KR0163504B1 - Cleansing soap composition for removing the make-up - Google Patents

Cleansing soap composition for removing the make-up Download PDF

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KR0163504B1
KR0163504B1 KR1019950024463A KR19950024463A KR0163504B1 KR 0163504 B1 KR0163504 B1 KR 0163504B1 KR 1019950024463 A KR1019950024463 A KR 1019950024463A KR 19950024463 A KR19950024463 A KR 19950024463A KR 0163504 B1 KR0163504 B1 KR 0163504B1
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oil
weight
nonionic surfactant
composition
cleansing
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KR970009769A (en
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홍경우
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성재갑
주식회사엘지화학
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11Encapsulated compositions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14Preparations for removing make-up

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Cosmetics (AREA)

Abstract

본 발명은 음이온계면활성제를 주 세정성분으로 하고 여기에 비이온계면활성제 및 캡슐화된 오일을 배합시킴으로써 비누의 물성을 유지하면서도 유성오염을 쉽게 제거할 수 있는 효능을 갖는 클린싱비누 조성물에 관한 것이다.The present invention relates to a cleansing soap composition having an effect of easily removing oily contamination while maintaining physical properties of a soap by using an anionic surfactant as a main cleaning component and blending a nonionic surfactant and an encapsulated oil thereto.

Description

메이크업 제거용 클린싱비누 조성물Cleansing soap composition for removing makeup

본 발명은 메이크업 및 유성오염을 제거하는 클린싱비누 조성물에 관한 것이다. 좀더 구체적으로, 본 발명은 음이온계면활성제를 주 세정성분으로 하고 여기에 비이온계면활성제 및 캡슐화 된 오일을 배합시킴으로써 비누의 물성을 유지하면서도 유성오염을 쉽게 제거할 수 있는 효능을 갖는 클린싱비누 조성물에 관한 것이다.The present invention relates to a cleaning soap composition for removing makeup and oil pollution. More specifically, the present invention provides a cleansing soap composition having an effect of easily removing oil contamination while maintaining the physical properties of soap by combining anionic surfactant as a main cleaning component and nonionic surfactant and encapsulated oil. It is about.

일반적으로 비누 등 세안료의 세정 대상이 되는 피지량은 약 100㎍/㎠인 것에 비해 메이크업량은 개인차가 있지만 약 100㎎/㎠ 정도로서 양적으로 상당하다.Generally, the amount of sebum to be washed to face washes, such as soap, is about 100 µg / cm 2, while the amount of makeup is individual.

이러한 메이크업의 제거에는 보통 기본 원료가 유제인 클린싱 크림을 이용하는데, 이때 유제는 메이크업의 오일 성분을 용해시키고 분체를 분산시켜 오염물을 쉽게 제거시키는 역할을 한다. 그러나, 유성클린싱제의 경우에는 세정 대상인 메이크업 성분과 동일한 친유성 성분이므로 메이크업 오염물과의 친화성이 높고 세정력도 우수한 장점이 있는 반면, 제거 후 오일감이 남아 비누, 세안제 등으로 다시 세안해야 하는 이중세안의 번거로운 점이 있다.In order to remove the makeup, a cleansing cream is usually used as an essential ingredient, an emulsion. The emulsion serves to easily dissolve contaminants by dissolving the oil component of the makeup and dispersing powder. However, in the case of the oil-based cleansing agent, since it has the same lipophilic component as the makeup component to be cleaned, it has high affinity with the makeup contaminants and excellent cleaning power. There is a hassle.

한편, 이러한 유성클린싱제의 단점을 개선하고자 물과 함께 사용할 수 있고 사용감도 우수한 계면활성제형의 수성클린싱제가 개발된 바 있으나, 이는 오염의 가용화 및 유화능에 한계가 있어 클린싱제로서 문제점을 갖고 있다.On the other hand, in order to improve the disadvantages of the oil-based cleansing agent has been developed a surfactant-type aqueous cleaning agent that can be used with water and excellent in use, this has a problem as a cleansing agent because there is a limit to the solubilization and emulsification of the contamination.

