KR100189324B1 - Construction method for preventing dew condensation of concrete structure - Google Patents

Construction method for preventing dew condensation of concrete structure Download PDF

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KR100189324B1
KR100189324B1 KR1019970013038A KR19970013038A KR100189324B1 KR 100189324 B1 KR100189324 B1 KR 100189324B1 KR 1019970013038 A KR1019970013038 A KR 1019970013038A KR 19970013038 A KR19970013038 A KR 19970013038A KR 100189324 B1 KR100189324 B1 KR 100189324B1
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layer
methacrylate
waterproof
concrete
mortar
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KR19980076357A (en
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신범수
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신범수
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • C04B41/522Multiple coatings, for one of the coatings of which at least one alternative is described
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/49Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
    • C04B41/4905Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
    • C04B41/4922Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as monomers, i.e. as organosilanes RnSiX4-n, e.g. alkyltrialkoxysilane, dialkyldialkoxysilane
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5098Cermets
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/64Insulation or other protection; Elements or use of specified material therefor for making damp-proof; Protection against corrosion
    • E04B1/644Damp-proof courses
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials

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  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
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  • Organic Chemistry (AREA)
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  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
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  • Civil Engineering (AREA)
  • Building Environments (AREA)

Abstract

본 발명은 콘크리트 건축물의 결로 방지 처리법에 관한 것으로, 이 방법은 피방수층인 콘크리트 또는 몰탈의 표면에 실리콘 에멀젼을 도포하여 피방수층의 표면 내부에 방수씰링층(Sealing layer)를 형성하는 단계; 방수씰링층이 형성된 피방수층의 표면에 시멘트계 컴파운드를 도포하여 도막방수층을 형성하는 단계; 물의 일부를 실리콘 에멀젼으로 치환하여 만든 몰탈을 상기 도막방수층 위에 미장하여 미장몰탈층을 형성하는 단계를 포함하여 이루어진다.The present invention relates to a method for preventing condensation of concrete buildings, the method comprising: applying a silicone emulsion on the surface of the concrete or mortar that is the waterproof layer to form a sealing layer (sealing layer) inside the surface of the waterproof layer; Forming a waterproof coating layer by applying a cement compound to the surface of the waterproof layer in which the waterproof sealing layer is formed; Plastering mortar formed by substituting a part of water with a silicone emulsion on the waterproof layer to form a mortar layer.

이 방법에 의하면, 별도의 보호벽을 쌓거나 단열재 시공을 하지 않고 방수시공과 마감 몰탈 미장만으로 결로 현상을 방지할 수 있음은 물론 시공이 간단하여 공기 단축, 원가 절감, 미장층의 들뜸 방지의 효과가 있다.According to this method, condensation can be prevented only by waterproofing and finishing mortar plastering without laying a separate protective wall or insulating material, and it is simple to install, which has the effect of shortening the air, reducing cost, and preventing lifting of the plaster layer. have.

Description

콘크리트 건축물의 결로 방지 처리법Condensation prevention method of concrete building

본 발명은 콘크리트 건축물의 결로 방지 처리법에 관한 것으로, 보다 상세하게는 콘크리트 건축물에 있어서 지하층, 베란다, 목욕탕, 수영장, 물탱크 저수조 및 폐수처리장 등에 적용될 수 있으며, 또한 지반침하, 구조적 응력에 의한 건축물의 균열 부위의 보수시에도 적용할 수 있는 콘크리트의 결로 방지 처리법에 관한 것이다.The present invention relates to a method for preventing condensation of concrete buildings, and more particularly, in concrete buildings, the present invention can be applied to underground floors, verandas, baths, swimming pools, water tank reservoirs, and wastewater treatment plants. The present invention relates to a method for preventing condensation of concrete that can be applied to repairing cracks.

종래에는 콘크리트 건축물의 경우, 일반적으로 지하층의 내벽에 결로 현상이 발생하는 것을 방지하기 위하여 콘크리트 벽체에 방수시공 한 후 벽체에 붙혀 또는 약 10∼20㎝ 정도 이격시켜 보호벽을 쌓고 미장 마감하거나, 또는 콘크리트 벽체에 방수시공과 미장마감한 후 그 위에 별도의 단열재 시공하였다.Conventionally, in the case of concrete buildings, in order to prevent condensation from occurring on the inner wall of the basement layer, after waterproofing the concrete walls, they are attached to the walls or spaced about 10 to 20 cm apart to build a protective wall and finish plastering, or concrete After waterproofing and plastering on the walls, a separate insulation was constructed on it.

그러나 단열재를 시공하는 방법은 인접한 단열재 사이에서 결로 현상이 발생하는 단점이 있으며, 별도로 보호벽을 쌓는 방법은 실내 면적이 줄어들고 시공 비용이 증가하는 문제점을 갖고 있다.However, the method of constructing the insulation has the disadvantage that the condensation occurs between the adjacent insulation, the method of building a separate protective wall has a problem that the interior area is reduced and the construction cost increases.

