JP2003336091A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JP2003336091A JP2003336091A JP2002292353A JP2002292353A JP2003336091A JP 2003336091 A JP2003336091 A JP 2003336091A JP 2002292353 A JP2002292353 A JP 2002292353A JP 2002292353 A JP2002292353 A JP 2002292353A JP 2003336091 A JP2003336091 A JP 2003336091A
- Authority
- JP
- Japan
- Prior art keywords
- cleaning composition
- formula
- group
- components
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、皮膚等に対する刺
激が少なく、低温安定性、起泡性に優れ、泡質がクリー
ミーで、かつ使用感が良好な洗浄剤組成物に関する。TECHNICAL FIELD The present invention relates to a detergent composition which is less irritating to the skin and the like, has excellent low temperature stability and foaming properties, has a creamy foam quality, and has a good feeling in use.
【0002】[0002]
【従来の技術及びその問題点】リン酸エステル系界面活
性剤は、石鹸、アルキルエーテルサルフェート、アルキ
ルサルフェート等に比べて皮膚や毛髪に対する刺激が低
く、皮膚洗浄剤の成分として広く応用されている。また
その特徴ゆえに、広範囲の他のアニオン界面活性剤や非
イオン界面活性剤との混合系などに応用されている。と
ころで、一般に、リン酸エステル系界面活性剤はモノエ
ステルとジエステルの混合物として得られ、アルキルリ
ン酸エステルには、水溶性が悪く起泡力も劣るジアルキ
ルリン酸が混在している。これを洗浄剤主成分として単
独で用いたのでは、一般に起泡力、低温安定性等に問題
が有るため、更に助剤を配合する方法が提案されてい
る。助剤として特定構造のヒドロキシスルホベタインを
用いる方法(例えば、特許文献1参照。)は、起泡力増
強、低温安定性改善の点で比較的優れた方法であるが、
起泡力、泡質の両方を満足するものではなかった。ま
た、助剤として、トリアルキルアミノ酢酸ベタインやト
リアルキルアミノプロパンスルホベタインを用いる方法
(例えば、特許文献2参照。)は起泡力、水溶性が高め
られるが、起泡力と泡質の両方を満足するものではなか
った。一方、助剤としてアミンオキサイド及び高級脂肪
酸塩を用いる方法(例えば、特許文献3参照。)は、モ
ノアルキルリン酸エステル塩の場合には起泡力、泡質の
改善の点ではある程度効果があるが、モノアルキルリン
酸エステル塩/ジアルキルリン酸エステル塩の比率が9
0/10未満であると、起泡力、泡質の両方を満足する
ことは困難である。2. Description of the Related Art Phosphate ester type surfactants have less irritation to the skin and hair than soaps, alkyl ether sulfates, alkyl sulfates and the like, and are widely applied as components of skin cleansing agents. Also, due to its characteristics, it is applied to a wide range of other anionic surfactants and mixed systems with nonionic surfactants. By the way, generally, a phosphate ester surfactant is obtained as a mixture of a monoester and a diester, and a dialkyl phosphate having poor water solubility and poor foaming power is mixed in the alkyl phosphate ester. If this is used alone as the main ingredient of the detergent, there is generally a problem in foaming power, low temperature stability, etc. Therefore, a method of further blending an auxiliary agent has been proposed. The method using hydroxysulfobetaine having a specific structure as an auxiliary agent (see, for example, Patent Document 1) is a relatively excellent method in terms of enhancing foaming power and improving low temperature stability.
Both the foaming power and the foam quality were not satisfied. Further, a method using trialkylaminoacetic acid betaine or trialkylaminopropane sulfobetaine as an auxiliary agent (see, for example, Patent Document 2) enhances foaming power and water solubility, but both foaming power and foam quality are improved. Was not satisfied. On the other hand, the method of using an amine oxide and a higher fatty acid salt as an auxiliary agent (see, for example, Patent Document 3) is effective to some extent in terms of improving foaming power and foam quality in the case of a monoalkyl phosphate ester salt. However, the ratio of monoalkyl phosphate ester salt / dialkyl phosphate ester salt is 9
When it is less than 0/10, it is difficult to satisfy both the foaming power and the foam quality.
【0003】[0003]
【特許文献1】特開昭62−138594号公報[Patent Document 1] Japanese Patent Laid-Open No. 62-138594
【特許文献2】特開昭53−26808号公報[Patent Document 2] JP-A-53-26808
【特許文献3】特開昭58−103598号公報[Patent Document 3] JP-A-58-103598
【0004】[0004]
【発明が解決しようとする課題】従って、本発明は、皮
膚等に対する刺激が少なく、起泡性に優れ、泡質がクリ
ーミーで、使用感が良好で、低温安定性に優れ、製造時
の配合が容易な洗浄剤組成物を提供することを目的とす
る。Therefore, the present invention has less irritation to the skin and the like, excellent foaming property, creamy foam quality, good feeling in use, excellent low temperature stability, and formulation at the time of production. It is an object of the present invention to provide a cleaning composition that is easy to remove.
