KR0182656B1 - Method of manufacturing micro-organism contact filtration agent - Google Patents

Method of manufacturing micro-organism contact filtration agent Download PDF

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Publication number
KR0182656B1
KR0182656B1 KR1019960017867A KR19960017867A KR0182656B1 KR 0182656 B1 KR0182656 B1 KR 0182656B1 KR 1019960017867 A KR1019960017867 A KR 1019960017867A KR 19960017867 A KR19960017867 A KR 19960017867A KR 0182656 B1 KR0182656 B1 KR 0182656B1
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molding
producing
waste
present
molding die
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KR970074684A (en
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채범석
윤창진
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채범석
윤창진
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

본원 발명의 목적은 표면과 내면이 얼기설기한 섬유상 재질로 많은 공극이 형성되므로써 부재의 내부를 포함한 양측표면으로 혐기성 및 호기성 미생물이 잘 달라붙어 탈리되지 아니하고 성장할 수 있는 미생물 접촉여과제의 제조방법을 제공하는데 있다.SUMMARY OF THE INVENTION An object of the present invention is to provide a method for producing a microorganism contact filter which can grow without anaerobic and aerobic microorganisms sticking to both sides including the inside of a member by forming many voids with a fibrous material whose surface and inner surface are frozen. It is.

본원 발명의 다른 목적은 단일재료로 구성되므로 제조가 간단하고 강도가 커서 수명이 오래가는 미생물 접촉여과제의 제조방법을 제공하는데 있다.Another object of the present invention is to provide a method for producing a microbial contact filter which is simple in manufacture and has a long strength and thus has a long lifetime since it is composed of a single material.

상기한 목적을 달성하기 위한 본 발명 여과제의 제조방법은 곡물용 마대등의 폴리프로필렌(PP) 폐기물을 180℃∼300℃에서 용융시켜 덩어리로 형성하여 냉각시키는 공정과; 상기 용융된 폐 폴리프로필렌 덩어리를 직경 2∼15㎜로 파쇄하는 공정과; 상기 파쇄물을 스크류 압출기에 넣어 가열장치로 열을가해 초기 온도를 200℃∼300℃로 가열하여 밀어내면서 출구 온도가 45℃∼55℃로 유지하도록 압출하는 공정과; 상기 출구온도 조건의 압출물을 성형금형을 통과시켜 원하는 단면형상을 갖도록 성형하는 공정과; 상기 성형금형을 통과하는 성형물을 이송방향으로 잡아당겨 뽑아내므로써 다공성의 섬유상 조직으로 성형하는 인출공정과; 및 상기 연속적으로 인출되는 성형물을 일정길이로 절단하는 절단 공정과;를 포함하여 제조하는 것임을 특징으로 한다.Method for producing a filter medium of the present invention for achieving the above object is a step of melting polypropylene (PP) waste, such as grain sacks at 180 ℃ to 300 ℃ to form a lump to cool; Crushing the molten waste polypropylene mass to a diameter of 2 to 15 mm; Inserting the shredder into a screw extruder, applying heat to a heating device, and extruding the outlet temperature at 45 ° C. to 55 ° C. while heating and pushing out the initial temperature to 200 ° C. to 300 ° C .; Molding the extrudate under the exit temperature condition to have a desired cross-sectional shape by passing a molding die; A withdrawal process of forming a porous fibrous structure by pulling the molded product passing through the molding die in a conveying direction; And a cutting step of cutting the continuously drawn molding to a predetermined length.

Description

오·페수 정화처리용 미생물 접촉여과제의 제조방법Manufacturing method of microorganism contact filter for sewage treatment

제1도는 본 발명에 의해 제도된 오·폐수 정화처리용 미생물 접촉 여과제를 나타내는 도면.1 is a view showing a microbial contact filter for wastewater purification treatment according to the present invention.

제2도는 스크류 압출기에서의 성형과정을 나타내는 도면.2 is a view showing a molding process in a screw extruder.

제3도는 성형금형을 나타내는 도면.3 is a view showing a molding die.

제4도는 성형물의 인출로울러를 나타내는 도면.4 is a view showing a take-out roller of the molding.

* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

1 : 여과재 2 : 섬유상조직1: filter medium 2: fibrous structure

3 : 공간부 4 : 파쇄물3: space part 4: crushed material

5 : 압출기 6 : 호퍼5: extruder 6: hopper

7 : 스크류 8 : 가열장치7 screw 8 heating device

9 : 냉각장치 10 : 성형금형9: cooling device 10: molding mold

11,11' : 인출로울러11,11 ': Drawer roller

[산업상 이용분야][Industrial use]

본 발명은 오·폐수 정화처리를 위한 미생물 접촉여과제의 제조 방법에 관한 것이다.The present invention relates to a method for producing a microbial contact filter for waste water purification treatment.

[종래기술][Private Technology]

종래 호기성 및 혐기성 미생물의 생존공간을 제공하여 미생물로 하여금 각종 유기물을 분해하여 정화하는 미생물 접촉여과제로는 한국특허 공보 95-2547 호에 개재되어 있는 발명이 있다.As a microbial contact filter for providing a living space of aerobic and anaerobic microorganisms and decomposing and purifying various organic matters, there is an invention disclosed in Korean Patent Publication No. 95-2547.

상기 특허공보에 의한 선발명은 폐비닐(PE)과 같은 폐합성수지를 주재료로 하고 여기에 석분, 활성탄, 여과사등의 부재료를 일정비율로 혼합분쇄하고 이를 고온에서 용융하면서 불순물을 탄화시킨후 곧바로 C형 단면을 갖도록 압출냉각시켜 미생물 접촉여과제를 성형하는 것을 요지로 하고 있다.According to the patent publication, waste synthetic resins such as waste vinyl (PE) are used as the main material, mixed with the raw materials such as stone powder, activated carbon, and filtered sand at a predetermined ratio, and then melted at a high temperature to carbonize impurities and immediately after C is carbonized. The present invention is directed to forming a microbial contact filter by extrusion cooling to have a mold cross section.

상기한 발명에 의하면 압출성형시 부재료가 팽출하면서 여과제의 표면이 울퉁불퉁하게 형성되어 표면적이 증대되고 표면의 갈라짐이 형성되어 미생물의 흡착 및 생장이 용이하게 된다.According to the above invention, as the subsidiary material swells during extrusion molding, the surface of the filter medium is unevenly formed, so that the surface area is increased and surface cracks are formed to facilitate the adsorption and growth of microorganisms.

그러나 상기한 선발명에 의한 여과제는 종래 사용되던 요구르트병이나 패트병 및 각종여과제등에 비하여 미생물 성장조건을 위한 여과제의 표면 형상이 개선되었기는 하나 이역시 다음과 같이 문제점을 안고 있다.However, the filter agent according to the above invention has improved surface morphology of the filter medium for microbial growth conditions as compared to yogurt bottles, plastic bottles, and various filter agents used in the related art.

첫째, 주재료가 폐비닐(PE)이고 고온(200℃∼250℃)에서 용융한후 바로 압출하기 때문에 PE응용물이 덩어리를 형성하게 되어 최종압출시 조직내부까지 기공이 생기지는 않으며 표면역시 울퉁불퉁하긴하나 PE가 녹으면서 펴지기 때문에 미생물이 쉽게 달라붙어 층을 형성하기에는 너무 매끄럽게 성형되므로써 혐기성 미생물이 성장할 수 있는 공간이 부족하고 미생물층이 쉽게 탈리되는 문제점이 있으며 둘째, 석분이나 활성탄등은 PE와 함께 혼합하여 융용처리되어 압출할 때 여과제 표면이 갈라지도록 하는데에는 도움을 주나 반대로 취성을 크게하여 쉽게 깨지는 문제점이 있으며 또한 여러 가지 부재를 사용하여 제조하여야 하므로 번거로울뿐 아니라 연속적인 압출성형시 성형속도가 늦을 수 밖에 없어 여과제의 생산성을 현저히 떨어뜨린다는 문제점이 지적되고 있다.First, since the main material is waste vinyl (PE) and melted at high temperature (200 ℃ ~ 250 ℃) and then extruded immediately, PE application forms agglomerates, and no pores are formed in the tissue during final extrusion. However, because PE melts and spreads, microorganisms easily stick to each other, forming too smoothly to form a layer, so there is a problem that there is insufficient space for anaerobic microorganisms to grow, and the microbial layer is easily detached. When the mixture is melted and extruded, it helps to crack the surface of the filter, but on the contrary, it is brittle and has a problem of being easily broken due to its brittleness. In addition, it has to be manufactured by using various members. It is too late to significantly reduce the productivity of the filter This is being pointed out.