본 발명은 상기한 종래 기술의 문제점을 해결하기 위한 것으로, 그 목적은 별도의 보호벽을 쌓거나 단열재 시공을 하지 않고 방수시공과 마감 몰탈미장 만으로 결로 현상을 방지할 수 있음은 물론 동시에 시공이 간단하여 공기 단축, 원가 절감, 미장층의 들뜸 방지의 효과를 갖는 콘크리트 건축물의 결로 방지 처리법를 제공하는 데에 있다.The present invention is to solve the above problems of the prior art, the purpose of which is to prevent condensation only by waterproofing and finishing mortar plastering without a separate protective wall or insulating material construction, and at the same time simple construction It is to provide a condensation prevention treatment method of concrete building having the effect of shortening the air, reducing the cost, and preventing the lifting of the plaster layer.

도 1 은 본 발명에 따른 콘크리트 건축물의 결로 방지 처리 후의 단면도.1 is a cross-sectional view after the condensation prevention treatment of a concrete building according to the present invention.

* 도면의 주요 부분에 대한 부호의 설명 *Explanation of symbols on the main parts of the drawings

10: 콘크리트 모체 12: 방수씰링층10: concrete matrix 12: waterproof sealing layer

20: 도막방수층 30: 미장몰탈층20: waterproofing layer 30: plaster mortar layer

본 발명의 목적을 달성하기 위한 콘크리트 건축물의 결로 방지 처리법은,Condensation prevention treatment method of a concrete building for achieving the object of the present invention,

피방수층인 콘크리트 또는 몰탈의 표면에 실리콘 에멀젼을 도포하여 피방수층의 표면 내부에 방수씰링층(Sealing layer)를 형성하는 단계;Forming a waterproof sealing layer inside the surface of the waterproof layer by applying a silicone emulsion on a surface of concrete or mortar that is the waterproof layer;

방수씰링층이 형성된 피방수층의 표면에 시멘트계 컴파운드를 도포하여 도막방수층을 형성하는 단계; 및,Forming a waterproof coating layer by applying a cement compound to the surface of the waterproof layer in which the waterproof sealing layer is formed; And,

물의 일부를 실리콘 에멀젼으로 치환하여 만든 몰탈을 상기 도막방수층 위에 미장하여 미장몰탈층을 형성하는 단계를 포함하여 구성된 데에 그 특징이 있다.Plasma mortar made by substituting a part of water with a silicone emulsion is formed on the coating layer to form a mortar layer.

본 발명을 보다 구체적으로 설명한다.The present invention will be described in more detail.

먼저 결로 방지 처리를 하고자 하는 콘크리트 구조물의 내벽(철근 콘크리트, 무근 콘크리트 등)이나 시멘트 몰탈(피방수층)의 표면에 실리콘 에멀젼을 분사 도포시키면 피방수층의 표면에서 내부로 실리콘에멀젼이 흡착, 침투되면서 자연 건조되어 최고 15㎜ 두께로 방수씰링층이 형성된다.First, spray silicone coating on the inner wall (reinforced concrete, unreinforced concrete, etc.) or cement mortar (surface of waterproof layer) of concrete structure to prevent condensation. It is dried to form a waterproof sealing layer up to 15 mm thick.

여기서 방수씰링층 형성에 사용되는 실리콘 에멀젼은 하기 식1로 표시되는 실란 100중량부와, 콜로이드실리카 2∼20중량부, 바람직하게는 5∼10중량부, 유화제 2∼40중량부, 알코올 5∼20중량부 및 물로 조성된 것이며, 각 성분을 구체적으로 설명하면 다음과 같다.Here, the silicone emulsion used for forming the waterproof sealing layer is 100 parts by weight of the silane represented by the following formula 1, 2 to 20 parts by weight of colloidal silica, preferably 5 to 10 parts by weight, emulsifier 2 to 40 parts by weight, alcohol 5 to It is composed of 20 parts by weight and water, and each component will be described in detail as follows.

[식 1][Equation 1]

Figure kpo00001
Figure kpo00001

상기 식 1에서, R은 탄소원자가 2∼17개인 하이드로카복실 그룹이고, R'는 가수분해성 그룹이며, n은 1 또는 2 이다.In Formula 1, R is a hydrocarboxyl group having 2 to 17 carbon atoms, R 'is a hydrolyzable group, and n is 1 or 2.

구체적으로, 상기 실란으로는 에틸트리에톡시실란, 에틸트리메톡시실란, 에틸트리-n-프로폭시실란, 프로필트리에톡시실란, 트로필트리디메틸아미노실란, 부틸트리에톡시실란, 부틸트리메톡시실란, 이소부틸에톡시실란, 이소부틸트리메톡시실란, 이소부틸트리아세톡시실란, n-헥실트리메톡시실란, 비닐트리에톡시실란, 페닐트리메톡시실란, 옥틸트리메톡시실란, 옥틸메틸디이소프로폭시실란, 라우릴트리메톡시실란, 2-에틸헥실트리메톡시실란, 데실트리에톡시실란, 도데실트리브로모실란, 테트라데실트리에톡시실란, 헥사데실트리에톡시실란, 옥타데실트리에톡시실란 등이 있으며, 이는 단량체 단독으로 또는 이들의 이량체, 삼량체 및 올리고머와 혼합하여 사용할 수 있다. 특히, 단량체의 분자량이 150∼500 인 것을 사용하는 것이 좋다.Specifically, the silane may be ethyltriethoxysilane, ethyltrimethoxysilane, ethyltri-n-propoxysilane, propyltriethoxysilane, trophyltridimethylaminosilane, butyltriethoxysilane, butyltrimeth Oxysilane, isobutylethoxysilane, isobutyltrimethoxysilane, isobutyltriacetoxysilane, n-hexyltrimethoxysilane, vinyltriethoxysilane, phenyltrimethoxysilane, octyltrimethoxysilane, octyl Methyldiisopropoxysilane, lauryltrimethoxysilane, 2-ethylhexyltrimethoxysilane, decyltriethoxysilane, dodecyltribromosilane, tetradecyltriethoxysilane, hexadecyltriethoxysilane, octadecyl Triethoxysilane and the like, which may be used alone or in combination with dimers, trimers and oligomers thereof. In particular, it is good to use the thing whose molecular weight of a monomer is 150-500.

