KR950002547B1 - Biological contact-material for waste water treatment - Google Patents
Biological contact-material for waste water treatment Download PDFInfo
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- KR950002547B1 KR950002547B1 KR1019920015925A KR920015925A KR950002547B1 KR 950002547 B1 KR950002547 B1 KR 950002547B1 KR 1019920015925 A KR1019920015925 A KR 1019920015925A KR 920015925 A KR920015925 A KR 920015925A KR 950002547 B1 KR950002547 B1 KR 950002547B1
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- stone powder
- activated carbon
- sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/10—Packings; Fillings; Grids
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
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- Life Sciences & Earth Sciences (AREA)
- Biodiversity & Conservation Biology (AREA)
- Microbiology (AREA)
- Hydrology & Water Resources (AREA)
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- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biological Treatment Of Waste Water (AREA)
Abstract
Description
제1도는 본 발명의 실시예에 의한 미생물 접촉여재의 사시도.1 is a perspective view of a microbial contact medium according to an embodiment of the present invention.
제2도는 제1도의 종단정면도.2 is a longitudinal sectional front view of FIG.
제3도는 제1도의 횡단측면도.3 is a cross-sectional side view of FIG.
제4도는 격자상으로 쌓아올린 경우의 예시도.4 is an exemplary view when stacked in a lattice form.
제5도는 호기성 생물막에 있어서의 대사의 모식도.5 is a schematic diagram of metabolism in an aerobic biofilm.
* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings
1 : 접촉여재 2 : 내면1: Contact medium 2: Inside
3 : 표면 4 : 요철면3: surface 4: uneven surface
본 발명은 폐비닐과 같은 폐합성수지를 주재로 하고 여기에 석분, 활성탄, 여과사를 부재로 한 오·페수, 하수처리용 미생물 접촉여재와 그 제조방법에 관한 것이며, 특히 오·폐수, 하수중의 호기성 미생물의 흡착번식을 왕성하게 하여 오·폐수 및 하수의 정화효율을 극대화시킬 수 있는 오·폐수, 하수처리용 미생물 접촉여재와 그 제조방법에 관한 것이다.The present invention relates to wastewater, microbial contact media for sewage treatment, and a method of manufacturing the same, mainly containing waste synthetic resins such as waste vinyl, and containing stone powder, activated carbon, and filtered sand. The present invention relates to a microorganism contact medium for sewage and wastewater and sewage treatment, and a method of manufacturing the same, which can maximize the efficiency of purification of wastewater and sewage by vigorous adsorption of aerobic microorganisms.
호기성 생물막에 있어서 오·폐수, 하수중의 유기물 및 질소, 인 등은 생물막에 존재하는 미생물에 의해 섭취된다. 생물막은 미생물이 조밀한 집합체를 이뤄서 활성 슬러지와 같이 분산돼 있지 않기 때문에 하나의 미생물 세포의 측면에서 보면 오·폐수, 하수의 접촉이 불충분하다.In aerobic biofilms, organic matter in wastewater, sewage, nitrogen, phosphorus, etc. are ingested by microorganisms present in the biofilm. The biofilm is a dense aggregate of microorganisms and is not dispersed like activated sludge. Therefore, in terms of one microbial cell, contact between wastewater and wastewater is insufficient.
이같은 처리단점을 보완하여 생물막법에 여재(濾材 : media)를 형성, 부착하여 생물막의 표면적을 증대시킴으로써, 오·폐수의 접촉을 충분히 이뤄지게 해 안정된 처리효율을 높이는 방안이 시도되고 있다.In order to compensate for these treatment disadvantages, by forming and attaching a media to the biofilm method to increase the surface area of the biofilm, there is an attempt to improve stable treatment efficiency by making contact with the waste water sufficiently.
