경편직물로서 표지 및 이지와 이들 사이에 루우프를 형성함으로써 물은 발수하면서 기름만을 효과적으로 흡착·포진하여 제거할 수 있게 구성되어서 발유도, 발수도 및 정적, 동적 흡수율과 분진포집효율 그리고 인장강도 및 신도와 동적흡유율과 정적흡유특성을 갖추어 기름오염부분에 효과적으로 사용될 수 있는 유·수 선택분리투과성이 우수한 환경오염방지용 포지이다.The present invention relates to an environmental pollution prevention forge excellent in oil and water selective separation permeability, and has no oil and water selective separation permeability in the conventional environmental pollution prevention forges, and has a low strength and elongation, so that it is possible to control oil waste and to control waste oil. It solves the problem of not being able to perform the filtration process properly. It is a warp knitted fabric composed of double-latssel pieces using polypropylene yarn. Oil and water selective permeability that can be effectively used for oil contaminated parts with oil repellency, water repellency and static, dynamic absorption and dust collection efficiency, tensile strength, elongation, dynamic absorption and static absorption characteristics. Excellent for environmental pollution prevention.

Description

유·수 선택분리투과성이 우수한 환경오염방지용 포지Environmental pollution prevention paper with excellent permeability for oil and water separation

제1도는 본 발명에 따른 포지(布地)의 편성도이고,1 is a knitting of the forge according to the present invention,

제2도는 본 발명에 따른 포지의 측면도이며,2 is a side view of the forge according to the present invention,

제3도의 (a)(b)(c)는 본 발명에 따라 제조된 포지의 흡착시험 과정을 차례로 찍은 사진으로서, 기름이 완전 흡착됨을 나타낸다.Figure 3 (a) (b) (c) is a photograph taken sequentially the adsorption test process of the forge prepared according to the present invention, indicating that the oil is completely adsorbed.

* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

1 : 표지(表地) 2 : 이지(裏地)1: cover 2: easy

3 : 루우프 4 : 표지와 루우프의 연결부분3: Loop 4: Connection between the cover and the loop

5 : 이지와 루우프의 연결부분5: Connection between Easy and Loop

본 발명은 유(油)·수(水)의 선택분리투과성이 우수한 환경오염방지용 포지에 관한 것이다.The present invention relates to an environmental pollution prevention paper having excellent permeability for selective separation of oil and water.

일반적으로 기름에 의한 환경오염은 사고선박에 의한 해양·해변오염과, 양식장 및 상수원 보호구역으로의 기름유입 그리고 물과 섞인 폐유가 방출되는 세차장 및 차량 정비공장과 같은 각종 산업현장에서 다양한 형태로 이루어지고 있다.In general, environmental pollution caused by oil can take various forms in various industrial sites such as car and car repair shops where marine and beach pollution caused by accident vessels, oil inflow to aquaculture farms and water supply protection areas, and waste oil mixed with water are released. ought.

종래에는 기름에 의한 환경오염방지작업을 수행함에 있어서 수면 위에 있는 기름을 직접 제거하거나 기름을 중화시켜 줄 수 있는 약제를 사용했었다.Conventionally, in performing environmental pollution prevention work by oil, a drug that can directly remove oil on the water surface or neutralize oil was used.

기름을 직접 제거함에 있어서 통상의 포지를 기름유출해상에 던져서 이 포지에 기름이 흡수되도록 한 다음 이를 치수했었다. 그러나 통상의 포지는 기름기와 물기가 함께 흡수되었기 때문에 특히 물기가 먼저 포지에 흡수된 상태에서는 기름기가 제대로 흡수되지 않게 되어서 기름제거효율이 매우 낮았다.In the direct removal of oil, conventional forge was thrown onto an oil spill to allow oil to be absorbed and then dimensioned. However, since the conventional forge was absorbed together with the oil and water, the oil removal efficiency was very low since the oil was not absorbed properly, especially when the water was first absorbed into the forge.

또 기름유출규모가 큰 유조선과 간은 대형선박의 사고시에는 오염지역이 확산되지 않도록 팬스(fence)를 치고, 이 팬스를 어망처럼 견인하여서 포집된 기름을 제거하는 것이 바람직함에도 불구하고 종래의 포지는 유·수 선택분리성이 없었기 때문에 포지자체에 큰 하중이 작용하게 되므로 팬스를 어망처럼 견인할 수 없어서 단순히 오염지역이 확산되지 않도록 기름띠를 일정한 해역에 머무르도록 하는 것에 불과한 것이었다.In the event of an accident of a large ship, the tanker and the liver that have a large oil spill size have to fence so that the contaminated area does not spread, and it is preferable to tow the pan like a fishing net to remove the collected oil. Since there was no segregation of oil and water, the load was applied to the forge itself, so the pan could not be towed like a fishing net, so it was simply to keep the oil strip in a fixed area so that the contaminated area could not spread.