【0005】[0005]
【課題を解決するための手段】本発明者らは、リン酸エ
ステル系界面活性剤を使用した洗浄剤組成物について、
高級脂肪酸又はその塩と特定のスルホベタインを併用配
合することにより、皮膚等に対する刺激が少なく、低温
安定性、起泡性に優れ、泡質がクリーミーで、かつ使用
感が良好な洗浄剤組成物が得られることを見いだした。
また、このような組成であるため、製造時の配合が容易
であった。すなわち、本発明は次の成分(A)、(B)
及び(C)を含有する洗浄剤組成物及びその製造法を提
供するものである:
(A)(a1)一般式(1)で表されるリン酸モノエス
テルと(a2)一般式(2)で表されるリン酸ジエステ
ルとの混合物であって、その含有比率が重量比で
(a1)/(a2)=85/15〜50/50であるリン
酸エステル系界面活性剤:DISCLOSURE OF THE INVENTION The inventors of the present invention have proposed a detergent composition using a phosphate ester type surfactant,
By combining a higher fatty acid or a salt thereof and a specific sulfobetaine together, a detergent composition with less irritation to the skin, excellent stability at low temperature, excellent foaming property, creamy foam quality, and good feeling in use I found that
Moreover, since it has such a composition, the compounding at the time of manufacture was easy. That is, the present invention provides the following components (A) and (B)
(A) (a 1 ) a phosphoric acid monoester represented by the general formula (1) and (a 2 ) a general formula ( 2) a phosphoric acid diester represented by 2), the content ratio of which is (a 1 ) / (a 2 ) = 85/15 to 50/50 by weight:
【0006】[0006]
【化3】 [Chemical 3]
【0007】(式中、R1、R2及びR3はそれぞれ炭素
数8〜18の直鎖又は分岐鎖のアルキル基又はアルケニ
ル基を示し、X1、X2及びYはそれぞれ水素原子、アル
カリ金属原子、アルカリ土類金属原子、アルカノールア
ミン又はアンモニウムを示し、平均付加モル数k、m及
びnはそれぞれ0〜10の数を示す);
(B)一般式(3)
R4-COOM (3)
(式中、R4は炭素数7〜17の飽和又は不飽和の脂肪
族炭化水素基を示し、Mは水素原子、アルカリ金属原
子、アルカノールアミン又はアンモニウムを示す)で表
される高級脂肪酸又はその塩;
(C)一般式(4):(In the formula, R 1 , R 2 and R 3 each represent a linear or branched alkyl group or alkenyl group having 8 to 18 carbon atoms, and X 1 , X 2 and Y each represent a hydrogen atom or an alkali. Represents a metal atom, an alkaline earth metal atom, an alkanolamine or ammonium, and the average added mole numbers k, m and n each represent a number of 0 to 10); (B) General formula (3) R 4 —COOM (3 ) (In the formula, R 4 represents a saturated or unsaturated aliphatic hydrocarbon group having 7 to 17 carbon atoms, and M represents a hydrogen atom, an alkali metal atom, an alkanolamine or ammonium) or a higher fatty acid represented by A salt thereof; (C) general formula (4):
【0008】[0008]
【化4】 [Chemical 4]
【0009】(式中、R5は炭素数8〜18の飽和又は
不飽和の炭化水素基を示し、R6及びR 7はそれぞれメチ
ル基を示し、Zは水素原子又は水酸基を示す)で表され
るスルホベタイン。(Where R isFiveIs saturated with 8 to 18 carbon atoms or
Represents an unsaturated hydrocarbon group, R6And R 7Are each
And Z is a hydrogen atom or a hydroxyl group).
Sulfobetaine.
【0010】[0010]
【発明の実施の形態】本発明に用いる低刺激性の基剤で
ある成分(A)の一般式(1)及び(2)で表されるリ
ン酸エステルにおいて、R1、R2及びR3としては炭素
数10〜16、特に12〜14のアルキル基であるのが
好ましく、X1、X2及びYはカリウム又はナトリウムの
ようなアルカリ金属原子又はトリエタノールアミンが好
ましく、特に水に対する溶解性の点からカリウムが好ま
しい。エチレンオキサイド平均付加モル数k、m及びn
は起泡力の観点から0〜4モル、特に0〜2モルが好ま
しい。成分(A)中のアルキルリン酸モノエステル(a
1)とアルキルリン酸ジエステル(a2)との含有比率
は、配合の容易さの観点から重量比(a1)/(a2)=
85/15〜50/50であり、80/20〜70/3
0が好ましい。アルキルリン酸モノエステル(a1)の
含有率が低いと起泡性が劣り、含有率が高いとアルキル
リン酸エステル混合物の融点が高くなり、配合が困難と
なる。成分(A)のリン酸エステル系界面活性剤の含有
量は、泡立ち、洗浄力及び配合の容易さの観点から本発
明の洗浄剤組成物の5〜40重量%が好ましく、8〜3
0重量%が特に好ましい。BEST MODE FOR CARRYING OUT THE INVENTION In the phosphoric acid ester represented by the general formulas (1) and (2) of the component (A) which is a mild base material used in the present invention, R 1 , R 2 and R 3 can be used. Is preferably an alkyl group having 10 to 16 carbon atoms, particularly 12 to 14 carbon atoms, X 1 , X 2 and Y are preferably an alkali metal atom such as potassium or sodium or triethanolamine, and particularly water-soluble. From the viewpoint of, potassium is preferable. Average number of moles of ethylene oxide added k, m and n
Is preferably 0 to 4 mol, particularly preferably 0 to 2 mol from the viewpoint of foaming power. Alkyl phosphoric acid monoester (a) in component (A)
The content ratio of 1 ) to the alkyl phosphoric acid diester (a 2 ) is the weight ratio (a 1 ) / (a 2 ) = from the viewpoint of easy blending.
85/15 to 50/50, 80/20 to 70/3
0 is preferred. When the content of the alkyl phosphoric acid monoester (a 1 ) is low, the foaming property is inferior, and when the content is high, the melting point of the alkyl phosphoric acid ester mixture becomes high and the compounding becomes difficult. The content of the phosphate ester-based surfactant as the component (A) is preferably 5 to 40% by weight of the detergent composition of the present invention from the viewpoint of foaming, detergency and ease of blending, and 8 to 3
0% by weight is particularly preferred.