이런 사용목적을 가진 여재는 적어도 하기와 같은 요건을 구비해야 효과적이다. 이를테면, 표면적이 크고 공극율이 높아야 하며, 생물막의 흡착성이 양호하고 슬러지로 인해 막힘(폐쇄)도 없어야 하며, 또한 오·폐수, 하수에 의한 부식, 변형, 변질이 없어야 함은 물론 여재와 여재가 교반수류로 인해 움직이거나 생물막이탈이 없어야 하고 이와 함께 저렴한 가격으로 수요를 충족시킬 수 있는 조건등이다.A media having this purpose of use must have at least the following requirements to be effective. For example, the surface area should be large, the porosity is high, the adsorption of the biofilm should be good, there should be no clogging due to sludge, and there should be no corrosion, deformation, or deterioration caused by sewage and wastewater, sewage. There must be no movement or biofilm drop due to water flow, and the condition to meet demand at low price.
본 발명은 위에 열거한 제조건을 충분히 만족시킬 수 있는 오·폐수·하수처리용 미생물 접촉여재를 제공하기 위한 것으로서, 비닐하우스를 철거할 때 수없이 쏟아져 나와 그 폐기에 많은 골머리를 앓던 폐비닐 따위의 폐합성수지를 주재로 하고 여기에 강도보강과 공극율 증대 및 호기성 미생물의 흡착성 증대용으로 석분, 활성탄, 여과사를 부재로 한 값싼 오·폐수, 하수처리용 미생물 접촉여재를 제공하는 것이 목적이다.The present invention is to provide a microorganism contact medium for wastewater and sewage treatment that can satisfy the above-mentioned conditions sufficiently, such as waste vinyl that spilled out numerous times when dismantling the plastic house and suffered a lot of trouble in its disposal. It is an object of the present invention to provide inexpensive wastewater and wastewater contacting microorganisms for the treatment of sewage, activated carbon, and filtered sand for strengthening strength, increasing porosity and adsorbing aerobic microorganisms.
즉, 본 발명은 주로 비닐하우스에서 나오는 고·저밀도 폴리에틸렌 폐수지필름을 주재로 하고 이것을 세절한 것에 부원료로 석분, 활성탄, 여과사를 혼합하여 여러 차례에 걸쳐 녹인 다음에 실계치 보다도 대략30% 가량 구경이 작은 압출다이스를 이용, 압출하여 내면과 표면이 울퉁불퉁한 요철면을 갖고 주면의 적어도 일부분이 길이방향으로 터진 C형 단면의 여재를 제조하는 것을 주된 특징으로 한다.That is, the present invention is mainly made of high and low density polyethylene waste resin film from the plastic house, and finely divided into fine raw material, activated carbon, and filter sand as a raw material, and then melted several times, about 30% of the actual value. The main feature is to produce a C-shaped cross-section media having at least a portion of the main surface of which has a concave-convex concave-convex surface on the inner surface and a surface thereof by extruding by using an extrusion die having a small diameter.
주재와 부재의 혼합비율은 1 : 0.07-0.1가 바람직하다. 부재의 혼합비가 7% 미만이면 공극율이 규정치이하가 되어 호기성 미생물의 흡착성이 기대에 못미치고 반대로 부재의 혼합비가 10%를 넘으면 성형성이 나쁘고 압축물은 취성이 강해 부러지거나 부서지기 쉬운 취약성이 드러난다.As for the mixing ratio of a main material and a member, 1: 0.07-0.1 is preferable. If the mixing ratio of the member is less than 7%, the porosity is less than the specified value, and the adsorption of aerobic microorganisms is less than expected. On the contrary, if the mixing ratio of the member is more than 10%, the moldability is bad and the compressed material is brittle and brittle or brittle. .
