KR0169684B1 - Detergent for synthetic fiber of a washing machine - Google Patents

Detergent for synthetic fiber of a washing machine Download PDF

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Publication number
KR0169684B1
KR0169684B1 KR1019960008606A KR19960008606A KR0169684B1 KR 0169684 B1 KR0169684 B1 KR 0169684B1 KR 1019960008606 A KR1019960008606 A KR 1019960008606A KR 19960008606 A KR19960008606 A KR 19960008606A KR 0169684 B1 KR0169684 B1 KR 0169684B1
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weight
fiber
washing machine
detergent
present
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KR1019960008606A
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Korean (ko)
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KR970065702A (en
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문종열
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배순훈
대우전자주식회사
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38618Protease or amylase in liquid compositions only
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38627Preparations containing enzymes, e.g. protease or amylase containing lipase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/12Soft surfaces, e.g. textile
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0026Low foaming or foam regulating compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43Solvents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

본 발명은 세탁기의 인조섬유세탁세제에 관한 것으로서, 종래의 인조섬유 세탁세제는 손세탁시 물에 대한 천수성 및 유화성을 좋게 하기 위하여 솔벤트(노말파라핀, 이소프로필알콜)를 첨가된 중성 및 드라이 세제를 넣고 세탁을 하게 되지만, 상기 습윤강도가 약한 섬유일 경우에는 섬유의 손상과 탈색이 되는 문제점을 가지고 있었다.The present invention relates to an artificial fiber laundry detergent of a washing machine, and the conventional artificial fiber laundry detergent includes a neutral and dry detergent in which solvent (normal paraffin, isopropyl alcohol) is added in order to improve water and emulsification properties for water during hand washing. The laundry is put, but when the wet strength is a weak fiber, the fiber was damaged and discolored.

이를 해결하기 위하여 본 발명은 알칸올아미드 5-10중량%, 라우릴알콜에록시레이트 20-30중량%, 린니어알콜알킬렌옥사이드 5-10중량%, 붕산 0.01-0.05중량%, 솔비탄 올레이트 5-10중량%, 에틸씨엠씨 1-3중량%, 리파아제 0.5-1중량%, 프로테아제 0.1-0.5중량%, 실리콘 0.5-1중량%, 향 0.3-1중량% 및 물 잔량으로 이루어져 물과 접촉시 습윤강도가 약한 인조섬유를 세탁시 변색, 수축에 의한 변형 및 손상없이 세탁할 수 있는 세탁기의 인조섬유 세탁세제를 제공하는데 있다.To solve this problem, the present invention provides 5-10% by weight of alkanolamide, 20-30% by weight of lauryl alcohol hydroxylate, 5-10% by weight of linear alcohol alkylene oxide, 0.01-0.05% by weight of boric acid, sorbitan 5-10% by weight, 1-3% by weight of ethyl CMC, 0.5-1% by weight of lipase, 0.1-0.5% by weight of protease, 0.5-1% by weight of silicone, 0.3-1% by weight of fragrance and water balance The present invention provides an artificial fiber laundry detergent of a washing machine that can wash artificial fibers having weak wet strength without deformation and damage due to discoloration, shrinkage, and the like.

Description

세탁기의 인조섬유 세탁세제Artificial Fiber Laundry Detergent

본 발명은 세탁기의 인조섬유 세탁세제에 관한 것으로서, 특히 물과 접촉시 습윤강도가 약한 인조섬유를 세탁시 변색, 수축에 의한 변형 및 손상없이 세탁할 수 있도록 한 세탁기의 인조섬유 세탁세제에 관한 것이다.The present invention relates to an artificial fiber laundry detergent of a washing machine, and more particularly, to an artificial fiber laundry detergent of a washing machine in which an artificial fiber having a low wet strength when contacted with water can be washed without being discolored, deformed or damaged by washing. .

최근 들어, 섬유산업의 발달로 인하여 소비자의 취향이 천연섬유와 합성섬유를 이용한 간편하고 실용적인 섬유에서 고급스런 외관을 강조하는 큐프라와 같은 인조섬유인 고급소재로 바뀌어가면서 많이 선호하게 되어 큐프라가 널리 보급되고 있는 실정이다.Recently, due to the development of the textile industry, consumer preferences have changed from simple and practical fibers using natural fibers and synthetic fibers to high-quality materials such as artificial fibers such as cupra that emphasize the luxurious appearance. It is widely spread.

이렇게 널리 보급되어 가고 있는 상기 큐프라 인조섬유는 섬유길이가 짧아 직접 의류소재로 이용하기에 부적당한 것과, 전혀 섬유의 형태를 가지지 않는 것을 화학구조상 섬유를 만들 수 있는 천연중합체를 원료로 화학적, 기계적 조작을 거쳐 다시 섬유로 만든 인조 재생섬유로, 주는 여성용 블라우스, 남성셔츠 등과 같은 고급소재로 사용되게 된다.The cupra artificial fiber, which is being widely used in this way, has a short fiber length, which is unsuitable for use directly as a garment material, and does not have any form of fiber at all. Artificial regenerated fiber made from fibers after manipulation, and used for high-quality materials such as women's blouses and men's shirts.