[발명이 해결하고자 하는 과제]Problems to be Solved by the Invention

이에 본원 발명은 상기한 문제점을 감안하여 제안된 것으로서 그의 목적으로 하는바는 표면과 내면이 얼기설기한 섬유상 재질로 많은 공극이 형성되므로써 부재의 내부를 포함한 양측표면으로 혐기성 및 호기성 미생물이 잘 달라붙어 탈리되지 아니하고 성장할 수 있는 미생물 접촉여과제의 제조방법을 제공하는데 있다.Accordingly, the present invention has been proposed in view of the above problems, and its purpose is to form a large number of pores of the fibrous material of the surface and the inner surface, so that the anaerobic and aerobic microorganisms are well attached to both sides including the inside of the member. To provide a method for producing a microbial contact filter that can be grown without.

본원 발명의 다른 목적은 단일재료로 구성되므로 제조가 간단하고 강도가 커서 수명이 오래가는 미생물 접촉여과제의 제조방법을 제공하는데 있다.Another object of the present invention is to provide a method for producing a microbial contact filter which is simple in manufacture and has a long strength and thus has a long lifetime since it is composed of a single material.

[과제를 해결하기 위한 수단][Means for solving the problem]

상기한 목적을 달성하기 위한 본 발명의 미생물 접촉여과제의 제조방법은 곡물용 마대등의 폴리프로필렌(PP) 폐기물을 180℃∼300℃에서 용융시켜 덩어리로 형성하여 냉각시키는 공정과; 상기 용융된 폐 폴리프로필렌 덩어리를 직경 2∼15㎜로 파쇄하는 공정과; 상기 파쇄물을 스크류 압출기에 넣어 초기온도를 200℃∼300℃로 가열하여 밀어내면서 출구온도가 45℃∼55℃로 유지하도록 압출하는 공정과; 상기 출구온도 조건의 압출물을 성형금형을 통과시켜 원하는 단면형상을 갖도록 성형하는 공정과; 상기 성형금형을 통과하는 성형물을 이송방향으로 잡아당겨 뽑아 내므로써 다공성의 섬유상 조직으로 성형하는 인출공정과; 및 상기 연속적으로 인출되는 성형물을 일정길이로 절단하는 절단공정과;를 포함하여 제조하는 것임을 특징으로 한다.Method for producing a microbial contact filter of the present invention for achieving the above object comprises the steps of melting polypropylene (PP) waste such as grain sacks at 180 ℃ to 300 ℃ to form agglomeration and cooling; Crushing the molten waste polypropylene mass to a diameter of 2 to 15 mm; Inserting the crushed material into a screw extruder and extruding the outlet temperature at 45 ° C. to 55 ° C. while heating and pushing out the initial temperature at 200 ° C. to 300 ° C .; Molding the extrudate under the exit temperature condition to have a desired cross-sectional shape by passing a molding die; A withdrawal step of forming a porous fibrous structure by pulling out the molded product passing through the molding die in a conveying direction; And a cutting process of cutting the continuously drawn molding to a predetermined length.

[실시예]EXAMPLE

이하 본 발명에 의한 제조방법의 실시예에 대하여 설명한다.Hereinafter, examples of the manufacturing method according to the present invention will be described.

제1도는 본 발명에 의한 제조방법에 의해 제조된 미생물 접촉 여과제를 나타내는 도면(사진)으로 여과제(1)의 단면 형상은 V, U, C형등 미생물이 접촉할 수 있는 내외부 공간부가 있는 형상이면 족하며 길이 방향을 따라 섬유상조직(2)이 얼기설기하게 늘어지고 조직사이에는 많은 공극(3)이 형성되어 있다.1 is a view showing a microbial contact filter prepared by the manufacturing method according to the present invention (photo), the cross-sectional shape of the filter (1) is a shape having internal and external spaces that microorganisms such as V, U, C type can contact The back face is short and the fibrous tissue 2 stretches along the length direction, and many voids 3 are formed between the tissues.