상기 콜로이드실리카는 pH가 8∼11이고, SiO2의 함량이 20% 이하인 실리카졸을 사용하는 것이 좋으며, 시판되고 있는 제품으로 날콕 1115, 2326 (날코케미칼사 제품), 니아콜 215 (니아콜사 제품), 스노텍스 20 (닛산 케미칼사 제품), 시톤 W15 (몬산토사 제품) 등을 사용할 수 있다.The colloidal silica is preferably a silica sol having a pH of 8 to 11, the SiO 2 content of 20% or less, and commercially available products such as Nalkok 1115, 2326 (manufactured by Nalco Chemical), Niacol 215 (manufactured by Niacol) ), Snowtex 20 (manufactured by Nissan Chemical), and Shiton W15 (manufactured by Monsanto).

상기 유화제로는 폴리옥시프로필렌매니톨디올레이트, 폴리옥시에틸렌솔비톨올레이트, 폴리옥시에틸렌스테아레이트, 솔비탄모노스테아레이트, 솔비탄모노올레이트, 글리세롤모노스테아레이트, 폴리옥시에틸렌솔비톨헥사스테아레이트, 솔비탄트리스테아레이트, 솔비탄트리올레이트로 구성된 솔비탄지방산에스테르류, 지방산글리세라이드류, 폴리옥시에틸렌알코올류 및 폴리옥시에틸렌솔비탄지방산에스테르류로부터 선택된 비이온계 유화제를 1종 이상을 혼합하여 사용한다. 또한 비이온계 유화제에 폴리하이드록시 화합물을 첨가 사용하면 더욱 좋다.The emulsifiers include polyoxypropylene mannitol dioleate, polyoxyethylene sorbitol oleate, polyoxyethylene stearate, sorbitan monostearate, sorbitan monooleate, glycerol monostearate, polyoxyethylene sorbitol hexastearate, One or more nonionic emulsifiers selected from sorbitan fatty acid esters composed of sorbitan tristearate and sorbitan trioleate, fatty acid glycerides, polyoxyethylene alcohols, and polyoxyethylene sorbitan fatty acid esters Use it. Moreover, it is more preferable to add and use a polyhydroxy compound to a nonionic emulsifier.

상기 알코올로는 탄소원자가 4∼12개이고, 수소결합력이 강하며, 용해성 파라미터값이 9∼16인 것을 사용하는 것이 좋으며, 이로는 메탄올, 에탄올, n-부탄올, 이소프로판올, 2-에톡시에올 t-부탄올, 2-에틸헥산올, 이소아밀알코올, n-옥틸알코올, 2-에틸부탄올, n-헥산올, n-아밀알코올, 시클로헥산올, n-프로판올, 벤질알코올 등이 있다.The alcohol is preferably 4 to 12 carbon atoms, a strong hydrogen bonding force, and a solubility parameter of 9 to 16, which is methanol, ethanol, n-butanol, isopropanol, 2-ethoxyethanol t Butanol, 2-ethylhexanol, isoamyl alcohol, n-octyl alcohol, 2-ethylbutanol, n-hexanol, n-amyl alcohol, cyclohexanol, n-propanol, benzyl alcohol and the like.

또한 물로는 지하수, 수돗물 , 빗물 등을 사용할 수 있으나, 이들에 함유된 불순물에 의해 실리콘 에멀젼의 저장안정성이 떨어지게 되므로 증류수를 사용하는 것이 가장 좋다.In addition, ground water, tap water, rainwater, etc. may be used as water, but distilled water is best used because the storage stability of the silicone emulsion is deteriorated by impurities contained therein.

다음, 방수씰링층이 형성된 콘크리트 모체의 표면에 중도 또는 상도로 시멘트계 컴파운드를 분사 도포 또는 브러쉬 도장하여 건조 후 두께가 최고 3㎜인 무기질 도막방수층을 형성한다.Next, a spray coating or brush coating is applied to the surface of the concrete matrix on which the watertight sealing layer is formed, in an intermediate or upper degree, to form an inorganic coating waterproof layer having a thickness of up to 3 mm after drying.

이와 같이 형성한 도막방수층은 방수의 역할을 할 뿐만 아니라 그 위에 도포되는 몰탈미장층과의 계면접착력이 우수하여 피방수층 표면이 잘 건조되지 않았거나 평활도가 불량하더라도 시공불량, 피방수층의 표면과 방수층간 접착불량(계면 접착력 부족, 방수층의 들뜸 및 파손 등)이 발생할 염려가 없다.The coating layer formed in this way not only plays a role of waterproofing but also has excellent interfacial adhesion with the mortar plastering layer applied thereon, even if the surface of the waterproof layer is poorly dried or poor in smoothness. There is no fear of poor adhesion between layers (lack of interfacial adhesion, lifting and breakage of waterproof layer).