그러나, 상기 인조섬유인 큐프라는 일반적인 천연섬유와 달리 섬유자체가 습윤강도가 작아 물과 접촉시 본래의 성질을 잃어버려 형태가 달라지게 된다.However, the cupra, the artificial fiber, unlike the general natural fiber, the fiber itself has a small wet strength, and loses its original properties when contacted with water, thereby changing its shape.

즉, 상기 인조섬유의 경우, 수중에서 습윤강도를 살펴보면 상기 표 1에 도시한 바와 같이 나타나므로 상기 인조섬유(큐프라)는 건조시 강도에 비하여 습윤시 강도변화(감소율)이 30%-40% 정도로 크게 변형 및 수축율이 발생되게 된다. 따라서, 세탁시 세탁기로 세탁하기에는 부적합하여 주로 손세탁을 한다.That is, in the case of the artificial fiber, when looking at the wet strength in water as shown in Table 1, the artificial fiber (cupra) is 30% -40% strength change (reduction rate) when wet compared to the strength when drying The degree of deformation and shrinkage is large enough. Therefore, it is not suitable for washing with a washing machine during washing, and is mainly hand-washed.

그러나, 종래의 인조섬유세탁세제는 손세탁시 물에 대한 천수성 및 유화성을 좋게 하기 위하여 솔벤트(노말파라핀, 이소프로필알콜)를 첨가된 중성 및 드라이 세제를 넣고 세탁을 하게 되지만, 상기 습윤강도가 약한 섬유일 경우에는 섬유의 손상과 탈색이 되는 문제점을 가지고 있었다.However, the conventional synthetic fiber laundry detergent is washed with a neutral and dry detergent added with a solvent (normal paraffin, isopropyl alcohol) in order to improve the water and emulsification properties for hand washing, but the wet strength is weak In the case of fibers, the fibers were damaged and discolored.

본 발명의 목적은 상기한 바와 같은 선행 기술의 제반 폐단 및 문제점을 해결하기 위해 연구 개발한 것으로서, 습윤강도가 약한 인조섬유 세탁시 인조섬유에 변색, 변형이나 손상을 주지 않으면서 세탁할 수 있는 세탁기의 인조섬유세탁세제를 제공하는데 있다.An object of the present invention is a research and development to solve all the problems and problems of the prior art as described above, washing machine that can be washed without discoloring, deformation or damage to the artificial fiber when washing the synthetic fibers with weak wet strength To provide an artificial textile laundry detergent.

상기와 같은 목적을 달성하기 위하여 본 발명은 알칸올아미드 5-10중량%, 라우릴알콜에록시레이트 20-30중량%, 린니어알콜알킬렌옥사이드 5-10중량%, 붕산 0.01-0.05중량%, 솔비탄 올레이트 5-10중량%, 에틸씨엠씨 1-3중량%, 리파아제 0.5-1중량%, 프로테아제 0.1-0.5중량%, 실리콘 0.5-1중량%, 향 0.3-1중량% 및 물잔량으로 이루어진 것을 특징으로 하는 세탁기의 인조섬유 세탁세제에 있다.In order to achieve the above object, the present invention provides 5-10% by weight of alkanolamide, 20-30% by weight of lauryl alcohol hydroxylate, 5-10% by weight of linear alcohol alkylene oxide, and 0.01-0.05% by weight of boric acid. 5-10 wt% sorbitan oleate, 1-3 wt% ethyl CMC, 0.5-1 wt% lipase, 0.1-0.5 wt% protease, 0.5-1 wt% silicone, 0.3-1 wt% fragrance In the artificial fiber laundry detergent of a washing machine characterized in that made.

이하에서 본 고안을 첨부도면에 의거하여 상세하게 설명함으로써 본 발명의 구체적인 특징들이 보다 쉽게 이해될 것이다.Hereinafter, specific features of the present invention will be more easily understood by explaining the present invention in detail with reference to the accompanying drawings.

이하 실시예에 의거 본 발명을 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to the following Examples.

[실시예]EXAMPLE

표 2에 도시한 바와 같이 섬유와 섬유 사이에 끼어있는 오염을 용이하게 분해하는 계면활성제, 세척력을 증진하는 보조제, 지방 및 단백질을 제거하는 효소, 거품발생을 억제하는 소포제, 향, 물을 소정의 비율로 혼합 조성하였다.As shown in Table 2, a surfactant which easily decomposes the contamination between the fibers and the fiber, an aid for increasing the washing power, an enzyme for removing fat and protein, an antifoaming agent for suppressing foaming, flavor, and water are prescribed. The composition was mixed at a ratio.