따라서 종래에는 팬스내로 모아진 기름을 별도로 제거처리해야만 했었다.Therefore, conventionally, the oil collected in the pan had to be separately removed.

본 발명자는 이와 같은 종래의 제반 문제점을 예의 검토한 결과, 물은 투과시키고 기름만을 포집시켜 흡유성을 향상시킴과 아울러 인장신도와 강도를 크게 해줄 수 만 있다면 해양과 하천에서 어망처럼 견인할 수 있는 팬스로도 할 수 있고, 각종 폐유를 방출하는 산업현장에서는 유·수분리용 필터로도 유용하게 사용할 수 있는 것임을 알게 되어서 유·수선택분리투과성이 우수한 환경오염방지용 포지를 완성하기에 이르렀다.As a result of thorough examination of such conventional problems, the inventors of the present invention can improve the oil absorption by permeating water and collecting only oil, and can tow like fishing nets in oceans and rivers if they can increase tensile elongation and strength. It was found that it can be used as a fan and can be used as a filter for oil and water separation in industrial sites that emit various waste oils, thus completing the environmental pollution prevention forge with excellent oil and water selective separation permeability.

즉, 본 발명의 유·수선택분리투과성이 우수한 환경오염방지용 포지는 폴리프로필렌(polypropylene)사를 사용하여 더블랏셀편(double raschel knitting)으로 편성된 경편직물(warp knitted fabric)로서 표지 및 이지와 이들 사이에 루우프가 형성되도록 편성된 것이다.In other words, the environmental pollution prevention forge excellent in oil and water selective separation permeability of the present invention is a warp knitted fabric knitted with a double raschel knitting using a polypropylene yarn. A loop is formed between them.

이하, 본 발명을 첨부된 도면을 참조하여 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

제1도 및 제2도에 상세히 도시된 바와 같이 본 발명에 따른 유·수선택분리 투과성이 우수한 환경오염방지용 포지(D)는 제1도의 편성도에서 가이드 바아(L1) 또는 (L6)는 각기 표지(1) 또는 이지(2)를, 가이드바아(L2) 또는 (L5)는 표지(1) 또는 이지(2)와 루우프(loop)(3)와의 연결부분(4) 또는 (5)를 각기 형성하며, 가이드바아(L3) 및 (L4)는 루우프(3)를 형성함으로써, 표지(1) 및 이지(2)와 이들 표지(1) 및 이지(2) 사이에 파일이 동시에 편성(編成)되어 루우프(3)가 형성되도록 구성된 것이다.As shown in detail in FIGS. 1 and 2, the environmental pollution prevention forge D having excellent permeability between water and water selective separation according to the present invention is a guide bar (L 1 ) or (L 6 ) in the knitting degree of FIG. Indicates a cover (1) or easy (2), respectively, the guide bar (L 2 ) or (L 5 ) is the connection (4) or () of the cover (1) or easy (2) and loop (3), respectively ( 5), and the guide bars L 3 and L 4 form loops 3 to form piles between the indicia 1 and the easy 2 and the indicia 1 and the easy 2. At the same time, they are knitted to form a loop 3.

이와 같이 형성된 본 발명에 의한 폴리프로필렌으로 된 유·수선택분리투과성이 우수한 환경오염방지용 포지는 파일의 루우프 사이의 공간의 모세관 현상과 포지 그 자체의 재질 특성에 의하여 종래의 포지에 비하여 물을 발수 내지 투과시키고 기름만을 포집할 수 있는 성능이 우수할 뿐만 아니라 비중이 0.90∼0.91로 가벼워서 물위에 뜨며 강,신도가 우수하여서 환경오염방지팬스로 만들었을 때 어망처럼 견인하면서 포집된 기름을 제거할 수 있고, 유·수분리용 필터로도 활용할 수 있는 장점이 있다.Thus, the polypropylene made of polypropylene according to the present invention has excellent oil and water separation permeability, and thus, water repellent water is compared with the conventional paper by the capillary phenomenon of the space between the loops of the pile and the material characteristic of the paper itself. Not only has excellent performance to permeate and collect oil but also has a specific gravity of 0.90 to 0.91, so it floats on water, and has high strength and elongation. In addition, there is an advantage that can be utilized as a filter for oil and water separation.