상기 도막방수층 형성에 사용되는 시멘트계 컴파운드는 아크릴에멀젼 단독으로 또는 아크릴에멀젼에 스티렌 부타디엔 고무 라텍스, 아크릴로니트릴 부타디엔 고무 라텍스, 클로로프렌 고무 라텍스로 구성된 고무계 라텍스 1종 이상을 100 : 20∼300 중량부로 혼합한 후 쏘로씰(쏘로 시스템사 제품)과 5∼50 : 100 중량부로 혼합하거나, 또는 아크릴에멀젼과 시멘트 단독 또는 소석회와 혼합한 것을 10∼30 : 100 중량부로 혼합한 후 여기에 점도 조절을 위하여 일정량의 물을 가하여 만든 것을 사용한다.The cement compound used for forming the waterproofing layer of the coating layer is 100: 20 to 300 parts by weight of at least one rubber latex composed of styrene butadiene rubber latex, acrylonitrile butadiene rubber latex, and chloroprene rubber latex alone or in an acrylic emulsion. After mixing with Soro Seal (Soro System Co., Ltd.) 5 to 50: 100 parts by weight, or mixed with an acrylic emulsion and cement alone or calcined with 10 to 30: 100 parts by weight of a certain amount to adjust the viscosity Use something made by adding water.

상기 아크릴에멀젼은 아크릴레이트류 모노머 100 중량부에 음이온 유화제 0.6∼30 중량부, 반응개시제 0.1∼1 중량부를 혼합한 후 상온∼200℃의 온도에서 30분 내지 24시간 중합반응시켜 제조한 것이다.The acrylic emulsion is prepared by mixing an acrylic emulsifier 0.6-30 parts by weight and a reaction initiator 0.1-1 part by weight with 100 parts by weight of an acrylate monomer and then polymerizing the reaction at a temperature of room temperature to 200 ° C for 30 minutes to 24 hours.

여기서 아크릴 모노머로는 메틸메타크릴레이트, 에틸메타크릴레이트, 이소프로필메타크릴레이트, n-부틸메타크릴레이트, 이소부틸메타크릴레이트, n-헥실메타크릴레이트, 라우릴메타크릴레이트, 2-하이드록시에틸메타크릴레이트, 하이드록시프로필메타크릴레이트, 글리시딜메타크릴레이트, 에틸아크릴레이트, 이소프로필아크릴레이트, n-부틸아크릴레이트, 2-에틸헥실아크릴레이트를 단독 또는 2종 이상 혼합하여 사용한다.Herein, the acrylic monomers include methyl methacrylate, ethyl methacrylate, isopropyl methacrylate, n-butyl methacrylate, isobutyl methacrylate, n-hexyl methacrylate, lauryl methacrylate and 2-hydride. Oxyethyl methacrylate, hydroxypropyl methacrylate, glycidyl methacrylate, ethyl acrylate, isopropyl acrylate, n-butyl acrylate, 2-ethylhexyl acrylate do.

유화제로는 도데실메틸암모늄브로마이드, 헥사데실트리메틸암모늄브로마이드, 도데실피리디움클로라이드, 도데실하이드로클로라이드를 단독 또는 2종 이상 혼합하여 사용한다.As an emulsifier, dodecyl methyl ammonium bromide, hexadecyl trimethyl ammonium bromide, dodecyl pyridium chloride, and dodecyl hydrochloride are used individually or in mixture of 2 or more types.

개시제로는 2,2-아조비스(2-아미디프로판)디하이드로클로라이드, 2,2-아조비스이소부티로니트릴, 2-터셔리부틸아조-2-시아노프로판, 2-터셔리부틸아조-2-시아노부탄, 2-터셔리부틸아조-2-시아노-4-메틸펜탄, 큐밀퍼옥사이드네오데카노에이트, 터셔리부틸퍼옥시-2-에틸헥사노에이트 등이 사용될 수 있다.Initiators include 2,2-azobis (2-amidipropane) dihydrochloride, 2,2-azobisisobutyronitrile, 2-tert-butyl azo-2-cyanopropane, 2-tert-butyl azo 2-cyanobutane, 2-tert-butyl azo-2-cyano-4-methylpentane, cumyl peroxide neodecanoate, tert-butyl peroxy-2-ethylhexanoate and the like can be used.

다음 상기 도막방수층 위에 단열 특성과 결로 방지 특성을 겸비하는 몰탈미장층을 최고 30㎜ 두께로 형성한다. 몰탈미장층은 종래의 몰탈 배합에서 물의 일부 즉, 5∼50%를 실리콘 에멀젼으로 치환한 것으로, 미장 마감 후 충분히 건조되면 물을 흡수 또는 투수하지 않게됨은 물론 단열 특성과 결로 방지 특성을 갖게 된다.Next, a mortar plastering layer having a heat insulating property and a condensation preventing property is formed on the coating film waterproof layer to a thickness of up to 30 mm. Mortar plastering layer is a part of the water in the conventional mortar mix, that is, 5 to 50% by replacing with a silicone emulsion, and when sufficiently dried after plastering will not absorb or permeate the water, as well as having heat insulating properties and condensation prevention properties.