【0011】成分(B)の一般式(3)で表される高級
脂肪酸又はその塩において、R4は好ましくは炭素数9
〜17、より好ましくは炭素数11〜17、特に好まし
くは炭素数11〜13のアルキル基であり、Mはアルカ
リ金属原子、アルカノールアミン又はアンモニウムが好
ましく、特に好ましくはカリウム又はナトリウムのよう
なアルカリ金属原子である。この高級脂肪酸塩は、洗浄
剤組成物を製造する配合槽中で高級脂肪酸と塩基を中和
反応せしめて調製しても良い。また、高級脂肪酸塩の一
部はリン酸エステル塩の対イオンと塩交換を生じていて
も本発明の効果の妨げとはならない。成分(B)は、成
分(C)にない泡質改善効果、すなわち、クリーミーな
泡質をもたらし、また、起泡性も向上させる。In the higher fatty acid or salt thereof represented by the general formula (3) as the component (B), R 4 preferably has 9 carbon atoms.
To 17, more preferably an alkyl group having 11 to 17 carbon atoms, particularly preferably 11 to 13 carbon atoms, M is preferably an alkali metal atom, an alkanolamine or ammonium, particularly preferably an alkali metal such as potassium or sodium. Is an atom. This higher fatty acid salt may be prepared by neutralizing the higher fatty acid and a base in a mixing tank for producing the detergent composition. Even if some of the higher fatty acid salts undergo salt exchange with the counterion of the phosphate ester salt, the effect of the present invention is not hindered. The component (B) brings about a foam quality improving effect which the component (C) does not have, that is, a creamy foam quality, and also improves foamability.
【0012】成分(B)の高級脂肪酸又はその塩は単独
又は2種以上の混合物として使用することができる。成
分(B)の含有量は、本発明の洗浄剤組成物の洗浄性、
起泡性を与える点から、1〜20重量%が好ましく、1
〜10重量%が更に好ましく、2〜8重量%が特に好ま
しい。The higher fatty acid or the salt thereof as the component (B) can be used alone or as a mixture of two or more kinds. The content of the component (B) is the detergency of the detergent composition of the present invention,
From the viewpoint of giving foamability, 1 to 20% by weight is preferable, and 1
-10% by weight is more preferable, and 2-8% by weight is particularly preferable.
【0013】本発明の洗浄剤組成物において成分(A)
と成分(B)の好ましい含有量は上記のとおりである
が、更に成分(A)と成分(B)の含有比は、重量比で
95/5〜50/50とすることが洗浄力、起泡力、泡
の感触及び皮膚刺激性の点から好ましく、90/10〜
70/30が特に好ましい。In the detergent composition of the present invention, the component (A)
The preferred contents of the component (B) and the component (B) are as described above, and the content ratio of the component (A) and the component (B) is 95/5 to 50/50 in terms of the weight ratio. 90 / 10-90 is preferable from the viewpoint of foam power, foam feel and skin irritation.
70/30 is particularly preferred.
【0014】成分(C)のスルホベタインは前記一般式
(4)で表される。式(4)において、Zは水酸基であ
るのが好ましく、R5は炭素数10〜16のアルキル基
又はアルケニル基であるのが好ましく、Zが水酸基でか
つR5が炭素数10〜16のアルキル基又はアルケニル
基であるのがより好ましく、特にR5がラウリル基又は
ミリスチル基であるもの、すなわちラウリルジメチルヒ
ドロキシスルホベタイン及びミリスチルジメチルヒドロ
キシスルホベタインが好ましい。成分(C)は低温安定
性を維持し、起泡力を向上させる効果がある。成分
(C)の含有量は、本発明の洗浄剤組成物の0.1〜2
0重量%が好ましく、1〜15重量%が更に好ましく、
2〜12重量%が特に好ましい。成分(A)及び(B)
の合計含有量に対して成分(C)の含有量の比率は、低
温安定性及び起泡力向上の観点から重量比で[(A)+
(B)]/(C)=40/2〜10/7、特に30/2
〜20/7であるのが好ましい。成分(A)、(B)及
び(C)を併用することにより、リン酸エステル系界面
活性剤固有の低刺激性を維持しながら、リン酸エステル
系界面活性剤の欠点である起泡性と泡質が改善される。
泡質はクリーミーとなり好ましい。また、リン酸エステ
ル系界面活性剤特有の使用感である、肌がつっぱらない
ということが認知され、使用感が良好である。更に、本
発明の組成に由来して、製造時の配合が、粘度の上昇が
なく、容易となる。The sulfobetaine as the component (C) is represented by the above general formula (4). In the formula (4), Z is preferably a hydroxyl group, R 5 is preferably an alkyl group or an alkenyl group having 10 to 16 carbon atoms, Z is a hydroxyl group and R 5 is an alkyl group having 10 to 16 carbon atoms. It is more preferably a group or an alkenyl group, and particularly preferably a group in which R 5 is a lauryl group or a myristyl group, that is, lauryldimethylhydroxysulfobetaine and myristyldimethylhydroxysulfobetaine. The component (C) maintains low temperature stability and has an effect of improving foaming power. The content of the component (C) is 0.1 to 2 of the detergent composition of the present invention.