따라서, 상기 언급한 바와 같은 문제점을 해결하기 위한 노력의 일환으로 EP 0324575(가오)은 음이온계면활성제와 함께 3 내지 8의 HLB(hydrophilic-lipophilic balance)가를 갖는 측쇄형 비이온계면활성제를 함유하는 메이크업 제거 조성물을 제공하고 있으며, 유니레버특허(출원번호:9218792.1)는 10 내지 14의 HLB가를 갖는 비이온계면활성제를 함유하는 메이크업 제거 조성물을 제공하고 있다. 그러나 이러한 비이온계면활성제의 첨가로 인해 유성오염에 대한 가용화력을 증가시켰음에도 불구하고 만족할만한 결과를 얻기가 힘들었고 또한, 고형 화장비누로 제조하기는 더더욱 불가능하였다.Therefore, in an effort to solve the above-mentioned problems, EP 0324575 (Gao) is a makeup containing a branched nonionic surfactant having a hydrophilic-lipophilic balance (HLB) of 3 to 8 with an anionic surfactant. A removal composition is provided, and Unilever patent (application number: 9218792.1) provides a makeup removal composition containing a nonionic surfactant having an HLB value of 10 to 14. However, despite the increase in solubility for oil pollution due to the addition of such nonionic surfactants, it was difficult to obtain satisfactory results, and it was even more impossible to prepare a solid cosmetic soap.

이와 같은 상황에서 이러한 여러 가지 문제점을 해결하고 바람직한 성질을 같은 클린싱비누 조성물을 제조하기 위해 광범위한 연구를 수행한 결과, 본 발명자는 비이온계면활성제와 마이크로캡슐레이션(micro encapsulation)화된 액상오일을 첨가하면 메이크업 제거 효과도 아주 우수할 뿐아니라 사용감까지 뛰어난 고형 클린싱 비누의 제조가 가능하다는 사실을 발견하고 본 발명을 완성하게 되었다. 이하, 본 발명의 구성을 상세히 설명한다.In such a situation, extensive research has been conducted to solve these problems and to prepare a cleansing soap composition having the desired properties. As a result, the present inventors have found that the addition of a nonionic surfactant and microencapsulated liquid oil The present invention has been completed by discovering that it is possible to prepare a solid cleansing soap that is not only excellent in removing makeup but also excellent in use. Hereinafter, the configuration of the present invention will be described in detail.

본 발명은 주 세정성분인 음이온계면활성제에 비이온계면활성제 및 캡슐화된 오일을 배합시킨 것임으로 특징으로 하는 클린싱비누 조성물에 관한 것이다.The present invention relates to a cleansing soap composition comprising a nonionic surfactant and an encapsulated oil in combination with an anionic surfactant as a main cleaning component.

본 발명에서 세정성분으로 사용하는 음이온계면활성제로는 지방산의 나트륨염 및 칼륨염, N-아실글루타메이트, N-아실이세티오네이트의 나트륨염, 설포숙시네이트, 알킬에테르설페이트, 알킬에테르카르복실레이트, 아실메틸타우레이트 중에서 선택된 1종 이상을 언급할 수 있다.Anionic surfactants used as cleaning components in the present invention include sodium and potassium salts of fatty acids, sodium salts of N-acylglutamate, N-acyl isethionate, sulfosuccinates, alkyl ether sulfates, and alkyl ether carboxyls. Mention may be made of one or more selected from late, acylmethyltaurate.

또한, 비이온계면활성제로는 지방산 모노글리세라이드류, 다가알콜의 모노에스테르류, 솔비탄에스테르류(스판계), 폴리옥시에틸렌 솔비탄에스테르류(트윈계), 에틸렌옥사이드의 부가몰수가 4 내지 12인 직쇄 또는 측쇄형 지방알콜의 에스테르류 중에서 선택된 1종 이상을 사용할 수 있으며, 이와 같이 사용가능한 비이온계면활성제의 HLB 수치 범위는 약 3 내지 14이다.In addition, as nonionic surfactant, the addition mole number of fatty acid monoglycerides, the monoester of polyhydric alcohol, sorbitan ester (span type), polyoxyethylene sorbitan ester (twin type), and ethylene oxide is 4 thru | or One or more selected from esters of 12 straight or branched fatty alcohols may be used, and the HLB values of such non-ionic surfactants that can be used are about 3 to 14.