주재인 폐합성수지는 자연건조시기고 거기에 묻은 오물을 털어버린 다음 알맞은 크기로 절단하여 용융기에 투입하기 좋게 한다. 이 절단물에 부재를 섞어 가지고 1, 2, 3차 용융에 차례로 투입하여 녹인다. 각 단계에서의 용융온도는 200-250℃, 소요시간은 4-6분 정도이다.The waste synthetic resin, which is the main subject, is naturally dried, shakes off the dirt on it, and cuts it into an appropriate size so that it can be added to the melter. The cut material is mixed with the members, and then poured into the first, second, and third melts, and dissolved. The melting temperature in each step is 200-250 ° C and the time required is 4-6 minutes.
1단계 용융과정에서는 주·부재에 섞인 불순물을 대략 그 절반정도 태워서 탄화하는 것이 주된 목적이고 2차 용융과정은 나머지 불순물 마저 완전히 태워서 탄화하는 과정, 3차 용융은 탄화물과 주·부재를 융합시켜 압출하기 좋게 하기 위한 과정이며,3차 용융직후에는 곧바로 압출과정으로 이어진다. 압출속도는 0.020-0.024/초 정도가 이상적이며, 내, 표면의 요철은 고온·고압하에 압출할 때 대기중으로 나오면서 팽창되는 과정에서 형성된다.In the first stage melting process, the main purpose is to burn about half of the impurities mixed in the main / member and carbonize them.The second stage melting process completely burns the remaining impurities and carbonizes. It is a process to make it better, and immediately after the third melting, it immediately leads to the extrusion process. The extrusion speed is ideally about 0.020-0.024 / second, and the inner and the surface irregularities are formed in the process of expanding into the air when extruding under high temperature and high pressure.
여기서 불순물이란 폐비닐에 묻어 있는 나무조각등의 탄화성물질을 가리키며, 이들이 소각 제거되지 않고 잔류하면 압출불량, 압출물의 품질저하, 작업곤란과 같은 부작용이 뒤따른다.Impurities refer to carbonaceous materials such as wood chips in waste vinyl, and if they remain unincinerated, side effects such as poor extrusion, poor quality of the extrudate, and difficulty in working.
석분은 유동성을 극력 억제하여 안정성을 높이기 위해서, 또 활성탄과 여과사는 공극율과 표면적 증대를 위하여 각각 사용하는 것이다.Stone powder is used to increase the stability by suppressing fluidity as much as possible, and activated carbon and filter sand are used to increase porosity and surface area, respectively.
다이스를 통과한 직후의 압출물은 다이스공의 단면적 보다도 대략 130%정도 팽창되며, 이러는 과정에서 접촉여재(1)의 내면(2)과 표면(3)은 불규칙한 요철면(4)으로 변화된다. 이와 같은 불규칙한 요철면(4)은 평활면 또는 규칙적인 연속파형 곡면등에 비해 단위면적당 포면적이 넓고, 거친면인 까닭에 오·폐수·하수중의 미생물이 흡착 번식하기 쉬운 환경을 조성하는데 훨씬 유리해진다.The extrudate immediately after passing through the die expands by about 130% than the cross-sectional area of the die hole. In this process, the inner surface 2 and the surface 3 of the contact medium 1 change into irregular irregularities 4. The irregular irregular surface 4 has a larger area per unit area than a smooth surface or a regular continuous wave surface, and is a rough surface, which is more advantageous for creating an environment in which microorganisms in wastewater, sewage, and sewage are easily adsorbed and propagated. Become.
그리고, 압출 다이스는 C형 압출공을 갖고 있다. 따라서, 압출물의 단면도 원주면의 일부가 길이방향을 따라 터진 형상 극, C자형 단면을 갖게 된다. 이렇게 터진 부분은 격자쌓기로 미생물 접촉재를 설치할 때 직하위 접촉여재 위에 직상위 접촉여재를 차곡차곡 쌓기쉽고 적층상태도 안정감을 가질 뿐만 아니라 길이방향의 양단면과 밑이 열려서 접촉여재의 안팎면 주위로 유수의 흐름과 접촉이 원활하고 미생물의 흡착성도 훨씬 증대된다.The extrusion die has a C-type extrusion hole. Therefore, a part of the cross-sectional circumferential surface of the extrudate has a shaped pole and a C-shaped cross section along the longitudinal direction. When the microorganism contact material is installed by lattice stacking, the exploded part is easy to stack the top contact medium on top of the bottom contact medium, and the lamination state is also stable, and both ends and bottoms in the longitudinal direction are opened, so that the inner and outer sides of the contact medium are open. The flow and contact with the flowing water are smooth and the adsorption of microorganisms is much higher.