0 wt% is preferable, 1 to 15 wt% is more preferable,
2-12% by weight is particularly preferred. Ingredients (A) and (B)
The ratio of the content of the component (C) to the total content of [(A) +
(B)] / (C) = 40/2 to 10/7, especially 30/2
It is preferably ˜20 / 7. By using the components (A), (B) and (C) in combination, the foaming property, which is a drawback of the phosphate ester type surfactant, is maintained while maintaining the low irritation characteristic of the phosphate ester type surfactant. The foam quality is improved.
The foam quality is creamy, which is preferable. Further, it is recognized that the skin is not taut, which is a feeling of use peculiar to the phosphate ester surfactant, and the feeling of use is good. Further, due to the composition of the present invention, the compounding at the time of production becomes easy without any increase in viscosity.
【0015】本発明の洗浄剤組成物には、その使用目的
に応じ、更に色素、香料、殺菌剤、消炎剤、キレート
剤、増泡剤、増粘剤、粘度調整剤、パール化剤、防腐
剤、湿潤剤、pH調整剤、他の界面活性剤等を本発明の
効果を損なわない範囲で配合することができる。The detergent composition of the present invention further comprises pigments, fragrances, bactericides, antiphlogistics, chelating agents, foaming agents, thickeners, viscosity modifiers, pearlizing agents and preservatives, depending on the purpose of use. Agents, wetting agents, pH adjusters, other surfactants and the like can be added within a range that does not impair the effects of the present invention.
【0016】本発明の洗浄剤組成物の剤型について特に
制限はなく、従来より公知の種々の剤型、例えば液体シ
ャンプー、クリーム状洗顔料、ボディーシャンプー等と
することができる。There is no particular limitation on the dosage form of the detergent composition of the present invention, and various conventionally known dosage forms such as liquid shampoo, cream-type facial cleanser, body shampoo and the like can be used.
【0017】本発明の洗浄剤組成物の製造方法は下記の
工程からなる:
1)成分(A)、(B)及び(C)を含有する混合物を
調製し、
2)次にこの混合物を容器に詰める。
成分(A)、(B)及び(C)を混合する時に、それら
の順序は問わずまた同時であってもよい。成分(A)配
合時に粘度増加が認められるので、40〜80℃で加熱
攪拌するのが好ましい。本発明の組成を持つことによ
り、混合時に急激な増粘を生じることなく、10000
mPa・s以下で製造が可能となる。The method for producing the detergent composition of the present invention comprises the following steps: 1) preparing a mixture containing components (A), (B) and (C), and 2) then adding the mixture to a container. Stuff in. When the components (A), (B) and (C) are mixed, their order does not matter and they may be simultaneous. Since an increase in viscosity is observed when the component (A) is blended, it is preferable to heat and stir at 40 to 80 ° C. By having the composition of the present invention, the viscosity of 10,000
It is possible to manufacture at mPa · s or less.
【0018】[0018]
【実施例】実施例1〜12及び比較例1〜6
表1〜3に示す組成の洗浄組成物を、各成分を70℃で
混合して製造(pHを7〜8に調整)し、製造時の状
態、起泡力、起泡性、泡質、使用感及び低温安定性を評
価した。結果を表1〜3に示す。EXAMPLES Examples 1 to 12 and Comparative Examples 1 to 6 Cleaning compositions having the compositions shown in Tables 1 to 3 were prepared by mixing the respective components at 70 ° C. (adjusting the pH to 7 to 8) to prepare the compositions. The state, foaming power, foaming property, foam quality, feeling of use and low temperature stability were evaluated. The results are shown in Tables 1 to 3.
【0019】(1)製造時の状態
洗浄剤組成物の製造時の状態を、次の規準で肉眼評価し
た。
○:容易に配合
×:粘度上昇し配合不可(1) State during production The state of the detergent composition during production was visually evaluated according to the following criteria. ◯: Easy to mix ×: Viscosity increases and cannot be mixed
【0020】(2)起泡力試験
洗浄剤組成物の3%(4°硬水)水溶液に人工汚れとし
てラノリンを0.5%加え、平型プロペラで40℃に於
いて回転数1000r/minで10秒毎反転の条件下
で、5分間シリンダー中で撹拌し、撹拌終了後の泡量に
より評価を行った。(2) Foaming power test 0.5% of lanolin as an artificial stain was added to a 3% (4 ° hard water) aqueous solution of a detergent composition, and a flat propeller was operated at 40 ° C and a rotation speed of 1000 r / min. Stirring was performed in the cylinder for 5 minutes under the condition of reversing every 10 seconds, and evaluation was performed by the foam amount after the stirring was completed.
【0021】(3)起泡性、泡質及び使用感
常法に従って調製した洗浄剤組成物を手のひらに洗浄剤
1gを塗布して手、腕を洗浄したときの起泡性及び泡質
を専門パネラー10名により下記の評価規準に従い評価
した。
(起泡性)
A:泡量が非常に多い。
B:泡量が多い。
C:泡量がやや少ない。
D:泡量が少ない。
(泡質)
A:きめ細かく、かつ非常にクリーミーで良好な泡質。
B:クリーミーで良好な泡質。
C:ややクリーミーな泡質
D:軽く粗い泡質。
(使用感)
A:使用感良好。
B:使用感やや良好。
C:使用感悪い。(3) Foaming property, foaming quality and feeling of use Specializing in foaming property and foaming quality when 1 g of cleaning agent is applied to the palm of a cleaning composition prepared according to a conventional method and the hands and arms are washed. It was evaluated by 10 panelists according to the following evaluation criteria. (Foaming property) A: The amount of bubbles is very large. B: A large amount of bubbles. C: The amount of bubbles is slightly small. D: The amount of bubbles is small. (Foam quality) A: Fine and very creamy and good foam quality. B: Creamy and good foam quality. C: Slightly creamy foam quality D: Light and coarse foam quality. (Feeling in use) A: Good feeling in use. B: Usability is slightly good. C: The feeling of use is bad.