이하, 도 1에 나타낸 바와 같이 콘크리트 모체(10)의 표면에 방수씰링층(12)을 형성하고, 그 위에 도막방수층(20) 및 몰탈미장층(30)을 형성하여서 되는 본 발명에 따른 콘크리트의 결로 방지 시공법을 실시예를 통해 상세하게 설명하고자 한다.Hereinafter, as shown in FIG. 1, the waterproof sealing layer 12 is formed on the surface of the concrete matrix 10, and the waterproofing layer 20 and the mortar plastering layer 30 are formed thereon. The condensation prevention construction method will be described in detail by examples.

[실시예 1]Example 1

먼저 콜로이드실리카로서 날콕 1115 (날코케미칼사 제품) 5g과 2-에톡시에탄올 7g 및 n-부탄올 5g을 춘분히 혼합한 다음, 2-에틸헥실트리에톡시실란 100g을 서서히 가하여 교반하고 나서 폴리옥시에틸렌솔비톨올레이트 20g을 첨가 교반한 후 증류수 360g을 넣고 희석하여 안정된 우유빛 실리콘 에멀젼을 얻었다.First, 5 g of Nalcock 1115 (manufactured by Nalco Chemical Co., Ltd.), 7 g of 2-ethoxyethanol and 5 g of n-butanol are mixed as a colloidal silica. Then, 100 g of 2-ethylhexyltriethoxysilane is gradually added to the mixture, followed by stirring. After stirring and adding 20 g of sorbitol oleate, 360 g of distilled water was added thereto and diluted to obtain a stable milky silicone emulsion.

그리고 에틸메타크릴레이트 70g과 2-하이드록시에틸메타크릴레이트 30g에 유화제로 도데실메틸암모늄브로마이드 2.9g을 넣고 물 230g으로 유화분산시킨 다음 여기에 반응개시제로 2,2-아조비스(2-아미디프로판)디하이드로콜로라이드 0.08g을 주입하고 3시간 동안 중합시켜 우유빛 아크릴에멀젼을 얻었다. 다음 이 아크릴 에멀젼 120g, 쏘로씰 (쏘로시스템사 제품) 1㎏, 물 360g을 혼합 교반하여 시멘트계 컴파운드를 제조하였다.Then, 70 g of ethyl methacrylate and 30 g of 2-hydroxyethyl methacrylate were added 2.9 g of dodecylmethylammonium bromide as an emulsifier, followed by emulsification and dispersion with 230 g of water, followed by 2,2-azobis (2-azo) as a reaction initiator. 0.08 g of midipropane) dihydrocollide was injected and polymerized for 3 hours to give a milky acrylic emulsion. Next, 120 g of this acrylic emulsion, 1 kg of Soro Seal (manufactured by Soro System Co., Ltd.), and 360 g of water were mixed and stirred to prepare a cement compound.

시멘트 벽돌(190×90×55㎜)과 동일 크기의 콘크리트 시료 표면에 상기에서 얻은 실리콘 에멀젼을 도포하고 우유빛이 없어진 후 시멘트계 컴파운드를 브러쉬를 사용하여 1㎜의 두께로 2회 도포하였다. 그리고 상온에서 2시간 경과 후 포틀란트시멘트 : 모래 : 물 : 실리콘에멀젼을 1 : 3 : 0.6 : 0.4의 부피비로 혼합한 몰탈을 두께 12㎜로 미장 마감하고, 72시간 건조시켜 시료를 준비하였다.The silicone emulsion obtained above was applied to the surface of the concrete sample of the same size as the cement brick (190 × 90 × 55 mm), and after the milky color disappeared, the cement compound was applied twice with a thickness of 1 mm using a brush. After 2 hours at room temperature, a mortar mixed with a volume of cement, sand, water, and silicone emulsion in a volume ratio of 1: 3: 0.6: 0.4 was plastered to a thickness of 12 mm and dried for 72 hours to prepare a sample.

다음 시료의 한쪽면을 컷팅하여 물속에 72시간 침지시킨 후 꺼내어 물의 침투 여부를 관찰하여 보았더니, 방수씰링층과 도막방수층으로 격리된 몰탈미장층에는 물이 스며들지 못했으며, 컷팅면을 통해 그 외의 부분에는 물이 스며들었다.After cutting one side of the sample and immersing it in water for 72 hours, it was taken out and observed for water penetration. When the mortar plaster layer separated by the waterproof sealing layer and the waterproof layer was not penetrated by water, the surface was cut through the cutting surface. The other part water soaked.

[실시예 2]Example 2

포틀란트 시멘트 879g과 소석회 130g을 실시예 1에서 얻은 아크릴 에멀젼 145g 및 물 360g과 함께 교반하여 얻은 시멘트계 컴파운드를 사용한 것 이외에는 실시예 1과 같은 방법으로 시료를 만들어 침지시험을 실시하였다. 그 결과는 실시예 1 과 비슷하였다.A sample was prepared and immersed in the same manner as in Example 1 except that 879 g of Portland cement and 130 g of slaked lime were used together with the cement compound obtained by stirring together with 145 g of the acrylic emulsion obtained in Example 1 and 360 g of water. The result was similar to that of Example 1.