[시험예 1][Test Example 1]

상기 실시예(표 2)에서 조성된 본 발명 인조섬유세제를 사용하여 다음과 같은 조건에서 세탁한 후 수축율을 측정하여 본 결과 표 3과 같이 나타났다.After washing under the following conditions using the present invention artificial fiber detergent prepared in the Example (Table 2), the shrinkage was measured as shown in Table 3 as a result.

시험조건Exam conditions

1. 시험사용세탁기 : 전자동세탁기1. Test washing machine: Fully automatic washing machine

2. 수온 : 7℃2. Water temperature: 7 ℃

3. 시험의류 : 인조섬유세제 및 큐프라 셔츠(100%)3. Test Clothing: Artificial Textile Detergent and Cupra Shirt (100%)

4. 세제량 : 물 40ℓ, 기준 20g4. Detergent: 40ℓ of water, 20g of standard

5. 드라이코스5. Dry Course

1) 종래 드라이 세제1) Conventional Dry Detergent

2) 수입 드라이 세제2) imported dry detergent

상기 표 3의 1, 2, 3에 나타난 바와 같이 본 발명 인조섬유세제의 경우, 상기 기존 드라이버세제와 수축률을 측정하여 본 결과, 4회 세탁후에 수축률은 기존 드라이세제들의 경우, 평균 세탁수축률 5.25, 4.49로 나타난 반면에 본 발명 인조섬유세제의 경우 1.74로 나타났고, 또한 4회 세탁수축률에 대하여 다름질 후 수축률 경우, 기존 드라이세제는 평균 수축률 3.43, 2.75로 나타난 반면에 본 발명 인조섬유세제의 경우 0.86로 나타났다.As shown in Tables 1, 2, and 3 of the present invention, the synthetic fiber detergent, as a result of measuring the shrinkage rate with the existing driver detergent, as a result, after 4 washes, the average dry shrinkage rate is 5.25, On the other hand, in the case of artificial fiber detergent of the present invention, 1.74, and in the case of shrinkage after 4 times of shrinkage, the existing dry detergent showed an average shrinkage rate of 3.43, 2.75, whereas the case of the artificial fiber detergent of the present invention 0.86.

이상에서 상세하게 설명한 바와 같이 본 발명의 인조섬유세탁세제는 기존 드라이제로 세탁할 때 비하여 전혀 수축률이 발생하지 않은 것을 알 수 있어, 상기 본 발명 인조섬유세탁세제로 세탁시 인조섬유에 변색, 변형 및 손상을 주지 않고 세탁을 할 수 있는 특유의 효과가 있는 것이다.As described in detail above, the artificial fiber laundry detergent of the present invention can be seen that no shrinkage occurred at all compared to when washing with the conventional dry agent, discoloration, deformation and There is a distinctive effect that can be washed without damage.

Claims (2)

알칸올아미드 5-10중량%, 라우릴알콜에록시레이트 20-30중량%, 린니어알콜알킬렌옥사이드 5-10중량%, 붕산 0.01-0.05중량%, 솔비탄 올레이트 5-10중량%, 에틸씨엠씨 1-3중량%, 리파아제 0.5-1중량%, 프로테아제 0.1-0.5중량%, 실리콘 0.5-1중량%, 향 0.3-1중량% 및 물 잔량으로 이루어진 것을 특징으로 하는 세탁기의 인조섬유 세탁세제.5-10% by weight of alkanolamide, 20-30% by weight of lauryl alcohol oxylate, 5-10% by weight of linear alcohol alkylene oxide, 0.01-0.05% by weight of boric acid, 5-10% by weight of sorbitan oleate, 1-3% by weight of ethyl CMC, 0.5-1% by weight of lipase, 0.1-0.5% by weight of protease, 0.5-1% by weight of silicone, 0.3-1% by weight of fragrance and water remaining amount of washing machine . 제1항에 있어서, 알칸올아미드 5중량%, 라우릴알콜에록시레이트 30중량%, 린니어알콜알킬렌옥사이드 10중량%, 붕산 0.02중량%, 솔비탄 올레이트 5중량%, 에틸씨엠씨 2.98중량%, 리파아제 0.5중량%, 프로테아제 0.2중량%, 실리콘 1중량%, 향 0.3중량% 및 물 잔량으로 이루어진 것을 특징으로 하는 세탁기의 인조섬유 세탁세제.According to claim 1, 5% by weight alkanolamide, 30% by weight lauryl alcohol hydroxylate, 10% by weight linear alcohol alkylene oxide, 0.02% by weight boric acid, 5% by weight sorbitan oleate, 2.98% ethyl CMC %, Lipase 0.5% by weight, protease 0.2% by weight, silicone 1% by weight, fragrance 0.3% by weight and water remaining amount of the artificial fiber laundry detergent of the washing machine.
KR1019960008606A 1996-03-27 1996-03-27 Detergent for synthetic fiber of a washing machine KR0169684B1 (en)

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KR0169684B1 true KR0169684B1 (en) 1999-01-15

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