【0022】(4)低温安定性試験
洗浄剤組成物をガラスビンに入れ、5℃で10日間保存
後、5℃より取り出し、室温(25℃)に1時間放置
し、外観を次の基準で肉眼評価した。
◎:透明。
○:かすかに濁る。
△:やや濁る。
×:沈殿を生じ分離。(4) Low-temperature stability test The detergent composition was put in a glass bottle, stored at 5 ° C for 10 days, taken out from 5 ° C, and allowed to stand at room temperature (25 ° C) for 1 hour. evaluated. A: Transparent. ○: Slightly cloudy. Δ: Somewhat cloudy. X: Separation occurs and separation occurs.
【0023】[0023]
【表1】 [Table 1]
【0024】[0024]
【表2】 [Table 2]
【0025】[0025]
【表3】 [Table 3]
【0026】実施例13(ボディシャンプー) 下記の処方でボディシャンプーを製造した。 (重量部) ラウリルホスフェートK塩/ジラウリルホスフェートK塩 (モノラウリル体/ジラウリル体=75/25) 15 ラウリン酸カリウム 2.5 ミリスチン酸カリウム 2.5 プロピレングリコール 5 カチオン化セルロース〔ポイズC-150L;花王(株)社製〕 0.3 ラウリルヒドロキシスルホベタイン 5 ジステアリン酸エチレングリコール 2 メチルパラベン 0.2 プロピルパラベン 0.1 BHT 0.2 香料 0.05精製水 バランス 100.00Example 13 (Body shampoo) A body shampoo was prepared according to the following formulation. (Parts by weight) Lauryl phosphate K salt / dilauryl phosphate K salt (monolauryl body / dilauryl body = 75/25) 15 Potassium laurate 2.5 Potassium myristate 2.5 Propylene glycol 5 Cationized cellulose [Poise C-150L Manufactured by Kao Corporation] 0.3 Lauryl hydroxysulfobetaine 5 Ethylene glycol distearate 2 Methylparaben 0.2 Propylparaben 0.1 BHT 0.2 Perfume 0.05 Purified water balance 100.00
【0027】実施例14(ボディシャンプー)
下記の処方でボディシャンプーを製造した。
(重量部)
ラウリルホスフェートK塩/ジラウリルホスフェートK塩
(モノラウリル体/ジラウリル体=75/25) 20
ラウリン酸カリウム 7
ジプロピレングリコール 2
ポリオキシエチレンアルキルエーテル酢酸K塩 2
グリセリン 3
アクリル酸メタクリル酸アルキル共重合体a) 0.2
ラウリルヒドロキシスルホベタイン 8
ジステアリン酸エチレングリコール 2
サリチル酸 0.2
BHT 0.2
香料 0.05精製水 バランス
100.00
a):カーボポールETD2020;BFGoodrich社製
実施例13及び14のボディシャンプーは起泡性に優
れ、泡質がクリーミーで洗浄時の使用感が良好で、皮膚
に対する刺激が少なかった。Example 14 (Body shampoo) A body shampoo was prepared according to the following formulation. (Parts by weight) Lauryl phosphate K salt / dilauryl phosphate K salt (monolauryl body / dilauryl body = 75/25) 20 Potassium laurate 7 Dipropylene glycol 2 Polyoxyethylene alkyl ether acetic acid K salt 2 Glycerin 3 Acrylic acid Methacrylic acid Alkyl copolymer a) 0.2 Lauryl hydroxysulfobetaine 8 Ethylene glycol distearate 2 Salicylic acid 0.2 BHT 0.2 Perfume 0.05 Purified water balance 100.00 a): Carbopol ETD2020; Example 13 manufactured by BFGoodrich The body shampoos of Nos. 14 and 14 had excellent foaming properties, had a creamy foam quality, had a good feeling during use, and had little irritation to the skin.