[실시예 3]Example 3

건축물 지하 3층 벽체에 다음과 같이 세로 3m, 높이 4.2m의 넓이에 실시예 1과 같은 방법으로 결로 방지 처리하고, 또한 종래 방법인 시멘트 액체방수 C종/몰탈미장으로 시공한 후 하절기 약 120㎜ 비가 온 후 외기온도 26℃에서, 그리고 동절기 외부온도 -18℃에서 시공부위 벽체의 결로현상 여부를 비교 관찰하였다. 이때 전자는 벽체에 전혀 결로현상이 나타나지 않았는데 반해, 후자는 벽체에 물방울이 맺히면서 바닥으로 흘러내리는 결로현상이 심하게 나타났다.Condensation prevention treatment is performed on the 3rd floor of the building below 3m in height and 4.2m in height by the same method as in Example 1, and it is applied to cement liquid waterproofing Class C / Mortal plastering in the same way as in Example 1, and then it is about 120mm in summer. After rain, we observed the condensation of wall at 26 ℃ and outside temperature at -18 ℃ in winter. At the time, the former had no condensation on the wall, while the latter had condensation on the wall, causing water to condense to the floor.

[실시예 4]Example 4

실시예 1에서 제조한 실리콘 에멀젼을 그대로 사용하고, 시멘트계 컴파운드로는 쏘로씰 1㎏, 아크릴에멀젼 60g, SBR 라텍스 2108 (일본 JSR사 제품) 60g과 물 340g을 혼합하여 사용한 것 이외에는 상기 실시예 3과 같은 방법으로 결로현상을 관찰하였는 바, 결로현상 여부는 실시예 3과 같았다.The silicone emulsion prepared in Example 1 was used as it was, except that cement compound was used by mixing 1 kg of sawo seal, 60 g of acrylic emulsion, 60 g of SBR latex 2108 (manufactured by JSR Japan) and 340 g of water. Condensation was observed in the same manner, and condensation was the same as in Example 3.

[실시예 5]Example 5

옥틸트리에톡시실란 100g에 폴리옥시에틸렌모노올레이트 18g과 물 365g을 가하여 유화 분산시킨 다음, n-부탄올 5g과 n-옥틸알코올 5g을 넣고 충분히 혼합하고 나서 콜로이드실리카로 니아콜 215 (니아콜사 제품) 10g을 첨가 교반하여 우유빛 실리콘 에멀젼을 얻었다.18 g of polyoxyethylene monooleate and 365 g of water were added to 100 g of octyl triethoxysilane, and then emulsified and dispersed. Then, 5 g of n-butanol and 5 g of n-octyl alcohol were mixed and mixed sufficiently, followed by colloidal silica niacol 215 (manufactured by Niacol Corporation). 10 g) was added and stirred to obtain a milky silicone emulsion.

그리고 에틸메타크릴레이트 65g과 2-에틸헥실아크릴레이트 35g에 유화제로서 도데실하이드로클로라이드 2.6g을 넣고 220g의 물로 유화분산시킨 다음 반응개시제로 2-터셔리부틸아조-2-시아노프로판 0.2g을 첨가하여 3시간 동안 중합시킨 후 우유빛 아크릴 에멀젼을 얻었다. 그런 다음, 상기 아크릴 에멀젼 120g, 쏘로씰 1㎏ 및 물 360g을 넣고 교반하여 시멘트계 컴파운드를 제조하였다.Then, 65 g of ethyl methacrylate and 35 g of 2-ethylhexyl acrylate were added 2.6 g of dodecyl hydrochloride as an emulsifier, followed by emulsification and dispersion with 220 g of water, followed by 0.2 g of 2-tert-butylbutyl azo-2-cyanopropane as a reaction initiator. After addition and polymerization for 3 hours, a milky acrylic emulsion was obtained. Then, 120 g of the acrylic emulsion, 1 kg of sawo seals, and 360 g of water were added thereto to prepare a cement compound.

다음 실시예 1과 같은 방법으로 시료를 만들어 관찰하였는 바, 실리콘 에멀젼에 의한 방수씰링층의 두께가 벽돌인 경우 10㎜, 콘크리트인 경우 2.5㎜로 얇게 형성되었으나 실시예 1의 시료와 동일한 특성을 나타냈다.As a result of making the sample in the same manner as in Example 1, the thickness of the waterproof sealing layer by the silicone emulsion was thinly formed to 10 mm in case of brick and 2.5 mm in case of concrete, but showed the same characteristics as the sample of Example 1. .

[실시예 6]Example 6

실시예 5에서 제조한 실리콘 에멀젼과 시멘트계 컴파운드를 사용하여 실시예 3과 같이 시공하여 결로현상을 비교 관찰하였는 바, 실시예 3의 결과가 같았다.Using the silicone emulsion prepared in Example 5 and the cement-based compound as in Example 3 was compared to observe the condensation phenomenon, the results of Example 3 were the same.

이상에서 상세히 설명한 바와 같이, 본 발명은 별도의 보호벽을 쌓거나 단열재 시공을 하지 않고도 피방수층인 콘크리트 모체에 방수씰링층을 형성하고 그 위에 방수시공과 마감 몰탈 미장만을 하여 결로 현상을 완벽히 방지할 수 있음은 물론 동시에 시공이 간단하여 공기 단축, 원가 절감, 미장층의 들뜸 방지의 효과를 갖는다.As described in detail above, the present invention can completely prevent condensation by forming a waterproof sealing layer on the concrete matrix, which is the waterproof layer, and only waterproofing and finishing mortar plastering thereon without stacking a separate protective wall or installing insulation. At the same time, the construction is simple, which has the effect of shortening the air, reducing the cost, and preventing lifting of the plaster layer.