압출시의 압력은 200Ton/㎠, 압출후에는 냉각수로 강제냉각시키며, 냉각된 압출물은 소정의 길이로 절단한다.The pressure at the time of extrusion is 200 Ton / cm <2>, it is forced cooling by cooling water after extrusion, and the cooled extrudate is cut | disconnected to predetermined length.
이렇게 하여 완성한 본 발명의 미생물 접촉여재는 다음과 같은 장점이 있다.The microbial contact medium of the present invention thus completed has the following advantages.
ⓐ 정화에 관하여 미생물의 다양성이 높다.Ⓐ High microbial diversity with regard to purification
ⓑ 생물종류가 다양하고 안정된 생태계를 구성한다.Ⓑ Organize diverse and stable ecosystems.
ⓒ 수질의 부하변동에 대한 대응력이 강하다.Ⓒ Strong response to load fluctuations in water quality.
ⓓ 발생 슬러지량이 적다.Ⓓ Less sludge generated.
ⓔ 질화세균 및 탈질세균의 증식이 크다.Ⓔ The growth of nitride bacteria and denitrification bacteria is large.
ⓕ 수량, 수질의 변동이 강하다.Ⓕ The fluctuation of quantity and water quality is strong.
ⓖ 낮은 수온에서의 유기물 제거율이 높다.Ⓖ High removal rate of organics at low water temperature
ⓗ 고액분리가 양호하다.Ⓗ Solid liquid separation is good.
ⓘ 고, 저 농도의 처리가 가능하다.High and low concentrations are possible.
ⓙ 기존시설처리용량 부족시 시설증설없이 처리능력을 2-3배로 늘릴 수 있다.부족 If the capacity of existing facility is insufficient, the capacity can be increased 2-3 times without facility expansion.
ⓚ 슬루드 벌킹(slude bulking)현상이 발생치 않는다.◦ Slude bulking does not occur.
ⓛ 고도처리(3차 처리)에도 현저한 처리효율이 있다.Ⓛ Advanced treatment (third treatment) also has a remarkable treatment efficiency.
ⓜ 처리장의 적은 면적에서도 높은 효율을 나타내므로 경제적이다.It is economical because it shows high efficiency even in a small area of the treatment plant.
또, 본 발명에서 얻어지는 접촉여재와 기존의 접초여재와의 비교우위를 표로 나타내면 아래와 같다.In addition, the comparative advantage of the contact media obtained in the present invention and the conventional weed filter media is shown as follows.
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KR1019920015925A KR950002547B1 (en) | 1992-09-02 | 1992-09-02 | Biological contact-material for waste water treatment |
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KR950002547B1 true KR950002547B1 (en) | 1995-03-21 |
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Cited By (1)
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WO2002070103A1 (en) * | 2001-03-08 | 2002-09-12 | Korea Terrafil Co., Ltd. | Media for use in pollution control and apparatus for and method of manufacturing the same |
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KR100474482B1 (en) * | 2002-10-16 | 2005-03-10 | 장량 | Wastewater specie processing microorganism contact media's manufactory and product |
KR20040040038A (en) * | 2002-11-06 | 2004-05-12 | 장철순 | Media for Wastewater Treatment of Manufacturing Method |
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WO2002070103A1 (en) * | 2001-03-08 | 2002-09-12 | Korea Terrafil Co., Ltd. | Media for use in pollution control and apparatus for and method of manufacturing the same |
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