KR0182410B1 - Sn-bi-al alloy not containing pb - Google Patents
Sn-bi-al alloy not containing pb Download PDFInfo
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- KR0182410B1 KR0182410B1 KR1019960008425A KR19960008425A KR0182410B1 KR 0182410 B1 KR0182410 B1 KR 0182410B1 KR 1019960008425 A KR1019960008425 A KR 1019960008425A KR 19960008425 A KR19960008425 A KR 19960008425A KR 0182410 B1 KR0182410 B1 KR 0182410B1
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- tin
- soldering
- aluminum
- lead
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/26—Selection of soldering or welding materials proper with the principal constituent melting at less than 400 degrees C
- B23K35/262—Sn as the principal constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C13/00—Alloys based on tin
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C13/00—Alloys based on tin
- C22C13/02—Alloys based on tin with antimony or bismuth as the next major constituent
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Electric Connection Of Electric Components To Printed Circuits (AREA)
Abstract
중금속인 납(Pb)이 함유되지 않은 땜질(solder)재로서, 그 합금성분은 비스므스(Bi)를 0.5~30.0wt%(중량 백분율) 함유하고, 여기에 알루미늄(Al)을 0.1~3.0wt%(중량 백분율)함유하고, 나머지는 주석(Sn)인 것을 특징으로 하는 합금이다.A solder material that does not contain heavy metal lead (Pb), the alloying component of which contains bismuth (Bi) 0.5 to 30.0 wt% (weight percentage), and 0.1 to 3.0 wt of aluminum (Al) % (% By weight), and the remainder is tin (Sn).
본 발명인 새로운 합금은 종래의 납(Pb)-주석(Sn)합금과 비교하여 용융상태에서의 점도, 젖음성, 응고속도 및 응고 후 광택 등의 땜질특성에 조금도 손색이 없다.Compared with the conventional lead (Pb) -tin (Sn) alloy, the new alloy of the present invention is inferior to the soldering properties such as viscosity, wettability, solidification rate and post-solidification gloss in the molten state.
Description
본 발명은 납(Pb)이 함유되지 않은 땜질(solder)용 주석(Sn)-비스므스(Bi)-알루미늄(Al) 합금에 관한 것이다.The present invention relates to a tin (Sn) -bismuth (Bi) -aluminum (Al) alloy for solder that does not contain lead (Pb).
일반적으로 전기 및 전자용 동 및 동합금 부품을 땜질하는 경우에 납(Pb)이 40~70wt%(중량 퍼센트)함유한 땜납(solder)이 아직도 널리 사용되고 있으며, 근래에 들어서는 납(Pb) 성분으로 인한 공해문제가 심각히 지적되고 있다.In general, when soldering electrical and electronic copper and copper alloy parts, solder containing 40 to 70 wt% (wt. Percent) of lead (Pb) is still widely used, and due to the recent lead (Pb) component Pollution problems are seriously pointed out.
납(Pb) 성분은 중금속으로서, 일단 몸속에 들어오면 축적되어 인체에 해를 미치므로, 가능한 한 그 사용을 규제해야 하는 물질로 분류됨은 주지의 사실이다.It is well known that lead (Pb) is a heavy metal, and once it enters the body, it accumulates and harms the human body.
실제로 납땜질을 수행하는 작업장의 예에서는 납땜을 400~420℃정도의 고온으로 용융하여 땜질작업을 하므로 대기 중에 납성분이 비산되고 있다.In an example of a workshop where soldering is actually performed, soldering is performed by melting the solder at a high temperature of about 400 to 420 ° C., whereby lead components are scattered in the air.
따라서 이를 제거하기 위해, 집진장치 등으로써 대기의 오염을 막고는 있으나, 경우에 따라서는 완벽할 수가 없으며 장치의 가동 및 보수를 위해 부담하는 경제적 부담도 크다.Therefore, in order to remove this, the air pollution is prevented by a dust collector or the like, but in some cases it cannot be perfect, and the economic burden for operating and repairing the device is also great.
상기와 같은 문제점을 해결하기 위한 본 발명의 목적은 납(Pb)을 전혀 첨가하지 않은 환경친화적인 새로운 땜질용 합금을 개발함과 아울러 기존의 납(Pb)-주석(Sn)합금계 땜질재료에 비하여 강도와 도전율을 향상시킴으로써 전자부품 땜질부의 접착강도를 증가시키고 전기비저항을 줄여 노이즈를 감소시키는 효과를 얻도록 한 납(Pb)이 함유되지 않은 땜질(solder)용 주석(Sn)-비스므스(Bi)-알루미늄(Al)합금재를 제공하는데 있다.An object of the present invention for solving the above problems is to develop a new environmentally friendly soldering alloy that does not add lead (Pb) at all, as well as to existing lead (Pb) -tin (Sn) alloy-based soldering materials Compared with lead (Sn) -bismuth (solder) containing no lead (Pb) to increase the adhesive strength of the soldering parts of electronic parts by increasing the strength and conductivity, and to reduce the electrical resistivity, thereby reducing noise. It is to provide a Bi) -aluminum (Al) alloy material.