Claims (10)

피방수층인 콘크리트 또는 몰탈의 표면에 실리콘 에멀젼을 도포하여 피방수층의 표면 내부에 방수씰링층(Sealing layer)를 형성하는 단계;Forming a waterproof sealing layer inside the surface of the waterproof layer by applying a silicone emulsion on a surface of concrete or mortar that is the waterproof layer; 방수씰링층이 형성된 피방수층의 표면에 시멘트계 컴파운드를 도포하여 도막방수층을 형성하는 단계; 및,Forming a waterproof coating layer by applying a cement compound to the surface of the waterproof layer in which the waterproof sealing layer is formed; And, 물의 일부를 실리콘 에멀젼으로 치환하여 만든 몰탈을 도막방수층의 상부에 미장하여 미장몰탈층을 형성하는 단계;Plastering mortar formed by substituting a part of water with a silicone emulsion on top of the coating layer to form a mortar layer; 를 포함하는 콘크리트 건축물의 결로 방지 처리법.Condensation prevention method of concrete building comprising a. 제 1 항에 있어서, 상기 실리콘 에멀젼은 실란 100중량부, 콜로이드실리카 2∼20중량부, 유화제 2∼30중량부, 알코올 5∼20 중량부 및 물로 조성된 것임을 특징으로 하는 콘크리트 건축물의 결로 방지 처리법.The method of claim 1, wherein the silicone emulsion is composed of 100 parts by weight of silane, 2 to 20 parts by weight of colloidal silica, 2 to 30 parts by weight of emulsifier, 5 to 20 parts by weight of alcohol, and water. . 제 2 항에 있어서, 상기 실란은 하기 식으로 표현되는 것임을 특징으로 하는 콘크리트 건축물의 결로 방지 처리법.The method of claim 2, wherein the silane is represented by the following formula. [식][expression]
Figure kpo00002
Figure kpo00002
(상기 식에서, R은 탄소원자가 2∼17개인 하이드로카복실 그룹이고, R'는 가수분해성 그룹이며, n은 1 또는 2 이다.)(Wherein R is a hydrocarboxyl group having 2 to 17 carbon atoms, R 'is a hydrolyzable group and n is 1 or 2)
제 3 항에 있어서, 상기 실란은 에틸트리에톡시실란, 에틸트리메톡시실란, 에틸트리-n-프로폭시실란, 프로필트리에톡시실란, 트로필트리디메틸아미노실란, 부틸트리에톡시실란, 부틸트리메톡시실란, 이소부틸에톡시실란, 이소부틸트리메톡시실란, 이소부틸트리아세톡시실란, n-헥실트리메톡시실란, 비닐트리에톡시실란, 페닐트리메톡시실란, 옥틸트리메톡시실란, 옥틸메틸디이소프로폭시실란, 라우릴트리메톡시실란, 2-에틸헥실트리메톡시실란, 데실트리에톡시실란, 도데실트리브로모실란, 테트라데실트리에톡시실란, 헥사데실트리에톡시실란, 옥타데실트리에톡시실란, 이들의 이량체, 삼량체 및 올리고머로부터 선택된 1종 이상인 것을 특징으로 하는 콘크리트 건축물의 결로 방지 처리법.4. The silane according to claim 3, wherein the silane is ethyltriethoxysilane, ethyltrimethoxysilane, ethyltri-n-propoxysilane, propyltriethoxysilane, trophyltridimethylaminosilane, butyltriethoxysilane, butyl Trimethoxysilane, isobutylethoxysilane, isobutyltrimethoxysilane, isobutyltriacetoxysilane, n-hexyltrimethoxysilane, vinyltriethoxysilane, phenyltrimethoxysilane, octyltrimethoxysilane , Octylmethyldiisopropoxysilane, lauryltrimethoxysilane, 2-ethylhexyltrimethoxysilane, decyltriethoxysilane, dodecyltribromosilane, tetradecyltriethoxysilane, hexadecyltriethoxysilane, An octadecyltriethoxysilane, at least one selected from dimers, trimers and oligomers thereof, for preventing condensation in concrete buildings. 제 2 항에 있어서, 상기 콜로이드실리카는 pH가 8∼11이고, SiO2함량이 20% 이하인 실리카졸인 것을 특징으로 하는 콘크리트 건축물의 결로 방지 처리법.The method of claim 2, wherein the colloidal silica is a silica sol having a pH of 8 to 11, SiO 2 content of 20% or less. 제 2 항에 있어서, 상기 유화제는 폴리옥시프로필렌매니톨디올레이트, 폴리옥시에틸렌솔비톨올레이트, 폴리옥시에틸렌스테아레이트, 솔비탄모노스테아레이트, 솔비탄모노올레이트, 글리세롤모노스테아레이트, 폴리옥시에틸렌솔비톨헥사스테아레이트, 솔비탄트리스테아레이트, 솔비탄트리올레이트으로 구성된 솔비탄지방산에스테르류, 지방산글리세라이드류, 폴리옥시에틸렌알코올류 및 폴리옥시에틸렌솔비탄지방산에스테르류로부터 선택된 1종 이상인 것을 특징으로 하는 콘크리트 건축물의 결로 방지 처리법.The method of claim 2, wherein the emulsifier is polyoxypropylene manitol dioleate, polyoxyethylene sorbitol oleate, polyoxyethylene stearate, sorbitan monostearate, sorbitan monooleate, glycerol monostearate, polyoxyethylene At least one selected from sorbitan fatty acid esters composed of sorbitol hexastearate, sorbitan tristearate, and sorbitan trioleate, fatty acid glycerides, polyoxyethylene alcohols, and polyoxyethylene sorbitan fatty acid esters Condensation prevention treatment method of concrete building to assume. 