본 발명에 따른 조성물에서 비이온계면활성제는 1 내지 10중량%의 함량으로 사용하는 것이 바람직한데, 비이온계면활성제를 1중량% 미만으로 사용할 경우 충분한 가용화력을 나타내지 못하고 10중량% 이상으로 사용할 경우에는 작업성이 떨어지고 충분한 기포력을 기대하기 어려우며 사용감이 저하되는 단점이 있기 때문이다.In the composition according to the present invention, the nonionic surfactant is preferably used in an amount of 1 to 10% by weight, but when the nonionic surfactant is used in an amount of less than 1% by weight, it does not exhibit sufficient solubility and is used in an amount of 10% by weight or more. This is because the workability is poor, it is difficult to expect a sufficient foaming force, and there is a disadvantage that the feeling of use decreases.

한편, 캡슐화된 오일로는 미네랄 오일, 살구씨 오일, 아보카도 오일, 캐스터 오일 및 아몬드 오일 등의 식물성 오일(vegetable oil) 중에서 선택된 1종 이상을 사용한다. 특히, 본 발명에서는 캡슐화된 아몬드 오일의 일종인 알몬더민(ALMO-NDERMIN:Laboratories Serobiologiques Co.)을 사용했고 캡슐화된 미네랄 오일로는 3M 특허 USP-5,169,632호의 방법에 따라 제조된 것을 사용하였다. 그러나, 이러한 인캡슐레이션 방법이 본 발명의 범위를 제한하는 것은 아니다.Meanwhile, as the encapsulated oil, at least one selected from vegetable oils such as mineral oil, apricot seed oil, avocado oil, castor oil and almond oil is used. Particularly, in the present invention, almondder (ALMO-NDERMIN: Laboratories Serobiologiques Co.), which is a kind of encapsulated almond oil, was used, and the encapsulated mineral oil was prepared according to the method of 3M Patent USP-5,169,632. However, such encapsulation methods do not limit the scope of the present invention.

본 발명에 있어서 캡슐화된 오일은 5중량% 미만으로 사용할 경우 충분한 메이크업 제거 효과를 기대하기 어렵고 25중량% 이상으로 첨가할 경우 작업성이 떨어지고 세안후 오일감이 잔존하여 사용감이 현저히 저하되는 단점이 있으므로 바람직하게는 5 내지 25중량%의 범위로 함유시켜 사용한다.In the present invention, the encapsulated oil is less than 5% by weight, so it is difficult to expect a sufficient makeup removal effect, and when added at 25% by weight or more, workability is inferior and oily feeling remains after washing. Preferably it is used in the range of 5-25 weight%.

본 발명의 클린싱비누 조성물은 클린싱에 사용되는 통상적인 성분을 함유할 수 있으며, 조성물내에는 수분이 3 내지 15중량% 함유되도록 한다. 또한, 필요에 따라 산화방지제 및 염료 등의 기타 첨가물을 함유시킬 수 있다.The cleaning soap composition of the present invention may contain conventional ingredients used for cleansing, so that the composition contains 3 to 15% by weight of moisture. Moreover, other additives, such as antioxidant and dye, can be contained as needed.

본 발명의 클린싱비누 조성물은 통상의 제조방법에 따라 제조할 수 있다.The cleaning soap composition of this invention can be manufactured according to a conventional manufacturing method.

상기 설명을 구성을 갖는 본 발명에 따른 클린싱비누 조성물은 하기 실험예의 결과로부터 확인하듯이 사용감 및 기포력이 우수하면서도 메이크업 및 유성오염에 대한 클린싱 효과가 매우 우수한 특징을 갖는다.The cleansing soap composition according to the present invention having the above-described configuration has the characteristics of excellent clean-up effect against makeup and oil pollution while having excellent feeling and bubble power as confirmed from the results of the following experimental example.

이하, 본 발명을 실시예 및 비교예에 의거하여 보다 구체적으로 설명한다. 그러나, 이들 실시예는 본 발명에 대한 이해를 돕기 위한 것이지 어떤 의미로 든 본 발명의 범위가 이들 실시예에 한정되는 것은 아니다.EMBODIMENT OF THE INVENTION Hereinafter, this invention is demonstrated further more concretely based on an Example and a comparative example. However, these examples are only for the understanding of the present invention, and the scope of the present invention in any sense is not limited to these examples.

[실시예 1]Example 1

배합기에 증류수 10중량%, 소듐 코코일 이세치오네이트 73.0중량%, 비누소지(수분 12% 함유) 10.0중량%, 에틸렌옥사이드 라우릴 알콜에테르(EO:7몰부가) 1.0중량%, 캡슐화된 미네랄 오일 5.0중량%, 향료 1.0중량%를 가하고 균일하게 혼합한 후 성형하여 본 발명에 따른 클린싱비누 조성물을 제조하였다.10% by weight of distilled water, 73.0% by weight of sodium cocoyl isethionate, 10.0% by weight of soap (containing 12% of water), 1.0% by weight of ethylene oxide lauryl alcohol ether (7 molar parts of EO), encapsulated mineral oil 5.0% by weight, 1.0% by weight of fragrance was added and mixed uniformly to prepare a cleaning soap composition according to the present invention.