본 발명을 다음에 일 실시예를 들어 설명하나, 본 발명은 이에 한정되지 않고 본 발명의 범주 및 정신내에서 변형이 가능함은 물론이다.The present invention will be described below with reference to one embodiment, but the present invention is not limited thereto and can be modified within the scope and spirit of the present invention.

[실시예]EXAMPLE

100% 폴리프로필렌 120/24 실을 사용하여 더블랏셀 편으로 편성하여 10.0course/cm 밀도의 편지를 형성하되 표지 및 이지 사이를 파일로 연결되도록 편성하였다(제1도 및 제2도 참조).100% polypropylene 120/24 yarns were knitted into doubletlasel pieces to form letters of 10.0course / cm density, with the file between the cover and the easy to file (see FIGS. 1 and 2).

편성된 포를 통상의 발수가공등 후처리를 한 후 제품단위별로 절단한 다음 제품을 검사한 후 포장하였다.Knitted fabrics were processed after normal water repellent processing, cut into product units, and then inspected and packaged.

이렇게 하여 제조한 본 발명의 포지를 일정길이로 절단한 후 제3도(a)(b)(c)에 도시된 바와 같이 물 100ℓ에 방카C유를 부어 놓은 용기에 3초동안 침지시켜 유흡착력을 시험한 바, 제3도(c)에 나타난 바와 같이 용기의 기름은 모두 본 발명의 포지에 묻어 나왔으며, 용기의 물은 원상태로 깨끗이 환원되었다.The forge of the present invention prepared in this way was cut to a predetermined length, and then immersed in a container in which banca C oil was poured into 100 l of water for 3 seconds as shown in FIG. As shown in FIG. 3 (c), all of the oil in the container was buried in the forge of the present invention, and the water in the container was reduced to its original state.

이에 더하여, 본 실시예에 따라 제조된 포지를 일부 채취하여 다음 각각의 시험방식에 따라 테스트한 바, 다음과 같은 결과를 얻었다.In addition, a part of the forge manufactured according to the present embodiment was taken and tested according to the following test methods, and the following results were obtained.

단,발유도는 KS K 0526, 탄화수소법으로 측정한 것임.only, Oil repellency is measured by KS K 0526, hydrocarbon method.

발수도는 KS K 0590, 스프레이법으로 측정한 것임. Water repellency was measured by KS K 0590, spray method.

정적흡수율은 KS S 0815 5.27.1.B법으로 측정한 것임. Static absorption rate is measured by KS S 0815 5.27.1.B method.

분진포집효율은 ASHRAE Standard 52.1, 중량법으로 측정한 것임. Dust collection efficiency is measured by ASHRAE Standard 52.1, gravimetric method.

(풍속 2.5m/sec와 말기압 71.3mmAq에서 측정한 것임)(Measured at 2.5m / sec wind speed and 71.3mmAq terminal pressure)

인장강도는 KS K 0520, C.R.E, 그래브법으로 측정한 것임. Tensile strength measured by KS K 0520, CRE, Grab method.

(습윤조건은 상온수에서 침지한 후 시험한 것임)(Wetting conditions are tested after immersion in room temperature)

인장신도는 KS S 0520, C.R.E, 그래브법으로 측정한 것임. Tensile elongation is measured by KS S 0520, CRE, Grab method.

(습윤조건은 상온수에서 침지한 후 시험한 것임)(Wetting conditions are tested after immersion in room temperature)

동적 흡유율은 KS K 0339를 준용하여서 증류수 대신 경유를 사용한 것임. The dynamic oil absorption rate is based on KS K 0339 and light oil instead of distilled water

정적흡유성은 KS K 0815 5.27.1.B법을 준용하여서 증류수 대신 경유를 사용하여 측정한 것임. Static absorption is measured using light oil instead of distilled water in accordance with KS K 0815 5.27.1.B.

이상과 같이 표지와 이지조직 사이가 파일의 루우프로 연결된 본 발명의 유·수선택분리투과성이 우수한 환경오염방지용 포지는 강,신도가 우수할 뿐만아니라 무수히 많은 파일들 사이의 공간이 모세관 역할을 함과 아울러 상기 포지 그 자체의 특성으로 인하여 물은 발수시키고 다량의 기름만을 흡착, 포집시킬 수 있어서 우수한 유·수선택분리투과성을 발휘하게 되며, 특히 가벼워서 기름 유출 또는 오염지역에 사용할 때 설치가 용이하며 유흡착능력이 특출나다.As described above, the forgery for preventing contamination of the environment having excellent permeability and water selective separation permeability of the present invention connected between the cover and the easy tissue with the loop of the pile is not only excellent in strength and elongation but also has a space between a large number of piles serving as a capillary tube. In addition, due to the characteristics of the forge itself, the water is water-repellent and can absorb and collect only a large amount of oil, thereby exhibiting excellent oil and water selective separation permeability, and in particular, it is light and easy to install when used in an oil spill or contaminated area. Oil absorption ability is outstanding.