제 2 항에 있어서, 상기 알코올은 탄소원자가 4∼12개이고, 용해성 파라미터값이 9∼16인 것을 특징으로 하는 콘크리트 건축물의 결로 방지 처리법.The condensation prevention treatment method for a concrete building according to claim 2, wherein the alcohol has 4 to 12 carbon atoms and a solubility parameter value of 9 to 16. 제 1 항에 있어서, 상기 시멘트계 컴파운드는 아크릴에멀젼 단독 또는 스티렌 부타디엔 고무 라텍스, 아크릴로니트릴 부타디엔 고무, 클로로프렌 고무 라텍스로 구성된 고무계 라텍스 1종 이상을 혼합한 결과 쏘로씰을 혼합한 다음 일정량의 물을 가하여 만든 것임을 특징으로 하는 콘크리트 건축물의 결로 방지 처리법.The method of claim 1, wherein the cement compound is a mixture of acryl emulsion alone or at least one rubber latex consisting of styrene butadiene rubber latex, acrylonitrile butadiene rubber, chloroprene rubber latex mixed with the sawo seals and then a predetermined amount of water Condensation prevention treatment method of concrete building characterized in that it is made. 제 1 항에 있어서, 상기 시멘트계 컴파운드는 아크릴에멀젼에 시멘트 단독 또는 소석회와 함께 혼합한 후 물을 가하여 만든 것임을 특징으로 하는 콘크리트 건축물의 결로 방지 처리법.The method of claim 1, wherein the cement compound is mixed with cement alone or with slaked lime and then added to water in an acrylic emulsion. 제 8 항과 제 9 항 중 어느 한 항에 있어서, 상기 아크릴에멀젼은 메틸메타크릴레이트, 에틸메타크릴레이트, 이소프로필메타크릴레이트, n-부틸메타크릴레이트, 이소부틸메타크릴레이트, n-헥실메타크릴레이트, 라우릴메타크릴레이트, 2-하이드록시에틸메타크릴레이트, 하이드록시프로필메타크릴레이트, 글리시딜메타크릴레이트, 에틸아므릴레이트, 이소프로필아크릴레이트, n-부틸아크릴레이트, 2-에틸헥실아크릴레이트로 구성된 아크릴레이트류 모노머 1종 이상과, 도데실메틸암모늄브로마이드, 헥사데실트리메틸암모늄브로마이드, 도데실피리디움클로라이드, 도데실하이드로클로라이드로 구성된 음이온 유화제 1종 이상과, 그리고 2,2-아조비스(2-아미디프로판)디하이드로클로라이드, 2,2-아조비스이소부티로니트릴, 2-터셔리부틸아조-2-시아노프로판, 2-터셔리부틸아조-2-시아노부탄, 2-터셔리부틸아조-2-시아노-4-메틸펜탄, 큐밀퍼옥사이드네오데카노에이트, 터셔리부틸퍼옥시-2-에틸헥사노에이트로 구성된 반응개시제 1종 이상을 혼합하여 중합반응시킨 것임을 특징으로 하는 특징으로 하는 콘크리트의 결로 방지 처리법.10. The method of claim 8 or 9, wherein the acrylic emulsion is methyl methacrylate, ethyl methacrylate, isopropyl methacrylate, n-butyl methacrylate, isobutyl methacrylate, n-hexyl Methacrylate, lauryl methacrylate, 2-hydroxyethyl methacrylate, hydroxypropyl methacrylate, glycidyl methacrylate, ethyl amethacrylate, isopropyl acrylate, n-butyl acrylate, 2 At least one acrylate monomer composed of ethylhexyl acrylate, at least one anionic emulsifier composed of dodecylmethylammonium bromide, hexadecyltrimethylammonium bromide, dodecylpyridium chloride, dodecylhydrochloride, and 2, 2-azobis (2-amidipropane) dihydrochloride, 2,2-azobisisobutyronitrile, 2-tertiarybutylazo-2-cyanoprop , 2-tert-butyl azo-2-cyanobutane, 2-tert-butyl azo-2-cyano-4-methylpentane, cumyl peroxide neodecanoate, tert-butyl peroxy-2-ethylhexano Condensation prevention treatment method of concrete, characterized in that the polymerization reaction by mixing at least one reaction initiator consisting of a.
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KR100406212B1 (en) * 2000-10-23 2003-11-19 중앙방수기업주식회사 Manufacturing method of aqueous acrylic compound for floor
KR100526418B1 (en) * 2002-03-14 2005-11-08 한국건설기술연구원 Concrete surface treatment method using inorganic repairing agent for concrete
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KR100394466B1 (en) * 2000-12-30 2003-08-09 주식회사 한화 Waterproofing Composition Having Permeation Mechanism, Method for Producing the Same, and Hybrid Waterproofing Construction Method Using the Same
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