상기와 같은 본 발명의 목적은 동 및 동합금을 땜질하는 땜질재(solder)에 있어서, 0.5~30.0wt%(중량 백분율)비스므스(Bi)와, 0.1~3wt%(중량 백분율)알루미늄(Al)과, 나머지는 주석(Sn)으로 조성되는 것을 특징으로 하는 납(Pb)이 함유되지 않은 땜질(solder)용 주석(Sn)-비스므스(Bi)-알루미늄(Al)합금을 제공함으로써 달성된다.The object of the present invention as described above is 0.5 to 30.0 wt% (weight percent) bismuth (Bi) and 0.1 to 3 wt% (weight percent) aluminum (Al) in the solder (solder) for soldering copper and copper alloy And the remainder are achieved by providing a tin (Sn) -bismuth (Bi) -aluminum (Al) alloy for solder which is free of lead (Pb), which is characterized by being composed of tin (Sn).
상기한 바와 같은 목적을 달성하고 종래의 결점을 제거하기 위한 과제를 수행하는 본 발명의 실시예인 구성과 그 작용을 상세히 설명하면 다음과 같다.When explaining the configuration and the operation of the embodiment of the present invention to achieve the object as described above and to perform the problem for removing the conventional defects in detail.
융점이 낮고 합금이 잘되는 주석(Sn)과 비스므스(Bi)를 주성분으로 하고, 여기에 합금의 강도와 땜질특성을 개선할 수 있는 원소로서 미량의 알루미늄(Al)을 합금하였다.Tin (Sn) and bismuth (Bi), which have a low melting point and a good alloy, are the main components, and a small amount of aluminum (Al) is alloyed as an element capable of improving the strength and soldering properties of the alloy.
특히, 땜질특성으로서 땜질온도, 땜질속도, 용융상태에서의 땜질재의 점도,피 땜질재와의 젖음성 및 땜질 후 광택 등의 특성은 종래의 납(Pb)-주석(Sn)합금의 땜질재와 비교하여 손색이 없도록 하였다.In particular, the soldering characteristics such as soldering temperature, soldering speed, viscosity of the soldering material in the molten state, wettability with the soldering material and gloss after soldering are compared with those of the conventional lead (Pb) -tin (Sn) alloy. There was no inferiority.
합금의 특성을 보면, 용융점이 231℃인 주석(Sn)에 용융점이 271℃인 브스므스(Bi)를 합금하면 용융점이 점차 저하하여 이들의 합금 중량비율을 43:57로 합금할 경우에는 용융점이 139℃로 낮아진 저융점 공정합금이 된다.The alloy properties show that when alloying tin (Sn) with a melting point of 231 ° C. and smear (Bi) with a melting point of 271 ° C., the melting point gradually decreases, and when the alloy weight ratio is 43:57, the melting point It becomes a low melting process alloy lowered to 139 ° C.
주석(Sn)과 비스므스(Bi)의 2원합금에서 비스므스(Bi)함량을 다량증가시키는 경우에 강도는 향상되나 취성이 나타나게 된다.When the bismuth (Bi) content is increased in the binary alloy of tin (Sn) and bismuth (Bi), the strength is improved but brittleness appears.
이러한 취성을 억제함과 아울러 용융상태에서의 점도, 젖음성, 응고속도 및 응고 후 광택 등의 땜질특성을 고려하여 비스므스(Bi)의 함량을 0.5~30.0wt%(중량 백분율)인 공정점 이내로 제한하고, 여기에 알루미늄(Al)을 0.1~3wt%(중량 백분율)의 범위로 미량 합금하고 나머지는 주석(Sn)으로 하였다.In addition to suppressing brittleness and limiting the content of bismuth (Bi) within 0.5-30.0wt% (weight percentage) in consideration of the soldering characteristics such as viscosity, wettability, solidification rate and gloss after solidification in the molten state. To this, a small amount of aluminum (Al) in the range of 0.1 to 3 wt% (weight percent) was used, and the remainder was tin (Sn).
여기서 각각의 합금원소들의 함량을 조절하면, 땜질재의 땜질 특성을 제어할 수 있는 방안이 된다.Here, by adjusting the content of the respective alloying elements, there is a way to control the soldering properties of the brazing material.
이하 본 발명의 바람직한 실시예이다.Hereinafter is a preferred embodiment of the present invention.
[실시예]EXAMPLE
용융점이 높은 알루미늄(Al)은 순금속으로서 함께 용해하는 경우에 용탕의 온도를 700℃이상의 고온으로 올려야 하며, 이러한 상황에서는 비스므스(Bi)와 같은 금속의 산화가 결심하다.Aluminum (Al) having a high melting point must be heated to a high temperature of 700 ° C. or higher when it is dissolved together as a pure metal. In such a situation, oxidation of a metal such as Bismuth (Bi) is determined.