본 발명의 특징은 상기한 바와같이 엉성하고 내부공극이 많은 여과재를 제조하기 위하여 그를 충족시킬 수 있는 재질로 통상적인 PE재질이 아닌 농가에서 곡물의 수매, 유통 및 보관을 위해 사용하고난 폴리프로필렌(PP)재질의 폐곡물용 마대를 사용하는데 있다.A feature of the present invention is that the polypropylene has been used for the purchase, distribution and storage of grains in farms other than the conventional PE material, which is a material capable of satisfying such a coarse and highly porous filter material. PP) material is used for the waste grain sack.

PP재질의 폐곡물용 마대는 얇은 재질이어서 파쇄가 어렵기 때문에 180℃∼300℃에서 용융시켜 덩어리로 만든다음 2∼3일간 자연냉각시킨다. 덩어리가 완전히 냉각되면 파쇄기에 투입하여 직경이 2㎜∼15㎜의 크기로 분쇄한다.PP for waste grains is made of thin material, so it is difficult to break, so it melts at 180 ℃ ~ 300 ℃ to form agglomerates and then naturally cools for 2-3 days. When the mass is completely cooled, it is put into a crusher and pulverized to a size of 2 mm to 15 mm in diameter.

상기 파쇄물(4)은 제2도에서와 같이 스크류압출기(5)의 호퍼(6)에 투입하여 스크류(7)를 회전시켜 압출하여 전방으로 이송시킨다.The crushed material 4 is introduced into the hopper 6 of the screw extruder 5 as shown in FIG. 2 to rotate and extrude the screw 7 to be forwarded.

이때 압출되는 초기 단계에서 가열장치(8)를 통해 200∼300℃로 가열하는 상태에서 서서히 압출이 진행되도록 하며 압출출구 단계에서는 성형물의 온도가 45∼55℃를 유지하도록 한다.At this time, in the initial stage to be extruded, the extrusion is gradually progressed while heating to 200 to 300 ° C. through the heating device 8, and the temperature of the molded product is maintained at 45 to 55 ° C. at the extrusion exit step.

상기와 같이 압출출구에서의 성형물의 온도조건은 PP재질과 더불어 기공성을 갖는 섬유상 조직의 형성에 핵심적인 사항으로서 55℃이상일때는 성형물의 유연성이 너무커서 뭉쳐진 형태가 되므로 조직내부의 공극률이 현저히 저하되며 반대로 45℃이하에서는 성형성이 급격히 나빠져 원하는 모양이 안나오고 표면처리가 되질 않는다.As mentioned above, the temperature condition of the molded product at the extrusion exit is a key matter for the formation of the fibrous structure having porosity with the PP material. When the temperature is 55 ° C or higher, the flexibility of the molded product becomes too large so that the porosity inside the tissue is significantly reduced. On the contrary, below 45 ℃, the moldability deteriorates sharply, and the desired shape is not obtained and the surface treatment is not performed.

이에따라 입출단계에서의 출구온도를 상기 온도조건, 바람직하기로는 50℃정도를 유지하기 위해 냉각장치(9), 예를들면 수냉 또는 공냉에 의한 강제냉각장치가 설치되어 있다.Accordingly, the cooling device 9, for example, a forced cooling device by water cooling or air cooling, is installed in order to maintain the exit temperature in the entry / exit stage at the above temperature condition, preferably about 50 ° C.

상기 온도조건의 성형물은 곧바로 성형금형(10)을 통과시켜 원하는 단면형상(V, U, C형상)을 갖도록 길이방향으로 인출하게 된다.The molded article under the temperature condition is immediately passed through the mold 10 to be drawn out in the longitudinal direction to have a desired cross-sectional shape (V, U, C shape).

이때 압출기(5)에 의한 압출력만으로 성형물을 밀어내어 인출하기 아니하고 성형금형(10)의 전방에 설치되는 인출로울러(11)(11')로 협지하여 뽑아내므로써 조직이 섬유상 재질로 엉성하게 늘어지도록 한다.At this time, the tissue is loosely stretched into a fibrous material by pinching and pulling out the molded product by the extrusion force by the extruder 5, instead of pushing out the molded product and pulling it out with the withdrawal rollers 11 and 11 'installed at the front of the molding mold 10. To lose.

상기 인출로울러(11)(11')를 통과한 성형물을 절단기(12)로 일정 길이로 절단하게 되면 접촉여과제(1)의 제조과정이 끝나게 된다.When the molded product having passed through the take-out rollers 11 and 11 'is cut to a predetermined length by the cutter 12, the manufacturing process of the contact filter 1 is completed.