【0028】実施例15(洗顔料) 下記の処方で洗顔料を製造した。 (重量部) ラウリルホスフェートK塩/ジラウリルホスフェートK塩 (モノラウリル体/ジラウリル体=75/25) 19 ヤシ油脂肪酸カリウム塩 5 ジプロピレングリコール 1.5 プロピレングリコール 5 ソルビトール 5 ポリオキシエチレンアルキルエーテル酢酸K塩 (アルキル基:C12/C14=75/25, EO:10) 1.8 トリイソステアリン酸ポリオキシエチレンソルビタン(EO:160) 2 カチオン化セルロース〔ポイズC-150L;花王(株)社製〕 0.3 アクリル酸メタクリル酸アルキル共重合体b) 0.5 ラウリルヒドロキシスルホベタイン 5 ジステアリン酸エチレングリコール 2 メチルパラベン 0.2 プロピルパラベン 0.1 BHT 0.2 香料 0.05精製水 バランス 100.00 b):カーボポールETD2020;BFGoodrich社製Example 15 (Facial cleanser) A facial cleanser was produced according to the following formulation. (Parts by weight) Lauryl phosphate K salt / dilauryl phosphate K salt (monolauryl derivative / dilauryl derivative = 75/25) 19 Palm oil fatty acid potassium salt 5 Dipropylene glycol 1.5 Propylene glycol 5 Sorbitol 5 Polyoxyethylene alkyl ether acetic acid K salt (alkyl group: C 12 / C 14 = 75/25, EO: 10) 1.8 Polyoxyethylene sorbitan triisostearate (EO: 160) 2 Cationized cellulose [Poise C-150L; Kao Corporation) Manufacture] 0.3 Alkyl acrylate methacrylate copolymer b) 0.5 Lauryl hydroxy sulfobetaine 5 Ethylene glycol distearate 2 Methyl paraben 0.2 Propyl paraben 0.1 BHT 0.2 Perfume 0.05 Purified water balance 100. 00 b): Carbopol ETD2020; BF Goodrich
【0029】実施例16(洗顔料)
下記の処方で洗顔料を製造した。
(重量部)
ラウリルホスフェートトリエタノールアミン塩/ジラウリル
ホスフェートトリエタノールアミン塩
(モノラウリル体/ジラウリル体=73/27) 19
ラウリン酸トリエタノールアミン塩 2.5
ミリスチン酸トリエタノールアミン塩 2.5
グリセリン 16
トリイソステアリン酸ポリオキシエチレンソルビタン(EO:160) 2
カチオン化セルロース〔ポイズC-150L;花王(株)社製〕 0.5
アクリル酸メタクリル酸アルキル共重合体c) 0.5
ラウリルヒドロキシスルホベタイン 5.0
メチルパラベン 0.2
プロピルパラベン 0.1
BHT 0.2精製水 バランス
100.00
c):カーボポールETD2020;BFGoodrich社製
実施例15及び16の洗顔料は起泡性に優れ、泡質がク
リーミーで、洗浄時の使用感が良好で、皮膚に対する刺
激が少なかった。Example 16 (Facial cleanser) A facial cleanser was produced according to the following formulation. (Parts by Weight) Lauryl Phosphate Triethanolamine Salt / Dilauryl Phosphate Triethanolamine Salt (Monolauryl Form / Dilauryl Form = 73/27) 19 Lauric Acid Triethanolamine Salt 2.5 Myristic Acid Triethanolamine Salt 2.5 Glycerin 16 polyoxyethylene sorbitan triisostearate (EO: 160) 2 cationized cellulose [Poise C-150L; manufactured by Kao Corporation] 0.5 alkyl methacrylic acid acrylate copolymer c) 0.5 lauryl hydroxysulfobetaine 5.0 Methylparaben 0.2 Propylparaben 0.1 BHT 0.2 Purified water Balance 100.00 c): Carbopol ETD2020; BFGoodrich's Examples 15 and 16 have excellent foaming properties and foam quality. Creamy, good feeling when washing and less irritating to skin won.
【0030】実施例17(ボディシャンプー)
下記の処方でボディシャンプーを製造した。
(重量部)
ポリオキシエチレン(2)ラウリルホスフェートK塩/
ポリオキシエチレン(2)ジラウリルホスフェートK塩
(モノラウリル体/ジラウリル体=75/25) 15
ラウリン酸カリウム 2.5
ミリスチン酸カリウム 2.5
プロピレングリコール 5
カチオン化セルロース〔ポイズC-150L;花王(株)社製〕 0.3
ラウリルヒドロキシスルホベタイン 5
ジステアリン酸エチレングリコール 2
メチルパラベン 0.2
プロピルパラベン 0.1
BHT 0.2
香料 0.05精製水 バランス
100.00
実施例17のボディシャンプーは起泡性に優れ、泡質が
クリーミーで、洗浄時の使用感が良好で、皮膚に対する
刺激が少なかった。Example 17 (Body shampoo) A body shampoo was prepared according to the following formulation. (Parts by weight) Polyoxyethylene (2) lauryl phosphate K salt / Polyoxyethylene (2) dilauryl phosphate K salt (monolauryl body / dilauryl body = 75/25) 15 Potassium laurate 2.5 Potassium myristate 2. 5 Propylene glycol 5 Cationized cellulose [Poise C-150L; manufactured by Kao Corporation] 0.3 Lauryl hydroxysulfobetaine 5 Ethylene glycol distearate 2 Methylparaben 0.2 Propylparaben 0.1 BHT 0.2 Perfume 0.05 Purified water balance 100.00 The body shampoo of Example 17 was excellent in foaming property, had a creamy foam quality, had a good feeling during use, and had little skin irritation.
【0031】実施例18(洗顔料)
下記の処方で洗顔料を製造した。
(重量部)
ポリオキシエチレン(2)ラウリルホスフェートK塩/
ポリオキシエチレン(2)ジラウリルホスフェートK塩
(モノラウリル体/ジラウリル体=75/25) 15
ポリオキシエチレン(2)ミリスチルホスフェートK塩/
ポリオキシエチレン(2)ミリスチルホスフェートK塩
(モノミリスチル体/ジミリスチル体=75/25) 5
ヤシ油脂肪酸カリウム塩 5
ジプロピレングリコール 1.5
プロピレングリコール 5
ソルビトール 5
ポリオキシエチレンアルキルエーテル酢酸K塩 1.8
(アルキル基:C12/C14=75/25、EO:10)
トリイソステアリン酸ポリオキシエチレンソルビタン(EO:160) 2
カチオン化セルロース〔ポイズC-150L;花王(株)社製〕 0.3
アクリル酸メタクリル酸アルキル共重合体d) 0.5
ラウリルヒドロキシスルホベタイン 5
ジステアリン酸エチレングリコール 2
メチルパラベン 0.2
プロピルパラベン 0.1
BHT 0.2
香料 0.05精製水 バランス
100.00
d):カーボポールETD2020;BFGoodrich社製
実施例18の洗顔料は起泡性に優れ、泡質がクリーミー
で、洗浄時の使用感が良好で、皮膚に対する刺激が少な
かった。Example 18 (Facial cleanser) A facial cleanser was produced according to the following formulation. (Parts by weight) Polyoxyethylene (2) lauryl phosphate K salt / Polyoxyethylene (2) dilauryl phosphate K salt (monolauryl body / dilauryl body = 75/25) 15 Polyoxyethylene (2) myristyl phosphate K salt / Polyoxyethylene (2) myristyl phosphate K salt (monomyristyl body / dimyristyl body = 75/25) 5 Palm oil fatty acid potassium salt 5 Dipropylene glycol 1.5 Propylene glycol 5 Sorbitol 5 Polyoxyethylene alkyl ether acetic acid K salt 1. 8 (Alkyl group: C 12 / C 14 = 75/25, EO: 10) Polyoxyethylene sorbitan triisostearate (EO: 160) 2 Cationized cellulose [Poise C-150L; manufactured by Kao Corporation] 0. 3 Alkyl Methacrylate Copolymer d) 0.5 Lauri Lehydroxysulfobetaine 5 Ethylene glycol distearate 2 Methylparaben 0.2 Propylparaben 0.1 BHT 0.2 Perfume 0.05 Purified water balance 100.00 d): Carbopol ETD2020; BFGoodrich Example 18 face wash Excellent foamability, creamy foam quality, good feeling during washing, and little irritation to the skin.