따라서 먼저 알루미늄(Al)은 주석(Sn)으로써 모합금을 만들어 용융점을 낮추어 사용해야 좋다.Therefore, aluminum (Al) should be used to make the mother alloy with tin (Sn) to lower the melting point.
본 실시예에서는 90% 주석(Sn)-10% 알루미늄(Al)모합금을 만들어 그 용융점을 500℃로 맞추어 사용하였다.In this example, a 90% tin (Sn) -10% aluminum (Al) mother alloy was made and used at a melting point of 500 ° C.
즉, 주석(Sn),비스므스(Bi)및 주석(Sn)-알루미늄(Al)모합금을 평량하여 함께 장입하고 석조중의 용해온도를 500-550℃의 범위로 유지하고 가열하면, 기지원소인 주석(Sn)과 비스므스(Bi)가 먼저 용해하여 합금되며 이들의 합금비에 따라 공정점에 접근하여 용융점이 낮은 2원합금이 된다.That is, when tin (Sn), bismuth (Bi) and tin (Sn) -aluminum (Al) mother alloys are charged and charged together, the melting temperature in the stone is maintained in the range of 500-550 ° C and heated. Phosphorus tin (Sn) and bismuth (Bi) are first melted and alloyed, thereby approaching the process point according to their alloy ratio to form a binary alloy having a low melting point.
그리고 융점이 비교적 높아 용해되지 않고 있는 주석(Sn)-알루미늄(Al)모합금도 먼저 생긴 주석(Sn)과 비스므스(Bi)의 합금용탕에 의해 확산용해하게 되어 저융점의 3원 합금이 된다.In addition, the molten tin (Sn) -aluminum (Al) mother alloy, which has a relatively high melting point, is also diffused and melted by the first molten alloy of tin (Sn) and bismuth (Bi) to form a low melting ternary alloy. .
여기서 균일하고 신속히 용해를 촉진하기 위하여 가끔 용탕을 조용히 교반하여 준다.The molten metal is sometimes stirred quietly to promote dissolution uniformly and quickly.
그리고 주석(Sn)-알루미늄(Al)모합금이 거의 다 녹는 시점에서 석조의 온도가 350℃이하가 되도록 가열온도를 낮추면서 30-60분 정도 유지하여 균질한 합금이 되도록 한다.When the tin (Sn) -aluminum (Al) master alloy is almost completely melted, it is maintained at 30-60 minutes while lowering the heating temperature so that the temperature of the masonry is 350 ° C. or lower to make a homogeneous alloy.
다음의 표1은 본 발명의 땜질합금 중에서 몇 가지 대표적인 화학성분의 예이며 표2는 침적땜질법(dipping)에 의한 각 합금의 적정 땜질온도 및 땜질결과를 나타낸 것으로, 실용조건에 충분히 만족하고 있다.Table 1 below shows some representative chemical components of the soldering alloy of the present invention, and Table 2 shows the proper soldering temperature and soldering result of each alloy by dipping, and satisfies practical conditions. .
상기와 같은 본 발명의 합금은 땜질온도, 땜질속도, 용융상태에서의 땜질재의 점도, 피 땜질재와의 젖음성 및 땜질 후 광택 등의 효과를 종래의 다량 납(Pb)을 함유한 땜질재와 비교하여 손색이 없으며, 또한 중금속인 납(Pb)의 함량이 없어 중금속 오염의 문제가 없으면서도, 기존의 납(Pb)-주석(Sn)합금계 땜질재료에 비하여 강도와 도전율을 향상시킴으로써 전자부품 땜질부의 접착강도를 증가시키고 전기비저항을 줄여 노이즈를 감소시키는 등의 효과가 있다.The alloy of the present invention as described above compares the effects of the soldering temperature, the soldering speed, the viscosity of the soldering material in the molten state, the wettability with the soldering material and the gloss after soldering, compared with the conventional soldering material containing a large amount of lead (Pb). It has no deterioration, and there is no content of lead (Pb), which is a heavy metal, and there is no problem of heavy metal contamination, and the electronic parts are soldered by improving the strength and conductivity as compared with the conventional lead (Pb) -tin (Sn) alloy-based soldering It has the effect of reducing the noise by increasing the negative adhesive strength and reducing the electrical resistivity.
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KR1019960008425A KR0182410B1 (en) | 1996-03-22 | 1996-03-22 | Sn-bi-al alloy not containing pb |
US08/770,797 US5851482A (en) | 1996-03-22 | 1996-12-20 | Tin-bismuth based lead-free solder for copper and copper alloys |
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KR1019960008425A KR0182410B1 (en) | 1996-03-22 | 1996-03-22 | Sn-bi-al alloy not containing pb |
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KR0182410B1 true KR0182410B1 (en) | 1999-04-01 |
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