이에따라 상기한 제조공정을 마친 본 발명 여과제의 조직형상은 끈끈한 풀을 바른 손가락을 붙였다 떼어낼 때 늘어지는 풀실과 같이 얼기 설기하게 축방향으로 늘어진 형태를 갖게된다.Accordingly, the tissue shape of the filter medium of the present invention, which has completed the above-described manufacturing process, has a form axially stretched freely, such as a loose thread, when the sticky finger is attached and detached.

[발명의 효과][Effects of the Invention]

이상과 같은 본원 발명에 의하면 PP재질의 폐곡물용 마대를 이용하므로 환경문제 해결에 일조하며 조직내부가 얼기설기하여 기공성이 높으므로 극히 혐기성 미생물막이 조직내부와 양측표면에 걸쳐 두껍게 안정적으로 안착되어 탈리되지 않고 성장가능하므로 오·폐수중의 유기물을 분해하여 산화시키는 슬럿지 제거능력이 탁월하게 된다. 또한 단일의 PP재질로 형성되어 제조가 쉽고 강도가 높아 수명이 오래가는 효과가 있다.According to the present invention as described above, the use of PP material for the waste grain sack is used to help solve environmental problems, and because the inside of the tissue is frozen and porosity is high, extremely anaerobic microbial membrane is stably settled across the inside of the tissue and both surfaces and detached As it is possible to grow without sludge, the sludge removal ability to decompose and oxidize organic matter in waste water is excellent. In addition, since it is formed of a single PP material, it is easy to manufacture and has high strength, and has an effect of long life.

Claims (2)

곡물용 마대 등의 폴리프로필렌(PP) 폐기물을 180℃∼300℃에서 용융시켜 덩어리로 형성하여 냉각시키는 공정과: 상기 용융된 폐폴리프로필렌 덩어리를 직경 2∼15㎜로 파쇄하는 공정과; 상기 파쇄물을 스크류 압출기에 넣어 가열장치로 열을 가해 초기온도를 200℃∼300℃로 가열하여 밀어내면서 출구온도가 45℃∼55℃로 유지하도록 압출하는 공정과; 상기 출구온도 조건의 압출물을 성형금형을 통과시켜 원하는 단면형상을 갖도록 성형하는 공정과; 상기 성형금형을 통과하는 성형물을 이송방향으로 잡아당겨 뽑아내므로써 다공성의 섬유상 조직으로 성형하는 인출공정과; 및 상기 연속적으로 인출되는 성형물을 일정길이로 절단하는 통상의 절단 공정;을 포함하여 제조하는 것임을 특징으로 하는 오·폐수 정화처리용 미생물 접촉여과제의 제조방법.Melting polypropylene (PP) wastes such as grain sacks at 180 ° C. to 300 ° C. to form agglomerates and cooling the waste; and crushing the melted waste polypropylene agglomerates with a diameter of 2 to 15 mm; Inserting the shredder into a screw extruder, applying heat with a heating device, and extruding the outlet temperature at 45 ° C. to 55 ° C. while heating and pushing out the initial temperature to 200 ° C. to 300 ° C .; Molding the extrudate under the exit temperature condition to have a desired cross-sectional shape by passing a molding die; A withdrawal process of forming a porous fibrous structure by pulling the molded product passing through the molding die in a conveying direction; And a conventional cutting process of cutting the continuously drawn molding product to a predetermined length. The method of manufacturing a microorganism contact filter for wastewater purification, characterized in that it is produced. 제1항에 있어서, 상기 스크류 압출기의 출구온도를 유지하기 위해 냉각장치가 마련되어 있음을 특징으로 하는 오·폐수 정화처리용 미생물 접촉여과제의 제조방법.The method of claim 1, wherein a cooling device is provided to maintain the outlet temperature of the screw extruder.
KR1019960017867A 1996-05-25 1996-05-25 Method of manufacturing micro-organism contact filtration agent KR0182656B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002070103A1 (en) * 2001-03-08 2002-09-12 Korea Terrafil Co., Ltd. Media for use in pollution control and apparatus for and method of manufacturing the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002070103A1 (en) * 2001-03-08 2002-09-12 Korea Terrafil Co., Ltd. Media for use in pollution control and apparatus for and method of manufacturing the same

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