【0032】[0032]
【発明の効果】本発明の洗浄剤組成物は皮膚等に対する
刺激が少なく、起泡性に優れ、泡質がクリーミーで、し
かも洗浄時の使用感が良好で、低温安定性に優れ、製造
時の配合が容易である。EFFECT OF THE INVENTION The detergent composition of the present invention is less irritating to the skin and the like, has excellent foaming properties, has a creamy foam quality, has a good feeling during washing, has excellent low-temperature stability, and is excellent in manufacturing. Is easy to mix.
───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 4C083 AC122 AC132 AC182 AC242 AC392 AC442 AC472 AC482 AC712 AC901 AC902 AD042 AD092 AD132 BB41 CC23 EE01 EE06 EE07 EE10 4H003 AB03 AB39 AB44 AB46 AD05 DA02 EB04 EB09 EB42 ED02 FA16 FA17 FA18 ─────────────────────────────────────────────────── ─── Continued front page F-term (reference) 4C083 AC122 AC132 AC182 AC242 AC392 AC442 AC472 AC482 AC712 AC901 AC902 AD042 AD092 AD132 BB41 CC23 EE01 EE06 EE07 EE10 4H003 AB03 AB39 AB44 AB46 AD05 DA02 EB04 EB09 EB42 ED02 FA16 FA17 FA18
Claims (5)
テルと(a2)一般式(2)で表されるリン酸ジエステ
ルとの混合物であって、その含有比率が重量比で
(a1)/(a2)=85/15〜50/50であるリン
酸エステル系界面活性剤: 【化1】 (式中、R1、R2及びR3はそれぞれ炭素数8〜18の
直鎖又は分岐鎖のアルキル基又はアルケニル基を示し、
X1、X2及びYはそれぞれ水素原子、アルカリ金属原
子、アルカリ土類金属原子、アルカノールアミン又はア
ンモニウムを示し、平均付加モル数k、m及びnはそれ
ぞれ0〜10の数を示す); (B)一般式(3) R4-COOM (3) (式中、R4は炭素数7〜17の飽和又は不飽和の脂肪
族炭化水素基を示し、Mは水素原子、アルカリ金属原
子、アルカノールアミン又はアンモニウムを示す)で表
される高級脂肪酸又はその塩; (C)一般式(4): 【化2】 (式中、R5は炭素数8〜18の飽和又は不飽和の炭化
水素基を示し、R6及びR 7はそれぞれメチル基を示し、
Zは水素原子又は水酸基を示す)で表されるスルホベタ
インを含有する洗浄剤組成物。1. The following components (A), (B) and (C): (A) (a1) Monophosphoric acid represented by the general formula (1)
Tell and (a2) Diester phosphate represented by the general formula (2)
It is a mixture with
(A1) / (A2) = 85/15 to 50/50 phosphorus
Acid ester surfactant: [Chemical 1] (In the formula, R1, R2And R3Each has 8 to 18 carbon atoms
Represents a linear or branched alkyl group or alkenyl group,
X1, X2And Y are hydrogen atom and alkali metal source, respectively.
Child, alkaline earth metal atom, alkanolamine or
The average addition moles k, m and n are
The numbers 0 to 10 are shown); (B) General formula (3) RFour-COOM (3) (In the formula, RFourIs a saturated or unsaturated fat having 7 to 17 carbon atoms
Shows a group hydrocarbon group, M is a hydrogen atom, an alkali metal source
Child, alkanolamine or ammonium)
Higher fatty acids or salts thereof; (C) General formula (4): [Chemical 2] (In the formula, RFiveIs saturated or unsaturated carbonization having 8 to 18 carbon atoms
Indicates a hydrogen group, R6And R 7Are methyl groups,
Z is a hydrogen atom or a hydroxyl group)
A cleaning composition containing in.
/(B)=95/5〜50/50である請求項1記載の
洗浄剤組成物。2. The components (A) and (B) in a weight ratio of (A).
The cleaning composition according to claim 1, wherein / (B) = 95/5 to 50/50.
(C)との比率が重量比で[(A)+(B)]/(C)
=40/2〜10/7である請求項1又は2記載の洗浄
剤組成物。3. The weight ratio of the sum of the components (A) and (B) to the component (C) is [(A) + (B)] / (C).
= 40/2 to 10/7, The cleaning composition according to claim 1 or 2.
重量%含有する請求項1〜3のいずれか1項記載の洗浄
剤組成物。4. The cleaning composition contains 1 to 20 components (B).