[비교예 1]Comparative Example 1

배합기에 증류수 10중량%, 소듐 코코일 이세치오네이트 79.0중량%, 비누소지(수분 12% 함유) 10.0중량% 및 향료 1.0중량%를 가하고 균일하게 혼합한 후 성형하였다.10 wt% of distilled water, 79.0 wt% of sodium cocoyl isethionate, 10.0 wt% of soap (containing 12% water), and 1.0 wt% of fragrance were added to the blender, and the mixture was uniformly mixed.

실시예 2 내지 7 및 비교예 2 내지 6의 조성물도 하기 표1에 나타낸 물질들을 혼합하고 실시예 1에서와 동일한 방법으로 실시하여 각각 제조하였다.The compositions of Examples 2 to 7 and Comparative Examples 2 to 6 were also prepared by mixing the materials shown in Table 1 and performing the same method as in Example 1, respectively.

실시예 1 내지 7 및 비교예 1 내지 6에 의해 제조된 견본의 사용감, 메이크업 제거 효과를 하기 실험예에서와 같은 방법으로 측정하고 그 결과를 표2에 나타내었다.The usability and makeup removal effect of the samples prepared by Examples 1 to 7 and Comparative Examples 1 to 6 were measured by the same method as in the following Experimental Example, and the results are shown in Table 2.

[실험예 1:사용감 실험]Experimental Example 1: Feeling Experiment

20명의 사용자로 하여금 일반적인 세안조건과 동일하게 세안을 하게 한 후, 사용후의 사용감을 비교하였으며, 그 결과를 평가하고 평균값을 구하였다. 평가는 하기의 기준에 따라 수행하였다.After 20 users were rinsed under the same conditions as general washing conditions, they were compared with the feelings after use. The results were evaluated and averaged. Evaluation was performed according to the following criteria.

◎ : 아주 우수(오일감이 없고 부드러운감이 있음)◎: Very good (no oily feeling and soft feeling)

○ : 우수(오일감이 거의 없음)○: excellent (almost no oily feeling)

△ : 보통(약간의 오일감이 남음)△: normal (slightly oily feeling)

× : 나쁨(오일감이 많이 남음)×: bad (a lot of oil is left)

×× : 아주 나쁨(오일감이 아주 많이 남음)××: Very bad (a lot of oil is left)

[실험예 2:메이크업 제거 실험]Experimental Example 2: Makeup Removal Experiment

먼저 실시예 및 비교예에서 제조한 견본을 증류수로 희석하여 8% 수용액을 제조하였다. 3cm×3cm의 카프 스킨(calf skin)의 무게(무게 A)를 정확히 측정한 후 파운데이션 500㎎을 스킨 위에 도포하고 나서 무게(무게 B)를 측정하였다. 8% 시료용액 1㎖씩을 그 위에 도포하고 손으로 30초간 가볍게 문질러 준 다음, 즉시 유속이 일정한 수도물로 30초간 행구고 완전히 건조시킨 다음 무게(무게 C)를 측정하였다. 메이크업 제거율은 무게 A,B 및 C의 수치로부터 하기 식에 의거하여 계산하였다.First, the samples prepared in Examples and Comparative Examples were diluted with distilled water to prepare an 8% aqueous solution. After accurately measuring the weight (weight A) of a 3cm × 3cm calf skin, 500 mg of the foundation was applied onto the skin, and then the weight (weight B) was measured. 1 ml of 8% sample solution was applied thereon, rubbed lightly by hand for 30 seconds, immediately rinsed with tap water for 30 seconds, dried completely, and weighed (weight C). Makeup removal rate was calculated based on the following formula from the values of weights A, B and C.

상기 실험 결과에서 보는 바와 같이, 비이온계면활성제를 10중량% 초과하여 사용할 경우에는 사용감이 좋지 않고 오일 잔존감이 남는 결점이 있으며 1중량% 미만으로 사용할 경우에는 사용감이 우수하나 메이크업 제거 효율이 나빠지는 단점이 있다. 또한 캡슐화된 오일을 25중량% 초과 사용할 경우 세안 후 오일감이 심한 단점이 있고 5중량% 미만 사용할 경우 메이크업 제거 효율이 현저히 줄어드는 단점이 있다.As can be seen from the above test results, when using more than 10% by weight of the non-ionic surfactant, the feeling of use is not good, the oil remains unsatisfactory, and when used less than 1% by weight, the feeling of use is excellent but the makeup removal efficiency is deteriorated. Has its drawbacks. In addition, when the encapsulated oil is used in excess of 25% by weight, the oily feeling is severe after cleansing, and in the case of using less than 5% by weight, the makeup removal efficiency is significantly reduced.

따라서 사용감/메이크업 제거 효율이 우수한 클린싱비누를 제조하기 위해서는 비이온계면활성제를 1 내지 10중량%, 캡슐화된 오일을 5 내지 25중량% 사용하는 것이 바람직함을 알 수 있다.Therefore, it can be seen that it is preferable to use 1 to 10% by weight of the nonionic surfactant and 5 to 25% by weight of the encapsulated oil in order to prepare a cleaning soap having excellent usability / makeup removal efficiency.

Claims (3)

주 세정성분인 음이온계면활성제에 비이온계면활성제(HLB값 3 내지 14) 1 내지 10중량%, 및 미네랄 오일, 살구씨 오일, 아보카도 오일, 캐스터 오일 및 아몬드 오일 중에서 선택된 1종 이상을 캡슐화시킨 오일 5 내지 25중량%을 배합시킨 것임을 특징으로 하는 클린싱 고형 비누 조성물.An oil that encapsulates 1 to 10% by weight of nonionic surfactant (HLB value 3 to 14) and at least one selected from mineral oil, apricot seed oil, avocado oil, castor oil and almond oil in anionic surfactant as a main cleaning component. A cleansing solid soap composition comprising 5 to 25% by weight. 제1항에 있어서, 음이온계면활성제로가 지방산의 나트륨염 및 칼륨염, N-아실글루타메이트, N-아실이세티오네이트의 나트륨염, 설포숙시네이트, 알킬에테르설페이트, 알킬에테르카르복실레이트, 아실메틸타우레이트 중에서 선택된 1종 이상인 조성물.The method according to claim 1, wherein the anionic surfactants are sodium and potassium salts of fatty acids, N-acylglutamate, sodium salts of N-acyl isethionates, sulfosuccinates, alkyl ether sulfates, alkyl ether carboxylates, The composition is at least one selected from acylmethyl taurate. 제1항에 있어서, 비이온계면활성제가 지방산 모노글리세라이드류, 다가알콜의 모노에스테르류, 솔비탄에스테르류(스판계), 폴리옥시에틸렌 솔비탄에스테르류(트윈계), 에틸렌옥사이드의 부가몰수가 4 내지 12인 직쇄 또는 측쇄형 지방알콜의 에스테르류 중에서 선택된 1종 이상인 조성물.The nonionic surfactant according to claim 1, wherein the nonionic surfactant is fatty acid monoglycerides, monoesters of polyhydric alcohols, sorbitan esters (span-based), polyoxyethylene sorbitan esters (twin-based), and additional moles of ethylene oxide. The composition is at least one selected from esters of linear or branched fatty alcohol having 4 to 12.
KR1019950024463A 1995-08-08 1995-08-08 Cleansing soap composition for removing the make-up KR0163504B1 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100522208B1 (en) * 1997-12-26 2006-04-20 주식회사 엘지생활건강 Composition of water soluble cleaning cream
KR20180062927A (en) * 2016-12-01 2018-06-11 주식회사 엘지생활건강 Cosmetic Composition for Cleansing Make-up on the Skin
KR20180133170A (en) * 2017-06-05 2018-12-13 주식회사 엘지생활건강 Cleansing Cosmetic Composition Having Foam Boosting and Makeup Cleansing Properties

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100522208B1 (en) * 1997-12-26 2006-04-20 주식회사 엘지생활건강 Composition of water soluble cleaning cream
KR20180062927A (en) * 2016-12-01 2018-06-11 주식회사 엘지생활건강 Cosmetic Composition for Cleansing Make-up on the Skin
KR20180133170A (en) * 2017-06-05 2018-12-13 주식회사 엘지생활건강 Cleansing Cosmetic Composition Having Foam Boosting and Makeup Cleansing Properties

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