또한, 본 발명에 따라 형성된 상기 포지는 그 사용양태에 따라 매트형, 쿠션형, 로프형등 다양한 형태로 제조될 수 있다.In addition, the forge formed according to the present invention can be produced in various forms, such as mat, cushion, rope type depending on the use.

따라서, 본 발명에 따른 유·수선택분리투과성 포지는 연결식 부표(浮漂)에 감아서 이 연결식 부표를 기름유출지역에 설치하거나, 선박과 선박을 본 발명의 유·수선택분리투과성 포지로 연결함으로써 기름오염을 막아주는데 사용하며, 선박 후미에 30∼40m씩 달아서 오염지역을 선회하면서 기름을 제거할 수도 있으며, 가벼우므로 던져서 기름을 흡착시킨 후 건져 올릴 수도 있고, 가두리 양식장 주변에 설치하여 유류오염을 차단할 수도 있다. 특히 세차장, 차량정비소 배출구에 설치하여 기름유출을 방지하는데 사용될 수도 있다.Accordingly, the oil and water selective separation permeable forge according to the present invention may be wound around the buoy by installing the linked buoy in the oil spill area, or by connecting the vessel and the water to the oil and water selective separating permeability of the present invention. It is used to prevent oil pollution, and it is possible to remove oil while turning the polluted area by attaching 30 ~ 40m to the rear of the ship.It is light, so it can be thrown and adsorbed and lifted up, and installed around the cage farm to block oil pollution. It may be. In particular, it can be installed in car wash, vehicle maintenance outlet, and used to prevent oil spill.

상술한 유형으로 본 발명의 유·수선택분리투과성이 우수한 환경오염방지용 포지를 설치하여 사용하면 본 발명의 포지는 전혀 흡수력이 없어 물이 흡착되어 있지 않으므로 단지 기름만 묻은 상기 포지를 한 쌍의 로울러를 통과하여 압착함으로써 흡착된 기름을 짜낸 다음 권취하여 다시 재사용할 수 있고, 또 기름만이 배출되므로 이 기름을 탱크에 받아 정유공장에서 간단히 재생·가공처리될 수 있으므로 또한 경제적이다.In the above-described type, if the environmental pollution prevention forge having excellent oil / water selective separation permeability of the present invention is installed and used, the forge of the present invention has no absorbing power, and thus water is not adsorbed. It is economical because the oil can be squeezed out by pressing through, and then wound and re-used and reused again. Since only the oil is discharged, the oil can be received in a tank and simply regenerated and processed in a refinery.

Claims (1)

폴리프로필렌사를 사용하여 더블랏셀편으로 편성된 경편직물로서 표지(1) 및 이지(2)와 이들 사이에 연결부분(4)(5)에 의해 루우프(3)가 형성되도록 편성된 것을 특징으로 하는 유·수선택분리투과성이 우수한 환경오염방지용 포지.It is a warp knitted fabric knitted into a double-latssel piece using polypropylene yarn, characterized in that the loop (3) is formed by the cover (1) and the easy (2) and the connecting portion (4) (5) therebetween. Forge of environmental pollution prevention with excellent permeability between oil and water.
KR1019960024558A 1996-06-27 1996-06-27 Fabric for oil fence KR100210202B1 (en)

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KR1019960024558A KR100210202B1 (en) 1996-06-27 1996-06-27 Fabric for oil fence

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100369771B1 (en) * 2001-02-16 2003-02-06 주식회사 웅천텍스텍 High bulk warp knit sorbent for oil spill ocean
KR100517824B1 (en) * 2003-11-07 2005-09-28 노귀영 a blanket yard-goods made of PP yarn
KR20200095148A (en) * 2019-01-31 2020-08-10 신우산업주식회사 Manufacturing method of oil cotrollable bonding material and manufacturing method and deivce of the same

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100369771B1 (en) * 2001-02-16 2003-02-06 주식회사 웅천텍스텍 High bulk warp knit sorbent for oil spill ocean
KR100517824B1 (en) * 2003-11-07 2005-09-28 노귀영 a blanket yard-goods made of PP yarn
KR20200095148A (en) * 2019-01-31 2020-08-10 신우산업주식회사 Manufacturing method of oil cotrollable bonding material and manufacturing method and deivce of the same
KR102404206B1 (en) * 2019-01-31 2022-06-02 신우산업주식회사 Manufacturing method of oil cotrollable bonding material and manufacturing method and deivce of the same

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