The cleaning composition according to any one of claims 1 to 3, wherein the cleaning composition is contained in a weight percentage.
し、40〜80℃で加熱攪拌する工程を有する請求項1
〜4のいずれか1項記載の洗浄剤組成物の製造法。5. The method according to claim 1, further comprising the step of mixing the components (A), (B) and (C) and heating and stirring at 40 to 80 ° C.
5. The method for producing the cleaning composition according to any one of 4 to 4.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002292353A JP3813563B2 (en) | 2002-03-12 | 2002-10-04 | Cleaning composition |
CNB031194559A CN100400632C (en) | 2002-03-12 | 2003-03-12 | Detergent composition |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002066686 | 2002-03-12 | ||
JP2002-66686 | 2002-03-12 | ||
JP2002292353A JP3813563B2 (en) | 2002-03-12 | 2002-10-04 | Cleaning composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2003336091A true JP2003336091A (en) | 2003-11-28 |
JP3813563B2 JP3813563B2 (en) | 2006-08-23 |
Family
ID=28043688
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2002292353A Expired - Fee Related JP3813563B2 (en) | 2002-03-12 | 2002-10-04 | Cleaning composition |
Country Status (2)
Country | Link |
---|---|
JP (1) | JP3813563B2 (en) |
CN (1) | CN100400632C (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004092315A1 (en) * | 2003-04-14 | 2004-10-28 | Kao Corporation | Cleaning agent composition |
JP2009114156A (en) * | 2007-11-09 | 2009-05-28 | Kao Corp | Liquid cleanser composition |
JP2009275010A (en) * | 2008-05-16 | 2009-11-26 | Kao Corp | Skin cleanser composition |
JP2009275009A (en) * | 2008-05-16 | 2009-11-26 | Kao Corp | Skin cleanser composition |
JP2009275012A (en) * | 2008-05-16 | 2009-11-26 | Kao Corp | Skin cleanser composition |
JP2015196713A (en) * | 2014-03-31 | 2015-11-09 | ミヨシ油脂株式会社 | transparent liquid detergent composition |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101415810B (en) * | 2006-04-07 | 2011-06-22 | 花王株式会社 | Cleanser composition |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5943517B2 (en) * | 1981-12-14 | 1984-10-22 | 花王株式会社 | liquid cleaning composition |
JPH0246639B2 (en) * | 1985-12-12 | 1990-10-16 | Kao Corp | SENJOZAISOSEIBUTSU |
JP3327889B2 (en) * | 1999-12-24 | 2002-09-24 | 花王株式会社 | Detergent composition |
-
2002
- 2002-10-04 JP JP2002292353A patent/JP3813563B2/en not_active Expired - Fee Related
-
2003
- 2003-03-12 CN CNB031194559A patent/CN100400632C/en not_active Expired - Lifetime
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004092315A1 (en) * | 2003-04-14 | 2004-10-28 | Kao Corporation | Cleaning agent composition |
JP2009114156A (en) * | 2007-11-09 | 2009-05-28 | Kao Corp | Liquid cleanser composition |
JP2009275010A (en) * | 2008-05-16 | 2009-11-26 | Kao Corp | Skin cleanser composition |
JP2009275009A (en) * | 2008-05-16 | 2009-11-26 | Kao Corp | Skin cleanser composition |
JP2009275012A (en) * | 2008-05-16 | 2009-11-26 | Kao Corp | Skin cleanser composition |
JP2015196713A (en) * | 2014-03-31 | 2015-11-09 | ミヨシ油脂株式会社 | transparent liquid detergent composition |
Also Published As
Publication number | Publication date |
---|---|
CN100400632C (en) | 2008-07-09 |
CN1443837A (en) | 2003-09-24 |
JP3813563B2 (en) | 2006-08-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP2009062546A (en) | Detergent composition | |
JP2831638B2 (en) | Detergent composition | |
JP3035033B2 (en) | Liquid detergent composition | |
JP2004002632A (en) | Detergent composition | |
JP2003336091A (en) | Detergent composition | |
JP4806527B2 (en) | Cleaning composition | |
JP2587755B2 (en) | Detergent composition | |
JP4666343B2 (en) | Mixture of acyl taurine salts and detergent composition containing the same | |
JP7234746B2 (en) | cream cleanser | |
JP2005113067A (en) | Detergent composition | |
JP2003055690A (en) | Detergent composition | |
JP2839897B2 (en) | Skin cleansing composition | |
JP3018129B2 (en) | Liquid detergent composition | |
JPH1143698A (en) | Detergent composition | |
JP3024823B2 (en) | Detergent composition | |
JP3977718B2 (en) | Cleaning composition | |
JP2005113078A (en) | Detergent composition | |
JPH07278587A (en) | Detergent composition | |
JPH07138593A (en) | Detergent composition | |
JPH0641584A (en) | Liquid detergent composition | |
JP3024821B2 (en) | Detergent composition | |
JP3032043B2 (en) | Detergent composition | |
WO2007122802A1 (en) | Detergent composition | |
JP2831812B2 (en) | Detergent composition | |
JP4564120B2 (en) | Liquid detergent composition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20041021 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20051219 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20060110 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20060313 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20060530 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20060531 |
|
R151 | Written notification of patent or utility model registration |
Ref document number: 3813563 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100609 Year of fee payment: 4 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100609 Year of fee payment: 4 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110609 Year of fee payment: 5 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110609 Year of fee payment: 5 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120609 Year of fee payment: 6 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120609 Year of fee payment: 6 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130609 Year of fee payment: 7 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |